CN105907106A - Candy package wax and preparation method thereof - Google Patents
Candy package wax and preparation method thereof Download PDFInfo
- Publication number
- CN105907106A CN105907106A CN201610016523.4A CN201610016523A CN105907106A CN 105907106 A CN105907106 A CN 105907106A CN 201610016523 A CN201610016523 A CN 201610016523A CN 105907106 A CN105907106 A CN 105907106A
- Authority
- CN
- China
- Prior art keywords
- wax
- ethylene
- candy wrapping
- candy
- copolymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 235000009508 confectionery Nutrition 0.000 title claims abstract description 55
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 35
- 239000004014 plasticizer Substances 0.000 claims abstract description 28
- 239000002994 raw material Substances 0.000 claims abstract description 22
- 239000003381 stabilizer Substances 0.000 claims abstract description 21
- 238000003756 stirring Methods 0.000 claims abstract description 13
- 238000002156 mixing Methods 0.000 claims abstract description 9
- 238000001816 cooling Methods 0.000 claims abstract description 6
- 239000001993 wax Substances 0.000 claims description 76
- -1 phthalic acid ester Chemical class 0.000 claims description 33
- 239000010408 film Substances 0.000 claims description 26
- 239000012745 toughening agent Substances 0.000 claims description 26
- 229920001577 copolymer Polymers 0.000 claims description 18
- 229920005989 resin Polymers 0.000 claims description 9
- 239000011347 resin Substances 0.000 claims description 9
- 239000005038 ethylene vinyl acetate Substances 0.000 claims description 8
- 239000012188 paraffin wax Substances 0.000 claims description 8
- 229920000642 polymer Polymers 0.000 claims description 7
- 229920006242 ethylene acrylic acid copolymer Polymers 0.000 claims description 6
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims description 6
- 229920002367 Polyisobutene Polymers 0.000 claims description 5
- 239000004200 microcrystalline wax Substances 0.000 claims description 5
- FEXBEKLLSUWSIM-UHFFFAOYSA-N 2-Butyl-4-methylphenol Chemical class CCCCC1=CC(C)=CC=C1O FEXBEKLLSUWSIM-UHFFFAOYSA-N 0.000 claims description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 4
- 239000004698 Polyethylene Substances 0.000 claims description 4
- 229920005549 butyl rubber Polymers 0.000 claims description 4
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims description 4
- 239000002480 mineral oil Substances 0.000 claims description 4
- 235000010446 mineral oil Nutrition 0.000 claims description 4
- GLDOVTGHNKAZLK-UHFFFAOYSA-N n-octadecyl alcohol Natural products CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 claims description 4
- 229920001083 polybutene Polymers 0.000 claims description 4
- 229920000573 polyethylene Polymers 0.000 claims description 4
- 150000003568 thioethers Chemical class 0.000 claims description 4
- 239000005062 Polybutadiene Substances 0.000 claims description 3
- 229920002857 polybutadiene Polymers 0.000 claims description 3
- GTACSIONMHMRPD-UHFFFAOYSA-N 2-[4-[2-(benzenesulfonamido)ethylsulfanyl]-2,6-difluorophenoxy]acetamide Chemical compound C1=C(F)C(OCC(=O)N)=C(F)C=C1SCCNS(=O)(=O)C1=CC=CC=C1 GTACSIONMHMRPD-UHFFFAOYSA-N 0.000 claims description 2
- CAPNUXMLPONECZ-UHFFFAOYSA-N 3-(3,5-ditert-butyl-2-hydroxyphenyl)propanoic acid Chemical compound CC(C)(C)C1=CC(CCC(O)=O)=C(O)C(C(C)(C)C)=C1 CAPNUXMLPONECZ-UHFFFAOYSA-N 0.000 claims description 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 2
- 101710130081 Aspergillopepsin-1 Proteins 0.000 claims description 2
- 102100031007 Cytosolic non-specific dipeptidase Human genes 0.000 claims description 2
- AEMRFAOFKBGASW-UHFFFAOYSA-M Glycolate Chemical compound OCC([O-])=O AEMRFAOFKBGASW-UHFFFAOYSA-M 0.000 claims description 2
- 239000013032 Hydrocarbon resin Substances 0.000 claims description 2
- 239000004264 Petrolatum Substances 0.000 claims description 2
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 2
- 125000001931 aliphatic group Chemical group 0.000 claims description 2
- 125000003118 aryl group Chemical group 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- JXTHNDFMNIQAHM-UHFFFAOYSA-N dichloroacetic acid Chemical compound OC(=O)C(Cl)Cl JXTHNDFMNIQAHM-UHFFFAOYSA-N 0.000 claims description 2
- 229960005215 dichloroacetic acid Drugs 0.000 claims description 2
- 150000001993 dienes Chemical class 0.000 claims description 2
- 125000005442 diisocyanate group Chemical group 0.000 claims description 2
- 239000003822 epoxy resin Substances 0.000 claims description 2
- ABDHTRWEJSVHRU-UHFFFAOYSA-N ethene;2-methylpropyl prop-2-enoate Chemical compound C=C.CC(C)COC(=O)C=C ABDHTRWEJSVHRU-UHFFFAOYSA-N 0.000 claims description 2
- 235000010985 glycerol esters of wood rosin Nutrition 0.000 claims description 2
- 239000004519 grease Substances 0.000 claims description 2
- 229920006270 hydrocarbon resin Polymers 0.000 claims description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N o-dicarboxybenzene Natural products OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims description 2
- 229940066842 petrolatum Drugs 0.000 claims description 2
- 235000019271 petrolatum Nutrition 0.000 claims description 2
- 229920000647 polyepoxide Polymers 0.000 claims description 2
- 229920000728 polyester Polymers 0.000 claims description 2
- 229920001225 polyester resin Polymers 0.000 claims description 2
- 239000004645 polyester resin Substances 0.000 claims description 2
- 229920001228 polyisocyanate Polymers 0.000 claims description 2
- 239000005056 polyisocyanate Substances 0.000 claims description 2
- 229920000098 polyolefin Polymers 0.000 claims description 2
- 229920001451 polypropylene glycol Polymers 0.000 claims description 2
- 229920001296 polysiloxane Polymers 0.000 claims description 2
- 229920000346 polystyrene-polyisoprene block-polystyrene Polymers 0.000 claims description 2
- 229920005749 polyurethane resin Polymers 0.000 claims description 2
- 235000019260 propionic acid Nutrition 0.000 claims description 2
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 claims description 2
- 229920006395 saturated elastomer Polymers 0.000 claims description 2
- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 claims description 2
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 2
- QLZJUIZVJLSNDD-UHFFFAOYSA-N 2-(2-methylidenebutanoyloxy)ethyl 2-methylidenebutanoate Chemical compound CCC(=C)C(=O)OCCOC(=O)C(=C)CC QLZJUIZVJLSNDD-UHFFFAOYSA-N 0.000 claims 1
- 229920006026 co-polymeric resin Polymers 0.000 claims 1
- 229920006244 ethylene-ethyl acrylate Polymers 0.000 claims 1
- 239000005042 ethylene-ethyl acrylate Substances 0.000 claims 1
- 238000007493 shaping process Methods 0.000 claims 1
- 239000011248 coating agent Substances 0.000 abstract description 7
- 238000000576 coating method Methods 0.000 abstract description 7
- 239000000203 mixture Substances 0.000 abstract description 7
- 238000000034 method Methods 0.000 abstract description 6
- 238000004806 packaging method and process Methods 0.000 abstract description 5
- 238000002844 melting Methods 0.000 abstract description 4
- 230000008018 melting Effects 0.000 abstract description 4
- 238000011031 large-scale manufacturing process Methods 0.000 abstract description 3
- 238000010438 heat treatment Methods 0.000 abstract 2
- 238000000465 moulding Methods 0.000 abstract 1
- 239000004743 Polypropylene Substances 0.000 description 4
- 229920001155 polypropylene Polymers 0.000 description 4
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 3
- 239000004814 polyurethane Substances 0.000 description 3
- FNJSWIPFHMKRAT-UHFFFAOYSA-N Monomethyl phthalate Chemical group COC(=O)C1=CC=CC=C1C(O)=O FNJSWIPFHMKRAT-UHFFFAOYSA-N 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- FLKPEMZONWLCSK-UHFFFAOYSA-N diethyl phthalate Chemical compound CCOC(=O)C1=CC=CC=C1C(=O)OCC FLKPEMZONWLCSK-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000003292 glue Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000005022 packaging material Substances 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- RLRINNKRRPQIGW-UHFFFAOYSA-N 1-ethenyl-2-[4-(2-ethenylphenyl)butyl]benzene Chemical compound C=CC1=CC=CC=C1CCCCC1=CC=CC=C1C=C RLRINNKRRPQIGW-UHFFFAOYSA-N 0.000 description 1
- 101000801619 Homo sapiens Long-chain-fatty-acid-CoA ligase ACSBG1 Proteins 0.000 description 1
- 101000823778 Homo sapiens Y-box-binding protein 2 Proteins 0.000 description 1
- 102100033564 Long-chain-fatty-acid-CoA ligase ACSBG1 Human genes 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 230000000843 anti-fungal effect Effects 0.000 description 1
- 229940121375 antifungal agent Drugs 0.000 description 1
- 235000010634 bubble gum Nutrition 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229940112822 chewing gum Drugs 0.000 description 1
- 235000015218 chewing gum Nutrition 0.000 description 1
- 239000004205 dimethyl polysiloxane Substances 0.000 description 1
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 1
- 125000004494 ethyl ester group Chemical group 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
- C08L91/06—Waxes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D65/00—Wrappers or flexible covers; Packaging materials of special type or form
- B65D65/38—Packaging materials of special type or form
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
- C08L23/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
- C08L23/22—Copolymers of isobutene; Butyl rubber; Homopolymers or copolymers of other iso-olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Confectionery (AREA)
- Laminated Bodies (AREA)
Abstract
The invention discloses candy package wax. The candy package wax is prepared from 10-40% by mass of a tackifier, 1-10% by mass of a plasticizer, 0.1-5% by mass of a flexibilizer, 0.2-10% by mass of a film forming agent, 1-5% by mass of a stabilizing agent and the balance wax. A preparation method of the candy package wax comprises heating to melt wax, adding the tackifier, the plasticizer, the flexibilizer, the film forming agent and the stabilizing agent into the wax, heating the mixture to a temperature of 180 DEG C or more, carrying out stirring at a rotation rate of 10-30r/min until uniform mixing after complete melting of the raw materials and carrying out cooling molding to obtain the candy package wax. The candy package wax has good adhesion, temperature resistance and coating performances. The candy package wax can be simply operated, can be directly put into a wax melting cylinder of a candy packaging machine, is free of a blending process, has stable quality, can form a clean and flat candy package and can form a thin coating with good adhesion. The preparation method has simple processes and is convenient for operation and large-scale production.
Description
Technical field
The present invention relates to packaging material field, particularly relate to a kind of candy wrapping wax and preparation method thereof.
Background technology
For a long time, candy wrapping mostly with paper as packaging material, the especially product such as chewing gum and bubble gum,
At wrapping paper sealing part, the glue typically allocated with PUR and paraffin adheres to, on the one hand, PUR has many
Kind, manufacturer is not easy to select.Two, the technology of the master worker of allotment packaging glue is the most unbalanced, so,
The product quality fluctuation of manufacturer is bigger.The most viscous, it is not easy to strip off, or do not stick, easily come unglued.
Some is unreasonable with paraffin proportioning due to PUR, coats uneven, affects outward appearance.
Summary of the invention
It is an object of the invention to propose a kind of candy wrapping wax, described candy wrapping wax has well
Adhesive force and heat resistance, coating property is good.Simple to operate, only candy wrapping wax need to be directly placed into
The wax melting tank of candy wrapper, it is not necessary to additionally allocate, steady quality, the packaging external appearance of candy is clean,
Smooth, coating is thin but bonding is good.
The second object of the present invention is to provide the preparation method of a kind of candy wrapping wax, and the method technique is simple,
Easy to operate, it is simple to large-scale production.
The technical scheme is that and be achieved in that: a kind of candy wrapping wax, described candy wrapping wax is main
It is prepared from by the raw material of following mass fraction: the plasticizer of tackifier, 1%～10%, 0.1%～5% of 10%～40%
The stabilizer of the film forming agent of toughener, 0.2%～10%, 1%～5%, surplus be wax.
Further, described candy wrapping wax is mainly prepared from by the raw material of following mass fraction: 20%～30%
The stabilizer of the film forming agent of the toughener of the plasticizer of tackifier, 3%～7%, 0.1%～5%, 3%～7%, 2%～4%,
Surplus is wax.
Further, described candy wrapping wax is mainly prepared from by the raw material of following mass fraction: the thickening of 25%
Agent, the plasticizer of 5%, the toughener of 3%, the film forming agent of 5%, the stabilizer of 3%, surplus are wax.
Further, the one during described wax is paraffin, microwax, ceresine, Fischer Tropsch waxes and polyolefin-wax
Or it is multiple.
Further, described tackifier are hydrocarbon resin, polybutene, polyisobutene, group aliphatic resin, ring grease
Diene resin, Petropols, ester gum, rosin resin, aromatic resin, aliphatic-aromatic are common
One or more in poly resin and random polyolefin.
Further, described plasticizer is petrolatum, polybutadiene, phthalic acid ester, glycolate, ore deposit
One or more in thing oil and polybutene.
Further, described toughener is butyl rubber, linear saturated polyester, PEPA and two isocyanic acids
Ester polymer, ethylene-propylene copolymer, ethylene-vinyl acetate copolymer, propene-1-butene copolymer, ethene
-vinyl acetate-propylene copolymer, ene-propylene-butene mixed polymer, ethylene-acrylic acid copolymer, second
Alkene-octene copolymer, ethylene-stryene-propylene copolymer, ethylene-stryene-butylene copolymer and butylene-
One or more in styrol copolymer.
Further, described film forming agent is polyethylene, polypropylene, ethylene-vinyl acetate copolymer, ethene-the third
Olefin(e) acid ethyl ester EVA, ethylene-acrylic acid copolymer body, ethylene isobutyl acrylate EVA, polytetramethylene glycol
Modified polyester resin, epoxy resin or polyurethane resin, ethylene-propylene-1-butene polymers, styrene-
Butadiene-styrene block copolymer, SIS, PPG,
In polyisocyanates, styrene-ethylene butylene-styrene and styrene ethylene-propylene-styrene
One or more.
Further, described stabilizer be BHT, 2, tri-grades of butyl-4-methylphenols of 6-,
Double (tri-grades of butyl-4-hydroxy phenyls of 3,5-) thioether, methyl polysiloxane, four [β-(tri-grades of butyl of 3,5-
-4-hydroxy phenyl) propionic acid] pentaerythritol ester, double Lauryl Alcohol ester, double ten four carbon alcohols esters, double octadecanol ester
With one or more in β-(3,5-di-tert-butyl-hydroxy phenyl) propionic acid positive octadecanol ester.
The preparation method of a kind of candy wrapping wax, comprises the steps:
First wax is added heat fusing, be then added thereto to tackifier, plasticizer, toughener, film forming agent and steady
Determining agent, liter high-temperature, to more than 180 DEG C, stirs with the rotating speeds of 10～30 revs/min, treats that raw material is completely melt
After, stirring is to mixing, and cooling is molded, and prepares described candy wrapping wax.
The invention have the benefit that candy wrapping wax of the present invention, by tackifier, plasticizer,
Toughener, rationally the selecting and compatibility of film forming agent so that the tack of described candy wrapping wax, coating and
Elastic (antifungal gene ability) is more satisfactory, and so, Wax-coated layer is thin and uniform, smooth, and cohesive force is fitted
In, also will not come unglued when environment temperature is at about 70 DEG C.Described candy wrapping wax has good attachment
Power and heat resistance, coating property is good.Simple to operate, only candy wrapping wax need to be directly placed into candy bag
The wax melting tank of installation, it is not necessary to additionally allocating, steady quality, the packaging external appearance of candy is clean, smooth,
Coating is thin but bonding is good.The method technique is simple, easy to operate, it is simple to large-scale production.
Candy wrapping wax of the present invention is by rationally selecting and compatibility raw material so that it is have good attachment
There is while power good stripping performance, wrapping paper will not be torn, it addition, according to subscriber equipment situation
(having the equipment of Germany's production, the equipment of Korea S's production and home equipment) and the speed of equipment regulation, only need
Just it is adapted to high or low for wax cylinder temperature tune, there is the biggest using value.
Detailed description of the invention
For being more fully understood that the present invention, below by following example, the present invention made the most concrete elaboration,
But it is not to be construed as limitation of the invention, those skilled in the art is made according to foregoing invention content
Some nonessential improvement and adjustment, be also considered as being within the scope of the present invention.
Embodiment 1
A kind of candy wrapping wax, is prepared from by the raw material of following mass fraction:
Tackifier 10%, plasticizer 1%, toughener 0.1%, film forming agent 0.2%, stabilizer 1%, surplus are wax.
Described tackifier are random polystyrene；
Described plasticizer is polybutadiene；
Described toughener is butyl rubber；
Described film forming agent is polyethylene；
Described stabilizer is DBPC 2,6 ditertiary butyl p cresol；
Described wax is paraffin；
Preparation method is as follows:
First wax is added heat fusing, be then added thereto to tackifier, plasticizer, toughener, film forming agent and steady
Determining agent, liter high-temperature, to 180 DEG C, stirs with the rotating speeds of 10 revs/min, after raw material is completely melt, with
The rotating speed mix and blend of 30 revs/min prepares described candy wrapping wax to mixing in 4 hours.
Embodiment 2
A kind of candy wrapping wax, is prepared from by the raw material of following mass fraction:
Tackifier 40%, plasticizer 10%, toughener 5%, film forming agent 10%, stabilizer 5%, surplus are wax.
Described tackifier are polyisobutene；
Described plasticizer is Methyl Benzene-o-dicarboxylate；
Described toughener is ethylene-propylene copolymer；
Described film forming agent is polypropylene；
Described stabilizer is tri-grades of butyl-4-methylphenols of 2,6-；
Described wax is microwax；
Preparation method is as follows:
First wax is added heat fusing, be then added thereto to tackifier, plasticizer, toughener, film forming agent and steady
Determining agent, liter high-temperature, to 250 DEG C, stirs with the rotating speeds of 30 revs/min, after raw material is completely melt, with
The rotating speed mix and blend of 60 revs/min prepares described candy wrapping wax to mixing in 2 hours.
Embodiment 3
A kind of candy wrapping wax, is prepared from by the raw material of following mass fraction:
Tackifier 20%, plasticizer 3%, toughener 2%, film forming agent 3%, stabilizer 2%, surplus are wax.
Described tackifier are random polypropylene；
Described plasticizer is mineral oil；
Described toughener is propene-1-butene copolymer；
Described film forming agent is ethylene-acrylic acid copolymer body；
Described stabilizer is double (tri-grades of butyl-4-hydroxy phenyls of 3,5-) thioethers；
Described wax is Fischer Tropsch waxes；
Preparation method is as follows:
First wax is added heat fusing, be then added thereto to tackifier, plasticizer, toughener, film forming agent and steady
Determining agent, liter high-temperature, to more than 180 DEG C, stirs with the rotating speeds of 10～30 revs/min, treats that raw material is completely melt
After, stirring is to mixing, and cooling is molded, and prepares described candy wrapping wax.
Embodiment 4
A kind of candy wrapping wax, is prepared from by the raw material of following mass fraction:
Tackifier 30%, plasticizer 7%, toughener 4%, film forming agent 7%, stabilizer 4%, surplus are wax.
Described tackifier are random polypropylene 10%, polyisobutene 5% and random polystyrene 15%；
Described plasticizer is mineral oil 1%, Methyl Benzene-o-dicarboxylate 2% and ethyl phthalate 4%；
Described toughener is that propene-1-butene copolymer 1%, ethylene-propylene copolymer 1% and butylene-styrene are total to
Polymers 2%；
Described film forming agent is ethylene-acrylic acid copolymer body 1%, diisocyanate 2%, triisocyanate 4%；
Described stabilizer is that double (tri-grades of butyl-4-hydroxy phenyls of 3,5-) thioether 1%, 2,6-di-t-butyl are to first
1% and 2,6-tri-grade of butyl-4-methylphenol 2% of phenol；
Described wax such as is at the paraffin of quality, Tissuemat E and the polypropylene wax mixture；
Preparation method is as follows:
First wax is added heat fusing, be then added thereto to tackifier, plasticizer, toughener, film forming agent and steady
Determining agent, liter high-temperature, to more than 180 DEG C, stirs with the rotating speeds of 10～30 revs/min, treats that raw material is completely melt
After, stirring is to mixing, and cooling is molded, and prepares described candy wrapping wax.
Embodiment 5
A kind of candy wrapping wax, is prepared from by the raw material of following mass fraction:
Tackifier 25%, plasticizer 5%, toughener 3%, film forming agent 5%, stabilizer 3%, surplus are wax.
Described tackifier are polyisobutene；
Described plasticizer is mineral oil；
Described toughener is butyl rubber；
Described film forming agent is polyethylene；
Described stabilizer is dimethyl polysiloxane；
Described wax is paraffin, microwax mixture, and wherein the mass ratio of paraffin and microwax is 9:1；
Preparation method is as follows:
First wax is added heat fusing, be then added thereto to tackifier, plasticizer, toughener, film forming agent and steady
Determining agent, liter high-temperature, to more than 180 DEG C, stirs with the rotating speeds of 10～30 revs/min, treats that raw material is completely melt
After, stirring is to mixing, and cooling is molded, and prepares described candy wrapping wax.
The requirement of raw materials all for the present invention, all must use food-grade or packaging for foodstuff level raw material.
It addition, the physicochemical properties of embodiment of the present invention 1-5 gained candy wrapping wax are as follows:
The foregoing is only presently preferred embodiments of the present invention, not in order to limit the present invention, all at this
Within bright spirit and principle, any modification, equivalent substitution and improvement etc. made, should be included in this
Within bright protection domain.
Claims (9)
1. a candy wrapping wax, it is characterized in that, described candy wrapping wax is mainly prepared from by the raw material of following mass fraction: the stabilizer of the film forming agent of the toughener of the plasticizer of tackifier, 1%～10%, 0.1%～5%, 0.2%～10%, 1%～5%, the surplus of 10%～40% are wax.
2. candy wrapping wax as claimed in claim 1, it is characterized in that, described candy wrapping wax is mainly prepared from by the raw material of following mass fraction: the stabilizer of the film forming agent of the toughener of the plasticizer of tackifier, 3%～7%, 0.1%～5%, 3%～7%, 2%～4%, the surplus of 20%～30% are wax.
3. candy wrapping wax as claimed in claim 1, it is characterized in that, described candy wrapping wax is mainly prepared from by the raw material of following mass fraction: the tackifier of 25%, the plasticizer of 5%, the toughener of 3%, the film forming agent of 5%, the stabilizer of 3%, surplus are wax.
4. candy wrapping wax as claimed in claim 1, it is characterised in that: described wax is one or more in paraffin, microwax, ceresine, Fischer Tropsch waxes and polyolefin-wax.
5. candy wrapping wax as claimed in claim 1, it is characterised in that: described tackifier are one or more in hydrocarbon resin, polybutene, polyisobutene, Petropols, ester gum, rosin resin, group aliphatic resin, ring grease diene resin, aromatic resin, aliphatic-aromatic copolymer resins and random polyolefin；Described plasticizer is one or more in petrolatum, polybutadiene, phthalic acid ester, glycolate, mineral oil and polybutene.
A kind of candy wrapping wax the most according to claim 1, it is characterised in that: described toughener is butyl rubber, linear saturated polyester, PEPA and one or more in diisocyanate polymer, ethylene-propylene copolymer, ethylene-vinyl acetate copolymer, propene-1-butene copolymer, ethene-vinyl acetate-propylene copolymer, ene-propylene-butene mixed polymer, ethylene-acrylic acid copolymer, ethylene-octene copolymer, ethylene-stryene-propylene copolymer, ethylene-stryene-butylene copolymer and butylene-styrene copolymers.
A kind of candy wrapping wax the most according to claim 1, it is characterized in that: described film forming agent is polyethylene, polypropylene, ethylene-vinyl acetate copolymer, ethylene-ethylacrylate EVA, ethylene-acrylic acid copolymer body, ethylene isobutyl acrylate EVA, the polyester resin that polytetramethylene glycol is modified, epoxy resin or polyurethane resin, ethylene-propylene-1-butene polymers, SBS, SIS, PPG, polyisocyanates, one or more in styrene-ethylene butylene-styrene and styrene ethylene-propylene-styrene.
A kind of candy wrapping wax the most according to claim 1, it is characterized in that: described stabilizer is 2,6-BHT, 2, tri-grades of butyl-4-methylphenols of 6-, double (3, tri-grades of butyl-4-hydroxy phenyls of 5-) thioether, methyl polysiloxane, four [β-(3, tri-grades of butyl-4-hydroxy phenyls of 5-) propionic acid] pentaerythritol ester, double Lauryl Alcohol ester, double ten four carbon alcohols esters, one or more in double octadecanol ester and β-(3,5-di-tert-butyl-hydroxy phenyl) propionic acid positive octadecanol ester.
9. the preparation method of the candy wrapping wax as described in claim 1-8 is arbitrary, it is characterised in that comprise the steps:
First wax is added heat fusing, be then added thereto to tackifier, plasticizer, toughener, film forming agent and stabilizer, rise high-temperature to more than 180 DEG C, stirring with the rotating speeds of 10～30 revs/min, after raw material is completely melt, stirring is to mixing, cooling shaping, prepares described candy wrapping wax.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610016523.4A CN105907106A (en) | 2016-01-08 | 2016-01-08 | Candy package wax and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610016523.4A CN105907106A (en) | 2016-01-08 | 2016-01-08 | Candy package wax and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105907106A true CN105907106A (en) | 2016-08-31 |
Family
ID=56744306
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610016523.4A Pending CN105907106A (en) | 2016-01-08 | 2016-01-08 | Candy package wax and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105907106A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109628018A (en) * | 2018-11-29 | 2019-04-16 | 山东康威通信技术股份有限公司 | A method of oxidation PE wax is applied to circuit board sealing protection |
| CN110066631A (en) * | 2019-05-27 | 2019-07-30 | 广州市德馨蜡制品有限公司 | Pack wax and preparation method thereof |
| CN110437798A (en) * | 2019-08-07 | 2019-11-12 | 广州市德馨蜡制品有限公司 | It is packed for bonding wax and its preparation method and application |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101045854A (en) * | 2007-04-24 | 2007-10-03 | 上海泰尔精蜡有限公司 | Antiskid wax for board and manufacturing method thereof |
| CN101678925A (en) * | 2007-05-10 | 2010-03-24 | 国际壳牌研究有限公司 | Paraffin wax composition |
| CN102030995A (en) * | 2010-09-21 | 2011-04-27 | 北京同仁堂股份有限公司 | Packed wax composition as Chinese herbal honeyed pill |
| CN105017784A (en) * | 2015-08-20 | 2015-11-04 | 广州市德馨蜡制品有限公司 | Epilating wax for living stock and preparation method of epilating wax |
-
2016
- 2016-01-08 CN CN201610016523.4A patent/CN105907106A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101045854A (en) * | 2007-04-24 | 2007-10-03 | 上海泰尔精蜡有限公司 | Antiskid wax for board and manufacturing method thereof |
| CN101678925A (en) * | 2007-05-10 | 2010-03-24 | 国际壳牌研究有限公司 | Paraffin wax composition |
| CN102030995A (en) * | 2010-09-21 | 2011-04-27 | 北京同仁堂股份有限公司 | Packed wax composition as Chinese herbal honeyed pill |
| CN105017784A (en) * | 2015-08-20 | 2015-11-04 | 广州市德馨蜡制品有限公司 | Epilating wax for living stock and preparation method of epilating wax |
Non-Patent Citations (2)
| Title |
|---|
| 廖晖等编著: "《环保型胶粘剂配方及生产工艺》", 31 March 2007, 中南大学出版社 * |
| 齐贵亮主编: "《塑料压延成型实用技术》", 31 May 2013, 机械工业出版社 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109628018A (en) * | 2018-11-29 | 2019-04-16 | 山东康威通信技术股份有限公司 | A method of oxidation PE wax is applied to circuit board sealing protection |
| CN110066631A (en) * | 2019-05-27 | 2019-07-30 | 广州市德馨蜡制品有限公司 | Pack wax and preparation method thereof |
| CN110437798A (en) * | 2019-08-07 | 2019-11-12 | 广州市德馨蜡制品有限公司 | It is packed for bonding wax and its preparation method and application |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US8222336B2 (en) | Hotmelt adhesive with improved adhesion | |
| US6172156B1 (en) | Cohesively failing hot melt pressure sensitive adhesive | |
| CA3096804C (en) | Hot-melt formulations utilizing depolymerized polymeric material | |
| AU2019201887B2 (en) | Maleic anhydride grafted lldpe having high melt index | |
| US10385242B2 (en) | Adhesive compositions containing modified ethylene-based polymers | |
| JP2000507283A (en) | Olefin polymer-containing adhesive | |
| CN111019559A (en) | EVA hot melt adhesive for rapid box sealing and preparation method thereof | |
| KR20140012666A (en) | Coated psa granules | |
| CN113924210B (en) | Hot melt adhesive composition | |
| CN105907106A (en) | Candy package wax and preparation method thereof | |
| US3577372A (en) | Hot melt adhesive compositions | |
| JPH04236288A (en) | hot melt adhesive composition | |
| JP4382161B2 (en) | Hot melt adhesive | |
| CN106085021B (en) | Alloy-type coating material and preparation method thereof | |
| EP3234057A1 (en) | Hot melt adhesive composition for bonding packs of plastic containers | |
| CN110066631B (en) | Packaging wax and preparation method thereof | |
| JPH10102019A (en) | Hot melt adhesive composition and method for bonding polyolefin material | |
| WO2001046019A1 (en) | Method of packaging a thermoplastic composition with a film having a low complex viscosity and corresponding packaged article | |
| EP3374430A1 (en) | Composition for the preparation of an adhesive product | |
| WO2016196262A1 (en) | Glue compositions and methods | |
| CN114874530A (en) | Film material for packaging plastic adhesive, preparation process and use method thereof | |
| JP2012180490A (en) | Hot melt type adhesive composition and layered product prepared by using the same | |
| JP2022055960A (en) | Hot-melt composition | |
| JPH07278522A (en) | Hotmelt adhesive composition not causing tackiness and solidification of pellet or the like | |
| JPH101655A (en) | Hot melt adhesive and method for bonding polyolefin material |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB02 | Change of applicant information | ||
| CB02 | Change of applicant information |
Address after: 510000 Guangdong Province, Guangzhou city Zengcheng District Xian Cun Zhen Ji Gang Cun Sha Jiao Dang (soil) plant (No. A-3) Applicant after: GUANGZHOU DEXIN WAX PRODUCTS CO., LTD. Address before: Wo Zhen Bai Tang Cun Baiyun District of Guangzhou City, Guangdong province 510000 Songyuan Street No. 6 Applicant before: GUANGZHOU DEXIN WAX PRODUCTS CO., LTD. |
|
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160831 |