CN105803814A - Graphene-based high-strength conductive cloth and preparation method thereof - Google Patents
Graphene-based high-strength conductive cloth and preparation method thereof Download PDFInfo
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- CN105803814A CN105803814A CN201610248450.1A CN201610248450A CN105803814A CN 105803814 A CN105803814 A CN 105803814A CN 201610248450 A CN201610248450 A CN 201610248450A CN 105803814 A CN105803814 A CN 105803814A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06N3/042—Acrylic polymers
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0015—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
- D06N3/0034—Polyamide fibres
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0063—Inorganic compounding ingredients, e.g. metals, carbon fibres, Na2CO3, metal layers; Post-treatment with inorganic compounds
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2203/00—Macromolecular materials of the coating layers
- D06N2203/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06N2203/045—Vinyl (co)polymers
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2205/00—Condition, form or state of the materials
- D06N2205/02—Dispersion
- D06N2205/023—Emulsion, aqueous dispersion, latex
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2205/00—Condition, form or state of the materials
- D06N2205/10—Particulate form, e.g. powder, granule
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/04—Properties of the materials having electrical or magnetic properties
- D06N2209/041—Conductive
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Conductive Materials (AREA)
- Laminated Bodies (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The invention relates to the technical field of high-strength shield cloth materials, in particular to a graphene-based high-strength conductive cloth.The graphene-based high-strength conductive cloth comprises a base material and conductive glue layers.The two faces of the base material are covered with conductive glue layers.The conductive glue layers are prepared from, by mass, 0.5-3% of graphene powder, 1-5% of carbon nanotubes, 5-10% of conductive carbon black, 20-25% of a binding agent and 57-67.5% of water.The microchip diameter of the graphene powder is not larger than 10 micrometers.The base material is nylon fabric, the thickness is 0.10-1.00 mm, and the unit mass is 60-700 g/m<2>.The pulling strength of the high-strength conductive cloth is larger than 140 N/cm.The graphene powder, the carbon nanotubes and the carbon black are adopted as conductive media for preparing the conductive glue, coating is carried out, and the graphene-based high-strength conductive cloth is obtained, wherein the volume resistivity is smaller than1*10<3> ohm .cm, the surface resistance is smaller than 60 ohm, and pulling strength is larger than 140 N/cm.
Description
Technical field
The present invention relates to high-intensity shielding cloth material technical field, a kind of graphene-based high-strength conductive cloth and
Preparation method.
Background technology
For special equipment such as base camp tents, it is desirable to its cloth material possesses high mechanical properties, good reflection and absorbs electromagnetism
Ripple performance, to reach shielding and secrecy effect.
In the national standard of power cable, for 500 mm2, 10 KV and above power cable with cross-linked polyethylene insulation,
Require first wrapped floor height intensity conductive strips (cloth) material outside conductor, extrude interior external screen and insulation, this layer of conductive strips the most again
On the one hand (cloth) material is possible to prevent conductor strand stress to screen and the damage of insulating barrier in extrusion, another aspect and extrusion inner shield
Layer together, improves screen layer homogenizing electric field effect.
For requiring control cable and the signal cable that anti-high-frequency electromagnetic disturbs, it is also desirable in proof copper-wire braided screen layer around
Bag high intensity semiconductive cloth (carrying).Conductive fabric (carrying) material of prior art, because its conducting medium is mainly white carbon black, electric conductivity
Not ideal enough, its specific insulation is at 1 × 105 more than Ω cm, and sheet resistance is at 150 below Ω, thus can not meet very well
The needs of association area.
Summary of the invention
In order to solve the technical problem that: the conductivity of conductive fabric is the highest, and mechanical strength is weak, it is difficult to adapting to association area needs
Want, the invention provides a kind of graphene-based high-strength conductive cloth and preparation method thereof.
The technical solution adopted for the present invention to solve the technical problems is: a kind of graphene-based high-strength conductive cloth, high-strength
Degree conductive fabric includes base material and conductive adhesive layer, the coated on both sides conductive adhesive layer of base material, and conductive adhesive layer is pressed quality hundred by following component
Proportion by subtraction forms:
Graphene powder 0.5-3%；
Carbon nanotube 1-5%；
Conductive black 5-10%；
Adhesive 20-25%；
Water 57-67.5%；
Described adhesive is polybutylacrylate latex, ethyl acrylate emulsion, acrylate and methacrylic acid copolymer liquid, poly-vinegar
Acid vac emulsion, vinyl acetate-ethylene copolymerization emulsions or polyvinyl alcohol emulsions.
According to another embodiment of the invention, farther including, the microplate diameter of described Graphene powder is not more than 10 μ
m；Described base material is nylon fabrics, and thickness is 0.10-1.00 mm, and unit mass is 60-700 g/m2。
According to another embodiment of the invention, farther including, the pull-off force of described high-strength conductive cloth is more than 140
N/㎝。
According to another embodiment of the invention, farther including, described conductive adhesive layer uses following methods to prepare,
Comprise the following steps:
1), by mass percentage, by about 1/2 part of 57-67.5% water, add in agitator tank；
2), adhesive 20-25% is added in agitator tank, stir 30-35 min；
3), Graphene powder 0.5-3%, carbon nanotube 1-5%, conductive black 5-10% are sequentially added in agitator tank, stir 2-3 h；
4), adding in agitator tank by remaining water, stirring 1-2 h, to uniformly mixing, obtains conducting resinl；
5), conductive adhesive layer is become after conducting resinl solidification.
The preparation method of a kind of graphene-based high-strength conductive cloth, comprises the following steps:
1), at base material coated on both sides conductive adhesive layer, the linear velocity that base material moves ahead is 5-10 m/min, coats thickness on the two sides of base material
Degree is the conductive adhesive layer of 0.02-0.10 mm；Conductive adhesive layer is made up of by mass percentage following component: Graphene powder 0.5-3%,
Carbon nanotube 1-5%, conductive black 5-10%, adhesive 20-25%, water 57-67.5%；Adhesive be polybutylacrylate latex, third
Olefin(e) acid ethyl ester emulsion, acrylate and methacrylic acid copolymer liquid, polyvinyl acetate emulsion, vinyl acetate-ethylene copolymerization emulsions
Or polyvinyl alcohol emulsions；
2), after base material coated on both sides conductive adhesive layer under the conditions of 110-120 DEG C, toast 3-6 min, naturally cool to room temperature,
To graphene-based high-strength conductive cloth.
According to another embodiment of the invention, farther include: the microplate diameter of described Graphene powder is not more than 10 μ
m。
According to another embodiment of the invention, farther including: described base material is nylon fabrics, thickness is 0.10-
1.00 mm, unit mass is 60-700 g/m2。
According to another embodiment of the invention, farther include: described thickness of coating on base material two sides is 0.02-0.10
Mm conductive adhesive layer, by base material from equipped with process the coating unit of conducting resinl, the two sides of base material is coated with conducting resinl, then with scraping
Conducting resinl unnecessary for base material two sides is wiped off by plate.
According to another embodiment of the invention, farther include: described coating unit, before starting coating unit, will
Conducting resinl is injected in coating unit, and the drying tunnel temperature of baking is set to 110-120 DEG C, is incubated 30 min.
According to another embodiment of the invention, farther include: described conductive adhesive layer uses following methods to prepare,
Comprise the following steps:
1), by mass percentage, by about 1/2 part of 57-67.5% water, add in agitator tank；
2), adhesive 20-25% is added in agitator tank, stir 30-35 min；
3), Graphene powder 0.5-3%, carbon nanotube 1-5%, conductive black 5-10% are sequentially added in agitator tank, stir 2-3 h；
4), adding in agitator tank by remaining water, stirring 1-2 h, to uniformly mixing, obtains conducting resinl；
5), conductive adhesive layer is become after conducting resinl solidification.
The invention has the beneficial effects as follows, present invention employs Graphene powder, carbon nanotube and white carbon black and be situated between collectively as conduction
Matter prepares conducting resinl, coated prepares graphene-based high-strength conductive cloth, and specific insulation is 1 × 103 Below Ω cm,
Sheet resistance is more than 140 N/ at 60 below Ω, pull-off force.
Accompanying drawing explanation
The present invention is further described with embodiment below in conjunction with the accompanying drawings.
Fig. 1 is the structural representation of a kind of graphene-based high-strength conductive cloth of the present invention.
Fig. 2 is the preparation method flow chart of a kind of graphene-based high-strength conductive cloth of the present invention.
In figure, 1, basic unit, 2, conductive adhesive layer.
Detailed description of the invention
With embodiment, the present invention is described in further detail below in conjunction with the accompanying drawings.
As it is shown in figure 1, a kind of graphene-based high-strength conductive cloth of the present invention, being provided with base material 1, base material 1 is nylon fabrics, thick
Degree is 0.10-1.00 mm, and unit mass is 60-700 g/m2, the two sides of base material 1 scribbles conductive adhesive layer 2.
Conductive adhesive layer 2 is made up of by mass percentage following component: Graphene powder 0.5-3%, carbon nanotube 1-5%, conduction
White carbon black 5-10%, adhesive 20-25%, water 57-67.5%.
The particle diameter of Graphene powder is not more than 10 μm.Graphene powder, carbon nanotube, conductive black, as the solute of conduction, divide
It is scattered in solvent make graphene-based conducting resinl.
Adhesive is polybutylacrylate latex, ethyl acrylate emulsion, acrylate and methacrylic acid copolymer liquid, poly-vinegar
Acid vac emulsion, vinyl acetate-ethylene copolymerization emulsions or polyvinyl alcohol emulsions.Adhesive is as solvent, by Graphene, charcoal nanometer
Pipe, conductive black dissolve and form conducting resinl solution.
Water is tap water.
Conductive adhesive layer uses following methods to prepare, and comprises the following steps:
1), under room temperature (20 DEG C), by mass percentage, by 1/2 addition agitator tank of the tap water of 57-67.5%；
2), adhesive 20-25% is added in agitator tank, stir 30-35 min；
3), Graphene powder 0.5-3%, carbon nanotube 1-5%, conductive black 5-10% are sequentially added in agitator tank, stir 2-3 h；
4), adding in agitator tank by remaining water, stirring 1-2 h, to uniformly mixing, obtains conducting resinl；
5), conductive adhesive layer 2 is become after conducting resinl solidification.
As in figure 2 it is shown, the preparation method of a kind of graphene-based high-strength conductive cloth of the present invention, comprise the following steps:
One, room temperature (20 DEG C), coating thickness on base material two sides is 0.02-0.10 mm conductive adhesive layer, by base material from equipped with conduction
Process in the coating unit of glue, the two sides of base material is coated with conducting resinl, then entering base material two before drying unit with scraper plate
The unnecessary conducting resinl in face strikes off, and the gap between scraper plate sets according to the material thickness after gluing, and the linear velocity that base material moves ahead is
5-10 m/min, the thickness of rear substrate every conductive adhesive layer scraped by scraper plate is 0.02-0.10 mm.
Base material is nylon fabrics, and thickness is 0.10-1.00 mm, and unit mass is 60-700 g/m2。
Conducting resinl is made up of by mass percentage following component: Graphene powder 0.5-3%, carbon nanotube 1-5%, conductive black
5-10%, adhesive 20-25%, water 57-67.5%.
The particle diameter of Graphene powder is not more than 10 μm.Graphene powder, carbon nanotube, conductive black, as the solute of conduction, divide
It is scattered in solvent make graphene-based conducting resinl.
Adhesive is polybutylacrylate latex, ethyl acrylate emulsion, acrylate and methacrylic acid copolymer liquid, poly-vinegar
Acid vac emulsion, vinyl acetate-ethylene copolymerization emulsions or polyvinyl alcohol emulsions.Graphene powder, charcoal, as solvent, are received by adhesive
Mitron, conductive black are dissolved in solvent becomes conducting resinl solution.
Water is tap water.
Described conducting resinl uses following methods to prepare, and comprises the following steps:
1), under room temperature (20 DEG C), by mass percentage, by 1/2 addition agitator tank of the tap water of 57-67.5%；
2), adhesive 20-25% is added in agitator tank, stir 30-35 min；
3), Graphene powder 0.5-3%, carbon nanotube 1-5%, conductive black 5-10% are sequentially added in agitator tank, stir 2-3 h；
4), adding in agitator tank by remaining water, stirring 1-2 h, to uniformly mixing, obtains conducting resinl；
5), conductive adhesive layer 2 is become after conducting resinl solidification.
Two, after base material coated on both sides conductive adhesive layer under the conditions of 110-120 DEG C, toast 3-6 min, naturally cool to room
Temperature, obtains graphene-based high-strength conductive cloth.
Before starting coating unit, conducting resinl is injected in coating unit, the drying tunnel temperature of baking is set to 110-120
DEG C, it is incubated 30 min.
The component of embodiment 1-4 conducting resinl, technological parameter are shown in Table 1.
The preparation technology parameter of embodiment 1-4 graphene-based high-strength conductive cloth is shown in Table 2, uses hub internal diameter: Φ 76
mm、Φ80 mm、Φ100 mm、Φ105 mm、Φ150 mm；Tep reel external diameter: Φ 200 mm, Φ 250 mm, Φ 300 mm, Φ
350 mm、Φ400 mm、Φ430 mm。
The graphene-based high-strength conductive cloth that the present invention obtains, is tested by JB/T 10259-2001, and performance indications are shown in Table 3.
The component of conducting resinl of table 1 embodiment 1-4, preparation technology parameter
The preparation technology parameter of table 2 embodiment 1-4 graphene-based high-strength conductive cloth
The performance indications of table 3 embodiment 1-4 graphene-based high-strength conductive cloth
It can be seen that embodiments of the invention 1-4 from above-mentioned performance table 3, specific insulation is all 1 × 103 Below Ω cm,
Sheet resistance is all at 60 below Ω, and pull-off force is all higher than 140 N/, it is seen then that the application conductive fabric has high conductivity, high machine
Tool intensity, the present invention is especially suitable for base camp tent, cable shield material etc., and can better conform to the needs of association area.
Claims (9)
1. a graphene-based high-strength conductive cloth, high-strength conductive cloth includes base material (1) and conductive adhesive layer (2), base material (1)
Coated on both sides conductive adhesive layer (2), is characterized in that, described conductive adhesive layer (2) is made up of by mass percentage following component:
Graphene powder 0.5-3%；
Carbon nanotube 1-5%；
Conductive black 5-10%；
Adhesive 20-25%；
Water 57-67.5%；
Described adhesive is polybutylacrylate latex, ethyl acrylate emulsion, acrylate and methacrylic acid copolymer liquid, poly-vinegar
Acid vac emulsion, vinyl acetate-ethylene copolymerization emulsions or polyvinyl alcohol emulsions.
Graphene-based high-strength conductive cloth the most according to claim 1, is characterized in that:
Described base material (1) is nylon fabrics, and thickness is 0.10-1.00 mm, and unit mass is 60-700 g/m2；
The pull-off force of described high-strength conductive cloth is more than 140 N/.
One the most according to claim 1 graphene-based high-strength conductive cloth, it is characterised in that: described conductive adhesive layer (2)
Employing following methods prepares, and comprises the following steps:
1), by mass percentage, by about 1/2 part of 57-67.5% water, add in agitator tank；
2), adhesive 20-25% is added in agitator tank, stir 30-35 min；
3), Graphene powder 0.5-3%, carbon nanotube 1-5%, conductive black 5-10% are sequentially added in agitator tank, stir 2-3 h；
4), adding in agitator tank by remaining water, stirring 1-2 h, to uniformly mixing, obtains conducting resinl；
5), conductive adhesive layer (2) is become after conducting resinl solidification.
4. a preparation method for graphene-based high-strength conductive cloth, comprises the following steps:
1), at base material (1) coated on both sides conductive adhesive layer (2), the linear velocity that base material moves ahead is 5-10 m/min, on the two sides of base material
Coat the conductive adhesive layer (2) that thickness is 0.02-0.10 mm；Conductive adhesive layer (2) is made up of by mass percentage following component: stone
Ink alkene powder 0.5-3%, carbon nanotube 1-5%, conductive black 5-10%, adhesive 20-25%, water 57-67.5%；Adhesive is propylene
Acid butyl ester emulsion, ethyl acrylate emulsion, acrylate and methacrylic acid copolymer liquid, polyvinyl acetate emulsion, vinyl acetate-
Ethylene copolymerization emulsions or polyvinyl alcohol emulsions；
2), after base material (1) coated on both sides conductive adhesive layer (2) under the conditions of 110-120 DEG C, toast 3-6 min, naturally cool to
Room temperature, obtains graphene-based high-strength conductive cloth.
The preparation method of a kind of graphene-based high-strength conductive cloth the most according to claim 4, it is characterised in that: described stone
The microplate diameter of ink alkene powder is not more than 10 μm.
The preparation method of a kind of graphene-based high-strength conductive cloth the most according to claim 4, it is characterised in that: described base
Material (1) is nylon fabrics, and thickness is 0.10-1.00 mm, and unit mass is 60-700 g/m2。
The preparation method of a kind of graphene-based high-strength conductive cloth the most according to claim 4, it is characterised in that: described
It is 0.02-0.10 mm conductive adhesive layer (2) that thickness is coated on base material (1) two sides, by base material from equipped with warp the coating unit of conducting resinl
Crossing, the two sides of base material is coated with conducting resinl, is then wiped off by conducting resinl unnecessary for base material two sides with scraper plate.
The preparation method of a kind of graphene-based high-strength conductive cloth the most according to claim 7, it is characterised in that: described painting
Coating device, before starting coating unit, is injected into conducting resinl in coating unit, the drying tunnel temperature of baking is set to 110-
120 DEG C, it is incubated 30 min.
The preparation method of a kind of graphene-based high-strength conductive cloth the most according to claim 4, it is characterised in that lead described in:
Electricity glue-line (2) uses following methods to prepare, and comprises the following steps:
1), by mass percentage, by about 1/2 part of 57-67.5% water, add in agitator tank；
2), adhesive 20-25% is added in agitator tank, stir 30-35 min；
3), Graphene powder 0.5-3%, carbon nanotube 1-5%, conductive black 5-10% are sequentially added in agitator tank, stir 2-3 h；
4), adding in agitator tank by remaining water, stirring 1-2 h, to uniformly mixing, obtains conducting resinl；
5), conductive adhesive layer (2) is become after conducting resinl solidification.
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| CN201610248450.1A CN105803814A (en) | 2016-04-20 | 2016-04-20 | Graphene-based high-strength conductive cloth and preparation method thereof |
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| CN110010275A (en) * | 2019-04-30 | 2019-07-12 | 深圳市傲基电子商务股份有限公司 | High shielding wire rod, data line and method for manufacturing wire |
| GB2596293A (en) * | 2020-06-22 | 2021-12-29 | Univ Cranfield | A method and system for forming a fibre composite and a composite |
| WO2021260355A1 (en) * | 2020-06-22 | 2021-12-30 | Cranfield University | A method and system for forming a fibre composite and a composite |
| EP4168620A1 (en) * | 2020-06-22 | 2023-04-26 | Cranfield University | A method and system for forming a fibre composite and a composite |
| GB2596293B (en) * | 2020-06-22 | 2025-05-28 | Univ Cranfield | A method and system for forming a fibre composite and a composite |
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