CN105801002B - A kind of processing method of polyurethane rubber concrete material and the material - Google Patents
A kind of processing method of polyurethane rubber concrete material and the material Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B18/00—Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
- C04B18/04—Waste materials; Refuse
- C04B18/18—Waste materials; Refuse organic
- C04B18/20—Waste materials; Refuse organic from macromolecular compounds
- C04B18/22—Rubber, e.g. ground waste tires
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/16—Polyurethanes
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
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Abstract
一种聚氨酯橡胶混凝土材料及该材料的加工方法,含有以下物质及重量份:石料100份;橡胶粉1‑20份;聚氨酯3‑15份;所述石料包括粒径为小于5mm的石子、粒径为大于等于5且小于10mm的石子和粒径为大于等于10且小于15mm的石子;所述的聚氨酯为双组分或单组分热固性材料,拉伸强度>8MPa,拉伸断裂伸长率>50%,常温粘度<1500mPa·s。按照本发明提供的聚氨酯橡胶混凝土材料具有如下优点:本发明与现有技术相比降低了聚氨酯的用量,将成本降低约30%,废旧胶粉的加入进一步提高了材料的耐寒性能、抗疲劳性能,并且不渗水,用于铺装桥面、路面时,减小铺装层的厚度,减小面层重量,延长路面、桥面使用寿命。A polyurethane rubber concrete material and a processing method of the material, comprising the following substances and parts by weight: 100 parts of stone; 1-20 parts of rubber powder; 3-15 parts of polyurethane; Stones with a diameter greater than or equal to 5 and less than 10mm and stones with a particle diameter greater than or equal to 10 and less than 15mm; the polyurethane described above is a two-component or one-component thermosetting material with a tensile strength of >8MPa and a tensile elongation at break >50%, normal temperature viscosity <1500mPa·s. The polyurethane rubber concrete material provided by the present invention has the following advantages: compared with the prior art, the present invention reduces the consumption of polyurethane, reduces the cost by about 30%, and the addition of waste rubber powder further improves the cold resistance and fatigue resistance of the material , and no water seepage, when used to pave bridge decks and road surfaces, reduce the thickness of the pavement layer, reduce the weight of the surface layer, and prolong the service life of the road and bridge decks.
Description
技术领域technical field
本发明涉及一种聚氨酯橡胶混凝土材料,本发明还涉及该材料的加工方法。The invention relates to a polyurethane rubber concrete material, and also relates to a processing method of the material.
背景技术Background technique
目前路面、桥面铺装材料主要是沥青混凝土或改性沥青混凝土材料。由于沥青本身的性能特点,导致了铺装材料高温下易流淌,低温下易开裂。从而使路面、桥面出现了推移、车辙、坑槽、裂纹等一些列病害,影响了道路和桥梁的使用寿命,增加了道路和桥梁养护的经济成本和时间成本。为此,人们对新的铺装材料进行了探索和研究。例如,中国专利CN101497510公开了一种环氧树脂混凝土材料制备及方法。与沥青混凝土相比,环氧树脂混凝土材料表现出优异的粘接性能、耐高温性能、更高的强度;但是也存在一定的缺点,如耐寒性能一般,表现出低温脆性大、抗疲劳性能差、拌合和摊铺温度高等。又如中国专利CN104446140公开了一种改性聚氨酯橡胶混凝土薄层铺装材料。与环氧混凝土及沥青混凝土相比,这类材料表现出良好的低温性能,混凝土材料韧性提高,抗疲劳性能增加。环氧树脂和聚氨酯基混凝土材料尽管表现出来极优异的性能,但环氧树脂和聚氨酯胶结料的用量较大,通常为石料用量的20 ~ 30%,成本较高。At present, pavement materials for pavements and bridge decks are mainly asphalt concrete or modified asphalt concrete materials. Due to the performance characteristics of asphalt itself, the pavement material is easy to flow at high temperature and easy to crack at low temperature. As a result, a series of diseases such as shifting, rutting, potholes, and cracks appear on the road surface and bridge deck, which affects the service life of roads and bridges, and increases the economic and time costs of road and bridge maintenance. For this reason, people have carried out exploration and research to new pavement material. For example, Chinese patent CN101497510 discloses a preparation method of epoxy resin concrete material. Compared with asphalt concrete, epoxy resin concrete material exhibits excellent bonding performance, high temperature resistance, and higher strength; but there are also certain shortcomings, such as general cold resistance, high low temperature brittleness, and poor fatigue resistance. , mixing and paving temperature is high. Another example is Chinese patent CN104446140 which discloses a modified polyurethane rubber concrete thin-layer pavement material. Compared with epoxy concrete and asphalt concrete, this kind of material shows good low temperature performance, the toughness of concrete material is improved, and the fatigue resistance performance is increased. Although epoxy resin and polyurethane-based concrete materials exhibit excellent performance, the amount of epoxy resin and polyurethane binder is relatively large, usually 20 to 30% of the amount of stone, and the cost is relatively high.
发明内容Contents of the invention
本发明所要解决的技术问题在于克服上述现有技术之不足,提供一种耐寒性能、抗疲劳性能优异,密实不透水生产成本低的聚氨酯橡胶混凝土材料及该材料的加工方法。The technical problem to be solved by the present invention is to overcome the deficiencies of the above-mentioned prior art, and provide a polyurethane rubber concrete material with excellent cold resistance and fatigue resistance, dense and impermeable, and low production cost and a processing method of the material.
按照本发明提供的聚氨酯橡胶混凝土材料采用的主要技术方案为:The main technical scheme adopted according to the polyurethane rubber concrete material provided by the invention is:
含有以下物质及重量份:Contains the following substances and parts by weight:
石料100份;100 parts of stone;
矿粉0~8份;Mineral powder 0~8 parts;
橡胶粉1-20份;1-20 parts of rubber powder;
聚氨酯3-15份。3-15 parts of polyurethane.
本发明提供的聚氨酯橡胶混凝土材料还采用如下附属技术方案:The polyurethane rubber concrete material provided by the invention also adopts the following subsidiary technical schemes:
所述石料包括粒径为小于5mm的石子、粒径为5-10mm的石子和粒径为10-150mm的石子。The stone materials include stones with a particle size of less than 5mm, stones with a particle size of 5-10mm and stones with a particle size of 10-150mm.
所述粒径为小于5mm的石子、所述粒径为5-10mm的石子和所述粒径为10-150mm的石子的重量之比为60 ~ 80 : 10 ~ 20 : 10 ~ 20。The weight ratio of the stones with a particle size of less than 5 mm, the stones with a particle size of 5-10 mm, and the stones with a particle size of 10-150 mm is 60-80: 10-20: 10-20.
所述的聚氨酯为双组分或单组分热固性材料,拉伸强度 > 8MPa,拉伸断裂伸长率> 50%,常温粘度 < 1500mPa·s。The polyurethane is a two-component or one-component thermosetting material with a tensile strength > 8MPa, a tensile elongation at break > 50%, and a viscosity at room temperature < 1500mPa·s.
所述的橡胶粉的粒径为0.01 - 3mm。The particle size of the rubber powder is 0.01-3mm.
所述石料为玄武岩和/石灰岩。The stone materials are basalt and/or limestone.
所述橡胶粉为废旧橡胶粉。The rubber powder is waste rubber powder.
按照本发明提供的聚氨酯橡胶混凝土材料的加工方法采用的主要技术方案为:将石料与橡胶粉按照配合比例混合均匀后,加入聚氨酯,搅拌均匀后在温度-20 ~ 50℃下碾压成型,经过8 ~ 96h的养护,制得聚氨酯橡胶混凝土材料。The main technical scheme adopted in the processing method of the polyurethane rubber concrete material provided by the present invention is as follows: mix the stone material and the rubber powder uniformly according to the mixing ratio, add polyurethane, and after mixing evenly, roll and form at a temperature of -20 to 50°C. 8 ~ 96h of curing, made of polyurethane rubber concrete material.
按照本发明提供的聚氨酯橡胶混凝土材料与现有技术相比具有如下优点:本发明与现有技术相比降低了聚氨酯的用量,将成本降低约30%,废旧胶粉的加入进一步提高了材料的耐寒性能、抗疲劳性能,并且不渗水,用于铺装桥面、路面时可减小铺装层的厚度,减小面层重量,延长路面、桥面使用寿命。Compared with the prior art, the polyurethane rubber concrete material provided by the present invention has the following advantages: compared with the prior art, the present invention reduces the consumption of polyurethane, reduces the cost by about 30%, and the addition of waste rubber powder further improves the quality of the material. Cold resistance, fatigue resistance, and impervious to water, when used to pave bridge decks and roads, it can reduce the thickness of the pavement layer, reduce the weight of the surface layer, and prolong the service life of the road and bridge decks.
按照本发明提供的聚氨酯橡胶混凝土材料的加工方法与现有技术相比具有如下优点:工艺简单,步骤少,不易受外界条件影响,加工周期短,铺装效率高。Compared with the prior art, the processing method of the polyurethane rubber concrete material provided by the present invention has the following advantages: simple process, few steps, not easily affected by external conditions, short processing cycle, and high paving efficiency.
具体实施方式Detailed ways
实施例一Embodiment one
按照本发明提供的聚氨酯橡胶混凝土材料实施例,含有以下物质及重量份:According to the polyurethane rubber concrete material embodiment provided by the invention, contain following material and parts by weight:
石料100份;100 parts of stone;
矿粉0~8份;Mineral powder 0~8 parts;
橡胶粉1-20份;1-20 parts of rubber powder;
聚氨酯3-15份。3-15 parts of polyurethane.
所述的聚氨酯为双组分或单组分热固性材料,拉伸强度 > 8MPa,拉伸断裂伸长率> 50%,常温粘度 < 1500mPa·s。所述的橡胶粉的粒径为0.01-3mm,本实施例优选为0.05mm。所述石料为玄武岩和石灰岩,本实施例的石料为玄武岩。所述橡胶粉为废旧橡胶粉,采用废旧橡胶粉不仅易加工,降低生产成本,还将废旧橡胶变废为宝,减少了废旧橡胶无法再利用而对环境造成的污染。The polyurethane is a two-component or one-component thermosetting material with a tensile strength > 8MPa, a tensile elongation at break > 50%, and a viscosity at room temperature < 1500mPa·s. The particle size of the rubber powder is 0.01-3 mm, preferably 0.05 mm in this embodiment. The stone material is basalt and limestone, and the stone material in this embodiment is basalt. The rubber powder is waste rubber powder, and the waste rubber powder is not only easy to process, reduces production cost, but also turns waste rubber into treasure, and reduces environmental pollution caused by waste rubber being unable to be reused.
所述石料包括粒径为小于5mm的石子、粒径为5-10mm的石子和粒径为10-150mm的石子。所述粒径为小于5mm的石子、所述粒径为5-10mm的石子和所述粒径为10-150mm的石子的重量之比为60 ~ 80 : 10 ~ 20 : 10 ~ 20。The stone materials include stones with a particle size of less than 5mm, stones with a particle size of 5-10mm and stones with a particle size of 10-150mm. The weight ratio of the stones with a particle size of less than 5 mm, the stones with a particle size of 5-10 mm, and the stones with a particle size of 10-150 mm is 60-80: 10-20: 10-20.
本实施例中石料用量为100份,其中所述粒径为小于5mm的石子、所述粒径为5-10mm的石子和所述粒径为10-150mm的石子的重量之比为: 65% : 15% : 20%,合成级配为:In the present embodiment, the amount of stone used is 100 parts, wherein the weight ratio of the stones with a particle size of less than 5mm, the stones with a particle size of 5-10mm, and the stones with a particle size of 10-150mm is: 65% : 15% : 20%, the synthetic gradation is:
满足《公路沥青路面施工技术规范》(JTGF40—2004)对混合料的级配要求;Satisfies the gradation requirements of the "Technical Specifications for Construction of Highway Asphalt Pavement" (JTGF40-2004) for the mixture;
废旧橡胶粉的用量为6份,The consumption of waste rubber powder is 6 parts,
聚氨酯用量为9份,The amount of polyurethane is 9 parts,
矿粉用量为2份。Mineral powder consumption is 2 parts.
上述聚氨酯橡胶混凝土材料的加工方法为:将上述石料与废旧橡胶粉混合均匀,加入混合均匀的聚氨酯,搅拌1 min,在温度-20 ~ 50℃下碾压75次,养护24h时间。上述加工方法工艺简单,步骤少,不易受外界条件影响,加工周期短,铺装效率高。The processing method of the above-mentioned polyurethane rubber concrete material is as follows: uniformly mix the above-mentioned stone and waste rubber powder, add the uniformly mixed polyurethane, stir for 1 min, roll and compact 75 times at a temperature of -20 to 50°C, and maintain for 24 hours. The above-mentioned processing method has simple process, few steps, is not easily affected by external conditions, has short processing cycle and high paving efficiency.
本发明与现有技术相比降低了聚氨酯的用量,将成本降低约30%,废旧胶粉的加入进一步提高了材料的耐寒性能、抗疲劳性能,并且不渗水,用于铺装桥面、路面时,减小铺装层的厚度,减小面层重量,延长路面、桥面使用寿命。Compared with the prior art, the present invention reduces the amount of polyurethane used, reduces the cost by about 30%, and the addition of waste rubber powder further improves the cold resistance and fatigue resistance of the material, and is impervious to water. It is used for paving bridge decks and road surfaces. , reduce the thickness of the pavement layer, reduce the weight of the surface layer, and prolong the service life of the road surface and bridge deck.
实施例二Embodiment two
本实施例与上述实施例一大致相同,石料用量为100份,区别在于本实施中所述粒径为小于5mm的石子、所述粒径为5-10mm的石子和所述粒径为10-150mm的石子的重量之比为: 70% : 15% : 15%,合成级配为:This embodiment is roughly the same as the above-mentioned embodiment 1, and the amount of stone material is 100 parts. The weight ratio of 150mm stones is: 70% : 15% : 15%, and the synthetic gradation is:
满足《公路沥青路面施工技术规范》(JTGF40—2004)对混合料的级配要求;Satisfies the gradation requirements of the "Technical Specifications for Construction of Highway Asphalt Pavement" (JTGF40-2004) for the mixture;
废旧橡胶粉用量为12份,Waste rubber powder consumption is 12 parts,
聚氨酯用量为12份,The amount of polyurethane is 12 parts,
矿粉用量为4份。Mineral powder consumption is 4 parts.
上述聚氨酯橡胶混凝土材料的加工方法为:将上述石料与废旧橡胶粉混合均匀,加入混合均匀的聚氨酯,搅拌1 min,在温度-20 ~50℃下碾压75次,养护24h时间。The processing method of the above-mentioned polyurethane rubber concrete material is as follows: uniformly mix the above-mentioned stone and waste rubber powder, add the uniformly mixed polyurethane, stir for 1 min, roll and compact 75 times at a temperature of -20-50°C, and maintain for 24 hours.
实施例三Embodiment three
本实施例与上述实施例一大致相同,石料用量为100份,区别在于本实施中所述粒径为小于5mm的石子、所述粒径为5-10mm的石子和所述粒径为10-150mm的石子的重量之比为: 70% : 15% : 15%,合成级配为:This embodiment is roughly the same as the above-mentioned embodiment 1, and the amount of stone material is 100 parts. The weight ratio of 150mm stones is: 70% : 15% : 15%, and the synthetic gradation is:
满足《公路沥青路面施工技术规范》(JTGF40—2004)对混合料的级配要求;Satisfies the gradation requirements of the "Technical Specifications for Construction of Highway Asphalt Pavement" (JTGF40-2004) for the mixture;
废旧橡胶粉用量为20份,Waste rubber powder consumption is 20 parts,
聚氨酯用量为13份。The polyurethane consumption is 13 parts.
矿粉用量为4份The amount of mineral powder is 4 parts
上述聚氨酯橡胶混凝土材料的加工方法为:将上述石料与废旧橡胶粉混合均匀,加入混合均匀的聚氨酯,搅拌1 min,在温度-20 ~50℃下碾压75次,养护24h时间。The processing method of the above-mentioned polyurethane rubber concrete material is as follows: uniformly mix the above-mentioned stone and waste rubber powder, add the uniformly mixed polyurethane, stir for 1 min, roll and compact 75 times at a temperature of -20-50°C, and maintain for 24 hours.
实施例四Embodiment Four
本实施例与上述实施例一大致相同,石料用量为100份,区别在于本实施中所述粒径为小于5mm的石子、所述粒径为5-10mm的石子和所述粒径为10-150mm的石子的重量之比为: 70% : 15% : 15%,合成级配为:This embodiment is roughly the same as the above-mentioned embodiment 1, and the amount of stone material is 100 parts. The weight ratio of 150mm stones is: 70% : 15% : 15%, and the synthetic gradation is:
满足《公路沥青路面施工技术规范》(JTGF40—2004)对混合料的级配要求;Satisfies the gradation requirements of the "Technical Specifications for Construction of Highway Asphalt Pavement" (JTGF40-2004) for the mixture;
废旧橡胶粉用量为20份,Waste rubber powder consumption is 20 parts,
聚氨酯用量为15份。Polyurethane consumption is 15 parts.
矿粉用量为0份The amount of mineral powder is 0 parts
上述聚氨酯橡胶混凝土材料的加工方法为:将上述石料与废旧橡胶粉混合均匀,加入混合均匀的聚氨酯,搅拌1 min,在温度-20 ~50℃下碾压75次,养护24h时间。The processing method of the above-mentioned polyurethane rubber concrete material is as follows: uniformly mix the above-mentioned stone and waste rubber powder, add the uniformly mixed polyurethane, stir for 1 min, roll and compact 75 times at a temperature of -20-50°C, and maintain for 24 hours.
实施例五Embodiment five
本实施例与上述实施例一大致相同,石料用量为100份,区别在于本实施中所述粒径为小于5mm的石子、所述粒径为5-10mm的石子和所述粒径为10-150mm的石子的重量之比为: 70% : 15% : 15%,合成级配为:This embodiment is roughly the same as the above-mentioned embodiment 1, and the amount of stone material is 100 parts. The weight ratio of 150mm stones is: 70% : 15% : 15%, and the synthetic gradation is:
满足《公路沥青路面施工技术规范》(JTGF40—2004)对混合料的级配要求;Satisfies the gradation requirements of the "Technical Specifications for Construction of Highway Asphalt Pavement" (JTGF40-2004) for the mixture;
废旧橡胶粉的用量为20份,The consumption of waste rubber powder is 20 parts,
聚氨酯用量为13份。The polyurethane consumption is 13 parts.
矿粉用量为2份The amount of mineral powder is 2 parts
上述聚氨酯橡胶混凝土材料的加工方法为:将上述石料与废旧橡胶粉混合均匀,加入混合均匀的聚氨酯,搅拌1 min,在温度-20 ~50℃下碾压75次,养护48h时间。The processing method of the above-mentioned polyurethane rubber concrete material is as follows: uniformly mix the above-mentioned stone and waste rubber powder, add the uniformly mixed polyurethane, stir for 1 min, roll and compact 75 times at a temperature of -20-50°C, and cure for 48 hours.
上述5个实施例的制得的聚氨酯橡胶混凝土材料,性能测试结果如下表所示The obtained polyurethane rubber concrete material of above-mentioned 5 embodiments, performance test result is shown in the table below
尽管已经示出和描述了本发明的实施例,对于本领域的普通技术人员而言,可以理解在不脱离本发明的原理和精神的情况下可以对这些实施例进行变化,本发明的范围由所附权利要求及其等同物限定。While embodiments of the present invention have been shown and described, it will be understood by those skilled in the art that changes may be made to these embodiments without departing from the principles and spirit of the invention, the scope of which is defined by The appended claims and their equivalents are defined.
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| CN201610200660.3A CN105801002B (en) | 2016-03-31 | 2016-03-31 | A kind of processing method of polyurethane rubber concrete material and the material |
| PCT/CN2016/000259 WO2017165989A1 (en) | 2016-03-31 | 2016-05-13 | Polyurethane rubber concrete material and processing method therefor |
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| CN110255972A (en) * | 2019-04-29 | 2019-09-20 | 北京建筑大学 | A method of improving porous polyurethane mixture water stability |
| CN110342854A (en) * | 2019-07-12 | 2019-10-18 | 同济大学 | A kind of porous mixture of concrete bridge deck pavement polyurethane rubber and its preparation |
| CN110372295B (en) * | 2019-07-12 | 2021-02-02 | 同济大学 | High-strength high-toughness light polyurethane rubber bridge deck pavement material and preparation thereof |
| CN110438896B (en) * | 2019-07-12 | 2021-05-11 | 同济大学 | Polyurethane rubber drainage pavement structure for concrete bridge floor and construction method thereof |
| CN110683791A (en) * | 2019-09-18 | 2020-01-14 | 长安大学 | Super-silent pavement paving material and application |
| CN111138116A (en) * | 2020-01-09 | 2020-05-12 | 北京建筑大学 | Polyether polyurethane concrete paving material and preparation method thereof |
| CN113912327A (en) * | 2020-07-10 | 2022-01-11 | 苏州市相城交通建设投资(集团)有限公司 | Preparation method of high-performance anti-cracking asphalt mixture for tunnel joints |
| CN112832086B (en) * | 2020-12-30 | 2022-07-22 | 山东省交通规划设计院有限公司 | Combined ultrathin long-life pavement structure and construction method thereof |
| CN113548837A (en) * | 2021-08-09 | 2021-10-26 | 长安大学 | Epoxy-polyurethane composite adhesive and preparation method thereof and color elastic permeable pavement material |
| CN115259747B (en) * | 2022-06-28 | 2023-06-23 | 华北水利水电大学 | Composite modified polyurethane concrete and preparation method thereof |
| CN116254771B (en) * | 2023-02-20 | 2025-11-04 | 山东省交通科学研究院 | Method for laying single-component polyurethane mixture cement concrete bridge deck |
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| DE1931053A1 (en) * | 1969-06-19 | 1971-01-07 | Bayer Ag | Process for the production of synthetic resin concrete |
| US4630963A (en) * | 1984-09-05 | 1986-12-23 | Wyman Ransome J | Polymer concrete by percolation |
| DE102005027551A1 (en) * | 2005-06-14 | 2006-12-21 | Basf Ag | Method for producing a composite of stones and a plastic |
| AU2008300682B2 (en) * | 2007-09-14 | 2013-07-11 | Basf Se | Method for producing mineral-bearing cover layers for floor coverings |
| CN101497510B (en) * | 2009-03-03 | 2011-09-28 | 重庆鹏方路面工程技术研究院有限公司 | Modified epoxy resin concrete material and preparation thereof |
| CN102617070B (en) * | 2012-03-23 | 2014-02-19 | 重庆市智翔铺道技术工程有限公司 | Polyurethane asphalt concrete as well as preparation method and application thereof |
| CN102718433A (en) * | 2012-07-02 | 2012-10-10 | 河南万里路桥集团有限公司 | Non-blending macromolecule concrete and construction method thereof |
| CN103058585B (en) * | 2013-01-16 | 2014-05-21 | 河北工业大学 | Preparation method of polyurethane rubber particle mixture for road surface self-stress icebreaking |
| CN104176985B (en) * | 2014-08-11 | 2016-05-18 | 交通运输部公路科学研究所 | A kind of aqueous polyurethane emulsified bitulith and its production and use |
| CN104446140A (en) * | 2014-11-26 | 2015-03-25 | 安徽省交通投资集团有限责任公司 | Modified polyurethane concrete thin layer paving material |
| CN104876474B (en) * | 2015-04-22 | 2017-03-08 | 哈尔滨工程大学 | Bridge deck waterborne polyurethane polymer concrete and preparation method thereof |
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