CN1057478A - Metal working fluid - Google Patents
Metal working fluid Download PDFInfo
- Publication number
- CN1057478A CN1057478A CN 90104338 CN90104338A CN1057478A CN 1057478 A CN1057478 A CN 1057478A CN 90104338 CN90104338 CN 90104338 CN 90104338 A CN90104338 A CN 90104338A CN 1057478 A CN1057478 A CN 1057478A
- Authority
- CN
- China
- Prior art keywords
- sodium
- cutting fluid
- emulsion
- advisable
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000005555 metalworking Methods 0.000 title claims abstract description 10
- 239000012530 fluid Substances 0.000 title claims abstract description 9
- 239000002173 cutting fluid Substances 0.000 claims abstract description 28
- 239000000839 emulsion Substances 0.000 claims abstract description 21
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 claims abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 8
- DAJSVUQLFFJUSX-UHFFFAOYSA-M sodium;dodecane-1-sulfonate Chemical compound [Na+].CCCCCCCCCCCCS([O-])(=O)=O DAJSVUQLFFJUSX-UHFFFAOYSA-M 0.000 claims abstract description 8
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims abstract description 5
- 235000010234 sodium benzoate Nutrition 0.000 claims abstract description 5
- 239000004299 sodium benzoate Substances 0.000 claims abstract description 5
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims abstract description 5
- 235000019982 sodium hexametaphosphate Nutrition 0.000 claims abstract description 5
- NVIFVTYDZMXWGX-UHFFFAOYSA-N sodium metaborate Chemical compound [Na+].[O-]B=O NVIFVTYDZMXWGX-UHFFFAOYSA-N 0.000 claims abstract description 5
- 235000010288 sodium nitrite Nutrition 0.000 claims abstract description 5
- 239000007787 solid Substances 0.000 claims abstract description 5
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 claims abstract description 5
- 150000001252 acrylic acid derivatives Chemical class 0.000 claims abstract description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 15
- 150000001875 compounds Chemical class 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 10
- 239000000314 lubricant Substances 0.000 claims description 8
- 229910052751 metal Inorganic materials 0.000 claims description 7
- 239000002184 metal Substances 0.000 claims description 7
- 230000000694 effects Effects 0.000 claims description 4
- 239000003995 emulsifying agent Substances 0.000 claims description 4
- 239000011347 resin Substances 0.000 claims description 4
- 229920005989 resin Polymers 0.000 claims description 4
- HCJLVWUMMKIQIM-UHFFFAOYSA-M sodium;2,3,4,5,6-pentachlorophenolate Chemical compound [Na+].[O-]C1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl HCJLVWUMMKIQIM-UHFFFAOYSA-M 0.000 claims description 4
- 239000000243 solution Substances 0.000 claims description 4
- 230000015572 biosynthetic process Effects 0.000 claims description 3
- CYEJMVLDXAUOPN-UHFFFAOYSA-N 2-dodecylphenol Chemical group CCCCCCCCCCCCC1=CC=CC=C1O CYEJMVLDXAUOPN-UHFFFAOYSA-N 0.000 claims description 2
- 229920000178 Acrylic resin Polymers 0.000 claims description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 2
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 2
- 239000004141 Sodium laurylsulphate Substances 0.000 claims description 2
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 claims description 2
- 238000006359 acetalization reaction Methods 0.000 claims description 2
- 125000002777 acetyl group Chemical class [H]C([H])([H])C(*)=O 0.000 claims description 2
- 150000004996 alkyl benzenes Chemical class 0.000 claims description 2
- 239000012895 dilution Substances 0.000 claims description 2
- 238000010790 dilution Methods 0.000 claims description 2
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 claims description 2
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims description 2
- 239000011259 mixed solution Substances 0.000 claims description 2
- 230000004048 modification Effects 0.000 claims description 2
- 238000012986 modification Methods 0.000 claims description 2
- 229920000570 polyether Polymers 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims description 2
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 2
- 238000003786 synthesis reaction Methods 0.000 claims description 2
- 229920002554 vinyl polymer Polymers 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims 1
- 238000004140 cleaning Methods 0.000 abstract description 3
- 239000002612 dispersion medium Substances 0.000 abstract description 3
- DPDMMXDBJGCCQC-UHFFFAOYSA-N [Na].[Cl] Chemical compound [Na].[Cl] DPDMMXDBJGCCQC-UHFFFAOYSA-N 0.000 abstract 1
- 238000005461 lubrication Methods 0.000 abstract 1
- 238000003754 machining Methods 0.000 description 4
- 238000001816 cooling Methods 0.000 description 3
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 244000309464 bull Species 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000005238 degreasing Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 239000010721 machine oil Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
Landscapes
- Lubricants (AREA)
Abstract
Metal working fluid, it relates to water is the non-oily emulsion type cutting fluid of dispersion medium.The optimum formula of this cutting fluid is: sodium laurylsulfonate 0.22～0.30%, OP-10 0.22～0.30%, alcohol (＞95%) 1.5～2.0%, five sodium-chlor 0.08～0.1%, Sodium Benzoate and Sodium Nitrite each 0.04～0.05%, Sodium hexametaphosphate 99, sodium metaborate 0～0.6%, modified acrylate resin emulsion (solid content 26%) 8～10%, this cutting fluid has excellent lubrication, thermal conductivity, temperature tolerance and cleaning performance.
Description
The present invention relates to metalworking coolant, relating in particular to water is the non-oiliness cutting fluid of dispersion medium.
In the metalwork machining,, must use the metal working fluid that can play lubricated and cooling effect for precision and the work-ing life bright and clean, that prolong cutlery that guarantees workpiece surface.Before the eighties, the metal working fluid of use is low viscous machine oil or through the emulsive oily emulsion, these cutting fluids have needed cooling of metal machining and lubricant effect mostly, only its insufficient be the cost height, environmental pollution is serious.After entering the eighties, the non-oily emulsion type cutting fluid that with water is dispersion medium is come out successively, this class cutting fluid is main composition with water all, and contain lubricant (emulsifying agent), refractory agent, rust-preventive agent, process performances such as needed cooling, lubricated, cleaning so have metal mechanical cutting, and stable performance, cost is also cheap than oily emulsion.This class emulsion-type cutting fluid, because of its composition difference, thus the cutting fluid of formation kind.
The present invention aims to provide a kind of machining property excellence, good, the lower-cost non-oleaginous emulsion-type metal working fluid of rustless property.
The present invention realizes above-mentioned purpose like this:
Lubricant emulsion in this metal cutting fluid is a sodium laurylsulfonate, Sodium dodecylbenzene sulfonate, alkylbenzene polyethers sodium sulfonate, any one the simplification compound in sodium lauryl sulphate and the Dodecyl Mercaptan or the mixture of any several compounds and OP-10(are dodecyl phenol bull's eye oxidative ethane) mixture formed, the mixture of above-mentioned any simplification compound or several compounds and the weight ratio of OP-10 were good with 1: 1, consider from price and performance synthesis, lubricant emulsion is with sodium laurylsulfonate and OP-10 mixed solution the best, the total weight percent of this two compound in cutting fluid is advisable with 0.45～0.6%, and the ratio of the two is advisable with 1: 0.8～1.2.
The mixed type rust-preventive agent that rust-preventive agent in this cutting fluid is made up of sodium pentachlorophenate, Sodium Benzoate, Sodium Nitrite, the ratio of above-mentioned three compounds were good with 2: 1: 1; Then effect is better for the Sodium hexametaphosphate 99 of its total amount 10～25% of adding or sodium metaborate or its mixture in this mixed type rust-preventive agent.This mixed type rust-preventive agent is advisable with 1/1000th～2 at the total content of cutting fluid.
Refractory agent in this cutting fluid is with the modification acrylate resin emulsion of the polyvinyl acetal thing solution that hangs down degree of acetalization with the emulsion modified gained of acrylic resin.The content of this resin emulsion (solid content is 23～35%) is advisable with 6～12%.In order to improve the dispersiveness of resin emulsion and emulsifying agent, preferably add alcohol, the content of alcohol in cutting fluid is advisable with 1.0～2.5%.All the other are water.
The optimum formula of this cutting fluid is as follows:
Sodium laurylsulfonate 0.22～0.30%
OP-10 0.22～0.30%
Alcohol (〉=95%) 1.5～2.0%
Sodium pentachlorophenate 0.08～0.1%
Sodium Benzoate 0.04～0.05%
Sodium Nitrite 0.04～0.05%
Sodium hexametaphosphate 99, sodium metaborate 0～0.6%
Modified acrylate resin emulsion (solid content is in 26 ± 1%)
8～10%
All the other are water
The preparation method is as follows:
In still, add entry, add sodium laurylsulfonate and OP-10, under agitation condition, be warming up to 60 ℃, add mixed type rust-preventive agent, lower the temperature after 0.5 hour 60 ℃ of following insulated and stirred, when being cooled to 20～25 ℃, add alcohol, modified acrylate resin emulsion, continue to stir 0.5 hour metal working fluid.The cutting fluid of above-mentioned prescription is general commonly used, and available in case of necessity 1.5 times are used with interior water dilution; Be convenient transportation, can be made into the concentrated solution of above-mentioned prescription cutting fluid.
This metal cutting fluid has good lubricant, good thermal diffusivity and thermotolerance, and stronger degreasing cleaning performance is arranged, and has package stability and anti-freezing property preferably.Be applicable to the machining of multiple metal, especially ferrous metal, respond well, cost is lower.
Claims (3)
1, a kind of lubricant (emulsifying agent) that contains, refractory agent, the non-oily emulsion shaped metal cutting fluid of rust-preventive agent, it is characterized in that: the lubricant emulsion that Ben Qie disappears in the liquid is a sodium laurylsulfonate, Sodium dodecylbenzene sulfonate, alkylbenzene polyethers sodium sulfonate, the mixture that any one the simplification compound in sodium lauryl sulphate and the Dodecyl Mercaptan or the mixture of any several compounds and OP-10 (being dodecyl phenol+oxyethane) form, the mixture of above-mentioned any simplification compound or several compounds and the weight ratio of OP-10 were good with 1: 1, consider from price and performance synthesis, lubricant emulsion is with sodium laurylsulfonate and OP-10 mixed solution the best, the total weight percent of this two compound in cutting fluid is advisable with 0.45～0.6%, and the ratio of the two is advisable with 1: 0.8～1.2; The mixed type rust-preventive agent that rust-preventive agent in this cutting fluid is made up of sodium pentachlorophenate, Sodium Benzoate, Sodium Nitrite, the ratio of above-mentioned three compounds was good with 2: 1: 1, then effect is better for the Sodium hexametaphosphate 99 of its total amount 10～25% of adding or sodium metaborate or its mixture in this mixed type rust-preventive agent, and this mixed type rust-preventive agent is advisable with 1/1000th～2 at the total content of cutting fluid; Refractory agent in this cutting fluid is with the modification acrylate resin emulsion of the polyvinyl acetal thing solution that hangs down degree of acetalization with the emulsion modified gained of acrylic resin.The content of this resin emulsion (solid content is 23～35%) is advisable with 6～12%.In order to improve the dispersiveness of resin emulsion and emulsifying agent, preferably add alcohol, the content of alcohol in cutting fluid is advisable with 1.0～2.5%, and all the other are water.
2, metal working fluid according to claim 1 is characterized in that:
The optimum formula of this cutting fluid is as follows:
Sodium laurylsulfonate 0.22～0.30%
OP-10 0.22～0.30%
Alcohol (＞95%) 1.5～2.0%
Sodium pentachlorophenate 0.08～0.1%
Sodium Benzoate 0.04～0.05%
Sodium Nitrite 0.04～0.05%
Sodium hexametaphosphate 99, sodium metaborate 0～0.6%
Modified acrylate resin emulsion (solid content is in 26 ± 1%)
8～10%
All the other are water
3, metal working fluid according to claim 1 and 2 is characterized in that: the cutting fluid of above-mentioned prescription is general commonly used, and available in case of necessity 1.5 times are used with interior water dilution; Be convenient transportation, can be made into the concentrated solution of above-mentioned prescription cutting fluid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 90104338 CN1057478A (en) | 1990-06-22 | 1990-06-22 | Metal working fluid |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 90104338 CN1057478A (en) | 1990-06-22 | 1990-06-22 | Metal working fluid |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1057478A true CN1057478A (en) | 1992-01-01 |
Family
ID=4878519
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 90104338 Pending CN1057478A (en) | 1990-06-22 | 1990-06-22 | Metal working fluid |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1057478A (en) |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1045309C (en) * | 1993-11-23 | 1999-09-29 | 辛辛那提米勒克朗公司 | Sulfurized aqueous machining fluid composition |
| CN1051571C (en) * | 1995-03-09 | 2000-04-19 | 阿克佐诺贝尔公司 | Use of a betaine surfactant together with an anionic surfactant as a drag-reducing agent |
| CN100506519C (en) * | 2002-11-21 | 2009-07-01 | 三菱综合材料Pmg株式会社 | Method for forming compact from powder and metal mold apparatus for powder forming |
| CN100516184C (en) * | 2003-03-24 | 2009-07-22 | 三洋化成工业株式会社 | Lubricant for water-miscible metal working oil |
| US8153053B2 (en) | 2002-11-21 | 2012-04-10 | Diamet Corporation | Method for forming compact from powder and sintered product |
| CN102604728A (en) * | 2012-02-17 | 2012-07-25 | 苏州铱诺化学材料有限公司 | Environment-friendly emulsified cutting fluid and method for preparing same |
| CN101955837B (en) * | 2004-02-25 | 2012-10-10 | 出光兴产株式会社 | Alkyl acetal compound, process for producing the same, and lubricating oil composition |
| CN102899150A (en) * | 2012-09-28 | 2013-01-30 | 上海群乐船舶附件启东有限公司 | Metal cutting fluid |
| CN103025486A (en) * | 2010-08-03 | 2013-04-03 | 尤希路化学工业有限公司 | Aqueous processing solution for fixed abresive grain wire saw |
| CN103396864A (en) * | 2010-06-25 | 2013-11-20 | 张红雨 | Metal cutting fluid |
| CN103882445A (en) * | 2014-02-25 | 2014-06-25 | 安徽拓普森电池有限责任公司 | Rust-removal and rust-proof liquor capable of being coated and preparation method thereof |
| CN107523402A (en) * | 2017-09-11 | 2017-12-29 | 苏州艾乐蒙特机电科技有限公司 | A kind of metalworking fluid |
-
1990
- 1990-06-22 CN CN 90104338 patent/CN1057478A/en active Pending
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1045309C (en) * | 1993-11-23 | 1999-09-29 | 辛辛那提米勒克朗公司 | Sulfurized aqueous machining fluid composition |
| CN1051571C (en) * | 1995-03-09 | 2000-04-19 | 阿克佐诺贝尔公司 | Use of a betaine surfactant together with an anionic surfactant as a drag-reducing agent |
| CN100506519C (en) * | 2002-11-21 | 2009-07-01 | 三菱综合材料Pmg株式会社 | Method for forming compact from powder and metal mold apparatus for powder forming |
| US8153053B2 (en) | 2002-11-21 | 2012-04-10 | Diamet Corporation | Method for forming compact from powder and sintered product |
| CN100516184C (en) * | 2003-03-24 | 2009-07-22 | 三洋化成工业株式会社 | Lubricant for water-miscible metal working oil |
| CN101955837B (en) * | 2004-02-25 | 2012-10-10 | 出光兴产株式会社 | Alkyl acetal compound, process for producing the same, and lubricating oil composition |
| CN103396864A (en) * | 2010-06-25 | 2013-11-20 | 张红雨 | Metal cutting fluid |
| CN103025486A (en) * | 2010-08-03 | 2013-04-03 | 尤希路化学工业有限公司 | Aqueous processing solution for fixed abresive grain wire saw |
| CN102604728A (en) * | 2012-02-17 | 2012-07-25 | 苏州铱诺化学材料有限公司 | Environment-friendly emulsified cutting fluid and method for preparing same |
| CN102604728B (en) * | 2012-02-17 | 2014-10-29 | 苏州铱诺化学材料有限公司 | Environment-friendly emulsified cutting fluid and method for preparing same |
| CN102899150A (en) * | 2012-09-28 | 2013-01-30 | 上海群乐船舶附件启东有限公司 | Metal cutting fluid |
| CN103882445A (en) * | 2014-02-25 | 2014-06-25 | 安徽拓普森电池有限责任公司 | Rust-removal and rust-proof liquor capable of being coated and preparation method thereof |
| CN107523402A (en) * | 2017-09-11 | 2017-12-29 | 苏州艾乐蒙特机电科技有限公司 | A kind of metalworking fluid |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C01 | Deemed withdrawal of patent application (patent law 1993) | ||
| WD01 | Invention patent application deemed withdrawn after publication |