CN1056167C - Aerosol type dirty-cleaning and glazing protective agent cantaining high molecular component - Google Patents
Aerosol type dirty-cleaning and glazing protective agent cantaining high molecular component Download PDFInfo
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- CN1056167C CN1056167C CN96120220A CN96120220A CN1056167C CN 1056167 C CN1056167 C CN 1056167C CN 96120220 A CN96120220 A CN 96120220A CN 96120220 A CN96120220 A CN 96120220A CN 1056167 C CN1056167 C CN 1056167C
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- 238000004140 cleaning Methods 0.000 title claims 3
- 239000003223 protective agent Substances 0.000 title description 9
- 239000000443 aerosol Substances 0.000 title description 2
- 239000002904 solvent Substances 0.000 claims abstract description 18
- 239000000463 material Substances 0.000 claims abstract description 16
- -1 polydimethylsiloxane Polymers 0.000 claims abstract description 10
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims abstract description 8
- 229920000642 polymer Polymers 0.000 claims abstract description 8
- 239000004205 dimethyl polysiloxane Substances 0.000 claims abstract description 7
- 238000005498 polishing Methods 0.000 claims abstract description 4
- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 claims description 7
- 229920002857 polybutadiene Polymers 0.000 claims description 6
- 229920002521 macromolecule Polymers 0.000 claims description 4
- 230000001681 protective effect Effects 0.000 claims description 3
- 239000003112 inhibitor Substances 0.000 claims 3
- 230000003068 static effect Effects 0.000 claims 3
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 claims 2
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims 1
- 229920001971 elastomer Polymers 0.000 claims 1
- 150000002888 oleic acid derivatives Chemical class 0.000 claims 1
- 229920001195 polyisoprene Polymers 0.000 claims 1
- 239000005060 rubber Substances 0.000 claims 1
- 239000000600 sorbitol Substances 0.000 claims 1
- 238000005202 decontamination Methods 0.000 abstract description 17
- 230000003588 decontaminative effect Effects 0.000 abstract description 17
- 239000003502 gasoline Substances 0.000 abstract description 11
- 239000000203 mixture Substances 0.000 abstract description 11
- 239000002861 polymer material Substances 0.000 abstract description 11
- 239000002216 antistatic agent Substances 0.000 abstract description 6
- 239000010410 layer Substances 0.000 abstract description 5
- 239000010985 leather Substances 0.000 abstract description 4
- 239000011241 protective layer Substances 0.000 abstract description 4
- 229910052751 metal Inorganic materials 0.000 abstract description 3
- 239000002184 metal Substances 0.000 abstract description 3
- 229920002050 silicone resin Polymers 0.000 abstract description 3
- 238000005507 spraying Methods 0.000 abstract description 3
- 150000002739 metals Chemical class 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 10
- 230000000694 effects Effects 0.000 description 4
- 229920003049 isoprene rubber Polymers 0.000 description 4
- 239000012188 paraffin wax Substances 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 150000001335 aliphatic alkanes Chemical class 0.000 description 3
- 239000003963 antioxidant agent Substances 0.000 description 3
- 239000010408 film Substances 0.000 description 3
- 229940051841 polyoxyethylene ether Drugs 0.000 description 3
- 229920000056 polyoxyethylene ether Polymers 0.000 description 3
- 229920006395 saturated elastomer Polymers 0.000 description 3
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 2
- 239000004265 EU approved glazing agent Substances 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 2
- 238000009924 canning Methods 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229940057995 liquid paraffin Drugs 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 239000003380 propellant Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920002545 silicone oil Polymers 0.000 description 2
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000001993 wax Substances 0.000 description 2
- 239000000020 Nitrocellulose Substances 0.000 description 1
- 229920001214 Polysorbate 60 Polymers 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- PRXRUNOAOLTIEF-ADSICKODSA-N Sorbitan trioleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](OC(=O)CCCCCCC\C=C/CCCCCCCC)[C@H]1OC[C@H](O)[C@H]1OC(=O)CCCCCCC\C=C/CCCCCCCC PRXRUNOAOLTIEF-ADSICKODSA-N 0.000 description 1
- 239000004147 Sorbitan trioleate Substances 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000004203 carnauba wax Substances 0.000 description 1
- 235000013869 carnauba wax Nutrition 0.000 description 1
- 239000003818 cinder Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000000686 essence Substances 0.000 description 1
- 125000005456 glyceride group Chemical group 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 235000019337 sorbitan trioleate Nutrition 0.000 description 1
- 229960000391 sorbitan trioleate Drugs 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
本发明涉及一种基于非蜡物质的抛光组合物。由聚二甲基硅氧烷6～9份、抗静电剂0.8～1.2份、香精0.2份、溶剂汽油80～90份及高分子材料溶液3～6份组成。经喷涂去污后的材料表面不仅能形成一层光亮的有机硅树脂薄，还能形成一层具韧性和弹性的高分子保护层，并对材料表面微小损伤及擦痕有填平、修补作用，达到去污、上光、保护一次完成的目的。适用于车辆、皮革、家具、家用电器、电镀件及金属等材料表面去污、上光、保护。The present invention relates to a polishing composition based on a non-waxy substance. It consists of 6-9 parts of polydimethylsiloxane, 0.8-1.2 parts of antistatic agent, 0.2 part of essence, 80-90 parts of solvent gasoline and 3-6 parts of polymer material solution. The surface of the material after spraying and decontamination can not only form a layer of bright silicone resin, but also form a layer of tough and elastic polymer protective layer, and can fill and repair the small damage and scratches on the surface of the material , to achieve the purpose of decontamination, glazing and protection at one time. It is suitable for decontamination, glazing and protection on the surface of vehicles, leather, furniture, household appliances, electroplated parts and metals.
Description
本发明涉及一种基于非蜡物质的抛光组合物。The present invention relates to a polishing composition based on a non-waxy substance.
本发明为一种气雾剂型，适用于车辆、皮革、家具、家用电器、电镀件及金属等材料表面的去污、上光、保护剂。The invention is an aerosol formulation, which is suitable for decontamination, glazing and protective agent on the surfaces of vehicles, leather, furniture, household appliances, electroplated parts and metals.
目前专利及文献中所报道的去污、上光剂的主要成份为：溶剂汽油、聚二甲基硅氧烷、液体石蜡、抗静电剂、香精等。如CN1044113A专利申请公开了一种“防霉防锈上光保护剂及制造工艺”，系由30～50％(重量份)高分子化合物、5～8％抗氧剂、4～8％防护剂、58～61％溶剂组成；采用搅拌、加温(60～80℃)、冷却等制造工艺。产品可喷涂于皮革、金属、木制品等表面，起到防霉、防锈、上光保护作用。但没有说明高分子化合物、抗氧剂、防护剂及溶剂的具体成份。The main components of the decontamination and glazing agents reported in current patents and documents are: solvent gasoline, polydimethylsiloxane, liquid paraffin, antistatic agent, essence, etc. Such as CN1044113A patent application discloses a kind of " anti-mildew and anti-rust glazing protective agent and manufacturing process ", be by 30～50% (weight part) macromolecule compound, 5～8% antioxidant, 4～8% protective agent , 58 ~ 61% solvent composition; using stirring, heating (60 ~ 80 ℃), cooling and other manufacturing processes. The product can be sprayed on the surface of leather, metal, wood products, etc., to play the role of anti-mildew, anti-rust, and glazing protection. However, the specific ingredients of polymer compounds, antioxidants, protective agents and solvents are not specified.
专利申请CN1109490A公开了一种“多用途去污上光剂”，其特征在于组成中含有1～70％(重量份)的树脂(如松香衍生物，酚醛树脂，聚酰胺，醇酸树脂，聚氨酯树脂，聚酰，硝基纤维素等)和能够使树脂溶解的溶剂30～99％，含石蜡0～40％，助分散剂0～35％，表面活性剂0～15％，芳香剂1～3％。给出了四个实施例，其中实施例3为溶剂型的配方：顺丁烯二酸酐松香甘油酯60％，200号溶剂汽油35％，硅油1％，石蜡4％。但在其实施例1、2、4中出现了丁酮、醋酸乙酯等溶解性极强的有机溶剂，在起到去污作用的同时，会对材料表面的漆膜起到破坏作用，会使皮革退色及增塑剂被抽出而变硬。Patent application CN1109490A discloses a "multipurpose decontamination glazing agent", which is characterized in that the composition contains 1 to 70% (parts by weight) of resins (such as rosin derivatives, phenolic resins, polyamides, alkyd resins, polyurethane Resin, polyamide, nitrocellulose, etc.) and 30-99% solvent capable of dissolving resin, 0-40% paraffin, 0-35% auxiliary dispersant, 0-15% surfactant, 1-10% fragrance 3%. Four examples are given, wherein Example 3 is a solvent-based formula: maleic anhydride rosin glyceride 60%, No. 200 solvent gasoline 35%, silicone oil 1%, paraffin 4%. But in its embodiment 1, 2, 4, there are extremely strong organic solvents such as methyl ethyl ketone and ethyl acetate, which will destroy the paint film on the surface of the material while playing a decontamination effect. The leather fades and the plasticizer is extracted and hardened.
专利申请CN1049676A公开了一种“多功能去污上光剂”，应用高分子化学反应、水解产生去污作用，同时生成致密性薄膜光亮层。这是一种在被处理表面进行化学反应而产生去污、上光作用的保护剂。与通常由物理混合而制得的去污、上光剂有一定的差别。Patent application CN1049676A discloses a "multifunctional decontamination glazing agent", which uses polymer chemical reaction and hydrolysis to produce decontamination, and at the same time forms a dense thin film bright layer. This is a protective agent that undergoes chemical reactions on the treated surface to produce decontamination and glazing effects. It is different from decontamination and glazing agents which are usually prepared by physical mixing.
CN1061234A专利申请公开了一种“透明的液体去污上光蜡”，系由硅油、液状石蜡及使上述两者互溶的促进剂组成，具有去污、上光之功能，但对材料表面的保护效果不佳。CN1061234A patent application discloses a "transparent liquid decontamination and glazing wax", which is composed of silicone oil, liquid paraffin and an accelerator that makes the above two mutually soluble. It has the functions of decontamination and glazing, but the protection of the material surface not effectively.
CN1108283A专利申请公开了一种“机动车外壳增效复光液”，系由5份(重量)巴西棕榈蜡，1.5份辛基酚聚氧乙烯醚，1份十八烷醇聚氧乙烯醚，0.5份十二烷基硫酸钠，1份白油及0.2份100目煤渣经特殊工艺精制而成。是一种糊状表面抛光剂。CN1108283A patent application discloses a "motor vehicle shell synergistic restoration liquid", which is composed of 5 parts (by weight) of carnauba wax, 1.5 parts of octylphenol polyoxyethylene ether, 1 part of stearyl polyoxyethylene ether, 0.5 parts of sodium lauryl sulfate, 1 part of white oil and 0.2 parts of 100-mesh cinder are refined by special process. Is a paste surface polish.
中国专利申请：GK85106004、GK87101866、CN1030781A、CN1046747A、CN1051577A、CN1053078A、CN1059923A、CN1087660A、CN1087363A、CN1105691A、CN1102656A、CN1112151A、CN1103422A、CN1094077A、CN1096529A、CN1108284A等还公开了一系列乳液型去污、上光剂，某些配方中含有低分子量的蜡成份也有一定的保护作用，但具有遇水白浊化，成膜性差，难以形成高分子保护层。中国专利申请：GK85106004、GK87101866、CN1030781A、CN1046747A、CN1051577A、CN1053078A、CN1059923A、CN1087660A、CN1087363A、CN1105691A、CN1102656A、CN1112151A、CN1103422A、CN1094077A、CN1096529A、CN1108284A等还公开了一系列乳液型去污、上光剂， Some formulations contain low molecular weight wax components that also have a certain protective effect, but they have white turbidity when exposed to water, poor film-forming properties, and it is difficult to form a polymer protective layer.
本发明的目的旨在提供一种在组分中添加特殊高分子材料的去污、上光、保护剂，可使喷涂去污后的材料表面不仅形成一层光亮的有机硅树脂膜，还形成一层具韧性和弹性的高分子保护层。The purpose of the present invention is to provide a decontamination, glazing, and protective agent that adds special polymer materials to the components, so that the surface of the material after spraying and decontamination can not only form a layer of bright silicone resin film, but also form a protective agent. A tough and elastic polymer protective layer.
本发明是一类含有具备弹性、韧性、成膜性的高分子材料的溶剂型去污、上光、保护剂。其组成及含量为(重量份)：The invention is a kind of solvent-based decontamination, glazing and protective agent containing polymer materials with elasticity, toughness and film-forming properties. Its composition and content are (parts by weight):
6～10％高分子材料溶液 3～6份6～10% polymer material solution 3～6 parts
抗静电剂 0.8～1.2份Antistatic agent 0.8～1.2 parts
聚二甲基硅氧烷 6～9份
香精 0.2份Fragrance 0.2 parts
溶剂汽油 80～90份Solvent gasoline 80～90 parts
以C3～4饱和烷烃为抛射剂罐装。Canned with C 3~4 saturated alkanes as propellants.
其中6～10％高分子材料溶液为以溶剂汽油为溶剂，含6～10％高分子材料及含有占高分子材料重量1.2％的对苯二酚，所说的高分子材料为聚丁二烯橡胶(PB)或异戊橡胶(CIR)或苯乙烯-丁二烯-苯乙烯嵌段共聚物(SBS)。抗静电剂为聚氧乙烯山梨醇六油酸酯(Atlas G1086)或失水山梨醇三油酸酯聚氧乙烯醚(E020，Tween85)。Wherein 6-10% polymer material solution is solvent gasoline as solvent, contains 6-10% polymer material and contains hydroquinone accounting for 1.2% of polymer material weight, and said polymer material is polybutadiene rubber (PB) or isoprene rubber (CIR) or styrene-butadiene-styrene block copolymer (SBS). The antistatic agent is polyoxyethylene sorbitan hexaoleate (Atlas G1086) or sorbitan trioleate polyoxyethylene ether (E020, Tween85).
本发明通过添加特殊的具弹性、韧性及成膜性的高分子材料，如聚丁二烯橡胶(PB)、异戊橡胶(CIR)或苯乙烯-丁二烯-苯乙烯嵌段共聚物(SBS)及抗氧剂，克服了聚二甲基硅氧烷仅具上光、隔离作用，对材料表面物理保护作用极小的弱点，喷涂去污后的材料表面经擦拭，不仅能形成一层光亮的有机硅树脂膜，还能形成一层具韧性和弹性的高分子保护层，光亮度不降低，并且对材料表面微小的损伤及擦痕有填平、修补作用。添加了本发明所指的高分子材料后，可在组成中去除石蜡组分，克服了石蜡通水出现白浊化的问题。达到了去污、上光、保护一次完成的目的。The present invention adds special elastic, tough and film-forming polymer materials, such as polybutadiene rubber (PB), isoprene rubber (CIR) or styrene-butadiene-styrene block copolymer ( SBS) and antioxidants overcome the weakness that polydimethylsiloxane only has glazing and isolation effects, and has little physical protection effect on the surface of the material. After spraying and decontaminating the surface of the material, it can not only form a layer The bright silicone resin film can also form a tough and elastic polymer protective layer without reducing the brightness, and it can fill and repair the small damage and scratches on the surface of the material. After the polymer material referred to in the present invention is added, the paraffin component can be removed from the composition, and the problem of white turbidity of the paraffin through water is overcome. The purpose of decontamination, glazing and protection is achieved at one time.
下面通过实施例对本发明作进一步说明。Below by embodiment the present invention will be further described.
实施例一：Embodiment one:
首先于89.88g溶剂汽油中加入聚丁二烯橡胶10g，对苯二酚0.12g，搅拌溶解后备用。First, 10 g of polybutadiene rubber and 0.12 g of hydroquinone were added to 89.88 g of solvent gasoline, stirred and dissolved for later use.
在87g溶剂汽油中加入上述溶液3g，混合均匀后，激烈搅拌下缓慢加入抗静电剂Atlas G1086 0.8g，聚二甲基硅氧烷9g，香精0.2g，混合均匀后以C3～4饱和烷烃为抛射剂装罐。Add 3g of the above solution to 87g of solvent gasoline, mix well, slowly add antistatic agent Atlas G1086 0.8g, polydimethylsiloxane 9g, essence 0.2g under vigorous stirring, mix well and add C 3-4 saturated alkane Canning the propellant.
实施例二：Embodiment two:
配制其中含有相SBS重量的1.2％对苯二酚的8％ SBS的溶剂汽油溶液备用。Prepare the solvent gasoline solution of 8% SBS containing 1.2% hydroquinone of relative SBS weight wherein for subsequent use.
在86.8g溶剂汽油中加入聚二甲基硅氧烷8g，Tween85 1.0g，搅拌均匀后，加入上述备用溶液4g及香精0.2g，充分混合均匀后，以C3～4饱和烷烃为抛射剂装罐。Add 8g of polydimethylsiloxane and 1.0g of Tween85 to 86.8g of solvent gasoline. After stirring evenly, add 4g of the above-mentioned spare solution and 0.2g of essence. Can.
实施例三：Embodiment three:
配制其中含有相对异戊橡胶重量的1.2％对苯二酚的6％异戊橡胶的溶剂汽油溶液备用。A solvent gasoline solution of 6% isoprene rubber containing 1.2% hydroquinone relative to the weight of isoprene rubber was prepared for subsequent use.
在86.6g溶剂汽油中加入上述备用溶液6g，抗静电剂Atlas G1086 1.2g搅拌均匀后加入聚二甲基硅氧烷6g及香精0.2g，充分混合均匀后即可以C3～4饱和烷烃为抛射剂装罐。Add 6g of the above-mentioned spare solution to 86.6g of solvent gasoline, 1.2g of antistatic agent Atlas G1086 and stir well, then add 6g of polydimethylsiloxane and 0.2g of essence, mix well and then use C 3-4 saturated alkane as the projectile Canning.
实施例四～六：制备方法、条件同实施例一。
*其中含有占高分子材料重量1.2％的对苯二酚。*Contains 1.2% hydroquinone by weight of polymer material.
Claims (2)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN96120220A CN1056167C (en) | 1996-10-21 | 1996-10-21 | Aerosol type dirty-cleaning and glazing protective agent cantaining high molecular component |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN96120220A CN1056167C (en) | 1996-10-21 | 1996-10-21 | Aerosol type dirty-cleaning and glazing protective agent cantaining high molecular component |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1152596A CN1152596A (en) | 1997-06-25 |
| CN1056167C true CN1056167C (en) | 2000-09-06 |
Family
ID=5126191
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN96120220A Expired - Fee Related CN1056167C (en) | 1996-10-21 | 1996-10-21 | Aerosol type dirty-cleaning and glazing protective agent cantaining high molecular component |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1056167C (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101942666A (en) * | 2010-06-08 | 2011-01-12 | 季斌 | Stainless steel cleaning solution |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6749673B2 (en) * | 2002-11-08 | 2004-06-15 | S. C. Johnson & Son, Inc. | Biliquid foam furniture polish |
| CN102702982A (en) * | 2012-05-24 | 2012-10-03 | 浙江东化实业有限公司 | Full grain leather polishing mending cream |
| CN103666284A (en) * | 2013-11-22 | 2014-03-26 | 南通信一服饰有限公司 | Waterproof wear-resisting leather clothing brightener |
| CN106190622A (en) * | 2016-07-01 | 2016-12-07 | 陈小女 | A kind of aerial fog type car shampoo |
| CN106634618A (en) * | 2016-11-30 | 2017-05-10 | 湖州练市双龙木业有限公司 | Insect prevention furniture glazing agent and preparation method thereof |
| CN107974203A (en) * | 2017-12-05 | 2018-05-01 | 彭献良 | A kind of shoe polish and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1109490A (en) * | 1994-03-31 | 1995-10-04 | 广东省测试分析研究所 | Multipurpose dirt removing and polishing agent |
-
1996
- 1996-10-21 CN CN96120220A patent/CN1056167C/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1109490A (en) * | 1994-03-31 | 1995-10-04 | 广东省测试分析研究所 | Multipurpose dirt removing and polishing agent |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101942666A (en) * | 2010-06-08 | 2011-01-12 | 季斌 | Stainless steel cleaning solution |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1152596A (en) | 1997-06-25 |
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