CN1056032C - High-effective oil suspended mixture for killing mites and pests - Google Patents
High-effective oil suspended mixture for killing mites and pests Download PDFInfo
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- CN1056032C CN1056032C CN95109265A CN95109265A CN1056032C CN 1056032 C CN1056032 C CN 1056032C CN 95109265 A CN95109265 A CN 95109265A CN 95109265 A CN95109265 A CN 95109265A CN 1056032 C CN1056032 C CN 1056032C
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- suspension mixture
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- oil
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- oily suspension
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- 239000000203 mixture Substances 0.000 title claims abstract description 20
- 241000238876 Acari Species 0.000 title claims abstract description 7
- 241000607479 Yersinia pestis Species 0.000 title claims abstract description 7
- 239000003986 organophosphate insecticide Substances 0.000 claims abstract description 9
- 239000012053 oil suspension Substances 0.000 claims abstract description 8
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 18
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 11
- 238000010298 pulverizing process Methods 0.000 claims description 9
- HVLLSGMXQDNUAL-UHFFFAOYSA-N triphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)OC1=CC=CC=C1 HVLLSGMXQDNUAL-UHFFFAOYSA-N 0.000 claims description 8
- 239000002904 solvent Substances 0.000 claims description 7
- 239000000725 suspension Substances 0.000 claims description 7
- 239000004215 Carbon black (E152) Substances 0.000 claims description 6
- 239000004359 castor oil Substances 0.000 claims description 6
- 235000019438 castor oil Nutrition 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 6
- 229930195733 hydrocarbon Natural products 0.000 claims description 6
- 150000002430 hydrocarbons Chemical class 0.000 claims description 6
- 150000004885 piperazines Chemical class 0.000 claims description 6
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 6
- 239000004094 surface-active agent Substances 0.000 claims description 6
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 6
- 239000008158 vegetable oil Substances 0.000 claims description 6
- 239000003381 stabilizer Substances 0.000 claims description 5
- -1 styryl phenol formaldehyde resin Chemical compound 0.000 claims description 5
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 4
- KRTSDMXIXPKRQR-AATRIKPKSA-N monocrotophos Chemical compound CNC(=O)\C=C(/C)OP(=O)(OC)OC KRTSDMXIXPKRQR-AATRIKPKSA-N 0.000 claims description 4
- 239000003921 oil Substances 0.000 claims description 4
- 235000019198 oils Nutrition 0.000 claims description 4
- 239000004576 sand Substances 0.000 claims description 4
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 3
- 239000000642 acaricide Substances 0.000 claims description 3
- 229960000892 attapulgite Drugs 0.000 claims description 3
- 229910000278 bentonite Inorganic materials 0.000 claims description 3
- 239000000440 bentonite Substances 0.000 claims description 3
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 3
- 239000002131 composite material Substances 0.000 claims description 3
- OEBRKCOSUFCWJD-UHFFFAOYSA-N dichlorvos Chemical compound COP(=O)(OC)OC=C(Cl)Cl OEBRKCOSUFCWJD-UHFFFAOYSA-N 0.000 claims description 3
- MCWXGJITAZMZEV-UHFFFAOYSA-N dimethoate Chemical compound CNC(=O)CSP(=S)(OC)OC MCWXGJITAZMZEV-UHFFFAOYSA-N 0.000 claims description 3
- 229910052625 palygorskite Inorganic materials 0.000 claims description 3
- 229920001568 phenolic resin Polymers 0.000 claims description 3
- 229920000570 polyether Polymers 0.000 claims description 3
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- XJFIKRXIJXAJGH-UHFFFAOYSA-N 5-chloro-1,3-dihydroimidazo[4,5-b]pyridin-2-one Chemical group ClC1=CC=C2NC(=O)NC2=N1 XJFIKRXIJXAJGH-UHFFFAOYSA-N 0.000 claims description 2
- 239000005945 Chlorpyrifos-methyl Substances 0.000 claims description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 2
- 239000004202 carbamide Substances 0.000 claims description 2
- 229950001327 dichlorvos Drugs 0.000 claims description 2
- 239000006185 dispersion Substances 0.000 claims description 2
- 238000000227 grinding Methods 0.000 claims description 2
- NNKVPIKMPCQWCG-UHFFFAOYSA-N methamidophos Chemical compound COP(N)(=O)SC NNKVPIKMPCQWCG-UHFFFAOYSA-N 0.000 claims description 2
- 238000003801 milling Methods 0.000 claims description 2
- PZXOQEXFMJCDPG-UHFFFAOYSA-N omethoate Chemical compound CNC(=O)CSP(=O)(OC)OC PZXOQEXFMJCDPG-UHFFFAOYSA-N 0.000 claims description 2
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 2
- FITIWKDOCAUBQD-UHFFFAOYSA-N prothiofos Chemical compound CCCSP(=S)(OCC)OC1=CC=C(Cl)C=C1Cl FITIWKDOCAUBQD-UHFFFAOYSA-N 0.000 claims description 2
- AMFGTOFWMRQMEM-UHFFFAOYSA-N triazophos Chemical compound N1=C(OP(=S)(OCC)OCC)N=CN1C1=CC=CC=C1 AMFGTOFWMRQMEM-UHFFFAOYSA-N 0.000 claims description 2
- 238000005516 engineering process Methods 0.000 claims 2
- QVMHUALAQYRRBM-UHFFFAOYSA-N [P].[P] Chemical compound [P].[P] QVMHUALAQYRRBM-UHFFFAOYSA-N 0.000 claims 1
- 150000001412 amines Chemical class 0.000 claims 1
- 238000010130 dispersion processing Methods 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 claims 1
- 229920000742 Cotton Polymers 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 4
- 239000005654 Clofentezine Substances 0.000 abstract description 3
- UXADOQPNKNTIHB-UHFFFAOYSA-N clofentezine Chemical compound ClC1=CC=CC=C1C1=NN=C(C=2C(=CC=CC=2)Cl)N=N1 UXADOQPNKNTIHB-UHFFFAOYSA-N 0.000 abstract description 3
- 244000144730 Amygdalus persica Species 0.000 abstract description 2
- 235000006040 Prunus persica var persica Nutrition 0.000 abstract description 2
- 230000002195 synergetic effect Effects 0.000 abstract description 2
- 230000001988 toxicity Effects 0.000 abstract 2
- 231100000419 toxicity Toxicity 0.000 abstract 2
- 244000141359 Malus pumila Species 0.000 abstract 1
- 241000219094 Vitaceae Species 0.000 abstract 1
- 235000021016 apples Nutrition 0.000 abstract 1
- 239000012736 aqueous medium Substances 0.000 abstract 1
- 235000013601 eggs Nutrition 0.000 abstract 1
- 235000021021 grapes Nutrition 0.000 abstract 1
- 230000002265 prevention Effects 0.000 abstract 1
- GLUUGHFHXGJENI-UHFFFAOYSA-N Piperazine Chemical compound C1CNCCN1 GLUUGHFHXGJENI-UHFFFAOYSA-N 0.000 description 22
- 239000000843 powder Substances 0.000 description 13
- 239000000375 suspending agent Substances 0.000 description 7
- 235000013877 carbamide Nutrition 0.000 description 5
- 150000003014 phosphoric acid esters Chemical class 0.000 description 5
- 102000002322 Egg Proteins Human genes 0.000 description 4
- 108010000912 Egg Proteins Proteins 0.000 description 4
- 241001597008 Nomeidae Species 0.000 description 4
- 239000010779 crude oil Substances 0.000 description 4
- 210000004681 ovum Anatomy 0.000 description 4
- 150000003672 ureas Chemical class 0.000 description 4
- 239000000470 constituent Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- 241000238631 Hexapoda Species 0.000 description 2
- 241000344246 Tetranychus cinnabarinus Species 0.000 description 2
- 230000000895 acaricidal effect Effects 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 235000013399 edible fruits Nutrition 0.000 description 2
- 239000002917 insecticide Substances 0.000 description 2
- 230000002045 lasting effect Effects 0.000 description 2
- 239000012457 nonaqueous media Substances 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 239000000575 pesticide Substances 0.000 description 2
- 230000003449 preventive effect Effects 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 241000207199 Citrus Species 0.000 description 1
- 241000219146 Gossypium Species 0.000 description 1
- 241000220225 Malus Species 0.000 description 1
- 235000011430 Malus pumila Nutrition 0.000 description 1
- 235000015103 Malus silvestris Nutrition 0.000 description 1
- 244000170916 Paeonia officinalis Species 0.000 description 1
- 235000006484 Paeonia officinalis Nutrition 0.000 description 1
- 241000488581 Panonychus citri Species 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 235000009754 Vitis X bourquina Nutrition 0.000 description 1
- 235000012333 Vitis X labruscana Nutrition 0.000 description 1
- 240000006365 Vitis vinifera Species 0.000 description 1
- 235000014787 Vitis vinifera Nutrition 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 239000012872 agrochemical composition Substances 0.000 description 1
- 235000020971 citrus fruits Nutrition 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- YFVOXLJXJBQDEF-UHFFFAOYSA-N isocarbophos Chemical compound COP(N)(=S)OC1=CC=CC=C1C(=O)OC(C)C YFVOXLJXJBQDEF-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 239000002420 orchard Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 231100000820 toxicity test Toxicity 0.000 description 1
- 230000001018 virulence Effects 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to a high-efficiency oil suspension mixture for killing mites and pests. Clofentezine and organophosphorus insecticide are pulverized, homogenized and dispersed in a non-aqueous medium, and then the oil suspension mixture is prepared. The present invention has the strong toxicity of the added effects of the clofentezine and the organophosphorus insecticide to grown mites and has certain synergistic effect on the toxicity of mite eggs. The present invention is used for preventing harmful mites on crops, such as cotton, oranges, apples, grapes, peaches, etc., and the prevention efficiency reaches more than 90%; the oil suspension mixture has the characteristics of immediate effect and long effective period.
Description
The present invention relates to a kind of agrochemical composition, exactly is a kind of oil suspended mixture for killing mites and pests.
Four mite piperazines are selectivity miticides, and the Panonychus citri on the crops such as cotton, fruit tree is belonged to and children, effective as if mite and ovum, and the lasting period is long, but to becoming the mite weak effect, quick-acting is poor, to other insect nearly unavailable.The only effective to the one-tenth mite mostly of acaricidal action arranged in the organophosphorus insecticide, and to the ovum weak effect, the lasting period is also short, but has good quick-acting.Both are composite, have complementary advantages, be one of acaricidal approach of design ideal.
The objective of the invention is to provides a kind of desirable efficient mite mixture that kills by complex process for the mite pest of effectively killing in the crops.
Four mite piperazines are the former powder of solid, and are water insoluble, also are insoluble to most of organic solvents, generally are processed into suspending agent or wetting powder and are used for farmland and orchard.The phosphoric acid ester insecticide mostly is liquid crude greatly, can be dissolved in multiple organic solvent, but poor at water stability, very easily degraded.Therefore, oil-suspending agent is both composite optimal selections.Oil-suspending agent is the stable suspension system of high dispersive that one or more pesticide active ingredients (wherein having a kind of former medicine of solid that is at least) form in non-aqueous media.
The present invention realizes like this.
With former powder of four mite piperazines and part of auxiliary, solvent reaches the fineness (≤3 μ m) that suspends and require by ultra-fine grinding, this crushing process is finished in sand mill or sand milling still, clofentezine suspension agent after will pulverizing then is dispersed in the non-aqueous media (calling solvent in the following text) together with selected organophosphorus insecticide crude oil, surfactant, antisettling agent, stabilizing agent, and this dispersion process is finished in the homogeneous blender.
In oil suspension mixture, four mite piperazine active constituent contents are 5～25% (percentage by weights, down together), the organophosphorus insecticide active constituent content is 5～60%, and dosage of surfactant is 1～15%, and the antisettling agent consumption is 0.5～5%, stabilizing agent dosage is 0.5～2%, and surplus is a solvent.
Described organophosphorus insecticide is selected from a kind of insecticide in nuvacron, dichlorvos, omethoate, Rogor, Hostathion, isocarbophos, chlopyrifos, chlorpyrifos-methyl, Toyodan, the acephatemet, and total active constituent content is 5～60%.
Described surfactant can be one or both mixed surfactants in alkylbenzenesulfonate, castor oil polyoxyethylene ether, styryl phenyl APEO, the styryl phenol formaldehyde resin polyoxyethylene polyoxypropylene block co-polyether, and total consumption is 1～15%.
Described antisettling agent can be a kind of in white carbon, bentonite, the attapulgite, and consumption is 1～5%.
Described stabilizing agent can be a kind of in triphenyl phosphite, urea, the alkyl phosphoric acid ester derivative, and consumption is 0.5～2%.
Described solvent can be one or both mixed solvents in vegetable oil, senior fatty hydrocarbon ils, aromatic hydrocarbon, ethylene glycol, the glycerine.
The present invention's oil suspension mixture outward appearance is the peony suspending agent, and the physicochemical property of preparation and every technical indicator all meet the standard of relevant agricultural chemicals suspension agent.
The present invention's oil suspension mixture can be used for preventing and treating on the crops such as cotton, fruit tree the evil mite and can doublely control other insects.
Indoor toxicity test result to female one-tenth mite of Tetranychus cinnabarinus and ovum shows, four mite piperazines and organic phosphor desinsection miticide mix the summation action that act as each single agent that is paired into mite, but the virulence to the Tetranychus cinnabarinus ovum has certain synergistic effect, co-toxicity coefficient is between 138～245, changes to some extent along with the difference of organophosphorous pesticide and proportioning.
Field trial shows, oil-suspending agent of the present invention to the harmful mite on the crops such as cotton, citrus, apple, grape, peach have higher preventive effect, its preventive effect multipotency reaches more than 90%, and have very strong quick-acting and long lasting period.
Below be described in detail embodiments of the invention.
Embodiment 1:
Get 5.56 kilograms in the former powder of 90% 4 mite piperazine, 50 kilograms of 70% nuvacron crude oil, 5 kilograms of alkylbenzenesulfonate+castor oil polyoxyethylene ethers, 1 kilogram of white carbon, 0.5 kilogram of phosphoric acid ester derivant, 37.94 kilograms of ethylene glycol+vegetable oil disperse promptly to get product through pulverizing, homogenizing.
Embodiment 2:
Get 16.67 kilograms in the former powder of 90% 4 mite piperazine, 50 kilograms of 70% nuvacron crude oil, 8 kilograms of alkylbenzenesulfonate+castor oil polyoxyethylene ethers, 0.5 kilogram of white carbon, 0.5 kilogram of phosphoric acid ester derivant, 24.33 kilograms of ethylene glycol+vegetable oil disperse promptly to get product through pulverizing, homogenizing.
Embodiment 3:
Get 10 kilograms in the former powder of 90% 4 mite piperazine, 50 kilograms of 90% DDVP oils, 8 kilograms of alkylbenzenesulfonates+styryl phenyl APEO, 1.5 kilograms of white carbons, 0.5 kilogram of triphenyl phosphite, 30 kilograms of ethylene glycol+vegetable oil disperse promptly to get product through pulverizing, homogenizing.
Embodiment 4:
Get 11.11 kilograms in the former powder of 90% 4 mite piperazine, 42.86 kilograms of 70% omethoates, 7 kilograms of alkylbenzenesulfonates+styryl phenyl APEO, 0.5 kilogram of white carbon, 0.5 kilogram of phosphoric acid ester derivant, 38.03 kilograms of senior fatty hydrocarbon ils disperse promptly to get product through pulverizing, homogenizing.
Embodiment 5:
Get 8.89 kilograms in the former powder of 90% 4 mite piperazine, 40 kilograms of 80% isocarbophoses, 8 kilograms of castor oil polyoxyethylene ethers+styryl phenyl APEO, 1 kilogram of white carbon, 2 kilograms of ureas, 40.11 kilograms in aromatic hydrocarbon, through pulverize, homogenizing disperses promptly to get product.
Embodiment 6:
Get 8.89 kilograms in the former powder of 90% 4 mite piperazine, 42.67 kilograms of the former medicines of 75% chlopyrifos, 10 kilograms of alkylbenzenesulfonates+styryl phenyl APEO, 1 kilogram of white carbon, 2 kilograms of ureas, 35.44 kilograms in aromatic hydrocarbon, through pulverize, homogenizing disperses promptly to get product.
Embodiment 7:
Get 6.67 kilograms in the former powder of 90% 4 mite piperazine, 37.78 kilograms of 90% Rogor crude oil, 5 kilograms of alkylbenzenesulfonates+styryl phenyl APEO, 2 kilograms of white carbons, 1 kilogram of phosphoric acid ester derivant, 47.55 kilograms of senior fatty hydrocarbon ils disperse promptly to get product through pulverizing, homogenizing.
Embodiment 8:
Get 8.89 kilograms in the former powder of 90% 4 mite piperazine, 45.71 kilograms of 70% Toyodans, 7 kilograms of alkylbenzenesulfonates+styryl phenol formaldehyde resin polyoxyethylene polyoxypropylene block co-polyether, 2 kilograms of ureas, 2 kilograms of white carbons, 34.4 kilograms of senior fatty hydrocarbon ils disperse promptly to get product through pulverizing, homogenizing.
Embodiment 9:
Get 8.89 kilograms in the former powder of 90% 4 mite piperazine, 45.71 kilograms of 70% Hostathions, 6 kilograms of alkylbenzenesulfonates+styryl phenyl APEO, 2 kilograms of ureas, 1 kilogram of bentonite, 36.4 kilograms of senior fatty hydrocarbon ils, through pulverize, homogenizing disperses promptly to get product.
Embodiment 10:
Get 8.89 kilograms in the former powder of 90% 4 mite piperazine, 42.67 kilograms of 75% acephatemets, 6 kilograms of alkylbenzenesulfonate+castor oil polyoxyethylene ethers, 1 kilogram of attapulgite, 1 kilogram of triphenyl phosphite, 40.44 kilograms of ethylene glycol+vegetable oil disperse promptly to get product through pulverizing, homogenizing.
Claims (7)
1. oil suspended mixture for killing mites and pests is characterized in that: by miticide four mite piperazines and organophosphorus insecticide in solvent through pulverizing composite the forming of homogenizing dispersion processing technology,
(1) percentage by weight of each component is:
Four mite piperazines 5～25%
Organophosphorus insecticide 5～60%
Surfactant 1～15%
Antisettling agent 0.5～5%
Stabilizing agent 0.5～2%
Solvent complements to 100%
(2) described organophosphorus insecticide is selected from a kind of in nuvacron, dichlorvos, omethoate, Rogor, Hostathion, water amine phosphorus phosphorus, chlopyrifos, chlorpyrifos-methyl, Toyodan, the acephatemet.
2. oily suspension mixture according to claim 1 is characterized in that used surfactant is one or both combinations in the following kind: alkylbenzenesulfonate, castor oil polyoxyethylene ether, styryl phenyl APEO, styryl phenol formaldehyde resin polyoxyethylene polyoxypropylene block co-polyether.
3. oily suspension mixture according to claim 1 and 2 is characterized in that used antisettling agent is a kind of in white carbon, bentonite, the attapulgite.
4. oily suspension mixture according to claim 1 and 2 is characterized in that used stabilizing agent is: a kind of in triphenyl phosphite, urea, the alkyl phosphoric acid ester derivative.
5. oily suspension mixture according to claim 1 and 2 is characterized in that used solvent is one or both combinations of following kind; Senior fatty hydrocarbon ils, aromatic hydrocarbon, ethylene glycol, vegetable oil.
6. oily suspension mixture according to claim 1 and 2 is characterized in that this oil suspension mixture is to adopt sand mill or sand milling still and homogeneous blender grinding dispersion production technology and make.
7. the purposes of oily suspension mixture according to claim 1 and 2 is characterized in that this oil suspension mixture is used to prevent and treat harmful mite and the various pests on the crops.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN95109265A CN1056032C (en) | 1995-08-02 | 1995-08-02 | High-effective oil suspended mixture for killing mites and pests |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN95109265A CN1056032C (en) | 1995-08-02 | 1995-08-02 | High-effective oil suspended mixture for killing mites and pests |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1124568A CN1124568A (en) | 1996-06-19 |
| CN1056032C true CN1056032C (en) | 2000-09-06 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN95109265A Expired - Fee Related CN1056032C (en) | 1995-08-02 | 1995-08-02 | High-effective oil suspended mixture for killing mites and pests |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1056032C (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103271081B (en) * | 2013-04-10 | 2017-09-12 | 湖南农大海特农化有限公司 | Etoxazole-triazophospesticide pesticide composition |
| UA119331C2 (en) * | 2013-11-08 | 2019-06-10 | Новозімес Біоаґ А/С | COMPOSITIONS AND METHODS FOR TREATMENT OF PESTS |
| CN109744252B (en) * | 2018-12-18 | 2021-03-12 | 广西壮族自治区农业科学院园艺研究所 | Synergistic composition for preventing and treating citrus mites |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE233028C (en) * | ||||
| CN88103536A (en) * | 1987-06-13 | 1988-12-28 | 先灵农业化学公司 | Acaricide |
| CN1063016A (en) * | 1991-01-09 | 1992-07-29 | 希巴-盖吉股份公司 | Acaricide composition |
-
1995
- 1995-08-02 CN CN95109265A patent/CN1056032C/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE233028C (en) * | ||||
| CN88103536A (en) * | 1987-06-13 | 1988-12-28 | 先灵农业化学公司 | Acaricide |
| CN1063016A (en) * | 1991-01-09 | 1992-07-29 | 希巴-盖吉股份公司 | Acaricide composition |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1124568A (en) | 1996-06-19 |
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