CN105504134A - 一种水基型具有广泛用途的醋硅丙聚合乳液 - Google Patents
一种水基型具有广泛用途的醋硅丙聚合乳液 Download PDFInfo
- Publication number
- CN105504134A CN105504134A CN201510999717.6A CN201510999717A CN105504134A CN 105504134 A CN105504134 A CN 105504134A CN 201510999717 A CN201510999717 A CN 201510999717A CN 105504134 A CN105504134 A CN 105504134A
- Authority
- CN
- China
- Prior art keywords
- parts
- vinyl acetate
- silane
- emulsion
- polymerized emulsion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000839 emulsion Substances 0.000 title claims abstract description 33
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 12
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 title claims abstract description 5
- 229920002554 vinyl polymer Polymers 0.000 title claims abstract description 5
- 239000000178 monomer Substances 0.000 claims abstract description 18
- 239000006087 Silane Coupling Agent Substances 0.000 claims abstract description 9
- 239000003999 initiator Substances 0.000 claims abstract description 9
- 239000012874 anionic emulsifier Substances 0.000 claims abstract description 6
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims abstract description 5
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000008367 deionised water Substances 0.000 claims abstract description 4
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 4
- 239000000203 mixture Substances 0.000 claims description 11
- 229910052710 silicon Inorganic materials 0.000 claims description 11
- 239000010703 silicon Substances 0.000 claims description 11
- 239000000052 vinegar Substances 0.000 claims description 11
- 235000021419 vinegar Nutrition 0.000 claims description 11
- 150000001282 organosilanes Chemical class 0.000 claims description 9
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 8
- 239000013530 defoamer Substances 0.000 claims description 8
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 7
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 7
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 7
- 229910000077 silane Inorganic materials 0.000 claims description 6
- 239000007864 aqueous solution Substances 0.000 claims description 5
- 239000003995 emulsifying agent Substances 0.000 claims description 5
- 239000005977 Ethylene Substances 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 238000007599 discharging Methods 0.000 claims description 3
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 229920001296 polysiloxane Polymers 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims description 3
- 239000004160 Ammonium persulphate Substances 0.000 claims description 2
- WLHXYJADVQUYCW-UHFFFAOYSA-N C(C(=C)C)(=O)OOCCC[Si](C)(C)C Chemical compound C(C(=C)C)(=O)OOCCC[Si](C)(C)C WLHXYJADVQUYCW-UHFFFAOYSA-N 0.000 claims description 2
- 239000004159 Potassium persulphate Substances 0.000 claims description 2
- 239000007983 Tris buffer Substances 0.000 claims description 2
- 238000013019 agitation Methods 0.000 claims description 2
- 235000019395 ammonium persulphate Nutrition 0.000 claims description 2
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 claims description 2
- 150000002978 peroxides Chemical class 0.000 claims description 2
- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 claims description 2
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims description 2
- 235000019394 potassium persulphate Nutrition 0.000 claims description 2
- 238000003860 storage Methods 0.000 abstract description 5
- 230000007062 hydrolysis Effects 0.000 abstract description 4
- 238000006460 hydrolysis reaction Methods 0.000 abstract description 4
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- 238000002485 combustion reaction Methods 0.000 abstract 1
- 239000012875 nonionic emulsifier Substances 0.000 abstract 1
- 239000003755 preservative agent Substances 0.000 abstract 1
- 230000002335 preservative effect Effects 0.000 abstract 1
- 239000003053 toxin Substances 0.000 abstract 1
- 231100000765 toxin Toxicity 0.000 abstract 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 9
- 238000003912 environmental pollution Methods 0.000 description 3
- 239000003292 glue Substances 0.000 description 3
- 230000002045 lasting effect Effects 0.000 description 3
- 231100000252 nontoxic Toxicity 0.000 description 3
- 230000003000 nontoxic effect Effects 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- 239000004566 building material Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 238000004043 dyeing Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical group CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 description 1
- QYYMDNHUJFIDDQ-UHFFFAOYSA-N 5-chloro-2-methyl-1,2-thiazol-3-one;2-methyl-1,2-thiazol-3-one Chemical compound CN1SC=CC1=O.CN1SC(Cl)=CC1=O QYYMDNHUJFIDDQ-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical group C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 241000276489 Merlangius merlangus Species 0.000 description 1
- 238000012356 Product development Methods 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- GQIUQDDJKHLHTB-UHFFFAOYSA-N trichloro(ethenyl)silane Chemical compound Cl[Si](Cl)(Cl)C=C GQIUQDDJKHLHTB-UHFFFAOYSA-N 0.000 description 1
- 239000005050 vinyl trichlorosilane Substances 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
- -1 γ-(methacryloxy) propyl Chemical group 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F218/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid or of a haloformic acid
- C08F218/02—Esters of monocarboxylic acids
- C08F218/04—Vinyl esters
- C08F218/08—Vinyl acetate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
- C08F2/26—Emulsion polymerisation with the aid of emulsifying agents anionic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
- C08F2/30—Emulsion polymerisation with the aid of emulsifying agents non-ionic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D131/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Coating compositions based on derivatives of such polymers
- C09D131/02—Homopolymers or copolymers of esters of monocarboxylic acids
- C09D131/04—Homopolymers or copolymers of vinyl acetate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J131/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid, or of a haloformic acid; Adhesives based on derivatives of such polymers
- C09J131/02—Homopolymers or copolymers of esters of monocarboxylic acids
- C09J131/04—Homopolymers or copolymers of vinyl acetate
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
一种水基型具有广泛用途的醋硅丙聚合乳液，其组成的重量份数比为：聚乙烯醇5-30份，含不饱和双键的有机硅单体20-50份，丙烯酸丁酯200-300份，醋酸乙烯酯100-250份，去离子水400-500份，硅烷偶联剂2-8份，阴离子乳化剂10-15份，非离子乳化剂3-10份，消泡剂1-3份，引发剂1.0-2.5份，防腐剂1-5份。它具有极端的抗水解性能、抗超低温贮存稳定性、超长时间贮存稳定性；无毒无异味、无环境污染，机械稳定性优良；并具有持久的柔韧性，粘合速度快、强度高、不燃烧、不霉变等优点。
Description
技术领域
本发明涉及一种水基型具有广泛用途的醋硅丙聚合乳液(简称BEVA乳液)的制作方法，具体地说，涉及用于胶粘剂制造业、纺织印染工业、造纸业、建筑建材工业、涂料行业、制鞋行业等领域的功能乳液。
背景技术
BEVA乳液，因具有极端的抗水解性能、抗超低温贮存稳定性、超长时间贮存稳定性；无毒无异味、无环境污染，机械稳定性优良；并具有持久的柔韧性，粘合速度快、强度高、不燃烧、不霉变等优点而新生。
早期的VAE乳液主要成分为乙烯、醋酸乙烯，由于这些物严重的存在不抗水(遇水泛白溶化),不抗冻(零下5℃以上就破乳死胶)，贮存期短(半年左右就沉淀，胶水分离)。由于上述乳液的几大关键性能满足不了国际国内市场使用者的高条件要求，一直束缚着乳液使用者的产品开发和前进步伐。
随着国际国内乳液用户对VAE乳液存在的问题要求得到改善的愿望越来越强烈时，我们开使了乳液的研制，我们已试产成功的BEVA乳液在抗水方面能长期浸泡于水中不会被水解(溶化)；抗冻方面能在零下5℃以上保持完好的流动性，零下25℃冻结后能恢复如初；贮存方面可以长达5年保持完好，不会分离沉淀。因此，BEVA乳液逐渐成为VAE乳液的换代产品。
发明内容
为解决上述技术问题，本发明提供一种水基型具有广泛用途的醋硅丙聚合乳液，它具有极端的抗水解性能、抗超低温贮存稳定性、超长时间贮存稳定性；无毒无异味、无环境污染，机械稳定性优良；并具有持久的柔韧性，粘合速度快、强度高、不燃烧、不霉变等优点。
本发明是这样实现的：一种水基型具有广泛用途的醋硅丙聚合乳液，其组成的重量份数比为：
所述含不饱和双键的有机硅单体为甲基乙烯基硅烷或乙烯基三硅烷其中的一种。
所述硅烷偶联剂为γ-2丙基三乙氧基硅烷、γ-(甲基丙烯酰氧基)丙基三甲基硅烷、乙烯基三甲氧基硅烷或乙烯基三乙氧基硅烷其中的一种。
所示阴离子乳化剂为NP-40。
所述非离子乳化剂为OP-10。
所述消泡剂为有机硅类消泡剂为广州君胜有机硅材料有限公司生产的HY-206。
所述引发剂为无机过氧化物引发剂，本发明优选质量分数为1-5％的过硫酸铵或1-5％过硫酸钾的水溶液。
所述防腐剂为卡松，本发明中可根据需要选择性加入，主要作用是优化有效使用期限。
本发明一种水基型具有广泛用途的醋硅丙聚合乳液(简称BEVA乳液)的制作方法如下：
(1)在反应器内加入去离子水400-500份，聚乙烯醇5-30份，搅拌升温，待聚乙烯醇完全溶解后，降温至75-85℃；
(2)将反应单体醋酸乙烯酯100-200份、含不饱和双键的有机硅单体20-50份、丙烯酸丁酯200-300份加入滴加罐内混合均匀；
(3)在反应器内依次加入硅烷偶联剂2-8份，阴离子乳化剂10-15份、非离子乳化剂3-10份，消泡剂1-3份；
(4)搅拌条件下滴加混合单体，同时滴加单体总重量的0.5-1.3％的引发剂过硫酸铵或过硫酸钾水溶液，并在4-6h内滴加完成；
(5)滴加完成后升温至85-95℃熟化40-60min；
(6)然后降温至35-45℃，加入防腐剂1-5份，混合均匀后出料过滤包装即成。
与现有技术相比，本发明具有下述优点：
(1)本发明的一种水基型具有广泛用途的醋硅丙聚合乳液(简称BEVA乳液)的制作方法，具体地说，涉及用于胶粘剂制造业、纺织印染工业、造纸业、建筑建材工业、涂料行业、制鞋行业等领域。
(2)胶的稳定性好，-5-50℃的贮存条件下可以长达5年保持完好，不会分离沉淀。
(3)本发明的BEVA乳液，它具有极端的抗水解性能、抗超低温贮存稳定性、超长时间贮存稳定性；无毒无异味、无环境污染，机械稳定性优良；并具有持久的柔韧性，粘合速度快、强度高、不燃烧、不霉变等优点。
具体实施方式
下面结合实施例对本发明作详细、清楚的说明。
以下实施例仅是本发明的优先实施方式，应当指出的是，对于本领域的普通技术人员来说，在不脱离本发明原理的前提下，还可以做出若干的改进和推演，这些变化均应属于本发明的保护范围。
实施例1
一种水基型具有广泛用途的醋硅丙聚合乳液，其组成的重量份数比为：
所述的含不饱和双键的有机硅单体为甲基乙烯基硅烷；
所述的硅烷偶联剂为γ-氨丙基三乙氧基硅烷。
有机硅类消泡剂为广州君胜有机硅材料有限公司生产的HY-206
所述的BEVA乳液制备方法如下：
(1)在反应器内放入去离子水500kg，聚乙烯醇30kg，搅拌升温，待聚乙烯醇完全溶解后，降温至75-85℃；
(2)将反应单体醋酸乙烯酯250kg、丙烯酸丁酯250kg、含不饱和双键的有机硅单体25kg加入滴加罐内混合均匀；
(3)在反应器内依次加入硅烷偶联剂2kg，阴离子乳化剂12kg、非离子乳化剂5kg，钠消泡剂1kg；
(4)搅拌下滴加混合单体，同时滴加引发剂质量分数为1％-5％的过硫酸铵水溶液10kg，并在3-5小时内滴加完成；
(5)滴加完成后升温至85-95℃熟化40-60min；
(6)降温至35-45℃，加入防腐剂2kg，混合均匀后出料过滤包装即成。
实施例2
一种水基型具有广泛用途的醋硅丙聚合乳液，其组成的重量份数比为：
聚乙烯醇30份，
含不饱和双键的有机硅单体25份，
所述的含不饱和双键的有机硅单体为乙烯基三氯硅烷。
所述的硅烷偶联剂为γ-(甲基丙烯酰氧基)丙基三甲氧基硅烷。
实施例3
一种水基型具有广泛用途的醋硅丙聚合乳液，其组成的重量份数比为：
所述的含不饱和双键的有机硅单体为甲基乙烯基硅烷。
所述的硅烷偶联剂为乙烯基三甲氧基硅烷。
本发明的BEVA乳液性能指标如下：
| 项目 | 指标 | 结果 |
| 外观 | 白色乳液流质体 | 白色乳液流质体 |
| 固含％ | ≥50％ | 53％ |
| 粘度(mpa.s) | ≥2000 | 2500 |
| 抗水性(减量％) | ＜25 | 0.5 |
| 拉伸率 | ≥100％ | ＞200％ |
| 粘结强度(N/㎝2) | ≥50 | ＞500 |
| 耐黄变性(120℃烘烤) | 不变色 | 不变色 |
检测方法：环保标准可参照GB18583-2008。
Claims (2)
1.一种水基型具有广泛用途的醋硅丙聚合乳液，其特征在于：其组成的重量份数比为：
所述含不饱和双键的有机硅单体为甲基乙烯基硅烷或乙烯基三硅烷其中的一种；
所述硅烷偶联剂为γ-2丙基三乙氧基硅烷、γ-(甲基丙烯酰氧基)丙基三甲基硅烷、乙烯基三甲氧基硅烷或乙烯基三乙氧基硅烷其中的一种；
所示阴离子乳化剂为NP-40；
所述非离子乳化剂为OP-10；
所述消泡剂为有机硅类消泡剂；
所述引发剂为无机过氧化物引发剂；
其制作方法按以下步骤：
(1)在反应器内加入去离子水400-500份，聚乙烯醇5-30份，搅拌升温，待聚乙烯醇完全溶解后，降温至75-85℃；
(2)将反应单体醋酸乙烯酯100-200份、含不饱和双键的有机硅单体20-50份、丙烯酸丁酯200-300份加入滴加罐内混合均匀；
(3)在反应器内依次加入硅烷偶联剂2-8份，阴离子乳化剂10-15份、非离子乳化剂3-10份，消泡剂1-3份；
(4)搅拌条件下滴加混合单体，同时滴加单体总重量的0.5-1.3％的引发剂过硫酸铵或过硫酸钾水溶液，并在4-6h内滴加完成；
(5)滴加完成后升温至85-95℃熟化40-60min；
(6)然后降温至35-45℃，加入防腐剂1-5份，混合均匀后出料过滤包装即成。
2.根据权利要求1所述的一种水基型具有广泛用途的醋硅丙聚合乳液，其特征在于：所述引发剂质量分数为1-5％的过硫酸铵或1-5％过硫酸钾的水溶液。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510999717.6A CN105504134A (zh) | 2015-12-24 | 2015-12-24 | 一种水基型具有广泛用途的醋硅丙聚合乳液 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510999717.6A CN105504134A (zh) | 2015-12-24 | 2015-12-24 | 一种水基型具有广泛用途的醋硅丙聚合乳液 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105504134A true CN105504134A (zh) | 2016-04-20 |
Family
ID=55712475
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510999717.6A Pending CN105504134A (zh) | 2015-12-24 | 2015-12-24 | 一种水基型具有广泛用途的醋硅丙聚合乳液 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105504134A (zh) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106221627A (zh) * | 2016-08-10 | 2016-12-14 | 佛山市三水永恒达粘合剂有限公司 | 一种具有高绝缘性能的水基粘合剂及其制作方法 |
| CN106381097A (zh) * | 2016-10-13 | 2017-02-08 | 广东龙马化学有限公司 | 抗冻高粘无醛聚醋酸乙烯酯胶黏剂及其制备方法 |
| CN106674409A (zh) * | 2016-12-31 | 2017-05-17 | 佛山市顺德区巴德富实业有限公司 | 一种剑麻抛光轮定型用醋丙乳液及其制备方法 |
| CN107722881A (zh) * | 2017-10-18 | 2018-02-23 | 江西省林业科学院 | 一种醋丙乳液胶粘剂的制备方法 |
| CN110461888A (zh) * | 2017-02-17 | 2019-11-15 | 瓦克化学股份公司 | 聚合物水分散体在高分子多孔材料界面粘结的用途 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104830255A (zh) * | 2015-05-19 | 2015-08-12 | 佛山市三水永恒达粘合剂有限公司 | 一种织物硬挺胶浆及其制备方法和定型布 |
-
2015
- 2015-12-24 CN CN201510999717.6A patent/CN105504134A/zh active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104830255A (zh) * | 2015-05-19 | 2015-08-12 | 佛山市三水永恒达粘合剂有限公司 | 一种织物硬挺胶浆及其制备方法和定型布 |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106221627A (zh) * | 2016-08-10 | 2016-12-14 | 佛山市三水永恒达粘合剂有限公司 | 一种具有高绝缘性能的水基粘合剂及其制作方法 |
| CN106381097A (zh) * | 2016-10-13 | 2017-02-08 | 广东龙马化学有限公司 | 抗冻高粘无醛聚醋酸乙烯酯胶黏剂及其制备方法 |
| CN106674409A (zh) * | 2016-12-31 | 2017-05-17 | 佛山市顺德区巴德富实业有限公司 | 一种剑麻抛光轮定型用醋丙乳液及其制备方法 |
| CN110461888A (zh) * | 2017-02-17 | 2019-11-15 | 瓦克化学股份公司 | 聚合物水分散体在高分子多孔材料界面粘结的用途 |
| CN107722881A (zh) * | 2017-10-18 | 2018-02-23 | 江西省林业科学院 | 一种醋丙乳液胶粘剂的制备方法 |
| CN107722881B (zh) * | 2017-10-18 | 2019-09-13 | 江西省林业科学院 | 一种醋丙乳液胶粘剂的制备方法 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105949381B (zh) | 无胺防水乳液及其制备方法及含无胺防水乳液的防水涂料 | |
| CN102115517B (zh) | 无皂丙烯酸酯防锈乳液的制备方法 | |
| CN103012689B (zh) | 有机硅丙烯酸改性水性环氧乳液及其制备方法 | |
| CN105504134A (zh) | 一种水基型具有广泛用途的醋硅丙聚合乳液 | |
| CN113621103A (zh) | 一种无胺弹性丙烯酸酯乳液、防水涂料及制备方法 | |
| CN103059192B (zh) | 用于内、外墙涂料的pvdc胶乳及其制备方法和应用 | |
| CN103788298A (zh) | 羧基丁腈乳胶的制备方法及该羧基丁腈乳胶所制得的物品 | |
| CN109437657A (zh) | 一种零voc水泥基防水材料聚合乳液及其制备方法 | |
| CN104830255B (zh) | 一种织物硬挺胶浆及其制备方法和定型布 | |
| CN105111641B (zh) | 水性有机硅含氟聚合物分散体与其制备方法 | |
| CN103601404B (zh) | 一种混凝土养护剂及其制备方法 | |
| CN105111975A (zh) | 一种改性聚醋酸乙烯酯乳液胶黏剂的制备方法及其产物 | |
| CN108359046A (zh) | 一种有机硅改性丙烯酸乳液及其制备方法 | |
| CN114044847B (zh) | 一种高耐水耐脏污的丙烯酸酯乳液及制备方法 | |
| BR102013015328A2 (pt) | Polímeros de emulsão com melhor resistência à limpeza com esfregamento a úmido apresentando um ou mais compostos que contêm silicone | |
| CN104371612A (zh) | 用于聚酯泡沫与化纤布料贴合的多元聚合贴合胶 | |
| CN109942736A (zh) | 一种复合型有机硅改性核壳苯丙胶乳的制备方法 | |
| CN106085083A (zh) | 一种环保的水性复合涂料及其制备方法 | |
| CN107828302A (zh) | 一种多重交联高弹外墙乳液及其制备方法和应用 | |
| CN104356321A (zh) | 水性聚硅氧烷改性环氧树脂及其制备方法 | |
| CN101984010B (zh) | 一种工业用多用途环保粘合剂的制备方法 | |
| KR20000071052A (ko) | 수성 에멀젼 중합을 위한 유화제 | |
| CN106117421B (zh) | 一种水性环保型瓷砖背胶乳液及其制造方法 | |
| CN103275260A (zh) | 一种丙烯酸塑塑复合胶乳制备方法 | |
| CN109293833A (zh) | 用于建筑涂料的丁苯胶乳的制备方法及其产品 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160420 |