CN1054732C - Method for preparation of aflatoxin radically-removed low sodium salt enriched health-care soya sauce - Google Patents
Method for preparation of aflatoxin radically-removed low sodium salt enriched health-care soya sauce Download PDFInfo
- Publication number
- CN1054732C CN1054732C CN94110384A CN94110384A CN1054732C CN 1054732 C CN1054732 C CN 1054732C CN 94110384 A CN94110384 A CN 94110384A CN 94110384 A CN94110384 A CN 94110384A CN 1054732 C CN1054732 C CN 1054732C
- Authority
- CN
- China
- Prior art keywords
- weight
- hour
- preparation
- filter
- aflatoxin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229930195730 Aflatoxin Natural products 0.000 title claims abstract description 26
- 239000005409 aflatoxin Substances 0.000 title claims abstract description 26
- XWIYFDMXXLINPU-UHFFFAOYSA-N Aflatoxin G Chemical compound O=C1OCCC2=C1C(=O)OC1=C2C(OC)=CC2=C1C1C=COC1O2 XWIYFDMXXLINPU-UHFFFAOYSA-N 0.000 title claims abstract description 25
- 238000000034 method Methods 0.000 title claims abstract description 20
- 244000068988 Glycine max Species 0.000 title claims abstract description 12
- 235000010469 Glycine max Nutrition 0.000 title claims abstract description 12
- 238000002360 preparation method Methods 0.000 title claims description 24
- 235000015067 sauces Nutrition 0.000 title claims description 22
- 159000000000 sodium salts Chemical class 0.000 title description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 38
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 37
- 239000002994 raw material Substances 0.000 claims abstract description 35
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims abstract description 20
- 235000015099 wheat brans Nutrition 0.000 claims abstract description 20
- 235000011114 ammonium hydroxide Nutrition 0.000 claims abstract description 16
- 235000017060 Arachis glabrata Nutrition 0.000 claims abstract description 15
- 244000105624 Arachis hypogaea Species 0.000 claims abstract description 15
- 235000010777 Arachis hypogaea Nutrition 0.000 claims abstract description 15
- 235000018262 Arachis monticola Nutrition 0.000 claims abstract description 15
- 235000020232 peanut Nutrition 0.000 claims abstract description 15
- 150000003839 salts Chemical class 0.000 claims abstract description 14
- 240000004808 Saccharomyces cerevisiae Species 0.000 claims abstract description 12
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims abstract description 12
- 229920000053 polysorbate 80 Polymers 0.000 claims abstract description 12
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims abstract description 10
- 210000002318 cardia Anatomy 0.000 claims abstract description 10
- 238000007654 immersion Methods 0.000 claims abstract description 10
- 239000001103 potassium chloride Substances 0.000 claims abstract description 10
- 235000011164 potassium chloride Nutrition 0.000 claims abstract description 10
- 235000019796 monopotassium phosphate Nutrition 0.000 claims abstract description 8
- 239000003513 alkali Substances 0.000 claims abstract description 7
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 claims abstract description 6
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910021529 ammonia Inorganic materials 0.000 claims abstract description 5
- 239000000460 chlorine Substances 0.000 claims abstract description 5
- 229910052801 chlorine Inorganic materials 0.000 claims abstract description 5
- 229910000402 monopotassium phosphate Inorganic materials 0.000 claims abstract description 5
- PJNZPQUBCPKICU-UHFFFAOYSA-N phosphoric acid;potassium Chemical compound [K].OP(O)(O)=O PJNZPQUBCPKICU-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000000047 product Substances 0.000 claims description 31
- 235000001674 Agaricus brunnescens Nutrition 0.000 claims description 23
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 22
- 238000003756 stirring Methods 0.000 claims description 22
- 239000000463 material Substances 0.000 claims description 20
- 239000000843 powder Substances 0.000 claims description 17
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 16
- 239000000706 filtrate Substances 0.000 claims description 15
- 238000006243 chemical reaction Methods 0.000 claims description 12
- 108090000623 proteins and genes Proteins 0.000 claims description 12
- 102000004169 proteins and genes Human genes 0.000 claims description 12
- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical compound [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 claims description 11
- 239000004302 potassium sorbate Substances 0.000 claims description 11
- 235000010241 potassium sorbate Nutrition 0.000 claims description 11
- 229940069338 potassium sorbate Drugs 0.000 claims description 11
- 238000010992 reflux Methods 0.000 claims description 11
- 239000000243 solution Substances 0.000 claims description 10
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 claims description 9
- 235000010445 lecithin Nutrition 0.000 claims description 9
- 229940067606 lecithin Drugs 0.000 claims description 9
- 239000000787 lecithin Substances 0.000 claims description 9
- 230000003190 augmentative effect Effects 0.000 claims description 8
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 8
- 239000007864 aqueous solution Substances 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- 238000002242 deionisation method Methods 0.000 claims description 7
- 238000005516 engineering process Methods 0.000 claims description 7
- 238000005903 acid hydrolysis reaction Methods 0.000 claims description 6
- 244000028550 Auricularia auricula Species 0.000 claims description 5
- 235000000023 Auricularia auricula Nutrition 0.000 claims description 5
- 230000008030 elimination Effects 0.000 claims description 5
- 238000003379 elimination reaction Methods 0.000 claims description 5
- 238000006386 neutralization reaction Methods 0.000 claims description 4
- 230000007062 hydrolysis Effects 0.000 abstract description 14
- 238000006460 hydrolysis reaction Methods 0.000 abstract description 14
- 235000013555 soy sauce Nutrition 0.000 abstract description 9
- 241000233866 Fungi Species 0.000 abstract description 7
- 235000012054 meals Nutrition 0.000 abstract description 6
- 239000005708 Sodium hypochlorite Substances 0.000 abstract description 3
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 abstract description 3
- 238000004140 cleaning Methods 0.000 abstract 3
- 206010020772 Hypertension Diseases 0.000 abstract 1
- 206010028980 Neoplasm Diseases 0.000 abstract 1
- 201000011510 cancer Diseases 0.000 abstract 1
- 201000010099 disease Diseases 0.000 abstract 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 abstract 1
- 230000002349 favourable effect Effects 0.000 abstract 1
- 210000002216 heart Anatomy 0.000 abstract 1
- 210000003734 kidney Anatomy 0.000 abstract 1
- 210000004185 liver Anatomy 0.000 abstract 1
- 210000000056 organ Anatomy 0.000 abstract 1
- WTJKGGKOPKCXLL-RRHRGVEJSA-N phosphatidylcholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCCCCCCC=CCCCCCCCC WTJKGGKOPKCXLL-RRHRGVEJSA-N 0.000 abstract 1
- 239000003755 preservative agent Substances 0.000 abstract 1
- 239000013589 supplement Substances 0.000 abstract 1
- 208000024891 symptom Diseases 0.000 abstract 1
- 239000000284 extract Substances 0.000 description 13
- 235000014680 Saccharomyces cerevisiae Nutrition 0.000 description 10
- 229940024606 amino acid Drugs 0.000 description 10
- 150000001413 amino acids Chemical class 0.000 description 10
- 238000004458 analytical method Methods 0.000 description 7
- 235000017550 sodium carbonate Nutrition 0.000 description 6
- 235000011121 sodium hydroxide Nutrition 0.000 description 6
- 108010082495 Dietary Plant Proteins Proteins 0.000 description 5
- 244000046052 Phaseolus vulgaris Species 0.000 description 5
- 235000010627 Phaseolus vulgaris Nutrition 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 238000002791 soaking Methods 0.000 description 5
- 238000010298 pulverizing process Methods 0.000 description 4
- 241001506047 Tremella Species 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 235000016709 nutrition Nutrition 0.000 description 3
- GNSKLFRGEWLPPA-UHFFFAOYSA-M potassium dihydrogen phosphate Chemical class [K+].OP(O)([O-])=O GNSKLFRGEWLPPA-UHFFFAOYSA-M 0.000 description 3
- 230000000452 restraining effect Effects 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 2
- 102000004190 Enzymes Human genes 0.000 description 2
- 108090000790 Enzymes Proteins 0.000 description 2
- 240000000588 Hericium erinaceus Species 0.000 description 2
- 235000007328 Hericium erinaceus Nutrition 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical group [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 238000000855 fermentation Methods 0.000 description 2
- 230000004151 fermentation Effects 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- AWUCVROLDVIAJX-UHFFFAOYSA-N glycerol 1-phosphate Chemical compound OCC(O)COP(O)(O)=O AWUCVROLDVIAJX-UHFFFAOYSA-N 0.000 description 2
- 239000000413 hydrolysate Substances 0.000 description 2
- 238000002372 labelling Methods 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- AUHDWARTFSKSAC-HEIFUQTGSA-N (2S,3R,4S,5R)-3,4-dihydroxy-5-(hydroxymethyl)-2-(6-oxo-1H-purin-9-yl)oxolane-2-carboxylic acid Chemical compound [C@]1([C@H](O)[C@H](O)[C@@H](CO)O1)(N1C=NC=2C(O)=NC=NC12)C(=O)O AUHDWARTFSKSAC-HEIFUQTGSA-N 0.000 description 1
- 239000001763 2-hydroxyethyl(trimethyl)azanium Substances 0.000 description 1
- 241000228197 Aspergillus flavus Species 0.000 description 1
- 235000019743 Choline chloride Nutrition 0.000 description 1
- 208000004930 Fatty Liver Diseases 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 229920002488 Hemicellulose Polymers 0.000 description 1
- 206010019708 Hepatic steatosis Diseases 0.000 description 1
- GRSZFWQUAKGDAV-UHFFFAOYSA-N Inosinic acid Natural products OC1C(O)C(COP(O)(O)=O)OC1N1C(NC=NC2=O)=C2N=C1 GRSZFWQUAKGDAV-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 241000218636 Thuja Species 0.000 description 1
- 240000006794 Volvariella volvacea Species 0.000 description 1
- SNGZVXPRGLTKNU-RGMNGODLSA-N [Na].C(CC)N[C@@H](CCO)C(=O)O Chemical compound [Na].C(CC)N[C@@H](CCO)C(=O)O SNGZVXPRGLTKNU-RGMNGODLSA-N 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 229960001231 choline Drugs 0.000 description 1
- OEYIOHPDSNJKLS-UHFFFAOYSA-N choline Chemical compound C[N+](C)(C)CCO OEYIOHPDSNJKLS-UHFFFAOYSA-N 0.000 description 1
- SGMZJAMFUVOLNK-UHFFFAOYSA-M choline chloride Chemical compound [Cl-].C[N+](C)(C)CCO SGMZJAMFUVOLNK-UHFFFAOYSA-M 0.000 description 1
- 229960003178 choline chloride Drugs 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 208000010706 fatty liver disease Diseases 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 235000012041 food component Nutrition 0.000 description 1
- 235000011194 food seasoning agent Nutrition 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 239000004245 inosinic acid Substances 0.000 description 1
- 229940028843 inosinic acid Drugs 0.000 description 1
- 235000013902 inosinic acid Nutrition 0.000 description 1
- 239000013067 intermediate product Substances 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 210000000653 nervous system Anatomy 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 102000039446 nucleic acids Human genes 0.000 description 1
- 108020004707 nucleic acids Proteins 0.000 description 1
- 150000007523 nucleic acids Chemical class 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 230000035479 physiological effects, processes and functions Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 230000017854 proteolysis Effects 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 210000004994 reproductive system Anatomy 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 229940073490 sodium glutamate Drugs 0.000 description 1
- 229960002901 sodium glycerophosphate Drugs 0.000 description 1
- REULQIKBNNDNDX-UHFFFAOYSA-M sodium;2,3-dihydroxypropyl hydrogen phosphate Chemical compound [Na+].OCC(O)COP(O)([O-])=O REULQIKBNNDNDX-UHFFFAOYSA-M 0.000 description 1
- 231100000240 steatosis hepatitis Toxicity 0.000 description 1
- 230000001256 tonic effect Effects 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 150000003722 vitamin derivatives Chemical class 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
Landscapes
- Coloring Foods And Improving Nutritive Qualities (AREA)
Abstract
The present invention relates to a method for preparing health-care soy sauce essence of cardia salt supplement without aflatoxin. Soybean cake meal or peanut cake meal and wheat bran are used as raw materials; edible fungi, yeast, phosphatidyl choline, etc. used as auxiliary raw materials are added to the raw materials. Firstly, the raw materials exceeding standard indexes are processed by one of an ammonia or ammonia water immersion cleaning disintoxication method, a chlorine water or sodium hypochlorite solution immersion cleaning disintoxication method, and a tween-80 water solution immersion cleaning method to remove the aflatoxin; then, diluted hydrochloric acid is added for hydrolysis; then, the raw materials are neutralized by diluted alkali; potassium chloride, potassium dihydrogen phosphate and preservatives are added to filter liquor to obtain the soy sauce essence without containing the aflatoxin. The present invention can reduce cancer morbidity, can prevent and cure hypertension, and is favorable for disease symptoms of organs such as the heart, liver, kidney, etc.
Description
The present invention relates to a kind of preparation method of flavouring.
As everyone knows, the traditional preparation process method of soy sauce is to adopt to brewage fermentation method (being enzyme hydrolysis method), and its output cycle that feeds intake is long, and the hydrolysis intermediate product is many, easily dyes assorted bacterium.Along with science and technology development, people improve traditional enzyme hydrolysis legal system soy sauce, promptly adopt the acid water solution, as discussing in＜industrial chemistry〉(friendly Tian Xuanxiao work, clear and in March, 17, the 313rd page and the 318th page) in to have introduced amino acid soy sauce be with big dregs of beans hydrochloric acid hydrolysis, the amino acid mixing liquid of gained adds the soy sauce seasoning matter with in the sodium carbonate and back and just makes amino acid soy sauce.It does not have other nutritional labeling substantially again except that amino acid.And raw material that it is used such as big dregs of beans etc. are vulnerable to the pollution of some moulds such as aspergillus flavus, transfinite unexpectedly to 4000-8000PPb when serious, just remain in the soy sauce after their hydrolysis, often make aflatoxin surpass limiting the quantity of of regulation.
In view of above-mentioned weak point of the prior art, the object of the present invention is to provide a kind of with short production cycle and can eradicate the production method of the sauce extract of aflatoxin.
Purpose of the present invention can realize by following measure: a kind of Cardia Salt of eradicating aflatoxin is augmented the preparation method of health-care sauce essence, and it is with the protein raw material hydrochloric acid hydrolysis, with the alkali lye neutralization, it is characterized in that then:
(1) product of the present invention of preparation 1000 parts by weight adopts following raw material:
Soybean cake dregs or peanut dregs 60-100 weight portion
Wheat bran 60-108 weight portion
(2) purified treatment of raw material
A ammonia or ammoniacal liquor embathe disintoxication: powder raw material is filtered after 3-4 hour in 35-45 ℃ of immersion with the weak aqua ammonia of the 1-2% of 4 times of weight done, the warm water with 3 times of amounts embathes 2-3 time again, soaks big gun 20-30 minute at every turn, and filter is done stand-by,
Or b chlorine water or liquor natrii hypochloritis embathe disintoxication: with powder raw material with the 1-2% aqueous sodium hypochlorite solution of 4 times of weight in 35-45 ℃ soak 3-4 hour after filter do, warm water with 3 times of amounts embathes 2-3 time again, the each immersion 20-30 minute, filter is done stand-by, or the c Tween-80 aqueous solution embathes method: powder raw material is filtered after 3-4 hour with 0.01% Tween-80 emerge in worm water of 4 times of weight done, the warm water with 3 times of amounts embathes 2-3 time again, soaks 20-30 minute at every turn, filter is done stand-by
(3) preparation technology
A will be through the raw material that exceeds standard of above-mentioned processing with being that the 18-20% hydrochloric acid of 2.5 times of its weight is under stirring condition or atmospheric pressure reflux 20-24 hour, or in gauge pressure 2kg/cm
2115-125 ℃ was reacted 14-16 hour,
B is cooled to 40 ℃, slowly adds the aqueous sodium carbonate of 30-36% or 20% sodium hydroxide solution under stirring condition, makes pH value between 5.5-6.0,
C filters and with quantitative deionization warm water filter wash, filtrate merging is added 0.05-0.10% potassium sorbate anticorrisive agent again.The product of the present invention of best (1) preparation 1000 parts by weight, adopt following raw material and auxiliary material:
Soybean cake dregs or peanut dregs 60-100 weight portion
Wheat bran 60-108 weight portion
Edible mushroom 20-28 weight portion
Yeast 5-7 weight portion
Lecithin 5-7 weight portion
(2) purified treatment of raw material is identical with (2) in the claim 1,
(3) preparation technology
The raw material that exceeds standard that a crosses above-mentioned purified treatment is with being that the 18-20% hydrochloric acid of 2.5 times of main material weight is under stirring condition or atmospheric pressure reflux 18-20 hour, or in gauge pressure 2kg/cm
2115-125 ℃ was reacted 12-14 hour,
B is cooled to about 60 ℃, adds auxiliary material under stirring condition, and then is warmed up to 100 ℃, and under normal pressure back flow reaction 6-8 hour,
C is cooled to 40 ℃, slowly adds the aqueous sodium carbonate of 30-36% or 20% sodium hydroxide solution under stirring condition, makes pH value between 5.5-6.0,
D filters and with quantitative deionization warm water filter wash, filtrate is merged, and adds 0.05-0.10% potassium sorbate anticorrisive agent again.In product of the present invention, add the 7.6-8.0% potassium chloride of filtrate total amount and the potassium dihydrogen phosphate of 0.3-0.5%.Mushroom is 1: 1 with the weight ratio of auricularia auriculajudae in the edible mushroom.Adopt the hydrochloric acid hydrolysis of 5.5N.
The present invention carries out purified treatment with overproof vegetable protein raw material earlier, preferably adds auxiliary material, the method that adopts hydrochloric acid to be hydrolyzed then again.
Raw material of the present invention mainly contains vegetable protein, and this vegetable protein can be soybean cake dregs, peanut dregs and wheat bran.Though wherein wheat bran can be the manufacturing sauce extract protein sources is provided, but more mainly be owing to also contain a large amount of hemicelluloses (sugar contracts more) in the wheat bran, its hydrolysate combines the color that has determined soy sauce with the hydrolysate amino acid of protein, makes product possess the due style of traditional sauce extract.So the wheat bran micromicro of getting 60-108 part during 1000 parts of products of the present invention when preparation satisfies the needs of this product, remaining protein sources is then by a kind of the providing in other vegetable protein such as soybean cake dregs, the peanut dregs.When 1000 parts of products of the present invention of preparation, desirable soybean cake dregs or peanut dregs 60-100 part can meet the demands.Hydrochloric acid of the present invention is the watery hydrochloric acid of 18-20% (weight), preferably adopt the hydrochloric acid of 5.5N, addition is that 2.5 heavy multiple proportions of raw material are more suitable, and hydrolysis is incomplete very little as addition, and is also too many with the too many sodium chloride that generates of alkali as the too many neutralization of addition.For guarantee that sauce extract never degenerates in storing and using, the anticorrisive agent that is added in product of the present invention is a potassium sorbate, and it is stable that it is lower than antiseptic and inhibiting bacteria function effect in 8.0 o'clock at pH value, and pH value is low more, and its antibacterial action is strong more.Product slant acidity of the present invention, it is very suitable therefore to cook anticorrisive agent with it.When product adds the potassium sorbate of 0.05-0.10%, can satisfy anticorrosion simultaneously and needs mildew-resistant.
For increasing the nutritional labeling in the product of the present invention and improving its delicious degree, selected the auxiliary material that body-care is had help greatly for use: edible mushroom, yeast and lecithin.Wherein edible mushroom includes mushroom, mushroom, straw mushroom, flat mushroom, wind tail mushroom, Hericium erinaceus, black fungus and tremella.Not only amino acid whose content is very high in these edible mushrooms, but also 8 seed amino acids that contain that human body self can not synthesize and must replenish by food.In addition nutrition of edible fungi value also shows and contains abundant vitamin and multiple metallic element.With mushroom, mushroom, flat mushroom, auricularia auriculajudae is example, and the percentage composition of potassium, magnesium, phosphorus (oxide with them calculates) is as follows in their ash content:
K2O P2O5 MgO
Pester 55.95 25.23 1.47
Mushroom 63.92 20.05 1.88
Flat mushroom 64.26 22.91 3.83
Black fungus 35.50 8.64 6.43
The edible mushroom of getting 20-28 part (dry product) when 1000 parts of products of the present invention of preparation gets final product.Because mushroom class and auricularia auriculajudae class are two class fungus strains, for replenishing mutually, the proportionate relationship of the class of preferably pestering and auricularia auriculajudae class is 1: 1.The auxiliary material that also can add has yeast in the present invention, and it can be a Saccharomyces cerevisiae, also can be brewer's yeast.They are not higher than the inosinicacid and the black thuja acid that can progressively generate nucleic acid, mononucleotide and respective numbers under 100 ℃ the hydrolysising condition in temperature.The sodium salt and the L-sodium glutamate that generate them with in the alkali and back coexist, and can make its delicate flavour increase more than tens times.The yeast effect that adds 5-7 part (dry product) when 1000 parts of products of the present invention of preparation is just more satisfactory.It is auxiliary material that the present invention also adopts lecithin, and it generates phosphoglycerol and Choline Chloride after hydrolysis, and in phosphoglycerol and the alkali and generate sodium glycero-phosphate, it is the ideal of nervous system and reproductive system and effective tonic invigorator.Choline helps preventing and treating fatty liver, strengthens memory.The lecithin that adds 5-7 part (dry product) when 1000 parts of products of the present invention of preparation can produce a desired effect.
Need to begin to test for eradicating aflatoxin, when transfiniting (15-20 μ g/kg), must carry out purified treatment as finding raw material to be subjected to aflatoxin contamination by criticizing from raw material.Earlier siccative was pulverized the 60-80 mesh sieve before processing, one of three kinds of modes below selecting are then handled:
A ammonia or ammoniacal liquor embathe disintoxication: with powder raw material with the weak aqua ammonia of the 1-2% of 4 times of weight in 35-45 ℃ soak 3-4 hour after filter do, it is dried stand-by to embathe 2-3 (at every turn soaking full 20-30 minute) filter with the warm water of 3 times of amounts again.
B chlorine water or inferior filter acid sodium solution embathe disintoxication: with powder raw material with the concentration of 4 times of weight be 1-2% filter acid sodium solution in 35-45 ℃ soak 3-4 hour after filter do, the warm water with 3 times of amounts embathes (soaking 20-30 minute) 2-3 time at every turn again, filter is dried stand-by.
The c Tween-80 aqueous solution embathes method: with powder raw material with 4 times of weight contain Tween-80 (Tween80) 0.01% emerge in worm water 3-4 hour after filter do, the warm water with 3 times of amounts embathes 2-3 time again, soaks 20-30 minute at every turn, filter is dried stand-by.
Specific operation process of the present invention is as follows: get the vegetable protein metallic substance by above-mentioned proportionate relationship, getting is the hydrochloric acid that main material weighs 2.5 times 18-20% again, both evenly mix, place in the container that is provided with agitator and returned cold radiator cooler, it can be atmospheric pressure reflux 20-24 hour, also can be in gauge pressure 2kg/cm
2115-125 ℃ was reacted 14-16 hour, if want to add auxiliary material, and then atmospheric pressure reflux 18-20 hour, or dried gauge pressure 2kg/cm
2115-125 ℃ was reacted 12-14 hour, be cooled to then about 60 ℃, under stirring condition, add the various auxiliary materials of being got by the aforementioned ratio relation, and then be warmed up to 100 ℃ under normal pressure back flow reaction 6-8 hour, when sample analysis is treated the protein complete hydrolysis material in the container is cooled to below 40 ℃, low adding concentration under stirring condition is the Na2CO3 aqueous solution of 30-36%, or the hydrochloric acid in 20% the NaOH aqueous solution and the reaction vessel carries out neutralization reaction generation salt.When pH value reaches 5.5-6.0, be reaction end, filtration, and, the washing filtrate merging added the potassium sorbate anticorrisive agent again stir with quantitative deionization warm water filter wash.The 7.6-8.0% potassium chloride that preferably adds the filtrate total amount is used for replenishing the content of potassium.Add an amount of potassium dihydrogen phosphate in addition, can make the mouthfeel of product better, it is more suitable generally to add 0.3-0.5%.Top mixture refilters after fully stirring, and can to obtain outward appearance be dark brown liquid form product to brownish black.Also can be made into the instant series of products of paste, powdery, graininess and sheet according to market demand.
The present invention has following advantage compared to existing technology:
1, the content that adopts sauce extract that method of the present invention makes, its aflatoxin reaches the purpose of elimination basically below 5PPb,
2, method technology of the present invention simple, with short production cycle (only for brewage fermentation method 1/5), the production efficiency height,
3, the inventive method is an acidic hydrolysis, and not only proteolysis gets fully, also can not cause the optical isomerism effect of amino acid molecular.Used hydrochloric acid is generated salt by in the alkali and back, makes it to be fully utilized, and the starchiness in the raw material has become glucose.
4, adopt product that the inventive method makes except that containing a large amount of amino acid, also contain the multiple nutritional components of needed by human, play the effect of improving the health.
5, the product that adopts the inventive method to make, its contained salt part is a potassium chloride, is fit to the Human Physiology needs so more, becomes the Cardia Salt flavouring.
Example 1
100 kilograms of big dregs of beans, 60 kilograms of the wheat brans of learning from else's experience and pulverizing and crossing the 60-80 mesh sieve.Through check big dregs of beans to contain aflatoxin 350 μ g/kg, wheat bran contains aflatoxin 600 μ g/kg all above required standard.Adopting ammoniacal liquor to embathe disintoxication handles, being about to the above-mentioned powdery soybean dregs of rice and wheat bran filters dried with 640 kilogram 1% ammoniacal liquor in 35-45 ℃ of immersion after 4 hours, embathing 2 times (at every turn soaking 30 minutes) filter with 480 kilograms warm water again does, place in the container that is provided with agitator and returned cold radiator cooler, the hydrochloric acid that adds 5.5N again is warming up to boiling for 400 kilograms, keeping it refluxed 20 hours under normal pressure, sample analysis is after the protein complete hydrolysis, material in the container is cooled to below 40 ℃, still under stirring condition, adds 20% sodium hydrate aqueous solution lentamente.When reaching 6.0, pH value is reaction end, centrifugal filtration is also measured filtrate volume, use the quantitatively deionization warm water washing and filtering of (i.e. 1000 kilograms-filtrate volume) then, filtrate merging is added 0.5 kilogram of potassium sorbate, 100 kilograms in potassium chloride, 3 kilograms of potassium dihydrogen phosphates, refilter after fully stirring, can obtain outward appearance and be 1000 kilograms of dark brown sauce extracts.
Example 2
Repeat the operation of example 1, be cooled to about 60 ℃ in 18 hours when refluxing, under stirring condition, add 10 kilograms of mushroom powders, 10 kilograms of black fungus powders, 5 kilograms of brewer's yeasts and 5 kilograms of lecithin, and then be warmed up to 100 ℃, 8 hours sample analysis of back flow reaction under normal pressure.After the protein complete hydrolysis, repeat the operation of example 1 again, can obtain outward appearance and be 1000 kilograms of brown sauce extracts.
Example 3
100 kilograms of peanut meals, 60 kilograms of the wheat brans of learning from else's experience and pulverizing and crossing the 60-80 mesh sieve, peanut meal contains aflatoxin 2000 μ g/kg, wheat bran contains aflatoxin 4 μ g/kg through checking, and therefore only adopts the liquor natrii hypochloritis to embathe disintoxication processing peanut meal and gets final product.Filter dried with 1% propylhomoserin sodium water solution of 400 kilograms of ratios after 4 hours in 35-45 ℃ of immersion the powdery peanut meal, embathe (soaking 30 minutes) 2 times with 300 kilograms warm water more at every turn, after doing, filter repeats and example 1 identical operations again, wherein return time is 24 hours, neutralize with 30% sodium carbonate liquor, when pH value reaches 5.5, be reaction end, in filtrate, add 1 kilogram of potassium sorbate, 100 kilograms of potassium chloride, 3 kilograms of potassium dihydrogen phosphates, obtain outward appearance at last and be 1000 kilograms of dark brown sauce extracts.
Example 4
Repeat the operation of example 3, be cooled to about 60 ℃ in 20 hours when refluxing, under stirring condition, add 10 kilograms of mushroom powder, 10 kilograms of tremella powder, 5 kilograms of Saccharomyces cerevisiaes and 5 kilograms of lecithin, and then be warmed up to 100 ℃, 6 hours sample analysis of back flow reaction under normal pressure.After the protein complete hydrolysis, repeat the operation of example 2 again, can obtain outward appearance and be 1000 kilograms of brown sauce extracts.
Example 5
60 kilograms of the soybean cakes of learning from else's experience and pulverizing and crossing the 60-80 mesh sieve, 108 kilograms of wheat brans, through check big dregs of beans to contain aflatoxin 280 μ g/kg, wheat bran contains aflatoxin 70 μ g/kg, adopts diverse ways to handle respectively above-mentioned two kinds of raw materials.With the powdery soybean cake with 240 kilogram of 2% weak aqua ammonia in 35-45 ℃ soak 3 hours after filter do, embathe (soaking 20 minutes) 3 times with 180 kilograms warm water more at every turn, filter is dried stand-by.The powdery wheat bran is filtered after 3 hours and done with 432 kilograms Tween-80 0.01% emerge in worm water that contains, embathe 2 times with 324 kilograms warm water, soaked 30 minutes at every turn, filter is dried stand-by.Above-mentioned two kinds of treated raw materials are placed in the container that is provided with agitator and returned cold radiator cooler, add 420 kilograms of 18% hydrochloric acid again, in 2 kilograms/cm of gauge pressure
2115-125 ℃ of reaction 14 hours after sample analysis is treated the protein complete hydrolysis, is cooled to material in the container below 40 ℃, adds concentration lentamente and be 36% aqueous sodium carbonate under normal temperature and stirring condition.When pH value reaches 5.5, be reaction end, filter and with quantitative deionization warm water filter wash, fully refilter after the stirrings for 5 kilograms, can obtain outward appearance and be 1000 kilograms of the sauce extracts of brownish black adding 0.5 kilogram of potassium sorbate, 103 kilograms in potassium chloride, potassium dihydrogen phosphate filtrate merging.
Example 6
Repeat the operation of example 5, be cooled to about 60 ℃ in 12 hours when refluxing, under stirring condition, add 14 kilograms of Hericium erinaceus powder, 14 kilograms of black fungus powders, 7 kilograms of brewer's yeasts and 7 kilograms of lecithin, and then be warmed up to 100 ℃, under normal pressure, refluxed 8 hours sample analysis.After the protein complete hydrolysis, repeat the operation of example 3 again, can obtain outward appearance and be 1000 kilograms of the sauce extracts of brownish black.
Example 7
60 kilograms in peanut cake, 108 kilograms of the wheat brans of learning from else's experience and pulverizing and crossing the 60-80 mesh sieve, peanut cake contains aflatoxin 1650 μ g/kg, wheat bran contains aflatoxin 90 μ g/kg through checking, filter dried with 240 kilogram of 2% aqueous sodium hypochlorite solution after 3 hours in 35-45 ℃ of immersion the pulvis of peanut cake, embathe 3 times with 180 kilograms warm water again, soak filter in 20 minutes at every turn and do stand-by.Again the pulvis of wheat bran is filtered after 4 hours with 432 kilogram of 0.01% Tween-80 emerge in worm water and done.Repeat and example 5 identical operations again, wherein the reaction time is to neutralize with 20% NaOH in 16 hours, when pH value reaches 6.0, be reaction end, add 0.8 kilogram of potassium sorbate, 103 kilograms in potassium chloride, 3 kilograms of potassium dihydrogen phosphates in filtrate, obtaining outward appearance at last is 1000 kilograms of dark-brown sauce extracts.
Example 8
Repeat the operation of example 7, be cooled to about 60 ℃ in 14 hours when refluxing, under stirring condition, add 14 kilograms of phoenix-tail mushroom powder, 14 kilograms of tremella powder, 7 kilograms of Saccharomyces cerevisiaes and 7 kilograms of lecithin, and then be warmed up to 100 ℃, under normal pressure, refluxed 6 hours sample analysis.After the protein complete hydrolysis, repeat the operation of example 4 again, can obtain outward appearance and be 1000 kilograms of the sauce extracts of brownish black.
The quality index contrast of product quality indicator of the present invention and prior art is as follows:
Project product G B2717-81 amino-acid nitrogen of the present invention (restraining/100 milliliters) 〉=0.6 〉=0.4 salt (restraining/100 milliliters)≤8.0 〉=15.0 potassium chloride (restraining/100 milliliters)≤12.0---total acid (in the lactic acid grams per milliliter)≤2.5≤2.5 phosphorus are (in P2O5, restrain/100 milliliters) 〉=0.15---arsenic is (in As, milligram/kilogram)≤0.5≤0.5 lead (in Pb, milligram/kilogram)≤1.0≤1.0 AFB1s (μ g/ liter)＜5≤5 are annotated: 1. percentage in the present specification and mark are parts by weight.
2. aflatoxin content is measured and is selected from GB2717-81
Claims (6)
1, a kind of Cardia Salt of eradicating aflatoxin is augmented the preparation method of health-care sauce essence, and it is with the protein raw material hydrochloric acid hydrolysis, with the alkali neutralization, it is characterized in that then:
(1) the following raw material of product of the present invention of preparation 1000 parts by weight:
Soybean cake dregs or peanut dregs 60-100 weight portion
Wheat bran 60-108 weight portion
(2) purified treatment of raw material
A ammonia or ammoniacal liquor embathe disintoxication: powder raw material is filtered after 3-4 hour in 35-45 ℃ of immersion with the weak aqua ammonia of 4 times of weight 1-2% done, the warm water with 3 times of amounts embathes 2-3 time again, soaks 20-30 minute at every turn, and filter is done stand-by,
Or b chlorine water or liquor natrii hypochloritis embathe disintoxication: with powder raw material with the 1-2% liquor natrii hypochloritis of 4 times of weight in 35-45 ℃ soak 3-4 hour after filter do, the warm water with 3 times of amounts embathes 2-3 time again, soaks 20-30 minute at every turn, filter is dried stand-by,
Or the c Tween-80 aqueous solution embathes method: powder raw material is filtered after 3-4 hour with 0.01% Tween-80 emerge in worm water of 4 times of weight done, the warm water with 3 times of amounts embathes 2-3 time again, soaks 20-30 minute at every turn, and filter is done stand-by,
(3) preparation technology
A will be through the raw material that exceeds standard of above-mentioned processing with being that the 18-20% hydrochloric acid of 2.5 times of its weight is under stirring condition or atmospheric pressure reflux 20-24 hour, or in gauge pressure 2Kg/cm
2115-125 ℃ was reacted 14-16 hour,
B is cooled to 40 ℃ of sodium hydroxide solutions that slowly add 30-36% aqueous sodium carbonate or 20% under stirring condition, makes pH value between 5.5-6.0,
C filters and with quantitative deionization warm water filter wash, filtrate merging is added 0.05-0.1% potassium sorbate anticorrisive agent again.
2, a kind of Cardia Salt of eradicating aflatoxins is augmented the preparation method of health-care sauce essence, it is characterized in that:
(1) product of the present invention of preparation 1000 parts by weight adopts following main material:
Soybean cake dregs or peanut dregs 60-100 weight portion
Wheat bran 60-108 weight portion
And auxiliary material:
Edible mushroom 20-28 weight portion dry product
Yeast 5-7 weight portion dry product
Lecithin 5-7 weight portion dry product
(2) purified treatment of raw material,
A ammonia or ammoniacal liquor embathe disintoxication: the main material of powdery is filtered after 3-4 hour in 35-45 ℃ of immersion with the weak aqua ammonia of 4 times of weight 1-2% done, the warm water with 3 times of amounts embathes 2-3 time again, soaks 20-30 minute at every turn, and filter is done stand-by,
Or b chlorine water or liquor natrii hypochloritis embathe disintoxication: with the main material of powdery with the 1-2% liquor natrii hypochloritis of 4 times of weight in 35-45 ℃ soak 3-4 hour after filter do, the warm water with 3 times of amounts embathes 2-3 time again, soaks 20-30 minute at every turn, filter is dried stand-by,
Or the c Tween-80 aqueous solution embathes method: the main material of powdery is filtered after 3-4 hour with 0.01% Tween-80 emerge in worm water of 4 times of weight done, the warm water with 3 times of amounts embathes 2-3 time again, soaks 20-30 minute at every turn, and filter is done stand-by,
(3) preparation technology:
A will be through the main material that exceeds standard of above-mentioned processing with being that the 18-20% hydrochloric acid of 2.5 times of its weight is under stirring condition or atmospheric pressure reflux 18-20 hour, or in gauge pressure 2kg/cm
2115-125 ℃ was reacted 12-14 hour,
B is cooled to about 60 ℃, adds auxiliary material under stirring condition, and then is warmed up to 100 ℃ atmospheric pressure reflux reaction 6-8 hour,
C is cooled to 40 ℃ and slowly adds 30-36% aqueous sodium carbonate or 20% sodium hydroxide solution under stirring condition, makes pH value between 5.5-6.0,
D filters and with quantitative deionization warm water filter wash, filtrate merging is added 0.05-0.10% potassium sorbate anticorrisive agent again.
3, the Cardia Salt of elimination aflatoxin according to claim 1 and 2 is augmented the preparation method of health-care sauce essence, it is characterized in that: the 7.6-8.0% potassium chloride that also adds the filtrate total amount in product of the present invention.
4, the Cardia Salt of elimination aflatoxin according to claim 3 is augmented the preparation method of health-care sauce essence, it is characterized in that: the 0.3-0.5% potassium dihydrogen phosphate that also adds the filtrate total amount in product of the present invention.
5, the Cardia Salt of elimination aflatoxin according to claim 4 is augmented the preparation method of health-care sauce essence, it is characterized in that: mushroom is 1: 1 with the weight ratio of auricularia auriculajudae in the edible mushroom.
6, the Cardia Salt of elimination aflatoxin according to claim 1 is augmented the preparation method of health-care sauce essence, it is characterized in that: the hydrochloric acid hydrolysis that adopts 5.5N.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN94110384A CN1054732C (en) | 1994-07-07 | 1994-07-07 | Method for preparation of aflatoxin radically-removed low sodium salt enriched health-care soya sauce |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN94110384A CN1054732C (en) | 1994-07-07 | 1994-07-07 | Method for preparation of aflatoxin radically-removed low sodium salt enriched health-care soya sauce |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1114536A CN1114536A (en) | 1996-01-10 |
| CN1054732C true CN1054732C (en) | 2000-07-26 |
Family
ID=5034357
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN94110384A Expired - Fee Related CN1054732C (en) | 1994-07-07 | 1994-07-07 | Method for preparation of aflatoxin radically-removed low sodium salt enriched health-care soya sauce |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1054732C (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2538805B1 (en) * | 2010-02-23 | 2015-10-07 | Griffith Laboratories International, Inc. | Marinades for meat and seafood containing natural metabolites |
| CN102532085B (en) * | 2011-12-29 | 2014-03-12 | 晨光生物科技集团股份有限公司 | Method for extracting proanthocyanidin from peanut coats |
| CN104522755B (en) * | 2014-12-29 | 2017-11-17 | 晨光生物科技集团股份有限公司 | The removing process of aflatoxin in a kind of cottonseed |
| CN106522003B (en) * | 2016-11-09 | 2019-05-24 | 厦门壳氏新材料科技有限公司 | A kind of processing method of husk |
| CN106638073B (en) * | 2016-11-09 | 2018-12-14 | 厦门壳氏新材料科技有限公司 | A kind of husk processing method of efficient and environment-friendly type |
| CN107997114A (en) * | 2017-12-07 | 2018-05-08 | 浙江海洋大学 | A kind of preparation method of less salt krill soy sauce |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL9000367A (en) * | 1990-02-15 | 1991-09-02 | Feedpro B V I O | Inactivating mycotoxin in particulate raw material for foodstuff - by compressing to expel air, treating with ammonia and steam in reaction chamber, and compressing to expel ammonia and water |
| JPH0670701A (en) * | 1991-11-07 | 1994-03-15 | World Natsutsu:Kk | Method for attenuating aflatoxin and aflatoxin-attenuating solution used in this method |
| CN1086689A (en) * | 1993-06-17 | 1994-05-18 | 高汝云 | The method of a kind of mildew-resistant and the aflatoxin of dispelling |
| CN1088979A (en) * | 1992-12-31 | 1994-07-06 | 孔兆钦 | The brewing method of beer series containing no carcinogen |
-
1994
- 1994-07-07 CN CN94110384A patent/CN1054732C/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL9000367A (en) * | 1990-02-15 | 1991-09-02 | Feedpro B V I O | Inactivating mycotoxin in particulate raw material for foodstuff - by compressing to expel air, treating with ammonia and steam in reaction chamber, and compressing to expel ammonia and water |
| JPH0670701A (en) * | 1991-11-07 | 1994-03-15 | World Natsutsu:Kk | Method for attenuating aflatoxin and aflatoxin-attenuating solution used in this method |
| CN1088979A (en) * | 1992-12-31 | 1994-07-06 | 孔兆钦 | The brewing method of beer series containing no carcinogen |
| CN1086689A (en) * | 1993-06-17 | 1994-05-18 | 高汝云 | The method of a kind of mildew-resistant and the aflatoxin of dispelling |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1114536A (en) | 1996-01-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1054732C (en) | Method for preparation of aflatoxin radically-removed low sodium salt enriched health-care soya sauce | |
| WO1988007822A1 (en) | Product for proteolysis of all proteins | |
| CN108902676A (en) | Wheat-based polypeptide and modified starch compounding wheat analogies and preparation method thereof | |
| CN1389151A (en) | Technological process of producing seasoning with sea food leftover | |
| CN1045875C (en) | Coarse cereal instant noodles and production method thereof | |
| CN1097093A (en) | Cicer arietinum flour product and processing method thereof | |
| CN1280834A (en) | Water-soluble pearl component and its preparing process | |
| CN1197473C (en) | Functional chewing gum with edible gum and its production process | |
| KR20070050693A (en) | Fermented feed and its manufacturing method | |
| CN1077417C (en) | Brewage for health-care supplying iodine sauce extract with low sodium and without aflatoxin | |
| CN1339317A (en) | Poria oral liquor and its producing method | |
| CN1089440A (en) | Produce the method for animal feeding-stuff containing somatic protein with waste mushroom | |
| CN1069180C (en) | Process for low-salt solid closed circulation fermentation of soy sauce | |
| CN1031614C (en) | Treating method for betelnut added in food | |
| CN1374036A (en) | Health tonic and medicine produced with edible fungus and fruit and their production process | |
| CN1128223C (en) | Production process of compound L-amino acid calcium | |
| CN110179127B (en) | Nutrient supplement for promoting absorption of iron, zinc and calcium and preparation method thereof | |
| CN1144096A (en) | Preparation method of spirulina wine | |
| CN102342400A (en) | High-calcium xylitol | |
| CN107969502A (en) | A kind of preparation method for soybean milk powder of refreshing oneself | |
| CN1505982A (en) | Biological enzymolysis process of extracting nutriments from oyster to produce serial products | |
| CN1035016C (en) | Lycium Chinense, black rice beer preparing process | |
| CN1129435C (en) | Germanium Yeast Human Dietary Nutrition Supplement | |
| CN1210696A (en) | Drink made from black maize cob and its processing technology | |
| CN104291904B (en) | A kind of compound method of mung bean special fertilizer |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |