CN105284815B - A kind of composition pesticide containing pyraflufen-ethyl and pyrrole metsulfovax - Google Patents
A kind of composition pesticide containing pyraflufen-ethyl and pyrrole metsulfovax Download PDFInfo
- Publication number
- CN105284815B CN105284815B CN201510794984.XA CN201510794984A CN105284815B CN 105284815 B CN105284815 B CN 105284815B CN 201510794984 A CN201510794984 A CN 201510794984A CN 105284815 B CN105284815 B CN 105284815B
- Authority
- CN
- China
- Prior art keywords
- ethyl
- pyraflufen
- pyrrole metsulfovax
- composition pesticide
- cotton
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- KAESVJOAVNADME-UHFFFAOYSA-N Pyrrole Chemical compound C=1C=CNC=1 KAESVJOAVNADME-UHFFFAOYSA-N 0.000 title claims abstract description 57
- UDSJPFPDKCMYBD-UHFFFAOYSA-N Metsulfovax Chemical compound S1C(C)=NC(C)=C1C(=O)NC1=CC=CC=C1 UDSJPFPDKCMYBD-UHFFFAOYSA-N 0.000 title claims abstract description 30
- 239000005605 Pyraflufen-ethyl Substances 0.000 title claims abstract description 29
- APTZNLHMIGJTEW-UHFFFAOYSA-N pyraflufen-ethyl Chemical group C1=C(Cl)C(OCC(=O)OCC)=CC(C=2C(=C(OC(F)F)N(C)N=2)Cl)=C1F APTZNLHMIGJTEW-UHFFFAOYSA-N 0.000 title claims abstract description 29
- 239000000203 mixture Substances 0.000 title claims abstract description 26
- 239000000575 pesticide Substances 0.000 title claims abstract description 18
- 229920000742 Cotton Polymers 0.000 claims abstract description 26
- 201000010099 disease Diseases 0.000 claims abstract description 16
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 claims abstract description 16
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 8
- 239000000375 suspending agent Substances 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 235000010489 acacia gum Nutrition 0.000 claims description 4
- 239000001785 acacia senegal l. willd gum Substances 0.000 claims description 4
- 229920005551 calcium lignosulfonate Polymers 0.000 claims description 4
- RYAGRZNBULDMBW-UHFFFAOYSA-L calcium;3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Ca+2].COC1=CC=CC(CC(CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O RYAGRZNBULDMBW-UHFFFAOYSA-L 0.000 claims description 4
- 235000011187 glycerol Nutrition 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- 239000004576 sand Substances 0.000 claims description 4
- 239000000843 powder Substances 0.000 claims description 3
- 239000002994 raw material Substances 0.000 claims 2
- 239000004480 active ingredient Substances 0.000 abstract description 7
- 230000003449 preventive effect Effects 0.000 abstract description 4
- 239000012752 auxiliary agent Substances 0.000 abstract description 3
- 230000001225 therapeutic effect Effects 0.000 abstract 1
- 241000219146 Gossypium Species 0.000 description 22
- 230000000694 effects Effects 0.000 description 10
- 239000003795 chemical substances by application Substances 0.000 description 8
- 241000196324 Embryophyta Species 0.000 description 7
- 239000003814 drug Substances 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 230000002265 prevention Effects 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 230000000844 anti-bacterial effect Effects 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 3
- 238000007667 floating Methods 0.000 description 3
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 239000003899 bactericide agent Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 230000035613 defoliation Effects 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 230000002363 herbicidal effect Effects 0.000 description 2
- 239000004009 herbicide Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- ZSDSQXJSNMTJDA-UHFFFAOYSA-N trifluralin Chemical compound CCCN(CCC)C1=C([N+]([O-])=O)C=C(C(F)(F)F)C=C1[N+]([O-])=O ZSDSQXJSNMTJDA-UHFFFAOYSA-N 0.000 description 2
- PFFIDZXUXFLSSR-UHFFFAOYSA-N 1-methyl-N-[2-(4-methylpentan-2-yl)-3-thienyl]-3-(trifluoromethyl)pyrazole-4-carboxamide Chemical compound S1C=CC(NC(=O)C=2C(=NN(C)C=2)C(F)(F)F)=C1C(C)CC(C)C PFFIDZXUXFLSSR-UHFFFAOYSA-N 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 208000028399 Critical Illness Diseases 0.000 description 1
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Divinylene sulfide Natural products C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 description 1
- 241000221785 Erysiphales Species 0.000 description 1
- 240000002024 Gossypium herbaceum Species 0.000 description 1
- 235000004341 Gossypium herbaceum Nutrition 0.000 description 1
- 239000005816 Penthiopyrad Substances 0.000 description 1
- 241000228452 Venturia inaequalis Species 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 244000052616 bacterial pathogen Species 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 239000007884 disintegrant Substances 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000004494 ethyl ester group Chemical group 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000035558 fertility Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 230000002262 irrigation Effects 0.000 description 1
- 238000003973 irrigation Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000004530 micro-emulsion Substances 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 230000000361 pesticidal effect Effects 0.000 description 1
- 150000008048 phenylpyrazoles Chemical class 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000009331 sowing Methods 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 208000024891 symptom Diseases 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 229930192474 thiophene Natural products 0.000 description 1
- 230000017260 vegetative to reproductive phase transition of meristem Effects 0.000 description 1
- 239000004562 water dispersible granule Substances 0.000 description 1
- 239000004563 wettable powder Substances 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of composition pesticide containing pyraflufen-ethyl and pyrrole metsulfovax.It includes active ingredient and auxiliary agent, and wherein active ingredient is made up of pyraflufen-ethyl and pyrrole metsulfovax, and the weight ratio of the two is 1：5~1：10, active ingredient accounts for the 15%~50% of composition pesticide gross weight.The present composition has obvious preventive and therapeutic effect to cotton bell disease, plays a part of protecting bell volume increase, and dosage is few, facilitates dispenser, alleviates the pollution to environment.
Description
Technical field
The present invention relates to a kind of composition pesticide containing pyraflufen-ethyl and pyrrole metsulfovax, for preventing and treating cotton bell disease, belongs to agriculture
Industry technical field.
Background technology
Cotton bell disease is the general designation of cotton flowering and boll-setting period disease, and the upper bell of Cotton in China production is critically ill evil seriously.The essentialspecies of bell disease
Class has：Epidemic disease, rouge and powder disease, anthracnose, red rot etc., can fall ill in Growth of Cotton Boll period, the bell phase susceptible cotton that can directly cause harm
Bell, the symptom such as stiff valve, rotten is caused, has a strong impact on cotton quality and yield.
Pyraflufen-ethyl (Pyraflufen-ethyl), chemical name：The chloro- 5- of 2- (the chloro- 5- difluoro-methoxies -1- methyl pyrroles of 4-
Azoles -3- bases) -4- fluorophenoxyacetate ethyl esters are a kind of phenyl pyrazoles herbicide after seedling.After the medicament cauline leaf process, it can
It is rapidly absorbed in plant tissue, makes plant downright bad rapidly, or make cauline leaf dehydration withered under sunlight, has well
Defoliation effect.
Pyrrole metsulfovax (Penthiopyrad), chemical name：(RS)-N- [2- (1,3- dimethylbutyls) -3- thiophene phenyls] -
1- methyl -3- (trifluoromethyl) -1H- pyrazole-4-carboxamides, for the novel amide-type sterilization of Mitsui chemical company research and development
Agent, it has different fungicidal spectrums from existing carboxyl acylamide bactericide, there is excellent activity to rust, sclerotiniose, to gray mold,
Powdery mildew and scab of apple etc. also show that preferable bactericidal activity, to crop and Environmental security.
The content of the invention
It is an object of the invention to provide a kind of composition pesticide containing pyraflufen-ethyl and pyrrole metsulfovax.Pyrrole grass in said composition
Ether composition has defoliation effect, can improve cotton plants middle and lower part Growth of Cotton Boll environment, is allowed to be unfavorable for pathogenic bacteria to infect and give birth to
It is long, while pyrrole metsulfovax composition can effectively prevent and treat cotton bell disease.The composite behaviour is excellent, and protection effect is excellent, and reducing medicament makes
Dosage, beneficial to environmental protection.
The technical scheme is that：A kind of composition pesticide containing pyraflufen-ethyl and pyrrole metsulfovax, it is characterized in that, include
Effect composition and auxiliary agent, wherein active ingredient are made up of pyraflufen-ethyl and pyrrole metsulfovax, and the weight ratio of the two is 1：5~1：10, effectively
Composition accounts for the 15%~50% of composition pesticide gross weight.
Further, above-mentioned composition pesticide can be according to well known to a person skilled in the art method, using suitable agriculture
Medicine auxiliary agent, it is configured to the suitable agent agriculturally used such as suspending agent, dispersible oil-suspending agent, water dispersible granules, wettable powder
Type.Above-mentioned insecticides adjuvant includes solvent, emulsifying agent, wetting agent, disintegrant, stabilizer, dispersant, thickener, penetrating agent, pH and adjusted
Section agent, defoamer, antifreezing agent, carrier etc. are beneficial to the known substance that drug effect is stablized and played to active ingredient in the formulation, are all
It is to be commonly used in pesticidal preparations or allow the various composition used, specific composition and dosage to be determined according to recipe requirements by testing.
It is a further object to provide the above-mentioned composition pesticide containing pyraflufen-ethyl and pyrrole metsulfovax in preventing and treating cotton
The application of bell disease aspect, above-mentioned cotton bell disease include epidemic disease, rouge and powder disease, anthracnose, red rot etc..
The composition pesticide of the present invention prevents and treats the sick method of cotton bell：In cotton boll early stage, using pyraflufen-ethyl pyrrole
Metsulfovax suspending agent or other preparations, water is added to be made into suspension spray administration.
The beneficial effects of the invention are as follows：The present invention has obvious prevention effect to cotton bell disease, plays and protects bell volume increase
Effect.After the present invention is with pyraflufen-ethyl and pyrrole metsulfovax compounding simultaneously, its prevention effect has than bactericide pyrrole metsulfovax is used alone
Significantly improve, and reduce the dosage of agricultural chemicals, reduce cost.And dosage is few, facilitate dispenser, alleviate to ring
The pollution in border, application value is big, and economic and social benefit is very notable.
Embodiment
Matching somebody with somebody for composition pesticide of the present invention containing pyraflufen-ethyl and pyrrole metsulfovax can pass through embodiment 1, embodiment 2
It is specifically described with embodiment 3, but not limited to this.
Embodiment 1：
Match (parts by weight)：Pyraflufen-ethyl 3%, pyrrole metsulfovax 15%, calcium lignosulfonate 3%, empgen BB
4%, AEO 5%, glycerine 5%, Arabic gum 0.1%, remaining is supplied with water.By above-mentioned formula in proportion
Crushed in advance, add in sand mill and grind, obtained 18% pyraflufen-ethyl pyrrole metsulfovax is allocated after high shear mixing and is hanged
Floating agent.
Embodiment 2：
Match (parts by weight)：Pyraflufen-ethyl 3%, pyrrole metsulfovax 20%, calcium lignosulfonate 3%, empgen BB
4%, AEO 5%, glycerine 5%, Arabic gum 0.1%, remaining is supplied with water.By above-mentioned formula in proportion
Crushed in advance, add in sand mill and grind, obtained 23% pyraflufen-ethyl pyrrole metsulfovax is allocated after high shear mixing and is hanged
Floating agent.
Embodiment 3：
Match (parts by weight)：Pyraflufen-ethyl 3%, pyrrole metsulfovax 30%, calcium lignosulfonate 3%, empgen BB
4%, AEO 5%, glycerine 5%, Arabic gum 0.1%, remaining is supplied with water, by above-mentioned formula in proportion
Crushed in advance, add in sand mill and grind, obtained 33% pyraflufen-ethyl pyrrole metsulfovax is allocated after high shear mixing and is hanged
Floating agent.
Comparative example 1：
2% pyraflufen-ethyl microemulsion.
Comparative example 2：
20% pyrrole metsulfovax suspending agent.
For checking pyraflufen-ethyl and the prevention effect of pyrrole metsulfovax, the present invention has carried out field to pyraflufen-ethyl and pyrrole metsulfovax mixture
Between the test of pesticide effectiveness process it is as follows：
Each 66.6 square metres of plot area is tested, is often handled in triplicate.
Test site：Stubble is cotton before Selection experiment cotton field, and fertility is higher, and irrigation condition is good, and weed in cotton field is less, four
All environment are cotton, and herbicide used in cotton field is mixed native to broadcast preceding trefanocide (Trifluralin).
Experimental planting management condition：It is spring sowing cotton for studying thing, cotton culture managerial skills are higher, it is ensured that cotton is just
It is frequently grown development.Every mu of planting density is 3500-4000 strains.
Insecticide-applying way：Before Cotton Boll Rot big generation 10-15 days (about early August) dispenser once, using manually bearing
Shi Linong board sprayer spray pesticides, spray piece bore 0.7mm, pump enough air in, even spraying in bell table, middle and lower part blade and ground,
Every mu of actual used water amount is 60 liters (900 liters/hectare).
Investigation method and number：Two row cottons (sum is no less than 40 plants) are fixed per cell, investigate medicine respectively after administration
The rotten bell sum of 7,14 and 21 days afterwards.
Preventive effect calculates：
Preventive effect (%)=(the rotten bell number of the average individual plant of the rotten bell number-processing of the average individual plant of control)/rotten bell number of the average individual plant of control
×100
Result of the test refers to table 1.
Prevention effect of the composition pesticide of the invention containing pyraflufen-ethyl and pyrrole metsulfovax of table 1 to cotton bell disease
As can be seen from Table 1：Synergistic effect is obvious after pyraflufen-ethyl and pyrrole metsulfovax compounding, obvious to the preventive effect of cotton bell disease
It is better than single dose, is significantly reduced when the amount ratio of active ingredient is used alone in compound drug, total active ingredient is also relative to be reduced, from
And alleviate carrying capacity of environment, reduce use cost.
Claims (2)
1. a kind of composition pesticide containing pyraflufen-ethyl and pyrrole metsulfovax, it is characterized in that, the composition pesticide is suspending agent, it by
Following weight than raw material be made：Pyraflufen-ethyl 3%, pyrrole metsulfovax 30%, calcium lignosulfonate 3%, empgen BB
4%, AEO 5%, glycerine 5%, Arabic gum 0.1%, remaining is supplied with water；By the advance powder of above-mentioned raw materials
It is broken, add in sand mill and grind, allocate that 33% pyraflufen-ethyl pyrrole metsulfovax suspending agent is made after high shear mixing.
2. application of the composition pesticide containing pyraflufen-ethyl and pyrrole metsulfovax in terms of cotton bell disease is prevented and treated described in claim 1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510794984.XA CN105284815B (en) | 2015-11-18 | 2015-11-18 | A kind of composition pesticide containing pyraflufen-ethyl and pyrrole metsulfovax |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510794984.XA CN105284815B (en) | 2015-11-18 | 2015-11-18 | A kind of composition pesticide containing pyraflufen-ethyl and pyrrole metsulfovax |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105284815A CN105284815A (en) | 2016-02-03 |
| CN105284815B true CN105284815B (en) | 2018-02-13 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510794984.XA Expired - Fee Related CN105284815B (en) | 2015-11-18 | 2015-11-18 | A kind of composition pesticide containing pyraflufen-ethyl and pyrrole metsulfovax |
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Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108477151A (en) * | 2018-04-10 | 2018-09-04 | 山东棉花研究中心 | A kind of composition pesticide of the metsulfovax containing pyrrole and its application |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2705201B1 (en) * | 1993-05-19 | 1995-07-07 | Rhone Poulenc Agrochimie | Herbicide mixtures based on diflufenican and a 3-phenylpyrazole compound. |
| EP2822387A1 (en) * | 2012-03-01 | 2015-01-14 | Basf Se | Agrochemical compositions |
| CN103704220B (en) * | 2012-09-28 | 2015-01-14 | 深圳诺普信农化股份有限公司 | Compound antibacterial composition containing penthiopyrad |
| CN103704217A (en) * | 2012-10-09 | 2014-04-09 | 深圳诺普信农化股份有限公司 | Antibacterial composition |
| CN104082329A (en) * | 2014-07-23 | 2014-10-08 | 江苏瑞东农药有限公司 | High-efficiency cotton defoliating and boll-increasing composition |
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| Publication number | Publication date |
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| CN105284815A (en) | 2016-02-03 |
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