CN1050281C - Agent for treatment of hair - Google Patents

Abstract

The water-based hair treatment agent composed of cellulose-based cationic polymers and zwitterionic polymers has very good hair wet combing properties, and delays dry combing properties within a certain range, which is very important for fixed hairstyles. Ideal.

Description

hair treatment agent

The present invention relates to hair treatments comprising specific combinations of polymers.

The cleaning and maintenance of hair is an important part of human body maintenance. Shampooing and hairdressing, such as hair dyeing or perm, have damaging effects on the natural structure and properties of hair. After the hair is thus treated, for example, the wet and dry combability, the tenacity and fullness of the hair are not satisfactory, or the hair breakage increases.

Specific post-treatments have thus long been customary, the usual method being to treat the hair in a rinse-off manner with specific agents such as quaternary ammonium salts or specific polymers. Hair treated with this formulation has improved combability, strength and body, and reduced breakage.

Adding cationic polymers to hair treatment agents generally improves wet combing and dry combing properties; adding amphoteric or zwitterionic polymers can greatly improve wet combing properties, but has little effect on dry combing properties.

Further advantageous effects are often obtained in combination with several different types of active substances. For example German patent DE-A1-3044738 is known to improve hair treatment agents after adding mixtures of amphoteric and cationic polymers.

While this is desirable in all cases due to improved combability, ie reduced wet combing, the situation with dry combing is more complicated. While low combing action values characterize an improved combing action, at very low combing action the hair loses its firmness and fullness, so that in extreme cases no set style can be achieved. Therefore, in more complex hairstyles, it is entirely hopeful to improve the dry combing operation within a certain limit to improve the toughness of the hairstyle.

It has now surprisingly been found that formulations consisting of zwitterionic polymers in combination with certain cationic polymers lead to unexpected improvements in the properties of the hair.

Thus, the subject of the present invention comprises water-soluble formulations for the treatment of hair, containing, in addition to conventional cosmetic ingredients, compositions of cationic and zwitterionic polymers, characterized in that the cationic polymers of cellulose derivatives without imidazoline groups .

Cationic polymers useful in the present invention relate to cellulose derivatives.

Such cellulose derivatives are obtained by modifying the main chain of cellulose with cationic groups.

Examples of cellulosic hosts are cellulose, methylcellulose, ethylcellulose, hydroxyethylcellulose, hydroxypropylcellulose and methylhydroxypropylcellulose.

The conventionally used cationic groups are quaternary ammonium or phosphonium groups, preferably quaternary nitrogen atoms. The quaternary nitrogen atoms can have 4 different or partially identical substituents, and can also be part of the ring system. Preferred substituents are alkyl, aryl, alkaryl, cycloalkyl, alkoxyalkyl and alkoxyaryl groups having 1 to 4 carbon atoms, particularly preferred are trialkylammonium groups, especially trimethylammonium base. The cationic groups can be attached to the cellulose-based chain either directly or via intermediate groups. Preferred polymers are those in which cationic groups are linked to cellulose-based chains via alkyl chains or alkoxyalkyl groups. Anions corresponding to cationic groups are preferably halide groups, especially chloride groups, and methoxysulfate groups.

Examples of these compounds are described in US Patent 3,472,840, sold under the tradename Polymer JR ^R.

Another class of cationic cellulose derivatives is composed of cationic and nonionic units.

The cationic units may be equivalent to the above-mentioned cationic cellulose derivatives.

The cationic unit can also be a compound which, in addition to at least one cationic group, also has at least one polymerizable group. The polymerizable group is preferably vinyl. These cationic groups are preferably the aforementioned ammonium groups. These cationic units are, for example, diallyldimethylammonium chloride, methacrylamidopropyltrimethylammonium chloride, dimethylaminomethacrylate quaternized with diethylsulfate and diethylsulfate Quaternized dimethylaminoethyl methacrylate.

Nonionic units are for example cellulose, methylcellulose, ethylcellulose, hydroxyethylcellulose, hydroxypropylcellulose, methylhydroxypropylcellulose, vinylpyrrolidone, vinyl acetate, acrylamide, formazan Acrylamide, methyl acrylate, ethyl acrylate, methyl methacrylate and ethyl methacrylate. A preferred nonionic unit is hydroxyethylcellulose.

Examples of such copolymers are the compounds available under the name Celguat ^R.

Preferred polymers within the scope of the inventive concept are cationic copolymers consisting of at least one cationic unit and at least one nonionic unit. Particularly preferred is hydroxyethyl cellulose as a nonionic unit in the copolymer.

Celgua-t ^R L200, a copolymer composed of hydroxyethylcellulose and diallyldimethylammonium chloride, is a particularly preferred cationic polymer.

"Zwitterionic polymer" refers to a polymer containing quaternary ammonium groups and -COO- or -SO ₃ - groups in the molecule.

Examples of zwitterionic polymers described in the present invention are the compounds described in British Patent 2104091, European Patent 47714, 283817 and German Patent 2817369.

Particularly preferred zwitterionic polymers consist essentially of:

(α) the monomer containing quaternary ammonium group of general formula (I)

R ¹ -CH=CR ² -CO-X-(C _n H _2n )-N ⁽⁺⁾ R ³ R ⁴ R ⁵ A ^(-) (I) In the formula, R ¹ and R ² are independently hydrogen or methyl , R ³ , R ⁴ and R ⁵ are each independently an alkyl group of 1-4 carbon atoms, X is -NH or an oxygen atom, n is an integer of 2-5, A ^- is an organic or inorganic acid anion;

(β) monomeric carboxylic acid of general formula (II)

R ⁶ -CH=CR ⁷ -COOH (II) In the formula, R ⁶ and R ⁷ are each independently hydrogen or methyl.

These compounds can be used in the present invention either directly or in the form of salts, for example obtained by neutralizing the polymer product with an alkali metal hydroxide. The details of the preparation of these polymer products are explicitly referred to in German patent 3929973.

Particularly preferred polymers obtained from monomers of type (α) are those in which R ³ , R ⁴ and R ⁵ are methyl groups, X is an NH-group, ^A- is a halide ion, a methoxysulfate ion or an ethoxysulfate ion ; Acrylamidopropyltrimethylammonium chloride is a particularly preferred monomer of type (α). The above-mentioned (β)-type monomer is preferably acrylic acid or an alkali metal acrylic acid salt, especially a sodium salt.

In addition, the zwitterionic polymer preferably has a larger number of (α)-type monomers than (β)-type monomers, particularly preferably a ratio of (α):(β) monomers greater than 1.5.

The content of cationic and zwitterionic polymers used in the formulation of the invention is 0.01-10% by weight, particularly preferably 0.01-5% by weight, based on the total weight of the formulation.

Formulations containing cationic polymer to zwitterionic polymer between 5:1 and 1:1 by weight showed particularly strong effects.

It has also been found that particularly good results for the context of the invention are obtained when surfactants are added to the formulations according to the invention. This thus relates to anionic, cationic, amphoteric, zwitterionic or nonionic surfactants.

Examples of cationic surfactants used in the hair treatment agents of the present invention are especially quaternary ammonium compounds. Preferred ammonium halides such as alkyltrimethylammonium chloride, dialkyldimethylammonium chloride, trialkylmethylammonium chloride, e.g. cetyltrimethylammonium chloride, stearyltrimethylammonium chloride, Fatty Dimethyl Ammonium, Lauryl Dimethyl Ammonium Chloride, Lauryl Dimethyl Benzyl Ammonium Chloride and Tricetyl Methanum Chloride. Further useful cationic surfactants according to the invention are quaternized protein hydrolysates.

Cationic silicone oils are also suitable for use in the present invention, such as commercially available product Q2-7224 (manufacturer: Dow Corning; a stabilized trimethylsilyl hydroxyamino modified silicon), Dow Corning 929 emulsion (containing hydroxy-amino- Modified silicon, also known as Amodimethicone), SM-2059 (manufacturer: General Electric), SLM-55067 (manufacturer: Wacker), and Abil ^R -Quat3270 and 3272 (manufacturer: Th.Goldschmidt; diquaternized poly Dimethicone, Quaternium-80).

Alkylamidoamines, especially fatty amidoamines, such as stearamidopropyldimethylamine sold under the name Tego Amid ^R S18, have specifically good biodegradability in addition to a good hair care effect.

Quaternized esterified compounds, so-called "Esterquats", are also very biodegradable, such as dialkylammonium methoxysulfate and methyl-hydroxyalkyl-dioxane methoxysulfate sold under the trade name Stepantex ^R Acyloxyalkylammonium.

Examples of quaternized sugar derivatives which may be mentioned as cationic surfactants are the commercial product Gluequat ^R 100, under the CTFA designation "Laurylmethylglucose-10 Hydroxypropyldiammonium Chloride".

Particularly preferred cationic surfactants are trialkylamidoamines, quaternized ester derivatives and quaternized sugar derivatives.

The anionic surfactants suitable for the formulation of the present invention are all anionic surface-active substances suitable for the human body. It is characterized by a water-soluble anionic group such as carboxylate, sulfate, sulfonate or phosphate and a lipophilic alkyl group having about 10-22 carbon atoms. The molecule may also contain glycol ether or polyglycol ether groups, ester groups, ether groups, amido groups and hydroxyl groups. Examples of suitable anionic surfactants are each their sodium, potassium, ammonium salts and mono-, di- and trialkanol ammonium salts with 2 or 3 carbon atoms in the chain alcohol group, - with 10 to 22 carbon atoms straight-chain fatty acid (soap) of the formula RO-(CH ₂ -CH ₂ O) _x -CH ₂ -COOH ether-based carboxylic acid, R is 10

An alkyl group with ～22 carbon atoms, X=0 or 1～16, ——acyl sarcosine with an acyl group with 10 to 18 carbon atoms, ——acyl taurine with an acyl group with 10 to 18 carbon atoms, — - acyl isethionates with an acyl group of 10 to 18 carbon atoms, - mono- and di-alkyl sulfosuccinates with an alkyl group of 8 to 18 carbon atoms, and alkyl groups

Monoalkyl polysulfosuccinic acid with 8 to 18 carbon atoms and 1 to 6 oxyethyl groups

Oxyethyl esters, - linear alkyl sulfonates having 12 to 18 carbon atoms, - linear alpha-olefin sulfonates having 12 to 18 carbon atoms, - having 12 to 18 carbon atoms Atomic fatty acid α-thio fatty acid methyl ester, - formula RO (CH ₂ -CH ₂ O) _x -OSO ₃ H alkyl sulfate and alkyl polysulfate

Ethylene glycol ether ester, R is preferably a linear alkyl group with 10 to 18 carbon atoms, X=0 or 1

～12,——according to German patent DE-A-3725030 there is the hydroxysulfonic acid ester of surface activity

Mixtures, - sulfated hydroxyalkyl polyglycol ethers according to German patent DE-A-3723354

And (or) hydroxy allyl propylene glycol ether, - according to German patent DE-A-3926344, containing 12-24 carbon atoms and 1-6

Sulfonate of unsaturated fatty acid with double bond, - ester of tartaric acid and citric acid with alcohol, alcohol is 2-15 molecules of ethylene oxide and

(or) Addition products of propylene oxide and fatty alcohols with 8 to 22 carbon atoms.

The preferred anionic surfactant is alkyl sulfate, the alkyl group in the molecule is 10 to 18 carbon atoms and there are up to 12 glycol ether groups of alkyl polyglycol ether sulfate and ether-based carboxylic acid , and monoalkyl and dialkyl sulfosuccinates with an alkyl group of 8 to 18 carbon atoms, monoalkyl polysulfosuccinates with an alkyl group of 8 to 18 carbon atoms and 1 to 6 oxyethyl groups Oxyethyl ester.

Zwitterionic surfactants are compounds having at least one quaternary ammonium group and at least one ^-COO- or -SO ₃ ^- group in the molecule. Particularly suitable zwitterionic surfactants are so-called inner salts, such as N-alkyl-N,N-dimethylammonium-glycinates, e.g. cocoyl-dimethylammonium glycinates, N-acyl-aminopropyl-N , N-dimethylammonium glycinate, such as cocamidopropyl-dimethylammonium-glycinate, and 2-alkyl-3-carboxymethyl-3-hydroxyethyl-imidazoline, on the alkyl or acyl group Each has 8 to 18 carbon atoms, and cocamide ethyl hydroxyethyl carboxymethyl glycinate. A preferred zwitterionic surfactant is the known fatty acid amide derivative known under the CTFA designation cocamidopropyl inner salt.

Amphoteric surfactants are compounds which, in addition to C _8-18 -alkyl or acyl groups, contain at least one free amino group and at least one -COOH or -SO ₃ H group in the molecule, thus capable of forming internal salts. Examples of suitable amphoteric surfactants are N-alkylglycine, N-alkylaminopropionic acid, N-alkylaminobutyric acid, N-alkyliminodipropionic acid, N-hydroxyethyl-N-alkylaminopropyl Glycine, N-alkyl taurine, N-alkyl sarcosine, 2-alkylaminopropionic acid and alkylaminoacetic acid with 8 to 18 carbon atoms in the alkyl group. Particularly preferred amphoteric surfactants are N-cocoylaminopropionate, cocoylethylaminopropionate and _C12-18 -acylcysaminopropionate.

Nonionic surfactants contain hydrophilic groups such as polyol groups, polyalkylene glycol ether groups or combinations of polyol ethers and polyethylene glycol ether groups. These compounds are, for example: - 2 to 30 molecules ethylene oxide and (or) 0 to 5 molecules of propylene oxide and 8 to 22

Straight chain fatty alcohols with carbon atoms, fatty acids with 12 to 22 carbon atoms or alkyl groups with 8 to

Addition products of alkylphenols with 15 carbon atoms, C ₁₂ -C ₂₂ -fatty acids of addition products of 1-30 molecules of ethylene oxide and glycerol

Monoesters or diesters, - C ₈ to C ₂₂ alkyl mono- or oligoglucosides and their ethoxylated analogues, - 5 to 60 molecules of ethylene oxide with castor oil and hardened castor oil the addition product.

The compounds having an alkyl group used as surfactants may be the same in many cases. However, it is generally preferred to manufacture these substances from natural vegetable or animal raw materials, so that mixtures are obtained which have different alkyl chain lengths depending on the raw material.

Surfactants prepared from addition products of ethylene oxide and/or propylene oxide to fatty alcohols or derivatives of these products, either with a "normal" homologue distribution or with Product of narrow homologue distribution. By "normal" homogeneous distribution is meant a mixture of homologues formed by the reaction of fatty alcohols with alkylene oxides using alkali metals, alkali metal hydroxides or alkali metal alcoholates as catalysts. If, for example, hydrotalcite, alkaline earth metal salts of ether carboxylates, oxides, hydroxides or alcoholates of alkaline earth metals are used as catalysts, surfactants with a narrow homolog distribution, by contrast, are obtained. It may be preferable to use products with such a narrow homologue distribution.

The amount of surfactant used in the formulations of the present invention depends on the type of surfactant and the purpose of the formulation.

The content of cationic and/or nonionic surfactants in the hair aftertreatment is preferably 0.1-10% by weight, particularly preferably 0.1-3% by weight, based on the total weight of the formulation.

The cationic and/or nonionic surfactant content in the hair conditioner is also preferably 0.1-10% by weight, particularly preferably 0.1-5% by weight, based on the total amount of the formulation.

Shampoo preferably contains anionic surfactant, optionally combined with amphoteric and (or) nonionic surfactant, its content is 1～50% (weight) based on the total amount of formulation, especially preferably 3～20% (weight) .

The pH value of the formulation of the present invention is preferably 2.5-7, especially 3-6.

Shampoos, hair aftertreatments and conditioners are preferred formulations of the present invention. However, the formulation is also used in permanent curl formulations, hair dyes, dry irons and other conventional hair treatments.

The formula can be used in water-based or water-alcoholic solution, cream, lotion, jelly, emulsion and other dosage forms for making hairstyle cosmetics.

Formulations in the field of hair treatments and hair styling products also contain other known ingredients, these conventional ingredients are: - non-ionic polymers, such as vinylpyrrolidone/vinyl acrylate copolymers, poly

Vinylpyrrolidone and vinylpyrrolidone/vinyl acetate copolymer and polysilicon

oxane. - Anionic polymers such as polyacrylic acid, cross-linked polyacrylic acid, vinyl acetate/croton

Acid Copolymer, Vinylpyrrolidone/Vinyl Acetate Copolymer, Vinyl Acetate/

Butyl Maleate/Isobornyl Acrylate Copolymer, Methyl Vinyl Ether/Maleic Anhydride

Copolymer/acrylic acid/ethyl acrylate/N-tert-butylacrylamide terpolymer

things. - thickeners such as agar, guar gum, alginate, Xanthan-Gum (biosynthetic polymer

glue) and cellulose derivatives.

- structurants such as glucose and maleic acid, - hair care compounds such as phospholipids, such as soy lecithin, lecithin and cephalin, and

and silicone oils, - protein hydrolysates, especially elastin, collagen, keratin, milk protein, large

Hydrolysates of soy protein and wheat protein, their condensation products with fatty acids and

Quaternized protein hydrolysates, - fragrances, dimethylisosorbide and cyclodextrins, - solvents such as ethanol, isopropanol, ethylene glycol, propylene glycol, glycerol and diethylene glycol, - colorants agent,

- Anti-dandruff agents such as Piroctone Olamine and Zinc Omatine, - Other pH regulators, - Active substances such as panthenol, allantoin, pyrrolidone carboxylic acid and its salts, plant extracts and

Vitamins, - opacifiers, - thickeners, such as sugar esters, polyalcohol esters or polyalcohol alkyl ethers, - fats and waxes, such as spermaceti, beeswax, montan wax, paraffin and fatty alcohols, - fatty acids Alkanolamides, - complexing agents such as EDTA, NTA and phosphoric acid, - swelling and penetrating agents, such as glycerin, propylene glycol monoethyl ether, carbonates, bicarbonates, guanidine,

Urea and primary, secondary, and tertiary phosphates, - clouding agents such as latex, - pearlescent agents such as ethylene glycol mono and distearate, - aerosols such as propane-butane mixtures, N ₂ O , dimethyl ether, _CO2 and air, - antioxidants, - direct dyes, - so-called chromogenic and chromogenic components as precursors of oxidation dyes, - reducing agents such as thioglycolic acid and its derivatives , thiolactic acid, cysteamine, thioapple

Acids and alpha-mercaptoethanesulfonic acid, - oxidizing agents such as hydrogen peroxide, potassium bromate and sodium bromate.

Methods of treating hair with the formulations of the invention are also within the scope of the invention.

The preferred usage is to apply the effective components of the formulation of the present invention on the hair, and after a certain period of time (generally several seconds to about 20 minutes), wash it off from the hair with water or a cleansing agent that is mainly water.

The following examples further illustrate the invention.

The measurement research method of embodiment 1 wet combing property

Wet combability was determined by two different methods. Method 1 is based on the objective measurement of wet combing properties, and Method 2 is based on the subject's subjective evaluation. method 1:

Combability research is carried out according to the method of J.Soc.Cosm.Chen.1973 [24] 782.

Combability was all studied on brunette hair (Alkinco #6634, hair length 12cm, hair weight 1g), which relates to lightly pre-damaged hair (cold permed or dyed blond), as the average user would expect. After the zero measurement, the hair was immersed in 100ml of the test solution, and after acting for 5 minutes, it was rinsed with running water (1 l/min, 38° C.) for 1 minute. Hair was retested to determine wet combability. Method 2:

Locks of approximately 2 g in weight from the Kerling company were pre _- damaged respectively for permanent curl treatment and for "medium gold coloring" (treatment of the hair with a 6% _H2O2 solution brought to a pH value of 9.4 with the addition of ammonia for 30 minutes) and then treated with the addition of An aqueous solution of 12% active substance Texapon N25 (sodium lauryl ether sulfate) was washed twice and the hair was treated with 0.5 g of the test solution for 2 minutes. Finally, rinse with warm water at 30°C. result

In Table 1 the compositions of the tested mixtures and the combability results are listed. The values for carding operations according to method 1 are calculated on the basis of the measured value of zero. Meanings of symbols for subjective evaluation according to method 2: 1=very good, 2=good, 3=satisfactory, 4=pass, 5=fail.

Table 1

〔The amount indicated is by weight〕 Ingredient/Mixture V1 V2 E1 V3 V4 Celquat ^R L 200 ¹ 0,1 - 0,05 - 0,05 Acrylamidopropylmethylammonium chloride/dienoic acid-copolymer, neutralized with sodium hydroxide (polymer P1 according to DE 39 29 973) - 0,1 0,05 - -Amphomer ^{R 1a} - - - 0,1 0,05 water ←---------- 100 ----------→ Wet combing method 1 [%] 64 46 43 85 72 by method 2 2-3 2-3 1-2 3-4 3 1. Hydroxyethylcellulose/diallyldimethylammonium chloride (95% active substances; CTFA designation: Polyquaternium-4) (Delft National) 1a. Methyl methacrylate-tert-butylaminoethyl methacrylate-formazan 2-hydroxypropyl acrylate-N(1,1,3,3-tetramethylbutyl)acrylamide copolymer. II. Measurement and Research Method of Curl Holding Ability

15 cm long locks of hair (Kerling company, hair weight: 2 g) are treated with 0.5 g of the test mixture for 2 minutes. The hair was then rinsed, wrapped around a glass tube with an outer diameter of 2.0 cm, fixed and dried. The stability of the curls obtained after pulling out the glass rod is the so-called "curl retention value" (CR-value), which is defined as [(ll _x )/(ll _o )] x 100%, where 1 lock of hair The length (15cm), l _o is the length of the hair curl measured immediately after drying, and l _x is the length of the hair curl after hanging for X hours in the drying cabinet under standard conditions (25°C, relative air humidity 60%). result

Table 2 shows the test results of curl retention ability.

Table 2 Measured value/mixture V1 V2 E1 V3 V4 CR value after 6 hours (%) 81,4 82,6 86,5 88,4 82,98 hours (%) 79,8 79,7 83,7 86,2 81,3

The CR values of treatment with pure water were 83.2 (after 6 hours) and 79.9 (after 8 hours). III. Application Examples

The marked amount of the following examples is % by weight 1) Shampoo Stenol ^R 1618 ² 3,0 Cutina ^R GMS ³ 0,5 Eumulgin ^R B 1 ⁴ 0,4 Eumulgin ^R B 2 ⁵ 0,8 Eutanol ^R G ⁶ 1,0 Chlorinated acrylamide Propyltrimethylamine/acrylic acid copolymer, neutralized with sodium hydroxide (polymer P1 as per DE 39 29 973) 0,2 Celquat ^R L200 1,0 Gafquat ^R 755-N ⁷ 2,5 Water Add to 1002.C ₁₆ / C ₁₈ - fatty alcohol (HENKEL) 3. Glycerol monostearate (CTFA designation: glyceryl stearate) (HENKEL) 4. Adduct of cetyl stearyl alcohol with about 12 molecules of ethylene oxide (CTFA name: Ceteareth-12) (HENKEL) 5. Adduct of cetyl stearyl alcohol and about 20 molecules of ethylene oxide (CTFA name: Ceteareth-20) (HENKEL) 6. Prepared by Guerbet reaction Condensation products from saturated liquid fatty alcohols, mainly 20-carbon alcohols (CTFA name: Octyldodecanol) (HENKEL) 7. Vinylpyrrolidone/dimethylaminoethyl methacrylate copolymer, quaternized with diethyl sulfate ( 19% active substance in water) (GAF) 2) Shampoo Stenol ^R 1618 1,8 Tegoamid ^R S 18 ⁸ 1,6 1,2-Propanediol 1,0 Citric acid 0,6 Celquat ^R L200 1,2 Polymer P1 as per DE 39 29 973 0,2 Perfume water to 1008. N,N-Dimethyl-N'-stearyl-1,3-diaminopropane (CTFA designation: Stearamidopropyldimethylamine) (GOLDSCHMIDT) 3) Shampoo Stenol ^R 1618 1,8 Stepantex ^R VS 90 ⁹ 1,81,2-Propanediol 0,7 Citric acid 0,2 Celquat ^R L200 1,2 Polymer P1, according to DE 39 29 973 0,3 Fragrances, colorants , water added to 1009. N-methyl-N-(2-hydroxyethyl)-N, N-di(oleoyloxyethyl) ammonium ethoxysulfate (containing 90% active substance in isopropanol) ( STEPAN)4) Shampoo Stenol ^R 1618 2,5Eumulgin ^R B 1 1,0Eumulgin ^R B 2 1,0Cutina ^R CP ¹⁰ 1,0Eutanol ^R G 0,5Polawax ^R GP 200 ¹¹ 0,75Abil ^R Quat 3270 ¹² 0,5Dow Corning ^R 929-Emulsion ¹³ 2,6 polymer JR ^R 400 ¹⁴ 0,6 polymer P1 according to DE 39 29 973 0,4 citric acid 0,02 water to 10010. Esters from saturated long-chain fatty alcohols with fatty acids , especially cetyl palmitate (CTFA designation: cetyl palmitate (HENKEL) 11. Stearyl alcohol-polyethylene glycol stearate mixture (CTFA designation: stearyl alcohol (and) PEG-stem Fatty acid ester (CRODA) 12. Diquaternized polymethicone (CTFA designation: Quaternium-80) (GOLD-SCHMIDT) 13. Amino-functionalized polydimethylsiloxane (35% active substance) ( DOWCORNING) 14. Quaternized hydroxyethyl cellulose (CTFA name: Polyquaternium-10 (U-nion Carbide) 5) shampoo Rewoquat ^R w 7500 ¹⁵ 1,1Lanette ^R O ¹⁶ 3,0Eumulgin ^R B 1 0,8Eumulgin ^R B 2 1,6Cutina ^R GMS 0,5Eutanol ^R G 1,0 Polymer JR ^R -125 ¹⁷ 1,0 Polymer P1 according to DE 39 29 973 0,4 Water to 10015. Methoxysulfuric acid 1-Methyl -2-reduced fatty alkyl-3-oleic acid-amidoethylimidazoline (about 75% effective substance) (REWO) 16. A mixture of higher carbon saturated fatty alcohols, mainly cetyl alcohol and stearyl alcohol (CTFA name: Cetearyl Alcohol) (HENKEL) 17. Quaternized Hydroxyethyl Cellulose (CTFA-designation: Polyquaternium-10 (Union Carbide) 6) Shampoo Texapon ^R N 25 ¹⁸ 43,0 Dehyton ^R K ¹⁹ 10,0 Plantaren ^R -1200 ²⁰ 4,0Euperlan ^R PK 3000 ²¹ 1,6Arquad ^R 316 ²² 0,5Celquat ^R L200 1,2 Polymer P1 according to DE 39 29 973 0,2Glucamate ^R DOE 120 ²³ 0,5 Sodium Chloride 0,2 Water Add to 10018. Sodium Lauryl Ether Sulfate (approximately 28% active substance; CTFA designation Sodium Laureth Sulfate) (HENKEL) 19. Has the formula R-CONH(CH ₂ ) ₃ N ⁺ (CH ₃ ) ₂ CH ₂ COO ^- Betaine Structured fatty acid amide derivatives (approx. 30% active substance; CTFA designation: cocoamidopropyl inner salt) (HENKEL) 20. C ₁₂ -C ₁₆ alkyl glucosides with a degree of oligomerization of 1.4 (approximately 50% active substance; CTFA Name: lauryl polyglucoside) (HENKEL) 21. Liquid dispersion (about 62%) of pearlescent substance and amphoteric surfactant active substance; CTFA name: ethylene glycol distearate (and) glycerin (and) Laureth-4 (and) cocamidopropyl propyl salt) (HENKEL) 22. Tri-C ₁₆ -alkylmethylammonium chloride (AKZO) 23. Ethoxylated methyl glucoside dioleate (CTFA designation : PEG-120 Methyl Glucose Dioleate) (AMERCHOL) 7) Shampoo Texapon ^R N ^{70 24} 21,0 Plantaren ^R -1200 8,0 Genamin ^R DSAC ²⁵ 1,2 Cutina ^R EGMS ²⁶ 0,6 Polymer JR ^R -400 0,8 Polymer P1 as per DE 39 29 973 0,3 Antil ^R 141 liquid ²⁷ 1,3 Sodium chloride 0,2 Water to 10024. Sodium lauryl ether sulfate (approximately 72% active substances) (HENKEL) 25. Chlorine Dimethyl distearyl ammonium (HOECHST) 26. Ethylene glycol monostearate (about 25-35% monoester, 60-70% diester; CTFA name: ethylene glycol stearate) ( HENKEL) 27. Polyoxyethylene-Propylene Glycol Dioleate (40% Active Matter; CTFA Designation: Propylene Glycol (and) PEG-55 Propylene Glycol Oleate (GOLDSCHMIDT) 8) Shampoo Texapon ^R K 14 S ²⁸ 50,0 Dehyton ^R K 10,0AkypoR ^R LM 100 NV ²⁹ 4,5Cutina ^R AGS ³⁰ 2,0D-Panthenol 1 0,5 Glucose 1,0 Salicylic acid ure 0,4 Sodium chloride hlorid 0,5 Polymer P1 as per IB DE 39 29 973 0,6Celquat ^R L200 0,6 water Add to 10028. Sodium lauryl myristyl ether sulfate (about 28% active substance; CTFA designation: sodium myristyl ether sulfate) (HENKEL) 29.C ₁₂ ~C ₁₄ - Fatty alcohol + 10 molecules of ethylene oxide-acetic acid sodium salt (22% active substance; CTFA name: Laureth-11 sodium carboxylate) (CHEM-Y) 30. Ethylene glycol stearate (about 5-15% mono Esters, 85-95% diesters; CTFA-designation: ethylene glycol distearate) (HENKEL) 9) Shampoo Texapon ^R K 14 S 25,0Texapon ^R S8 3 ³¹ 7,5Eucarol ^R TA ³² 12,0AkypoR ^R LM 100 NV 9,0Dehyton ^R AB 30 ³³ 8,3Elfacos ^R GT 282S ³⁴ 0,5

sodium chloride chlorid 0,5

Polymer P1 according to IB DE 39 29 973 0,6

Polymer JR ^R -400 2,0

Add water to 10031. Disodium sulfosuccinate half ester based on alkyl polyglycol ether (about 40% active substance; CTFA designation: disodium lauryl ether sulfosuccinate) (HENKEL) 32. Lauryl alcohol + 7 molecules of ethylene oxide-tartrate sodium salt (about 25% active substance; CTFA designation: Laureth-7 tartaric acid) (AUSICHEM) 33. Fatty amine derivatives with inner salt structure (about 30% active substance; CTFA Name: coconut-betaine) (HENKEL) 34. Fatty alcohol + 60 molecules ethylene oxide-myristyl ether (CTFA name: Tal-loweth-60) myristyl glycol) (AKZO) 10) wet Hair conditioner (rinsable) Stenol ^R 1618 3,0

Eumulgin ^R B 1 0,5

Eumulgin ^R B 2 0,5

Cutina ^R CP 1,0

Eutanol ^R G 1,5

Carbopol 980 ³⁵ 0,004

Dow Corning ^R 929-Emulsion 2,9

Polymer P1 according to DE 39 29 973 0,3

Celquat ^R L200 2,0

Triethanolamine 0,09

Add water to 10035. Polyacrylic acid (GOODRICH) 11) Wet compress hair conditioner (keep on hair) Celquat ^R L 200 0,6Luviskol ^R K30 ³⁶ 0,2D-Panthenol 0,5Dehyquart ^R SP ³⁷ 1,0Nutrilan ^R I ³⁸ 1,0 Natrosol ^R 250 HR ³⁹ 1,1 Polymer P1 according to IB DE 39 29 973 0,5 Water added to 10036. Polyvinylpyrrolidone (95% active substance; CTFA designation: PVP) (BASF) 37. Phosphoric acid oxygen Aqueous solution of ethyl alkylammonium (about 50% active substance; CTFA designation: Quatarnium-52) (HENKEL) 38. Collagen hydrolyzate (about 39% active substance; CTFA designation: hydrolyzed collagen) (HENKEL) 39. Hydroxyethyl Cellulose (AQUALON) 12) Hair Color Cream C12-18-Fettalkohol 1,2 Lanette ^R O 4,0 Eumulgin ^R B 2 0,8 Cutina ^R KD 16 ⁴⁰ 2,0 Sodium Sulfite 0,5L (+) Ascorbic Acid 0,5 Ammonium Sulfate 0, 51,2-Propanediol 1,2P-Aminophenol 0,35P-Toluenediamine 0,85 2-Methylresorcinol 0,146-Methyl-m-aminophenol 0,42 Polymer P1 according to DE 39 29 973 0,5Celquat ^R L200 1,5 ammonia water 1,5 water added to 10040. Fatty acid mono/diglyceride-emulsifier-mixture (CTFA designation: oil glyceride (and) stearic acid glyceryl ester (and) potassium stearate) (HENKEL) 13 ) hair dye cream 12) color fixing emulsion

Texapon ^R N 25 2,1

Hydrogen peroxide (50%) 12,0

Turpinal ^R SL ⁴¹ 1,7

Latekoll ^R D ⁴² 12,0

Polymer P1 according to DE 39 29 973 0,1

Polymer JR ^R -400 0,1

Water added to 10041. 1-Hydroxyethane-1,1-diphosphoric acid (60% active substance; CTFA designation: Etidronic acid) (HENKEL) 42. Acrylate-methacrylic acid copolymer (25% active substance) (BASF )

This hair color cream has a pH of 10.0 and dyes hair a deep red. 14) Texapon ^R N 70 14,0Dehyton ^R K 10,0Akypo ^R RLM 45 NV ⁴³ 14,7Plantaren ^R -1200 4,0Cremophor ^R RH 40 ⁴⁴ 0,8 dye off CI12 719 0,02 dye off CI12 251 0, 02 Dye off CI12 250 0,04 Dye off CI56 059 0,03 PHB-ester 0,25 Celquat ^R L200 0,8 Polymer P1 as per DE 39 29 973 0,2 Fragrance qs water to 10043. Lauryl alcohol + 4, 5 Molecular ethylene oxide-sodium acetate (20.4% active substance) (CHEM-Y) 44. Hydrogenated castor oil + 45 molecular ethylene oxide (CTFA name: PEG-40 hydrogenated castor oil) (BASF)

After shampooing with this toned shampoo, hair is pearly beige. 15) Long lasting curling cream Plantaren ^R -800 ⁴⁵ 5,0 Thioglycolic acid 8,0 Turpinal ^R SL 0,5 Ammonia (25% ig) 7,3 Ammonium carbonate Irbonat 3,0 Cetyl/stearyl alcohol 5, 0 Guerbet-alcohol 4,0 Celquat ^R L200 1,2 Polymer P1 according to DE 39 29 973 1,0 Perfume qs water Add to 10045.C ₈ -C ₁₀ Alkyl glucosides with a degree of oligomerization of 1.6 (about 60% effective Substance) (HENKEL) Fixierlsung: Plantaren ^R -800 5,0 hardened castor oil 2,0 potassium bromate 3,5 cyanotriacetic acid 0,3 citric acid 0,2 polymer P1 according to DE 39 29 973 0, 4 polymer JR ^R -400 1,0 spice qs water add to 100

Claims (15)

1. A water-based hair treatment agent for treating hair containing, in addition to conventional cosmetic ingredients, cationic- and zwitterionic polymer compositions, characterized in that the cationic polymer is a cellulose derivative and does not contain The imidazoline group is characterized in that the zwitterionic polymer mainly consists of the following components: α) Monomers with quaternary ammonium groups of general formula (I) R ¹ -CH=CR ² -CO-Z-(C _n H _2n )-N ⁽⁺⁾ R ³ R ⁴ R ⁵ A ^(-) (I) formula R ¹ and R ² each independently represent hydrogen or methyl, R ³ , R ⁴ and R ⁵ each independently represent an alkyl group containing 1 to 4 carbon atoms, Z is an -NH- group or an oxygen atom, and n is An integer of 2 to 5, A ^- is an anion of an organic or inorganic acid, β) monomeric carboxylic acids of general formula (II), or alkali metal, alkaline earth metal, aluminum or ammonium salts of these acids R ⁶ -CH=CR ⁷ =COOH (II) In the formula, R ⁶ and R ⁷ each independently represent hydrogen or methyl. 2. Hair treatment composition according to claim 1, characterized in that the cationic polymer is a copolymer of at least one cationic unit and at least one nonionic unit. 3. Hair treatment composition according to claim 2, characterized in that the nonionic unit is hydroxyethylcellulose. 4. Hair treatment composition according to claim 1, characterized in that the substance of the type α) is acrylamidopropyltrimethylammonium chloride and the substance of the type β) is acrylic acid or an alkali metal salt thereof. 5. A hair treatment agent according to claim 4, wherein said alkali metal salt is a sodium salt. 6. Hair treatment composition according to any one of claims 1-3, characterized in that in the zwitterionic polymer The number of monomers in α) is greater than the number of monomers in β). 7. A hair treatment composition according to any one of claims 1 to 3, characterized in that, based on the total weight of the hair treatment composition, it contains -0.01 to 10% by weight of zwitterionic polymers, - 0.01 to 10% by weight of cationic polymer. 8. Hair treatment composition according to claim 7, characterized in that it contains 0.01-5% by weight of zwitterionic polymers. 9. Hair treatment composition according to claim 7, characterized in that it contains 0.01-5% by weight of cationic polymers. 10. Hair treatment composition according to claim 1, characterized in that it additionally contains a surfactant. 11. Hair treatment composition according to claim 10, characterized in that the surfactant is a cationic and/or nonionic surfactant. 12. The hair treatment agent according to any one of claims 1-3, characterized in that the pH value of the hair treatment agent is 2.5-7. 13. The hair treatment agent according to claim 12, wherein said pH is 3.0-6.0. 14. A method for treating hair, characterized in that the hair treatment agent according to any one of claims 1-13 is applied to the hair. 15. Method according to claim 14, characterized in that the hair is then rinsed with water or a predominantly aqueous cleansing agent.