CN104829892B - 一种鞋底用高耐磨橡胶材料及其制备方法 - Google Patents
一种鞋底用高耐磨橡胶材料及其制备方法 Download PDFInfo
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Abstract
本发明公开了一种鞋底用高耐磨橡胶材料及其制备方法，其由下列重量份的原料配制而成：丁苯橡胶100‑120、聚氨酯橡胶50‑70、超高分子量聚乙烯8‑12、二聚环戊二烯10‑14、巴豆油酸乙酯6‑8、碱式碳酸铅3‑5、对苯二甲酸二异辛酯5‑7、纳米金刚石15‑20、硼化锆10‑14、香豆素6‑8、N,N‑二乙基对苯二胺2‑3、二月桂酸二丁基锡6‑8、间苯二酚二缩水甘油醚4‑5、对叔辛基苯酚甲醛树脂2‑3、N，N’‑间苯撑双马来酰亚胺1‑2、氟化石墨7‑10、水镁石粉8‑10、多溴联苯醚5‑7、高耐磨炭黑20‑25。本发明制得的材料具有很好的耐磨、耐热、阻燃、耐老化等性能。
Description
技术领域
本发明涉及一种橡胶材料，具体地说是涉及一种鞋底用高耐磨橡胶材料及其制备方法。
背景技术
近年来，随着日常生活水平的不断提升，人们接触的各类款式、各种功能的鞋品也越来越多，其中鞋底材料带来的变化是鞋品功能变化的基础。鞋底、鞋帮结构的变化需要各种材料或单个或相互合理的组合，以期达到鞋品最佳的舒适性、卫生性、耐磨性和安全性要求。而影响胶鞋外底耐磨性能的原因主要有胶料配方设计、胶料加工工艺和鞋底硫化工艺三个方面的因素。
当前市场上可以购得的鞋底材料种类繁多，花样各异，对鞋底材料的要求包括鞋底重量轻、磨损低、抓地力强，具有较大的使用温度范围、对化学物和油脂的抗性等。其中，防滑、耐磨鞋底是大多数人群追求的，无论是日常上班族还是热爱户外的人群，选择一款防滑耐磨的鞋子是很有必要的。
发明内容
本发明的目的是提供一种鞋底用高耐磨橡胶材料及其制备方法。
为达到上述目的，本发明所采取的技术方案为：
一种鞋底用高耐磨橡胶材料，由下列重量份的原料配制而成：丁苯橡胶100-120、聚氨酯橡胶50-70、超高分子量聚乙烯8-12、二聚环戊二烯10-14、巴豆油酸乙酯6-8、碱式碳酸铅3-5、对苯二甲酸二异辛酯5-7、纳米金刚石15-20、硼化锆10-14、香豆素6-8、N,N-二乙基对苯二胺2-3、二月桂酸二丁基锡6-8、间苯二酚二缩水甘油醚4-5、对叔辛基苯酚甲醛树脂2-3、N，N’-间苯撑双马来酰亚胺1-2、氟化石墨7-10、水镁石粉8-10、多溴联苯醚5-7、高耐磨炭黑20-25。
一种鞋底用高耐磨橡胶材料的制备方法，包括以下步骤：
(1)将纳米金刚石、硼化锆、香豆素、氟化石墨、水镁石粉、多溴联苯醚、高耐磨炭黑加入二聚环戊二烯中，搅拌成糊状浆料，然后用研磨机将浆料研磨20-30min后，装入搅拌釜中搅拌均匀，得到混合浆料；
(2)将丁苯橡胶、聚氨酯橡胶、超高分子量聚乙烯、巴豆油酸乙酯、碱式碳酸铅、对苯二甲酸二异辛酯、N,N-二乙基对苯二胺、二月桂酸二丁基锡、间苯二酚二缩水甘油醚放入密炼机中密炼30-40min，待温度升到100-120℃时排胶，室温放置10-12h，得到混合胶体；
(3)将步骤(1)得到的混合浆料和步骤(2)得到的混合胶体在双辊开炼机上混炼，并加入对叔辛基苯酚甲醛树脂、N，N’-间苯撑双马来酰亚胺等，混炼均匀后送入双螺杆挤出机料斗，进行挤出造粒；
(4)将得到的橡胶颗粒放入平板硫化机中，设定硫化压力为3-5MPa，硫化的温度为120-150℃，硫化时间为6-8min，得到鞋底用高耐磨橡胶材料。
本发明的有益效果：
本发明使用丁苯橡胶、聚氨酯橡胶、超高分子量聚乙烯三种原料相互协同作用，使得材料具有很好的耐磨、耐热、耐老化性能，二月桂酸二丁基锡与对苯二甲酸二异辛酯、巴豆油酸乙酯等助剂一起构成粘合体系，对橡胶与纤维的粘合起着重要作用，提高橡胶制品的硬度，添加的二聚环戊二烯、间苯二酚二缩水甘油醚与纳米金刚石、硼化锆等搭配，提高橡胶耐磨性的同时，增加橡胶的柔韧性，添加的水镁石粉、多溴联苯醚可以改善橡胶的阻燃性能。
具体实施方式
下面结合具体实施例对本发明所述技术方案作进一步的说明。
实施例1：
一种鞋底用高耐磨橡胶材料，由下列重量份(kg)的原料配制而成：丁苯橡胶100、聚氨酯橡胶50、超高分子量聚乙烯8、二聚环戊二烯10、巴豆油酸乙酯6、碱式碳酸铅3、对苯二甲酸二异辛酯5、纳米金刚石15、硼化锆10、香豆素6、N,N-二乙基对苯二胺2、二月桂酸二丁基锡6、间苯二酚二缩水甘油醚4、对叔辛基苯酚甲醛树脂2、N，N’-间苯撑双马来酰亚胺1、氟化石墨7、水镁石粉8、多溴联苯醚5、高耐磨炭黑20。
一种鞋底用高耐磨橡胶材料的制备方法，包括以下步骤：
(1)将纳米金刚石、硼化锆、香豆素、氟化石墨、水镁石粉、多溴联苯醚、高耐磨炭黑加入二聚环戊二烯中，搅拌成糊状浆料，然后用研磨机将浆料研磨20-30min后，装入搅拌釜中搅拌均匀，得到混合浆料；
(2)将丁苯橡胶、聚氨酯橡胶、超高分子量聚乙烯、巴豆油酸乙酯、碱式碳酸铅、对苯二甲酸二异辛酯、N,N-二乙基对苯二胺、二月桂酸二丁基锡、间苯二酚二缩水甘油醚放入密炼机中密炼30-40min，待温度升到100-120℃时排胶，室温放置10-12h，得到混合胶体；
(3)将步骤(1)得到的混合浆料和步骤(2)得到的混合胶体在双辊开炼机上混炼，并加入对叔辛基苯酚甲醛树脂、N，N’-间苯撑双马来酰亚胺等，混炼均匀后送入双螺杆挤出机料斗，进行挤出造粒；
(4)将得到的橡胶颗粒放入平板硫化机中，设定硫化压力为3-5MPa，硫化的温度为120-150℃，硫化时间为6-8min，得到鞋底用高耐磨橡胶材料。
实施例2：
一种鞋底用高耐磨橡胶材料，由下列重量份(kg)的原料配制而成：丁苯橡胶110、聚氨酯橡胶60、超高分子量聚乙烯10、二聚环戊二烯12、巴豆油酸乙酯7、碱式碳酸铅4、对苯二甲酸二异辛酯6、纳米金刚石17.5、硼化锆12、香豆素7、N,N-二乙基对苯二胺2.5、二月桂酸二丁基锡7、间苯二酚二缩水甘油醚4.5、对叔辛基苯酚甲醛树脂2.5、N，N’-间苯撑双马来酰亚胺1.5、氟化石墨8.5、水镁石粉9、多溴联苯醚6、高耐磨炭黑22.5。
制备方法同实施例1。
实施例3：
一种鞋底用高耐磨橡胶材料，由下列重量份(kg)的原料配制而成：丁苯橡胶120、聚氨酯橡胶70、超高分子量聚乙烯12、二聚环戊二烯14、巴豆油酸乙酯8、碱式碳酸铅5、对苯二甲酸二异辛酯7、纳米金刚石20、硼化锆14、香豆素8、N,N-二乙基对苯二胺3、二月桂酸二丁基锡8、间苯二酚二缩水甘油醚5、对叔辛基苯酚甲醛树脂3、N，N’-间苯撑双马来酰亚胺2、氟化石墨10、水镁石粉10、多溴联苯醚7、高耐磨炭黑25。
制备方法同实施例1。
上述实施例1-3制得的鞋底用高耐磨橡胶材料的性能检测结果如下表所示：
Claims (2)
1.一种鞋底用高耐磨橡胶材料，其特征在于，由下列重量份的原料配制而成：丁苯橡胶100-120、聚氨酯橡胶50-70、超高分子量聚乙烯8-12、二聚环戊二烯10-14、巴豆油酸乙酯6-8、碱式碳酸铅3-5、对苯二甲酸二异辛酯5-7、纳米金刚石15-20、硼化锆10-14、香豆素6-8、N,N-二乙基对苯二胺2-3、二月桂酸二丁基锡6-8、间苯二酚二缩水甘油醚4-5、对叔辛基苯酚甲醛树脂2-3、N，N’-间苯撑双马来酰亚胺1-2、氟化石墨7-10、水镁石粉8-10、多溴联苯醚5-7、高耐磨炭黑20-25。
2.根据权利要求1所述的一种鞋底用高耐磨橡胶材料的制备方法，其特征在于，包括以下步骤：
(1)将纳米金刚石、硼化锆、香豆素、氟化石墨、水镁石粉、多溴联苯醚、高耐磨炭黑加入二聚环戊二烯中，搅拌成糊状浆料，然后用研磨机将浆料研磨20-30min后，装入搅拌釜中搅拌均匀，得到混合浆料；
(2)将丁苯橡胶、聚氨酯橡胶、超高分子量聚乙烯、巴豆油酸乙酯、碱式碳酸铅、对苯二甲酸二异辛酯、N,N-二乙基对苯二胺、二月桂酸二丁基锡、间苯二酚二缩水甘油醚放入密炼机中密炼30-40min，待温度升到100-120℃时排胶，室温放置10-12h，得到混合胶体；
(3)将步骤(1)得到的混合浆料和步骤(2)得到的混合胶体在双辊开炼机上混炼，并加入对叔辛基苯酚甲醛树脂、N，N’-间苯撑双马来酰亚胺，混炼均匀后送入双螺杆挤出机料斗，进行挤出造粒；
(4)将得到的橡胶颗粒放入平板硫化机中，设定硫化压力为3-5MPa，硫化的温度为120-150℃，硫化时间为6-8min，得到鞋底用高耐磨橡胶材料。
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| CN105860172B (zh) * | 2016-05-25 | 2017-12-01 | 泉州集友鞋业有限公司 | 一种耐磨鞋底材料及其制备方法 |
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| CN106519547A (zh) * | 2016-11-17 | 2017-03-22 | 无锡市长安曙光手套厂 | 一种聚氨酯耐磨鞋底材料 |
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