CN104818470A - Organic amine corrosion inhibition metal surface treatment agent - Google Patents
Organic amine corrosion inhibition metal surface treatment agent Download PDFInfo
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- CN104818470A CN104818470A CN201510168690.6A CN201510168690A CN104818470A CN 104818470 A CN104818470 A CN 104818470A CN 201510168690 A CN201510168690 A CN 201510168690A CN 104818470 A CN104818470 A CN 104818470A
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- organic amine
- water
- metal
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- 229910052751 metal Inorganic materials 0.000 title claims abstract description 32
- 239000002184 metal Substances 0.000 title claims abstract description 32
- 150000001412 amines Chemical class 0.000 title claims abstract description 13
- 230000005764 inhibitory process Effects 0.000 title claims abstract description 12
- 238000005260 corrosion Methods 0.000 title abstract description 12
- 230000007797 corrosion Effects 0.000 title abstract description 12
- 239000012756 surface treatment agent Substances 0.000 title abstract description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 20
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 14
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910000077 silane Inorganic materials 0.000 claims abstract description 14
- 239000004642 Polyimide Substances 0.000 claims abstract description 7
- 235000011187 glycerol Nutrition 0.000 claims abstract description 7
- 229920002401 polyacrylamide Polymers 0.000 claims abstract description 7
- 229920001721 polyimide Polymers 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 7
- 241000241413 Propolis Species 0.000 claims abstract description 4
- NBZBKCUXIYYUSX-UHFFFAOYSA-N iminodiacetic acid Chemical compound OC(=O)CNCC(O)=O NBZBKCUXIYYUSX-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229940069949 propolis Drugs 0.000 claims abstract description 4
- NVIFVTYDZMXWGX-UHFFFAOYSA-N sodium metaborate Chemical compound [Na+].[O-]B=O NVIFVTYDZMXWGX-UHFFFAOYSA-N 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 12
- 239000000839 emulsion Substances 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- 239000011347 resin Substances 0.000 claims description 6
- 229920005989 resin Polymers 0.000 claims description 6
- BXJPTTGFESFXJU-UHFFFAOYSA-N yttrium(3+);trinitrate Chemical compound [Y+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O BXJPTTGFESFXJU-UHFFFAOYSA-N 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 4
- 229910052760 oxygen Inorganic materials 0.000 abstract description 4
- 239000001301 oxygen Substances 0.000 abstract description 4
- 238000001179 sorption measurement Methods 0.000 abstract description 3
- 239000003518 caustics Substances 0.000 abstract description 2
- 230000001681 protective effect Effects 0.000 abstract description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 abstract 1
- 108010013296 Sericins Proteins 0.000 abstract 1
- 239000006087 Silane Coupling Agent Substances 0.000 abstract 1
- 230000007062 hydrolysis Effects 0.000 abstract 1
- 238000006460 hydrolysis reaction Methods 0.000 abstract 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 abstract 1
- QBAZWXKSCUESGU-UHFFFAOYSA-N yttrium(3+);trinitrate;hexahydrate Chemical compound O.O.O.O.O.O.[Y+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O QBAZWXKSCUESGU-UHFFFAOYSA-N 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000000758 substrate Substances 0.000 description 4
- 239000010949 copper Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 230000005587 bubbling Effects 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 231100001010 corrosive Toxicity 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 2
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- 241000370738 Chlorion Species 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 229910000640 Fe alloy Inorganic materials 0.000 description 1
- 230000000274 adsorptive effect Effects 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 239000013556 antirust agent Substances 0.000 description 1
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 1
- 239000012964 benzotriazole Substances 0.000 description 1
- 239000013043 chemical agent Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- IYRDVAUFQZOLSB-UHFFFAOYSA-N copper iron Chemical compound [Fe].[Cu] IYRDVAUFQZOLSB-UHFFFAOYSA-N 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000000280 densification Methods 0.000 description 1
- 238000002224 dissection Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000003411 electrode reaction Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 230000015784 hyperosmotic salinity response Effects 0.000 description 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 description 1
- 230000000116 mitigating effect Effects 0.000 description 1
- 238000002161 passivation Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
- KMUONIBRACKNSN-UHFFFAOYSA-N potassium dichromate Chemical compound [K+].[K+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O KMUONIBRACKNSN-UHFFFAOYSA-N 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- -1 rare earth ion Chemical class 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 235000010288 sodium nitrite Nutrition 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
Landscapes
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses an organic amine corrosion inhibition metal surface treatment agent which is composed of the following raw materials, by weight, 2-3 parts of glycerin, 4-6 parts of sericin, 0.8-1 part of polyacrylamide, 0.05-0.1 part of yttrium nitrate hexahydrate, 0.4-1 part of a silane coupling agent KH-550, 150-200 parts of water, 0.6-1 part of iminodiacetic acid, 0.3-0.4 part of propolis, 0.7-1 part of cocofatty acylamido propyl betaines, 0.2-0.3 part of polyimide and 1-2 parts of sodium metaborate. After hydrolysis of the added silane, an adsorption type film can be formed on metal surface so as to isolate water molecules and oxygen molecules in the environment, thus having a protective effect. With the addition of organic amine, a layer of adsorption film can be formed to prevent corrosive substances such as water, chloride ion and oxygen, etc. from contacting with metal, thus having an effect of preventing corrosion of metal.
Description
Technical field
The present invention relates generally to metal conditioner field, particularly relates to a kind of organic amine inhibition metal conditioner.
Background technology
Metal conditioner refers to the general name of chemical agent metallic surface being carried out to various process.Metal finishing includes oil removing, rust cleaning, phosphatization, the substrate pretreatment such as antirust, for metal coating techniques, metal protection technology are prepared, the use of substrate pretreatment quality to after this coating preparation and metal has a great impact, water soluble anti-rust agent wherein then may be dissolved in water and forms the aqueous solution, and metal can prevent rust corrosion after this aqueous solution process.Their rust inhibition can be divided three classes.
1. metal and rust-preventive agent generate the insoluble and sull of densification, thus prevent the anode dissolution of metal or promote the passivation of metal, thus suppressing corrosion of metal.This kind of rust-preventive agent is also called passivator, as Sodium Nitrite, potassium bichromate etc.In use, enough consumptions should be ensured.When using quantity not sufficient, can not form complete sull, on not covered very little metallic surface, corrosion electric current density increases, and easily causes severe local corrosion.2. metal and rust-preventive agent generate the salt of indissoluble, thus metal and corrosive medium are isolated, and avoid corrosion.Such as: the phosphoric acid salt had can generate insoluble phosphoric acid molysite with iron effect; Some silicate energy and iron, aluminium effect generate insoluble silicate etc.3. metal and rust-preventive agent generate the complex compound of insoluble, cover metallic surface and protect metal to avoid corrosion.Such as: benzotriazole and copper can generate inner complex Cu (C6H4N3) 2, be both water insolublely also insoluble to oil, thus can protect the surface of copper.
Summary of the invention
The object of the invention is just to provide a kind of organic amine inhibition metal conditioner.
The present invention is achieved by the following technical solutions:
A kind of organic amine inhibition metal conditioner, it is made up of the raw material of following weight parts:
Glycerine 2-3, silk gum 4-6, polyacrylamide 0.8-1, six water Yttrium trinitrate 0.05-0.1, silane resin acceptor kh-550 0.4-1, water 150-200, iminodiethanoic acid 0.6-1, propolis 0.3-0.4, AMONYL 380LC 0.7-1, polyimide 0.2-0.3, sodium metaborate 1-2.
A preparation method for organic amine inhibition metal conditioner, is characterized in that comprising the following steps:
(1) get silk gum, add the 50-60% of above-mentioned water weight, add silane resin acceptor kh-550, six water Yttrium trinitrates after stirring, 600-1000 rev/min of dispersed with stirring 10-20 minute, obtains silane liquid;
(2) by polyacrylamide, polyimide mixing, add glycerine after stirring, be heated to 60-70 DEG C, add above-mentioned silane liquid, insulated and stirred 20-30 minute at the temperature disclosed above, adds AMONYL 380LC, 700-1000 rev/min is stirred 5-7 minute, obtains silk gum emulsion;
(3) above-mentioned silk gum emulsion mixed with each raw material of residue, 800-1000 rev/min of dispersed with stirring 30-40 minute, obtains described metal conditioner.
Advantage of the present invention is:
The silane that the present invention adds can form adsorptive type rete in metallic surface after hydrolyzing thus water molecules in isolated environment and oxygen molecule play protective effect, the organic amine added can form one deck adsorption film, stop water, the corrosives such as chlorion and oxygen and metallic contact, play the effect preventing metallic corrosion, rare earth ion can corrode with metallic substrate surface generation oxygen uptake the OH-complexing produced and produce insoluble complex, this complex compound dehydration can form oxide precipitation to substrate surface further, the electrode reaction of slowing down corrosion, coordinate water-soluble silk glue, the stability forming film can be strengthened, improve antirust corrosion mitigating effect.
Embodiment
Embodiment 1:
A kind of organic amine inhibition metal conditioner, it is made up of the raw material of following weight parts:
Glycerine 2, silk gum 6, polyacrylamide 0.8, six water Yttrium trinitrate 0.05, silane resin acceptor kh-550 0.4, water 200, iminodiethanoic acid 0.6, propolis 0.4, AMONYL 380LC 0.7, polyimide 0.3, sodium metaborate 1.
A preparation method for organic amine inhibition metal conditioner, comprises the following steps:
(1) get silk gum, add 60% of above-mentioned water weight, add silane resin acceptor kh-550, six water Yttrium trinitrates after stirring, 1000 revs/min of dispersed with stirring 20 minutes, obtain silane liquid;
(2) by polyacrylamide, polyimide mixing, add glycerine after stirring, be heated to 70 DEG C, add above-mentioned silane liquid, insulated and stirred 30 minutes, adds AMONYL 380LC at the temperature disclosed above, and 1000 revs/min are stirred 7 minutes, obtain silk gum emulsion;
(3) above-mentioned silk gum emulsion mixed with each raw material of residue, 1000 revs/min of dispersed with stirring 40 minutes, obtain described metal conditioner.
Performance test:
Get that surface treatment agent of the present invention processes aluminium alloy respectively, copper-iron alloy sheet material is tested, the specification of two kinds of sheet materials is 80mm × 100mm × 4mm, by this sheet material lateral dissection, carry out spray test, agents useful for same to be concentration be 5% sodium chloride solution, test period 300 hours, measure the bubbling width formed in line of cut side, result bubbling width is 0;
Salt tolerance:
It is in the sodium chloride solution of 5% that the above-mentioned two kinds of sheet materials processed respectively are immersed in concentration, and soak 300 hours, material surface is substantially unchanged, soaks 300 hours, occurs without rust staining.
Claims (2)
1. an organic amine inhibition metal conditioner, is characterized in that what it was made up of the raw material of following weight parts:
Glycerine 2-3, silk gum 4-6, polyacrylamide 0.8-1, six water Yttrium trinitrate 0.05-0.1, silane resin acceptor kh-550 0.4-1, water 150-200, iminodiethanoic acid 0.6-1, propolis 0.3-0.4, AMONYL 380LC 0.7-1, polyimide 0.2-0.3, sodium metaborate 1-2.
2. a preparation method for organic amine inhibition metal conditioner as claimed in claim 1, is characterized in that comprising the following steps:
(1) get silk gum, add the 50-60% of above-mentioned water weight, add silane resin acceptor kh-550, six water Yttrium trinitrates after stirring, 600-1000 rev/min of dispersed with stirring 10-20 minute, obtains silane liquid;
(2) by polyacrylamide, polyimide mixing, add glycerine after stirring, be heated to 60-70 DEG C, add above-mentioned silane liquid, insulated and stirred 20-30 minute at the temperature disclosed above, adds AMONYL 380LC, 700-1000 rev/min is stirred 5-7 minute, obtains silk gum emulsion;
(3) above-mentioned silk gum emulsion mixed with each raw material of residue, 800-1000 rev/min of dispersed with stirring 30-40 minute, obtains described metal conditioner.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510168690.6A CN104818470A (en) | 2015-04-10 | 2015-04-10 | Organic amine corrosion inhibition metal surface treatment agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510168690.6A CN104818470A (en) | 2015-04-10 | 2015-04-10 | Organic amine corrosion inhibition metal surface treatment agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104818470A true CN104818470A (en) | 2015-08-05 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510168690.6A Pending CN104818470A (en) | 2015-04-10 | 2015-04-10 | Organic amine corrosion inhibition metal surface treatment agent |
Country Status (1)
| Country | Link |
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| CN (1) | CN104818470A (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20060127681A1 (en) * | 2003-02-25 | 2006-06-15 | Heribert Domes | Method for coating metallic surfaces with a silane-rich composition |
| CN102877052A (en) * | 2011-07-15 | 2013-01-16 | 日本帕卡濑精株式会社 | Drainage system obtained by the treatment processing and metal surface treatment agent and metal material |
-
2015
- 2015-04-10 CN CN201510168690.6A patent/CN104818470A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20060127681A1 (en) * | 2003-02-25 | 2006-06-15 | Heribert Domes | Method for coating metallic surfaces with a silane-rich composition |
| CN102877052A (en) * | 2011-07-15 | 2013-01-16 | 日本帕卡濑精株式会社 | Drainage system obtained by the treatment processing and metal surface treatment agent and metal material |
Non-Patent Citations (4)
| Title |
|---|
| 中国农业科学院蚕业研究所: "《栽桑养蚕技术大全》", 31 October 1994, 中国农业出版社 * |
| 冯练享等: "亚氨基二乙酸的生产和应用", 《农药》 * |
| 房柱: "《蜂胶》", 31 January 1999 * |
| 陈旭俊: "《工业清洗剂及清洗技术》", 31 March 2002 * |
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| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| EXSB | Decision made by sipo to initiate substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20150805 |
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| RJ01 | Rejection of invention patent application after publication |