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CN104522026A - Weed control composition containing propyrisulfuron and oxyfluorfen - Google Patents

Weed control composition containing propyrisulfuron and oxyfluorfen Download PDF

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Publication number
CN104522026A
CN104522026A CN201410823081.5A CN201410823081A CN104522026A CN 104522026 A CN104522026 A CN 104522026A CN 201410823081 A CN201410823081 A CN 201410823081A CN 104522026 A CN104522026 A CN 104522026A
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China
Prior art keywords
oxyfluorfen
sulfometuron methyl
promazine sulfometuron
propyrisulfuron
weed control
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CN201410823081.5A
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Chinese (zh)
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CN104522026B (en
Inventor
王礼文
陈佛祥
张志伟
朱刚
吴泽伟
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Guangdong Zhongxun Agri Science Corp
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Guangdong Zhongxun Agri Science Corp
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Abstract

The invention discloses a weed control composition containing propyrisulfuron and oxyfluorfen. The weed control composition comprises active ingredients such as the propyrisulfuron and the oxyfluorfen and also comprises pesticide auxiliaries, wherein the weight part ratio of the propyrisulfuron to the oxyfluorfen is (10 to 1)-(1 to 10), and the sum of the weight of the propyrisulfuron and the oxyfluorfen accounts for 1-80% of the weight of the composition. According to application requirements, the weed control composition disclosed by the invention can be prepared into any one of suspending agents, oil suspension, water dispersible granules and wettable powder and is used for preventing and controlling annual weeds in paddy fields. According to the composition, the effect of preventing and controlling the annual weeds in the paddy fields is obviously superior to that of each single agent, the use amount is reduced, and the drug resistance of the weeds is delayed.

Description

Herbicidal combinations containing promazine Sulfometuron Methyl and Oxyfluorfen
Technical field
The present invention relates to a kind of Herbicidal combinations containing promazine Sulfometuron Methyl and Oxyfluorfen, for active ingredient with promazine Sulfometuron Methyl and Oxyfluorfen, for preventing and kill off paddy field weed, especially with the paddy field annual weed that Paspalum distichum (Paspalum paspaloides), rhizoma alismatis (Alisma plantago-aquatica), short arrowhead (Sagittaria pygmaea) are advantage weeds.
Background technology
Promazine Sulfometuron Methyl (Propyrisulfuron), is a kind of selectivity broad-spectrum herbicide, has good preventive effect to the weeds of resistance to sulfonylurea herbicide, effective to above the average age for marriage barnyard grass, nutgrass flatsedge, broadleaved herb, can foliar spray, get rid of and execute.
Oxyfluorfen (Oxyfluorfen) is contact killing type weed killer herbicide.Its activity of weeding is played when there being light.Enter in plant corpus mainly through coleoptile, mesocotyl, less through root absorption, and have denier upwards to be transported by root to enter leaf portion, for before cotton, round onions, peanut, soybean, beet, fruit tree and vegetable fields bud, use after bud and prevent and kill off barnyard grass, sesbania, downy brome, green foxtail, datura, quackgrass, artemisiifolia, thorn chrysanthemum sth. made by twisting, piemarker, charlock unifacial leaf and broad leaved weed.
The present inventor conducts in-depth research promazine Sulfometuron Methyl, Oxyfluorfen mixture, discovery promazine Sulfometuron Methyl, Oxyfluorfen mixture have Synergistic to respond to paddy field annual weed, especially to Paspalum distichum (Paspalum paspaloides, PASPA), rhizoma alismatis (Alismaplantago-aquatica, ALIPL), short arrowhead (Sagittaria pygmaea, SAGPY) there is the response of significant Synergistic, after further study, the present invention is completed.
The object of the invention is to solve in prior art to farmland weed develop immunity to drugs problem and actual control efficiency poor, provide a kind of efficient, low toxicity, quick-acting are good and the lasting period is long, are conducive to the Herbicidal combinations of the farmland weed comprehensive regulation.
Another object of the present invention is used for preventing and kill off paddy field weed by this Herbicidal combinations, especially with the paddy field annual weed that Paspalum distichum (Paspalum paspaloides), lady's-grass (Digitaria sanguinalis), bent grass (Agrostis matsumurae) are advantage weeds.
Technical scheme: for achieving the above object, the invention provides a kind of Herbicidal combinations containing promazine Sulfometuron Methyl and Oxyfluorfen, it comprises active ingredient promazine Sulfometuron Methyl and Oxyfluorfen, the ratio of weight and number of promazine Sulfometuron Methyl and Oxyfluorfen is 10:1 ~ 1:10, promazine Sulfometuron Methyl and Oxyfluorfen weight summation percentage by weight are in the composition 1 ~ 80%, and all the other are agriculturally acceptable insecticides adjuvant.
Herbicidal combinations those skilled in the art of the present invention according to known method, can select suitable pesticidal preparations auxiliary element, make the formulation that suspending agent, oil-suspending agent, water dispersible granules, wetting powder etc. are agriculturally conventional.
The auxiliary agent used in Herbicidal combinations provided by the invention comprises solvent, emulsifier, wetting agent, stabilizing agent, dispersant, safener, thickener, pH adjusting agent, defoamer, antifreezing agent, deionized water, filler etc., all various auxiliary agents conventional in Pesticide formulation, concrete composition and consumption, according to recipe requirements, are determined through simple test.
The production technology of the various application forms of Herbicidal combinations provided by the invention all belongs to existing known technology, does not repeat them here.
The frequency of administration of the present composition and amount of application change with crops, weeds, weather condition and have small variations, can by the object using suitable dosage reach effectively control.
Herbicidal combinations provided by the invention has following beneficial effect:
1, Herbicidal combinations provided by the invention, obvious synergistic effect is shown in certain ratio range, the control efficiency of composition is significantly improved than single dose, reduce the using dosage of agricultural chemicals, decrease times for spraying, reduce drug cost, decrease the adverse effect of agricultural chemicals to ecotope.
2, Herbicidal combinations provided by the invention, the combination of two kinds of active ingredients, expands herbicidal spectrum, and a drug can solve weed problem, compensate for defect when single dose uses and limitation.
3, Herbicidal combinations provided by the invention, two kinds of active ingredient mechanism of action are different, can overcome the shortcoming that long-term single use easily produces resistance, extend the service life of medicament, to the comprehensive regulation important in inhibiting of Weed Resistance.
4, Herbicidal combinations provided by the invention, drug effect plays rapidly, and the lasting period is long, and use cost is low, easy to use, time saving and energy saving, and it applies huge economic benefit and social benefit.
Embodiment
In order to make object of the present invention, technical scheme and advantage more short and sweet, the following specific embodiment of the present invention is described, but the present invention is only limitted to absolutely not these examples.The following stated is only the good embodiment of the present invention, only for describing the present invention, can not be interpreted as the restriction to scope of the present invention.It should be pointed out that all any amendments done within the spirit and principles in the present invention, equivalent replacement and improvement etc., all should be included within protection scope of the present invention.
Assays Example 1: promazine Sulfometuron Methyl, Oxyfluorfen and composite to Paspalum distichum (Paspalumpaspaloides, PASPA), rhizoma alismatis (Alisma plantago-aquatica, ALIPL), short arrowhead (Sagittaria pygmaea, SAGPY) interior virulence determination test
Evaluate weed killer herbicide associated form (NY/T 1155.7-2006) according to Gowing method, its formula is as follows:
E 0 = X + Y - X × Y 100
In formula:
X be promazine Sulfometuron Methyl alone with certain dosage time fresh weight inhibition to target weeds;
Y be Oxyfluorfen alone with certain dosage time fresh weight inhibition to target weeds;
E 0for when promazine Sulfometuron Methyl, Oxyfluorfen two kinds of pharmacy mix to the theoretical value of target weeds fresh weight inhibition or desired value;
E is promazine Sulfometuron Methyl, Oxyfluorfen two kinds of pharmacy mix time to target weeds fresh weight inhibition be contrast measured value or observation.
Evaluation criterion: as E ﹣ E 0during > 10%, be expressed as synergistic function; As ﹣ 10%≤E ﹣ E 0when≤10%, show as collaborative summation action; As E ﹣ E 0during < ﹣ 10%, show as joint action of antagonism.
15 days promazine Sulfometuron Methyls after table 1, medicine, Oxyfluorfen and composite in greenhouse 3 the leaf phase PASPA, ALIPL, SAGPY control data
Weed killer herbicide associated form is evaluated according to Colby method, table 1 data show, promazine Sulfometuron Methyl, Oxyfluorfen binary combination are to Paspalum distichum (Paspalum paspaloides, PASPA), rhizoma alismatis (Alisma plantago-aquatica, ALIPL), short arrowhead (Sagittaria pygmaea, SAGPY) synergistic effect is remarkable, E-E 0value is all greater than 20%.
Example of formulations 1:40% promazine Sulfometuron Methyl Oxyfluorfen water dispersible granules.
Above-mentioned material is added in cone-type mixer together and mixes; pulverize by airslide disintegrating mill; material after pulverizing mixes through cone-type mixer again; mixed fineness of materials 98% is by 600 mesh standard sieves; add in kneader and be kneaded into plasticity material; finally this material is put into Squeezinggranulator extruder grain, after granulation, after drying, screening, namely obtain 40% promazine Sulfometuron Methyl Oxyfluorfen water dispersible granules.
Example of formulations 2:30% promazine Sulfometuron Methyl Oxyfluorfen wetting powder).
Above-mentioned material is added in cone-type mixer together and mixes, pulverize by airslide disintegrating mill, material after pulverizing is again through cone-type mixer mixing, and mixed fineness of materials 98%, by 600 mesh standard sieves, obtains 30% promazine Sulfometuron Methyl Oxyfluorfen wetting powder.
Example of formulations 3:35% promazine Sulfometuron Methyl Oxyfluorfen suspending agent.
Pulverized in advance in proportion by above-mentioned formula, then add in sand mill and grind, after high shear mixing, allotment obtains the promazine Sulfometuron Methyl Oxyfluorfen suspending agent of corresponding percentage by weight.
Example of formulations 4:25% promazine Sulfometuron Methyl Oxyfluorfen oil-suspending agent.
Above-mentioned material (except organobentonite) is joined in reactor mixer together, stir 2 hours, open pan feeding valve at the bottom of still, material is injected stage sand grinding machine to grind, fineness of materials 98% after grinding is by discharging after 1-5um, material puts into high-shear emulsifying still again together with the organobentonite dissolved in advance, namely can be made into the 25% promazine Sulfometuron Methyl Oxyfluorfen oil-suspending agent that flowing to property is good after emulsification.
Assays Example 2: promazine Sulfometuron Methyl, Oxyfluorfen herbicidal composition prevent and kill off transplant field paddy rice annual weed field control effectiveness test.
Test site is positioned at peaceful town, Panjin City Panshan County, Liaoning Province transplant field paddy rice annual weed and includes but are not limited to Paspalum distichum (Paspalum paspaloides, PASPA), barnyard grass (Echinochloacrusgalli, ECHCR), short arrowhead (Sagittaria pygmaea, SAGPY), rhizoma alismatis (Alismaplantago-aquatica, ALIPL).
Table 2, promazine Sulfometuron Methyl, Oxyfluorfen herbicidal composition are to peaceful town transplanted rice field annual weed field control effectiveness test result
Assays Example 3: promazine Sulfometuron Methyl, Oxyfluorfen herbicidal composition prevent and kill off rice seedling throwing field annual weed field control effectiveness test.
Test site is positioned at Chen Jiang town, Zhong Kai district of Huizhou City, rice seedling throwing field annual weed includes but are not limited to Leersia Sw (Leersia hexandra, LEEHE), Paspalum distichum (Paspalumpaspaloides, PASPA), moleplant seed (Leptochloa chinensis, LEPCH), Herba Cyperi Glomerati (Juncellus serotinus, JUNSE).
Table 3, promazine Sulfometuron Methyl, Oxyfluorfen herbicidal composition are to Chen Jiang town seedling throwing field annual weed field control effectiveness test result
As can be seen from the test results: Herbicidal combinations of the present invention can effectively prevent and kill off paddy field annual weed, expand herbicide spectrum, synergistic effect is remarkable.In process of the test, each medicament is showed no generation poisoning, to rice safety.

Claims (3)

1. one kind contains the Herbicidal combinations of promazine Sulfometuron Methyl and Oxyfluorfen, it is characterized in that: active ingredient is promazine Sulfometuron Methyl and Oxyfluorfen, the ratio of weight and number of promazine Sulfometuron Methyl and Oxyfluorfen is 10:1 ~ 1:10, and promazine Sulfometuron Methyl and Oxyfluorfen weight summation percentage by weight are in the composition 1 ~ 80%.
2. a kind of Herbicidal combinations containing promazine Sulfometuron Methyl and Oxyfluorfen according to claim 1, is characterized in that: its formulation can be the one in suspending agent, oil-suspending agent, water dispersible granules, wetting powder.
3. a kind of Herbicidal combinations containing promazine Sulfometuron Methyl and Oxyfluorfen according to claim 1 is to prevent and kill off the application in Paspalum distichum, rhizoma alismatis, short arrowhead paddy field annual weed.
CN201410823081.5A 2014-12-22 2014-12-22 Herbicidal combinations containing promazine Sulfometuron Methyl and Oxyfluorfen Active CN104522026B (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104824000A (en) * 2015-05-13 2015-08-12 广东中迅农科股份有限公司 Weeding composition containing propyrisulfuron, mefenacet and oxyfluorfen
CN105052970A (en) * 2015-07-29 2015-11-18 北京燕化永乐生物科技股份有限公司 Herbicidal composition
CN105724405A (en) * 2016-03-14 2016-07-06 南京华洲药业有限公司 Herbicidal composition containing trifloxysulfuron and oxylfluorfen and application thereof
CN114027316A (en) * 2016-12-27 2022-02-11 江苏龙灯化学有限公司 Weeding composition containing metazosulfuron and oxyfluorfen and application thereof
CN116746586A (en) * 2023-07-03 2023-09-15 黑龙江省农业科学院植物保护研究所 Ternary compound weeding composition and application thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005126415A (en) * 2003-09-30 2005-05-19 Sumitomo Chemical Takeda Agro Co Ltd Herbicidal composition
JP2007314519A (en) * 2006-04-28 2007-12-06 Sumitomo Chemical Co Ltd Herbicidal composition
US8138122B2 (en) * 2006-04-28 2012-03-20 Sumitomo Chemical Company, Limited Herbicidal composition

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2005126415A (en) * 2003-09-30 2005-05-19 Sumitomo Chemical Takeda Agro Co Ltd Herbicidal composition
JP2007314519A (en) * 2006-04-28 2007-12-06 Sumitomo Chemical Co Ltd Herbicidal composition
US8138122B2 (en) * 2006-04-28 2012-03-20 Sumitomo Chemical Company, Limited Herbicidal composition

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104824000A (en) * 2015-05-13 2015-08-12 广东中迅农科股份有限公司 Weeding composition containing propyrisulfuron, mefenacet and oxyfluorfen
CN105052970A (en) * 2015-07-29 2015-11-18 北京燕化永乐生物科技股份有限公司 Herbicidal composition
CN105724405A (en) * 2016-03-14 2016-07-06 南京华洲药业有限公司 Herbicidal composition containing trifloxysulfuron and oxylfluorfen and application thereof
CN105724405B (en) * 2016-03-14 2018-07-17 南京华洲药业有限公司 A kind of Herbicidal combinations and its application containing trifloxysulfuron and Oxyfluorfen
CN114027316A (en) * 2016-12-27 2022-02-11 江苏龙灯化学有限公司 Weeding composition containing metazosulfuron and oxyfluorfen and application thereof
CN116746586A (en) * 2023-07-03 2023-09-15 黑龙江省农业科学院植物保护研究所 Ternary compound weeding composition and application thereof

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