CN1043781C - Fireproof and heat insulating coating and its preparation - Google Patents
Fireproof and heat insulating coating and its preparation Download PDFInfo
- Publication number
- CN1043781C CN1043781C CN 95111236 CN95111236A CN1043781C CN 1043781 C CN1043781 C CN 1043781C CN 95111236 CN95111236 CN 95111236 CN 95111236 A CN95111236 A CN 95111236A CN 1043781 C CN1043781 C CN 1043781C
- Authority
- CN
- China
- Prior art keywords
- paint
- fireproof
- coating
- negative ion
- penetrating agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- 239000011248 coating agent Substances 0.000 title claims description 26
- 238000000576 coating method Methods 0.000 title claims description 26
- 150000002500 ions Chemical class 0.000 claims abstract description 16
- 239000000835 fiber Substances 0.000 claims abstract description 15
- 239000000725 suspension Substances 0.000 claims abstract description 14
- 239000000126 substance Substances 0.000 claims abstract description 12
- 239000004113 Sepiolite Substances 0.000 claims abstract description 9
- 238000004519 manufacturing process Methods 0.000 claims abstract description 9
- 235000019355 sepiolite Nutrition 0.000 claims abstract description 9
- 229910052624 sepiolite Inorganic materials 0.000 claims abstract description 9
- 238000003756 stirring Methods 0.000 claims abstract description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000000853 adhesive Substances 0.000 claims abstract description 8
- 230000001070 adhesive effect Effects 0.000 claims abstract description 8
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims abstract description 8
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims abstract description 5
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000000463 material Substances 0.000 claims description 17
- 239000003795 chemical substances by application Substances 0.000 claims description 12
- 230000000149 penetrating effect Effects 0.000 claims description 11
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 8
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 claims description 8
- 239000000391 magnesium silicate Substances 0.000 claims description 8
- 229910052919 magnesium silicate Inorganic materials 0.000 claims description 8
- 235000019792 magnesium silicate Nutrition 0.000 claims description 8
- 235000019353 potassium silicate Nutrition 0.000 claims description 7
- 229920002545 silicone oil Polymers 0.000 claims description 7
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 7
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 4
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- 239000004411 aluminium Substances 0.000 claims description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 4
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 4
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 4
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 4
- 239000006210 lotion Substances 0.000 claims description 3
- 239000003973 paint Substances 0.000 abstract description 9
- 238000009413 insulation Methods 0.000 abstract description 8
- 230000002265 prevention Effects 0.000 abstract description 4
- 238000010276 construction Methods 0.000 abstract description 2
- 239000010425 asbestos Substances 0.000 abstract 2
- 238000005259 measurement Methods 0.000 abstract 2
- 229910052895 riebeckite Inorganic materials 0.000 abstract 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 abstract 1
- 239000000440 bentonite Substances 0.000 abstract 1
- 229910000278 bentonite Inorganic materials 0.000 abstract 1
- 239000011325 microbead Substances 0.000 abstract 1
- 239000010451 perlite Substances 0.000 abstract 1
- 235000019362 perlite Nutrition 0.000 abstract 1
- 238000004321 preservation Methods 0.000 abstract 1
- 239000002994 raw material Substances 0.000 abstract 1
- 229910052710 silicon Inorganic materials 0.000 abstract 1
- 239000010703 silicon Substances 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 10
- 239000000047 product Substances 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- 230000009970 fire resistant effect Effects 0.000 description 4
- 239000003063 flame retardant Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000004566 building material Substances 0.000 description 2
- 238000004079 fireproofing Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000011345 viscous material Substances 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
Images
Landscapes
- Fireproofing Substances (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to sea silicon fireproof heat-insulation paint and a production method thereof. The paint uses asbestos fiber, sepiolite fiber, aluminum silicate fiber, silicate microbeads, perlite, bentonite, rapid penetrant, an electrostatic suspension and hot water as raw materials, and the paint is prepared by the steps of chemical asbestos opening, negative ion suspension preparation, comprehensive forced stir, paint volume weight measurement, pH value measurement, etc. The paint has the advantages of high fireproof temperature, long fireproof time, high adhesive force low cost and simple construction. The paint does no peel off at a high temperature. Even if the paint is completely carbonized, newly-formed substances can not peel off. The can be widely used for the fire prevention, the heat insulation and the heat preservation of various buildings, devices and tanks.
Description
The present invention relates to a kind of fire-retardant material and the production technique thereof that is used for buildings, equipment, pipeline, tank body, especially fireproof insulating mold coating and production method.
In disclosed domestic and international patent documentation, existing report about fire-retardant material, the following problem of fire-retardant material ubiquity in these reports: fire prevention time limit short (less than 2.4 hours), refractory temperature low (480 ℃～1000 ℃), paint solidification postadhesion power is poor, under fire or hot conditions, easily come off.
The purpose of this invention is to provide a kind of fireproof insulating mold coating and production method; it can not only play function of heat insulation to coverture when non-fire; and under fire condition; the protection thing there is good anti-fire action; and refractory temperature height (being higher than 1000 ℃); limit for length during fire prevention (being longer than 2.5 hours), strong adhesion does not at high temperature still come off.
The object of the present invention is achieved like this: make a kind of fireproof and heat insulating coating that is used for buildings, equipment, pipeline, tank body, it is characterized in that it forms (content unit is Kg) by following material:
1. hot water (70～95 ℃) 500～600
2. fibrous magnesium silicate 30～55
3. sepiolite fibre 10～20
4. aluminum silicate fiber 20～40
5. the silicate microballon 18～38
6. pearlstone 20～35
7. wilkinite 0～10
8. polyvinyl alcohol liquid 5～18
9. milky white adhesive 10～20
10. water glass 12～28
phosphoric acid aluminium liquid 1～7
tertiary sodium phosphate 0.01～1
high-temperature agglomerant 5～12
quickly penetrating agent 1～10
organic silicone oil 0.001～0.01
The present invention produces by above-mentioned component, and its preparation method mainly comprises the steps:
1. carry out chemical opener and preparation negative ion suspension respectively;
2. will go up step gained material and remaining component comprehensively forces to stir;
3. measure coating unit weight and pH value;
Wherein: chemical opener is that fibrous magnesium silicate, sepiolite fibre and 1/5 quickly penetrating agent are mixed; Preparation negative ion suspension is to get 1/5 hot water and 1/10 quickly penetrating agent mixes stirring with wilkinite, water glass, organic silicone oil; Measuring coating unit weight is whether check lotion unit weight reaches 0.73～0.80; Measuring pH value is to measure PH whether to equal 7.5～8.5 before forming product.
The present invention adopts fibrous magnesium silicate, sepiolite fibre and aluminum silicate fiber, can keep good negative ion suspension effect at basic, normal, high temperature state, thereby brings into play heat insulating, anti-fire action.
The present invention introduces silicate microballon and pearlstone, can strengthen fire-proof high-temperature resistant and heat insulating effect.
The present invention takes wilkinite, water glass, quickly penetrating agent; have suspension, chemical opener, ionic adsorption and high temperature bonding comprehensive action; and the high-consistency viscous substance can be created in the coating top layer to coating protection under fire or high temperature (more than 1000 ℃) state, simultaneously bondingly firmly and not comes off.
The present invention uses a small amount of organic silicone oil, can eliminate the foam that is produced because of preparation negative ion suspension.
The present invention adopts polyvinyl alcohol liquid, milky white adhesive, phosphoric acid aluminium liquid, tertiary sodium phosphate to play bonding effect under middle low-temperature condition; Quote high temperature adhesive, guarantee to have bonding effect preferably more than 1000 ℃ at high temperature.
The present invention combines with ion adsorption with various caking agents and forms good sticking power.
The present invention aborning, fibrous magnesium silicate and sepiolite fibre are carried out the chemical opener of quickly penetrating agent impregnating method, fibrous bundle is loosened and centrifugation, be convenient to mix back homogeneous band negative ion and be easy to form the network-like lotion coating of band negative ion with the other materials uniform mixing with negative ion suspension.
The present invention is in production technique; the function of preparation negative ion suspension is to make the staggered and uniform mixing of various heat preserving and insulating materials, distribution; and band negative ion and form the network state body; so that can not produce combustion phenomena during presence of fire; in the condition of high temperature more than 1000 ℃; produce the high-consistency viscous substance and appear at coatingsurface, coating is carried out flameproof protection and coating is not come off.Even the whole charings of coating, the novel substance of formation can not come off yet.
The effect that the present invention comprehensively forces to stir in process of production is to increase air chamber, reduces thermal conductivity, strengthens heat insulating effect, and each starting material is evenly distributed, and enriches to poise effect, and material is played one's part to the full.
The present invention measures pH value before forming product, its objective is to guarantee that coating is weakly alkaline, avoids the corrosion of coating to the protection thing, and can possess certain preservative activity.The purpose of measuring coating unit weight is to adjust each material content, so that reach necessary requirement.
The invention will be further described below in conjunction with drawings and Examples.
Fig. 1 is a process flow sheet of the present invention.
As shown in Figure 1, preparation process of the present invention is:
One, by following material and content prepare burden (content unit K g):
1. hot water (70～95 ℃) 540
2. fibrous magnesium silicate 50
3. sepiolite fibre 16
4. aluminum silicate fiber 36
5. the silicate microballon 30
6. pearlstone 27
7. wilkinite 6
8. polyvinyl alcohol liquid 10
9. milky white adhesive 16
10. water glass 21
phosphoric acid aluminium liquid 5
tertiary sodium phosphate 0.06
high-temperature agglomerant 10
quickly penetrating agent 6
organic silicone oil 0.004
Two, get fibrous magnesium silicate, sepiolite fibre and 1/5 quickly penetrating agent and mix, realize chemical opener.
Three, add 1/4 hot water in chemical opener gained material and soak, leave standstill, time of repose is 10～20 hours.
Four, the material after will leaving standstill carries out positive and negative stirring, positive and negative churning time each 5 minutes.
Five, get 1/5 hot water, 1/10 quickly penetrating agent and wilkinite, water glass and organic silicone oil and mix, preparation negative ion suspension.
Six, prepared negative ion suspension is carried out positive and negative stirring, churning time is 20～40 minutes.
Seven, add that through chemical opener and the prepared material of preparation negative ion suspension remaining hot water and other component comprehensively force to stir aforementioned, churning time is 40～70 minutes.
Eight, measure coating unit weight and pH value, unit weight is 0.75, and PH etc. 8 get final product.
Nine, packing, warehouse-in form product.
The present invention obtains significant effect owing to adopt above-mentioned component and production method in test and in using.By national fireproof building material quality examination center test shows, coat-thickness is when 37.7mm, and refractory temperature is 1070 ℃, be limited to 2.68 hours when fire-resistant, the fire performance index is considerably beyond national standard, and strong adhesion, under the fire condition, do not come off good effect of heat insulation.
The present invention compares with other fire proofing material, and outstanding feature is the fire-resistant time limit Long, temperature is high, adhesive strength is good, difficult drop-off, heat insulation property is good. It is right See the following form than effect:
Fire proofing material performance comparison table
| Title | Data source | Coating layer thickness mm | Refractory temperature ℃ | Fire-resistant time limit h (hour) | Adhesive strength (more than 1000 ℃) | Insulation |
| The fireproof insulating mold coating | Country fireproof building material quality testing center | 37.7 | 1070 | 2.68 | Do not come off under the Fire Conditions | 1050℃ |
| Steel Construction In China fireproof paint (thick coated type) standard GB/T 14907-94 | Handbook | 30 37.7 40 | 2.0 2.38 2.5 | Come off | 800℃ | |
| The fire proof and thermo-insulation coating material composition Japan's special permission discloses 86,120, 872; 1986.6.7 open | CA 106∶6509b | 480 ℃ missing of ignition | Come off | 500℃ | ||
| Fire-resistant coating for steel structure Japan's special permission discloses 82,223, 075; 1987.10.1 open | CA 108∶78183c | 40 | 1000℃ | 0.5 | Come off | 1000℃ |
The present invention except having above-mentioned advantage, have also that cost is low, low price, Advantage easy to use, it is compared with domestic like product, and price only is other product 60～75% of product. During use, only needing coating of the present invention directly is put on need fire prevention On the equipment of insulation. If need to shorten the engineering time, can spread coating of the present invention being coated with Dry with Far infrared heating plate afterwards.
Claims (2)
1, a kind of fireproof insulating mold coating is characterized in that it forms (content is Kg) by following material:
1. hot water (70～95 ℃) 500～600
2. fibrous magnesium silicate 30～55
3. sepiolite fibre 10～20
4. aluminum silicate fiber 20～40
5. the silicate microballon 18～38
6. pearlstone 20～35
7. wilkinite 0～10
8. polyvinyl alcohol liquid 5～18
9. milky white adhesive 10～20
10. water glass 12～28
phosphoric acid aluminium liquid 1～7
tertiary sodium phosphate 0.01～1
high-temperature agglomerant 5～12
quickly penetrating agent 1～10
organic silicone oil 0.001～0.01
2, a kind of production method of fireproof insulating mold coating as claimed in claim 1 is characterized in that mainly comprising the steps:
1. carry out chemical opener and preparation negative ion suspension respectively;
2. will go up step gained material and remaining component comprehensively forces to stir;
3. measure coating unit weight and pH value;
Wherein: chemical opener is that fibrous magnesium silicate, sepiolite fibre and 1/5 quickly penetrating agent are mixed; Preparation negative ion suspension is to get 1/5 hot water and 1/10 quickly penetrating agent mixes stirring with wilkinite, water glass, organic silicone oil; Measuring coating unit weight is whether check lotion unit weight reaches 0.73～0.80; Measuring pH value is to measure PH whether to equal 7.5～8.5 before forming product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 95111236 CN1043781C (en) | 1995-01-27 | 1995-01-27 | Fireproof and heat insulating coating and its preparation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 95111236 CN1043781C (en) | 1995-01-27 | 1995-01-27 | Fireproof and heat insulating coating and its preparation |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1109089A CN1109089A (en) | 1995-09-27 |
| CN1043781C true CN1043781C (en) | 1999-06-23 |
Family
ID=5078544
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 95111236 Expired - Fee Related CN1043781C (en) | 1995-01-27 | 1995-01-27 | Fireproof and heat insulating coating and its preparation |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1043781C (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6601647B2 (en) * | 2001-12-03 | 2003-08-05 | Halliburton Energy Services, Inc. | Methods, well cement compositions and lightweight additives therefor |
| CN100371397C (en) * | 2005-09-09 | 2008-02-27 | 南阳天意保温耐火材料有限公司 | Refractory composite heat insulating sprayed material |
| CN101245235B (en) * | 2007-02-12 | 2010-10-06 | 刘建军 | Composite silicate high-viscosity cold and hot coating thermal insulation slurry |
| CN103289454B (en) * | 2013-07-08 | 2015-02-25 | 华夏贝能（北京）生态科技有限公司 | Inorganic functional coating for degrading formaldehyde by negative ions and preparation method of coating |
| CN104087037A (en) * | 2014-07-15 | 2014-10-08 | 袁旋雷 | Fireproof thermal-insulating coating |
| CN104194535B (en) * | 2014-09-18 | 2016-08-17 | 苏州圣谱拉新材料科技有限公司 | A kind of valve insulating moulding coating and preparation method thereof |
| CN106609051A (en) * | 2015-10-26 | 2017-05-03 | 天津市新丽华色材有限责任公司 | Anti-corrosion thermal conductive coating |
| CN108249959A (en) * | 2017-08-04 | 2018-07-06 | 王贵锋 | A kind of nanometer combination liquid for generating negative oxygen ion, ceramics and preparation method thereof |
-
1995
- 1995-01-27 CN CN 95111236 patent/CN1043781C/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN1109089A (en) | 1995-09-27 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CA2317606C (en) | Fire barrier material | |
| CN100337963C (en) | Water-preserving materials and process for preparing same | |
| CN109439083B (en) | Ultrathin intumescent steel structure water-based fireproof coating and preparation method thereof | |
| CN1043781C (en) | Fireproof and heat insulating coating and its preparation | |
| CN104692758B (en) | The outdoor fire-retardant fire-resistant coating for steel structure of a kind of smoke-inhibiting type | |
| CN1057448A (en) | Fireproof coating material | |
| CN114634700B (en) | Aerogel modified polyurethane foam heat insulation board and preparation method thereof | |
| CN1276894C (en) | Aluminum-magnesium base heat insulating material and its production process | |
| CN1186403C (en) | Fireproof paint for steel structure of housing | |
| CN1106851A (en) | Compound insulation and fire-proof paint | |
| CN1055101C (en) | Water-proof heat-insulation coating | |
| CN114634331A (en) | Aerogel modified glass fiber thermal insulation board and preparation method thereof | |
| CN1085582A (en) | Hard rankinite insulation coating | |
| CN86102290A (en) | Based on material of calcium silicate hydrate and its production and application | |
| CN116200109B (en) | SiO-based2High-temperature-resistant heat-insulating coating of aerogel and preparation method thereof | |
| CN110423390B (en) | Flame-retardant weather-resistant expansion fireproof casing pipe and preparation method thereof | |
| CN112830718A (en) | Fireproof flame-retardant plate and preparation method thereof | |
| CN108586796A (en) | A kind of preparation method of the A2 grade fireproof heated boards of two-dimensional material enhancing EPS | |
| US20250346769A1 (en) | Multilayer composite intumescent fire-retardant coating material, preparation method therefor, and method of using the same | |
| CN121135363B (en) | An aerogel composite material for thermal insulation pipes and its preparation method | |
| CN113149588A (en) | Premixed inorganic paste-like thermal insulation material | |
| CN1260288C (en) | Waterproof heat insulated thermal-protection material | |
| CN1114336A (en) | Sound-proof and anti-vibration coating | |
| CN118791773A (en) | Indoor thermal insulation board and preparation method thereof | |
| CN105367033A (en) | Flame retardant and heat preservation slurry |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |