CN1043314C - Modified soluble organic adhesive for casting - Google Patents
Modified soluble organic adhesive for casting Download PDFInfo
- Publication number
- CN1043314C CN1043314C CN95103925A CN95103925A CN1043314C CN 1043314 C CN1043314 C CN 1043314C CN 95103925 A CN95103925 A CN 95103925A CN 95103925 A CN95103925 A CN 95103925A CN 1043314 C CN1043314 C CN 1043314C
- Authority
- CN
- China
- Prior art keywords
- acid
- casting
- alkali metal
- soluble organic
- vegetable oil
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000005266 casting Methods 0.000 title claims abstract description 7
- 239000000853 adhesive Substances 0.000 title claims description 6
- 230000001070 adhesive effect Effects 0.000 title claims description 6
- 235000015112 vegetable and seed oil Nutrition 0.000 claims abstract description 11
- 239000008158 vegetable oil Substances 0.000 claims abstract description 11
- 150000007524 organic acids Chemical class 0.000 claims abstract description 9
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims abstract description 8
- 239000011230 binding agent Substances 0.000 claims abstract description 8
- 238000004519 manufacturing process Methods 0.000 claims abstract description 6
- 238000000034 method Methods 0.000 claims abstract description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical group [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 6
- 239000007864 aqueous solution Substances 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 4
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims description 4
- 235000005985 organic acids Nutrition 0.000 claims description 3
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims description 2
- 150000008065 acid anhydrides Chemical class 0.000 claims description 2
- 239000001530 fumaric acid Substances 0.000 claims description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims description 2
- 239000011976 maleic acid Substances 0.000 claims description 2
- 238000010521 absorption reaction Methods 0.000 abstract description 2
- 239000003999 initiator Substances 0.000 abstract description 2
- 238000012986 modification Methods 0.000 abstract description 2
- 230000004048 modification Effects 0.000 abstract description 2
- 238000007334 copolymerization reaction Methods 0.000 abstract 1
- 230000003472 neutralizing effect Effects 0.000 abstract 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical group OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 239000002383 tung oil Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 235000019774 Rice Bran oil Nutrition 0.000 description 1
- 229910001854 alkali hydroxide Inorganic materials 0.000 description 1
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium peroxydisulfate Substances [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 1
- VAZSKTXWXKYQJF-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)OOS([O-])=O VAZSKTXWXKYQJF-UHFFFAOYSA-N 0.000 description 1
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000008165 rice bran oil Substances 0.000 description 1
Landscapes
- Mold Materials And Core Materials (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
本发明提供了一种铸造用改性水溶性有机粘结剂的制造方法，它是由有机酸与植物油在引发剂作用下进行共聚反应，然后用碱金属氢氧化物溶液中和而成。采用该方法生产的有机粘结剂的粘结强度、抗吸湿性能比改性前都有显著提高。The invention provides a manufacturing method of a modified water-soluble organic binder for casting, which is formed by carrying out a copolymerization reaction of an organic acid and vegetable oil under the action of an initiator, and then neutralizing it with an alkali metal hydroxide solution. The cohesive strength and moisture absorption resistance of the organic binder produced by the method are significantly improved compared with those before modification.
Description
The present invention relates to a kind of manufacture method of water-soluble organic binder for casting.
Existing CO
2Gas is urged hard water-soluble organic binder for casting (as polyvinyl alcohol, polyacrylate etc.), and adhesion strength is low, anti-moisture absorption property is poor, and particularly in the high-humidity climate environment, above-mentioned contradiction is more outstanding, thereby in use is very limited.
The objective of the invention is at deficiency of the prior art, produce a kind of available CO
2Acidic materials such as gas are urged hard casting vegetable oil soluble organic adhesive.The present invention is subjected to the peroxide initiator effect under given conditions and copolyreaction is taken place by aqueous solutions of organic acids and vegetable oil, with the alkali hydroxide soln neutralization, generates a kind of new soluble organic adhesive then.
The manufacture method of vegetable oil soluble organic adhesive is: add vegetable oil in the aqueous solutions of organic acids that has initator to exist, in temperature is that 80 °-130 ℃, pressure are to stir 2-6 hour under the 1-4atm condition, adding alkali metal hydroxide (aqueous solution) after copolyreaction is finished stirs, its percentage by weight is: organic acid 8～20%, vegetable oil 0.5～2.5%, initator 0.2～0.7%, alkali metal hydroxide 4～12%, Yu Weishui, organic acid are acrylic acid or are the mixture of acrylic acid and fumaric acid or maleic acid (acid anhydride).
Vegetable oil can be tung oil or modification rice bran oil or its mixture, and initator can be hydrogen peroxide or ammonium persulfate or benzoyl peroxide or two kinds mixture wherein, and alkali metal hydroxide is NaOH or potassium hydroxide or its mixture.
Because vegetable oil has participated in the organic acid copolyreaction, has changed hydrophilic tendency, therefore, the binding agent that the present invention produces is compared with the binding agent that does not add the vegetable oil making, and the intensity and the resistance to water soak of type (core) are significantly improved.
Embodiment:
In reactor, add 73% water, 15.6% acrylic acid, 0.4% hydrogen peroxide, 2% tung oil is heated to 102 ℃, and reaction is 4 hours under 102 ℃, the condition of 1atm.Slowly adding 8.5% NaOH (be made in advance 25% the aqueous solution) again stirs.
Experiment effect
Type (core) sand proportioning is: normal sand 100, binding agent 3.5, curing agent (mainly containing calcium hydroxide) 1.0.
Blow CO
2Gas solidifies: gassing time 10 seconds, CO
2Gas pressure 0.1MP
a, 18 ℃ of temperature, humidity 70%.
Claims (2)
1, a kind of manufacture method of modified soluble organic adhesive for casting, it is characterized in that: in the aqueous solutions of organic acids that has initator to exist, add vegetable oil, in temperature is 80 ℃-130 ℃, pressure is to stir 2-6 hour under the 1-4atm condition, adding alkali metal hydroxide (aqueous solution) after copolyreaction is finished stirs, its percentage by weight is: organic acid 8～20%, vegetable oil 0.5～2.5%, initator 0.2～0.7%, alkali metal hydroxide 4～12%, Yu Weishui, organic acid are acrylic acid or are the mixture of acrylic acid and fumaric acid or maleic acid (acid anhydride).
2, the manufacture method of binding agent according to claim 1 is characterized in that: added alkali metal hydroxide is NaOH or potassium hydroxide or its mixture.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN95103925A CN1043314C (en) | 1995-04-13 | 1995-04-13 | Modified soluble organic adhesive for casting |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN95103925A CN1043314C (en) | 1995-04-13 | 1995-04-13 | Modified soluble organic adhesive for casting |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1133214A CN1133214A (en) | 1996-10-16 |
| CN1043314C true CN1043314C (en) | 1999-05-12 |
Family
ID=5074927
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN95103925A Expired - Fee Related CN1043314C (en) | 1995-04-13 | 1995-04-13 | Modified soluble organic adhesive for casting |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1043314C (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101927319A (en) * | 2010-04-29 | 2010-12-29 | 苏州市兴业铸造材料有限公司 | Adhesive applicable for manufacturing casting mold and use thereof |
| CN106694793B (en) * | 2015-11-17 | 2019-12-03 | 胡坦斯·阿尔伯图斯化学厂有限公司 | Use of alkaline compositions, corresponding methods, molds and systems |
| MX2019001540A (en) * | 2016-08-12 | 2019-05-09 | Dow Global Technologies Llc | Method for making water-based pressure sensitive adhesive compositions. |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3305370A (en) * | 1962-06-20 | 1967-02-21 | Foseco Int | Mold composition for foundry use |
| CN1032127A (en) * | 1987-04-04 | 1989-04-05 | 天津市南开区铸造涂料厂 | Composite type binding material for casting |
| CN1076391A (en) * | 1992-03-17 | 1993-09-22 | 滨州师范专科学校 | A kind of method of utilizing cotton oil distillation residues to make moulding sand binder |
| CN1088859A (en) * | 1993-01-02 | 1994-07-06 | 大连市金州区同益化工厂 | High-strength adhesive for casting |
| CN1098960A (en) * | 1993-03-22 | 1995-02-22 | 阿姆威公司 | Home water purification system |
-
1995
- 1995-04-13 CN CN95103925A patent/CN1043314C/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3305370A (en) * | 1962-06-20 | 1967-02-21 | Foseco Int | Mold composition for foundry use |
| CN1032127A (en) * | 1987-04-04 | 1989-04-05 | 天津市南开区铸造涂料厂 | Composite type binding material for casting |
| CN1076391A (en) * | 1992-03-17 | 1993-09-22 | 滨州师范专科学校 | A kind of method of utilizing cotton oil distillation residues to make moulding sand binder |
| CN1088859A (en) * | 1993-01-02 | 1994-07-06 | 大连市金州区同益化工厂 | High-strength adhesive for casting |
| CN1098960A (en) * | 1993-03-22 | 1995-02-22 | 阿姆威公司 | Home water purification system |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1133214A (en) | 1996-10-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1293159C (en) | Method for preparing starch glue for lumber | |
| CN101649179B (en) | Modified soybean-based adhesive and preparation method thereof | |
| CN103122228B (en) | Bio-oil starch adhesive for wood and preparation method | |
| CN102002756A (en) | Method of preparing calcium sulfate whisker by using agglomerate fume desulfurized by-products | |
| CN108410254B (en) | A kind of water-based binder and food-contact water-based ink prepared by using the same | |
| CN105666613B (en) | The preparation method of the super-hydrophobic weather-proof magnetic function timber of oleophobic bactericidal, fire retardant | |
| CN1043314C (en) | Modified soluble organic adhesive for casting | |
| CN110997833B (en) | Aqueous coating composition | |
| DE602004006393D1 (en) | REVERSIBLE NETWORKED ADHESIVE RESIN COMPOSITIONS AND METHOD | |
| CN101240354A (en) | Acrylic resin/SiO2 nano composite tanning agent and preparation method thereof | |
| KR102370498B1 (en) | Inorganic low viscosity aqueous adhesive coating composition and its use | |
| CN116574452B (en) | A kind of water-resistant magnesium oxychloride inorganic adhesive for plywood and its preparation method | |
| NO20022445D0 (en) | Binder for the preparation of shaped bodies and shaped bodies made using said binder | |
| CN101486889B (en) | Monomer copolymerization modified soy protein adhesive and preparation thereof | |
| CN1539902A (en) | A kind of green nontoxic adhesive and preparation method thereof | |
| TWI322162B (en) | Curable composition and its uses | |
| CN114213141A (en) | Fire-free ceramsite with sodium silicate sand dust and carbide slag as activators and its preparation | |
| KR100879750B1 (en) | Method for preparing natural water-based paint composition and composition therefrom | |
| IE43835B1 (en) | Production of dispersions of polyvinyl acetate | |
| CN107214799A (en) | A kind of chemical modification silicon ash base fire retarding wood composite coating | |
| WO2024207578A1 (en) | Water-resistant paper-faced gypsum board using high-fluorine-content gypsum | |
| CN1075751C (en) | Water-soluble organic binder for casting | |
| CN118667526B (en) | A foam drilling fluid and its application | |
| CN105585272A (en) | Novel concrete reinforcing agent | |
| CN115785777B (en) | Low-temperature quick-drying waterproof coating and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |