CN104160007A - Fragrance composition for reducing lingering tobacco odor, and cigarette - Google Patents
Fragrance composition for reducing lingering tobacco odor, and cigarette Download PDFInfo
- Publication number
- CN104160007A CN104160007A CN201280071133.7A CN201280071133A CN104160007A CN 104160007 A CN104160007 A CN 104160007A CN 201280071133 A CN201280071133 A CN 201280071133A CN 104160007 A CN104160007 A CN 104160007A
- Authority
- CN
- China
- Prior art keywords
- ionone
- cigarette
- tobacco
- flavor compositions
- decalactone
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
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Classifications
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
- A24B15/30—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
- A24B15/281—Treatment of tobacco products or tobacco substitutes by chemical substances the action of the chemical substances being delayed
- A24B15/282—Treatment of tobacco products or tobacco substitutes by chemical substances the action of the chemical substances being delayed by indirect addition of the chemical substances, e.g. in the wrapper, in the case
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
- A24B15/30—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances
- A24B15/301—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances by aromatic compounds
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
- A24B15/30—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances
- A24B15/34—Treatment of tobacco products or tobacco substitutes by chemical substances by organic substances containing a carbocyclic ring other than a six-membered aromatic ring
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D1/00—Cigars; Cigarettes
- A24D1/002—Cigars; Cigarettes with additives, e.g. for flavouring
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/14—Use of materials for tobacco smoke filters of organic materials as additive
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11B—PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
- C11B9/00—Essential oils; Perfumes
- C11B9/0026—Essential oils; Perfumes compounds containing an alicyclic ring not condensed with another ring
- C11B9/0034—Essential oils; Perfumes compounds containing an alicyclic ring not condensed with another ring the ring containing six carbon atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Toxicology (AREA)
- General Health & Medical Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Manufacture Of Tobacco Products (AREA)
- Fats And Perfumes (AREA)
- Cigarettes, Filters, And Manufacturing Of Filters (AREA)
Abstract
A fragrance composition for reducing lingering tobacco odor, said fragrance composition comprising an ionone selected from the group consisting of alpha-ionone, beta-ionone and methyl ionone together with other fragrance component(s).
Description
Technical field
The present invention relates to a kind of cigarette of adhering to the flavor compositions of stink and using it for improving tobacco.
Background technology
In recent years, people improve the care of stench and foreign odor, therefore, have developed the various technology that relate to reodorant.Also developed various take eliminate the reodorant that " the adhering to stink " be adsorbed in clothes, cloth products, hair etc. and produce is object, in these reodorant, also exist take to be adsorbed in because the sidestream smoke in smoking etc. is discharged into tobacco stink around the reodorant (with reference to TOHKEMY 2007-77545 communique, the flat 9-505500 communique of Japanese Unexamined Patent Application Publication and TOHKEMY 2006-340785 communique) that " tobacco adheres to stink " that clothes, cloth products, hair etc. produce is object.But, do not attempt these odor control agent composition to be added in cigarette, if these compositions are directly made an addition in cigarette and used, produce combustion processes because of cigarette and make composition such problem that goes bad.In addition, if these compositions are directly made an addition in cigarette and used, need a large amount of interpolations, obviously damage the perfume (or spice) of tobacco itself and inhale taste (fragrant Eat taste).In brief, making an addition to the tobacco of using in cigarette adheres to stink and improves spices and seek can improve with minute quantity the effect that tobacco adheres to stink.
On the other hand, developed at present a kind of reodorant (with reference to TOHKEMY 2002-143285 communique, TOHKEMY 2002-143284 communique, TOHKEMY 2002-146386 communique and TOHKEMY 2009-179711 communique) that reduces tobacco odor of secondary smoke.And then, also developed the odor of secondary smoke deodorizing flavor compositions that grows tobacco, it is added in cigarette and uses (with reference to TOHKEMY 2009-179708 communique and Japanese kokai publication hei 11-124800 communique).Even if these flavor compositions mix with tobacco stink, can obviously not increase whole odor strength (that is, can not damage the perfume (or spice) of tobacco itself and inhale taste) yet, can be effectively by the deodorizing of tobacco odor of secondary smoke.But these compositions are the reodorant for reducing tobacco odor of secondary smoke, be not to imagine as the present invention to reduce the reodorant that tobacco adheres to stink.Tobacco adheres to stink as mentioned above for being adsorbed in the rear stinks that produce such as clothes, cloth products, hair, therefore, tobacco adheres to stink improves spices and need to consider that they are adsorbed in desorption after clothes and hair and the process that shows, is difficult to think that the flavor compositions that reduces tobacco odor of secondary smoke also can bring into play the effect that equal reduction tobacco adheres to stink.In addition, for tobacco, adhere to stink, in order to obtain improving fully effect, need to increase the deodorizing dosage of clothes and hair per unit area.In brief, in order to obtain sheltering the effect of the tobacco stink that is attached to clothes and hair, need to add more than to the more substantial reodorant of tobacco odor of secondary smoke deodorizing.On the other hand, as mentioned above, add a large amount of spices and can affect the perfume (or spice) of tobacco and inhale taste, therefore, tobacco adheres to stink and improves spices and still seek to show that with minute quantity stronger tobacco adheres to stink and improves effect.
Known, when flavor compositions is made an addition to cigarette, also need to study its addition means.As a kind of representational method, proposed to coat the method for cigarette coil paper.By coating coil paper, flavor compositions is attached to clothes and hair via sidestream smoke, then desorption and playing a role.But, show and to improve the flavor compositions of effect by stink almost all volatility is high at normal temperatures, be difficult to the long-time fully spices of amount that keeps on coil paper.And then, the known spices that makes an addition to coil paper through time move to pipe tobacco and goods wrapping material, this perfume (or spice) that likely affects tobacco is inhaled taste.
In order to solve such problem, a kind of spices of modifying of having carried out is disclosed, stable and do not there is volatility under its manufacture at tobacco product and storage condition, and under smoking condition discharging perfume compound by thermolysis or desorption.The for example flat 2-501075 communique of Japanese Unexamined Patent Application Publication or United States Patent (USP) the 4th, the spices that the glucosides that 804, No. 002 specification sheetss disclose a kind of acetal by containing sugar and perfume compound forms.But, in this technology, exist during the thermal decomposition product of glucosides is sneaked into cigarette when smoking and affect the such problem of tobacco fragrant suction taste.In addition, this technology cannot be applied to prepare the perfume compound of glucosides, and therefore, applicable perfume compound is limited.In addition, Japanese kokai publication hei 5-146285 communique or United States Patent (USP) the 5th, 144, No. 964 specification sheetss and the flat 7-504080 communique of Japanese Unexamined Patent Application Publication or United States Patent (USP) the 5th, 479, No. 949 specification sheetss disclose the technology of the cyclodextrin encapsulated spices of a kind of use.But, this technology also exist the thermal decomposition product of cyclodextrin when smoking sneak into cigarette in and affect the fragrant such problem of taste of inhaling of tobacco.In addition, can be restricted by the amount of cyclodextrin encapsulated spices, the adaptive viewpoint of machinery during from cigarette wraparound is considered, the amount that cyclodextrin is coated coil paper is also restricted, therefore, result is compared with the situation of spices directly being coated to coil paper, also has the problem that can only use a small amount of spices.Therefore, the spices that can apply this technology is limited to that having sufficient reductions tobacco adheres to the spices of stink effect on a small quantity, and the kind of spices is subject to system and limits.
Summary of the invention
As mentioned above, up to now, by making an addition to the reodorant of cigarette, improve the tobacco stink that is attached to clothes and hair method, touch problem itself example well known hardly, when not existing the perfume (or spice) of guaranteeing tobacco itself to inhale taste, tobacco is not adhered to the effective reodorant of stink.
Therefore, the object of the invention is to, provide a kind of and can improve the perfume (or spice) that tobacco adheres to stink and can not damage tobacco itself by less usage quantity and inhale the flavor compositions of taste and the cigarette of using it.
The discoveries such as the inventor, if the ionone and other fragrance component that are selected from α-ionone, β-ionone and methyl ionone are mixed, ionone can strengthen the flavour intensity of other fragrance component.In addition, find that the perfume (or spice) that these flavor compositions can not damage tobacco itself inhales taste, and can the adaptive addition of machinery when not reducing cigarette wraparound substantially improve the tobacco that is attached to clothes or hair and adhere to stink.And then if use γ-decalactone as other fragrance component, reinforced effects is more obvious.
According to an embodiment of the present invention, can provide a kind of flavor compositions that adheres to stink for improving tobacco, it contains ionone and other fragrance component being selected from α-ionone, β-ionone and methyl ionone.
In flavor compositions of the present invention, the containing ratio of described ionone is preferably 10 to 50 % by weight, more preferably 20 to 30 % by weight.
In flavor compositions of the present invention, above-mentioned other fragrance component is not particularly limited, for example, can enumerate: as the laurine of terpenic series aldehydes, piperitone as terpenic series ketone, geraniol as terpenic series alcohols, Geraniol, phantol, rhodinol, α-terpinol, terpinyl acetate as terpenic series ester class, dihydro myrcene as aliphatics chain alcohols, as aliphatics chain aldehydes trans-2-decenal, dihydro methyl jasmonate as aliphatics ring-type ketone, ethyl maltol, LINL-OX, anisyl acetate as aliphatic ester, benzyl butyrate, Laurate ethyl, hexanaphthene allyl propionate, γ-undecane lactone as aliphatics lactone, γ-decalactone, γ-nonyl lactone, γ-octalactone, Sclareolide, ω-pentadecane lactone (15-Pentadecanolide), δ-dodecane lactone, γ-heptalactone, tetradecanoic acid as aliphatic carboxylic acid class, aubepine as aromatic series aldehydes, vanillal, 4-isopropyl benzene formaldehyde, 4-ethylbenzene formaldehyde, phenylacrolein, 4-ethoxy-benzaldehyde, α-methyl-p-tert.-butyl phenylpropionaldehyde, 1-(4-methoxyphenyl)-1-penten-3-one as aromatic series ketone, raspberry ketone, methyl betanaphthyl ketone, 1-ethoxy-2-hydroxy-4-propenyl benzene as aromatic series alcohols, formic acid fennel ester as aromatic ester class, butyric acid phenyl chlorocarbonate, cinnamyl acetate, benzyl propionate, phenyl acetic acid 4-methoxy benzyl ester, cinnamyl propionate, methyl oaminobenzoate, isopropylformic acid phenyl chlorocarbonate, wintergreen oil, methyl cinnamate, ethyl cinnamate, 4-propyl group phenylmethylether as aromatic series ethers, methyl allylphenol, 3-propylidyne phthalide as aromatic series lactone, as 3-phenylpropionic acid of aromatic carboxylic acid class etc.These compositions also can be used separately, can also with the form (compound perfume) of mixture, use according to expectation.In these compositions, be preferably and be selected from laurine, geraniol, Geraniol, phantol, rhodinol, dihydro myrcene, trans-2-decenal, dihydro citric acid methyl, anisyl acetate, benzyl butyrate, hexanaphthene allyl propionate, γ-decalactone, γ-nonyl lactone, γ-octalactone, ω-pentadecane lactone (15-Pentadecanolide), aubepine, vanillal, α-methyl-p-tert.-butyl phenylpropionaldehyde, raspberry ketone, 1-ethoxy-2-hydroxy-4-propenyl benzene, formic acid fennel ester, butyric acid phenyl chlorocarbonate, cinnamyl acetate, cinnamyl propionate, in methyl cinnamate and ethyl cinnamate more than a kind.Particularly more preferably be selected from geraniol, Geraniol, rhodinol, anisyl acetate, γ-decalactone and γ-nonyl lactone, 1-ethoxy-2-hydroxy-4-propenyl benzene and formic acid fennel ester more than a kind.
Also can replace above-mentioned fragrance component or use the natural perfume that contains these compositions together with above-mentioned fragrance component.As such natural perfume, for example can enumerate: pamorusa oil, rose oil, Oleum Pelargonii Graveolentis, geraniumroseoil, volatile oil extracted from eucalyptus' leaves or twigs, spiceleaf leaf oil, alloy is oil vigorously, rusa oil, oleum graminis citrati, thyme oil, bay-oil, basil oil, bergamot oil, Fructus Citri Sarcodactylis rose oil, rose-wood oil, perfume tree oil, Radix Dauci Sativae grass oil, champaca(flower) oil, sage oil, coriander seed oil, virtue oil, virtue camphor tree, jasmine oil, eye-catching Oleum lavandula angustifolia, Oleum lavandula angustifolia, lavandula angustifolia stem oil, spike oil, Sweet marjoram oil, the former essence of narcissus, orange flower oil, orange oil, flores aurantii, petitgrain bigarade oil, Herba ophiorrhizae japonicae oil, ylang ylang oil, perfume tree oil, Herba Artemisiae Annuae oil, coriander, coriander seed, Artemisia pallens, Radix Dauci Sativae leaf oil, champaca(flower) oil, ladanum oil, malpighia glabra oil, carambola oil, olium anisi, Sweet fennel oil, tagetes oil, coriander, virtue camphor tree, narcissus wet goods.
In flavor compositions of the present invention, when described other fragrance component only consists of γ-decalactone, the containing ratio of preferred described γ-decalactone is 70 to 80 % by weight, and the containing ratio of described ionone is 20 to 30 % by weight.
According to other embodiment of the present invention, can provide a kind of and support above-mentioned tobacco and adhere to the cigarette that stink improves flavor compositions.Tobacco of the present invention adheres to stink and improves flavor compositions and conventionally can in the arbitrary operation that spices is made an addition to cigarette, add.As tobacco material, also can use arbitrary tobacco materials such as lobate tobacco (yellow kind, white rib kind, east kind etc.), thin slice tobacco, conventionally, these tobacco materials are used for cigarette with the form of pipe tobacco.Pipe tobacco can be also expanded form.In addition, tobacco of the present invention adheres to stink and improves arbitrary position that flavor compositions also can make an addition to tobacco material, material product (tobacco filter etc.).
The inventor etc. also find, if with the cyclodextrin encapsulated flavor compositions that contains ionone, can improve the undesirable perfume (or spice) that the thermal decomposition product by cyclodextrin causes and inhale taste.Therefore, cigarette of the present invention is preferably the cigarette forming with coil paper package pipe tobacco, wherein, and described coil paper coating or the useful cyclodextrin encapsulated described flavor compositions of spraying.
In cigarette of the present invention, inclusion is more than in the described flavor compositions of cyclodextrin, the glue spread on coil paper is preferably 100ppm and below 200ppm.
In the flavor compositions that contains ionone as above, the effect of the fragrance of other fragrance component that can be enhanced.Therefore, even for can not there is by cyclodextrin encapsulated amount the flavor compositions of sufficient masking effect, by with ionone use, also can strengthen fragrance to such an extent as to show sufficient masking effect.Its result, the analogy of spendable spices kind increased in the past, can increase the variability of fragrant matter.
Embodiment
Below, embodiments of the present invention are described.
Test 1
Not preferred fragrant the improve effect of inhaling taste of checking ionone to cyclodextrin thermal decomposition product.
[preparing cigarette]
Embodiment 1A: the cyclodextrin of cyclodextrin (CD) 75 weight parts and inclusion β-ionone (CD of inclusion BI) 25 weight parts are mixed with the form of powder.With respect to the 6.0wt% aqueous solution of carboxymethyl cellulose, this mixed powder is disperseed, be 16wt%, prepare dispersion liquid.Use the intaglio plate coating machine of Lian Jing Jing Ji Co., Ltd. system, at the central part of the wide coil paper of 27mm (P35) with 7mm width intaglio plate coating dispersion liquid.The cyclodextrin encapsulation rate of β-ionone is analyzed with GC-MSD, and result is that the glue spread of 9.2%, β-ionone on coil paper is that 23.2ppm/ props up.Use the cigarette sample of the coil paper making embodiment 1A of preparation.Cigarette is used common commercial cigarettes.
As the contrast of the cigarette sample with respect to embodiment 1A, prepare the cigarette sample of comparative example 1A, 1B and 1C.The cigarette sample of comparative example 1A, 1B and 1C is used respectively following coil paper.The coil paper of using in the cigarette sample of comparative example 1B and 1C carries out intaglio plate by utilization and above-mentioned same method by the dispersion liquid of regulation and is coated with to prepare.Use each coil paper comparison example 1A, 1B of preparation and the cigarette sample of 1C.Cigarette is used the commercial cigarettes identical with embodiment 1A.
Comparative example 1A: uncoated
Comparative example 1B: coating cyclodextrin (CD)
Comparative example 1C: the cyclodextrin (CD of inclusion DL) of coating cyclodextrin (CD)+inclusion γ-decalactone
[evaluation of fragrant suction taste]
By 3 special valuation officers in company, by point system, the cigarette sample of making is evaluated to the fragrant taste of inhaling.Mark as described below.
1 minute=fragrant inhale the non-constant of taste, 2 minutes=fragrant inhale taste poor, 3 minutes=fragrant inhale taste slightly poor, 4 minutes=fragrant inhale taste slightly good, 5 minutes=fragrant inhale taste good, 6 minutes=it is fragrant that to inhale taste very good.
The scoring of each sample is the arithmetical av of 3 special valuation officers' scoring.Score calculation is to one decimal place.Show the result in table 1.
[table 1]
Following content as shown in Table 1.Compare with using the cigarette of the comparative example 1A of uncoated coil paper, used the perfume (or spice) of cigarette of the comparative example 1B of the coil paper that is only coated with CD to inhale taste and be suppressed.Used the cigarette of embodiment 1A of coil paper of the CD that is coated with CD and inclusion BI with respect to the cigarette of comparative example 1B, had the fragrant effect of improving of inhaling taste, scoring is close to the cigarette of comparative example 1A.Use the cigarette of comparative example 1C of the coil paper of the CD that is coated with CD and inclusion DL to compare with the cigarette of comparative example 1B, do not shown the fragrant effect of improving of inhaling taste.
In the situation that using α-ionone or methyl ionone to replace β-ionone, also similarly confirm the fragrant taste of inhaling with the cigarette of embodiment 1A and improve effect.
Test 2
The reinforced effects of checking ionone to other fragrance component.Other fragrance component using in this test is γ-decalactone.
[preparation spice solution]
As spice solution, prepare γ-decalactone blend compositions (I+DL) or independent (only I) solution of ionone of (only DL), γ-decalactone and ionone separately.As ionone, prepare α-ionone, β-ionone or methyl ionone.γ-decalactone in each solution and the mixing ratio of ionone are as shown in table 2.As solvent, prepare propylene glycol (PG).About γ-decalactone separately and the blend compositions solution of γ-decalactone and ionone, in screw socket bottle, put into the PG of 20 μ L spices and 1000 μ L, prepare the PG solution of spices.Ionone content in the PG solution of the flavour content of the independent solution of ionone and the blend compositions of γ-decalactone and ionone is consistent.
[sensory evaluation]
Each spice solution of preparation is bonded to the front end of Wen Xiangzhi, by 3 in company special valuation officers, according to 6 grades of point systems, flavour intensity is evaluated.The blend compositions solution of the independent solution of γ-decalactone and γ-decalactone and ionone is evaluated to the flavour intensity of γ-decalactone in solution.The independent solution of ionone is evaluated to the flavour intensity of ionone.Mark as described below.
1 minute=flavour intensity is very weak, 2 minutes=flavour intensity is weak, 3 minutes=flavour intensity is slightly weak, 4 minutes=flavour intensity is slightly strong, 5 minutes=flavour intensity is strong, 6 minutes=flavour intensity is very strong.
The scoring of each sample is the arithmetical av of 3 special valuation officers' scoring.Score calculation is to one decimal place.Show the result in table 2.
[table 2]
Following content as shown in Table 2.Compare with the flavour intensity (3.2) of the independent solution of γ-decalactone, the blend compositions solution of γ-decalactone and ionone all can strengthen the flavour intensity of γ-decalactone.Even the known use level that reduces γ-decalactone because increasing the use level of ionone, but still increase on the flavour intensity sense organ of γ-decalactone.Flavour intensity with respect to the γ-decalactone of the independent solution of γ-decalactone (not adding ionone), if scoring is poor larger, be evaluated as reinforced effects larger, the containing ratio of ionone preferably 10～50wt%, more preferably 20～30wt% in the blend compositions solution of γ-decalactone and ionone.In the situation that use the arbitrary ionone in α-ionone, β-ionone and methyl ionone all to have such tendency.
On the other hand, the scoring of the flavour intensity of the independent solution of ionone is below 2.4, quite a little less than.This expression can be not changing whole fragrant matter, keep increasing whole flavour intensity under the state of fragrant matter of γ-decalactone.
Test 3
The effect of improving that checking tobacco adheres to stink.
[preparing cigarette]
Prepare the flavor compositions (adding up to 100wt%) of mixing ratio shown in table 3 and table 4.Cigarette is all used the cigarette identical with embodiment 1A.
1. embodiment 3A-3H and comparative example 3A-3D
Each flavor compositions is dissolved in after ethanol, and use syringe is coated whole of cigarette coil paper.The glue spread of the ethanolic soln of each flavor compositions is that 10 μ L/ prop up.Addition in table 3 (ppm) represents the spices addition with respect to every 1 cigarette (pipe tobacco weight 650mg).For example, in the situation that addition is 150ppm, in the ethanolic soln 10 μ L of flavor compositions, be dissolved with the flavor compositions of 650mg * 150ppm=97.5 μ g.Use the coil paper of preparation to make cigarette, carry out sensory evaluation.
2. embodiment 3I-3M
Make each flavor compositions inclusion in cyclodextrin.Similarly make the cyclodextrin of inclusion spices be dissolved in the 6.0wt% aqueous solution of carboxymethyl cellulose with test 1, prepare dispersion liquid.Use intaglio plate coating machine with 7mm width intaglio plate, to be coated with dispersion liquid at the central part of the wide cigarette coil paper of 27mm.Addition in table 2 (ppm) represents the addition of flavor compositions, by the addition of cyclodextrin and the encapsulation rate of each flavor compositions of inclusion spices, is determined.Use the coil paper of preparation to make cigarette, carry out sensory evaluation.
[sensory evaluation]
1) tobacco adheres to the evaluation of stink
Cigarette while making cigarette combustion is attached to respectively each starting material of polyester, cotton and hair, by 48 special valuation officers in company, by a pair of relative method (double blinding evaluation), carries out the evaluation that tobacco adheres to stink.Details is as described below.
Polyester (polyester of JIS standard, 5 * 5cm sheet), cotton (No. 3, the kissuto of JIS standard, 5 * 5cm sheet), hair (Osaka hairbrush Co., Ltd. system, people's hair black wool 100%) play respectively in having a pair of container of same volume.By the cigarette of uncoated spices product and the coating spices product same volume of burning in container separately, make sidestream smoke now be attached to respectively the starting material in same container.After cigarette is flame-out, from each container of burnt uncoated spices product and coating spices product, take out starting material, and starting material are separately put into the screw socket bottle with 3 bit digital.By special valuation officer, a pair of starting material of uncoated spices product/coating spices product are smelt and heard and compare tobacco and adhere to stink, select tobacco to adhere to the weak starting material of odor strength.
About the flavor compositions of test, whether have and improve tobacco and adhere to the functional of stink, and uncoated spices product between implement two-phase and detect (both sides detection), with following benchmark, evaluate.
Well=reliability is more than 95% level, has notable difference, and qualified=reliability is more than 90% level, has notable difference, defective=there is no a notable difference.
2) whole flavour intensity evaluation
By 3 special valuation officers in company, utilize point system to carry out respectively the evaluation of whole flavour intensity to each accompanying starting material of the cigarette of tobacco.Mark as described below.
0 minute=there is no that fragrance, 1 minute=flavour intensity are very weak, 2 minutes=flavour intensity weak, 3 minutes=flavour intensity is slightly weak, 4 minutes=flavour intensity is slightly strong, 5 minutes=flavour intensity is strong, 6 minutes=flavour intensity is very strong.
Each raw-material scoring is the arithmetical av of 3 special valuation officers' scoring.Score calculation is to one decimal place.
3) fragrant suction taste evaluation
By 3 special valuation officers in company, utilize point system to evaluate the fragrant taste of inhaling to the cigarette sample of making.Mark as described below.
1 minute=fragrant inhale the non-constant of taste, 2 minutes=fragrant inhale taste poor, 3 minutes=fragrant inhale taste slightly poor, 4 minutes=fragrant inhale taste slightly good, 5 minutes=fragrant inhale taste good, 6 minutes=it is fragrant that to inhale taste very good.
The scoring of each sample is the arithmetical av of 3 special valuation officers' scoring.Score calculation is to one decimal place.
Test-results is shown in to table 3 and table 4.
[table 3]
[table 4]
The known following content of result as shown in Table 3.
The contrast of contrast, embodiment 3G and comparative example 3C and the contrast of embodiment 3H and comparative example 3D from contrast, embodiment 3C and the comparative example 3B of embodiment 3A and comparative example 3A, compare with the flavor compositions that does not contain ionone, the flavor compositions that contains the arbitrary ionone in α-ionone, β-ionone and methyl ionone reduces the function that tobacco in each starting material adheres to stink and obviously rises, and whole flavour intensity and the fragrant taste aspect of inhaling also good.
And then, also known with contain ionone and γ-decalactone as other fragrance component beyond the flavor compositions of fragrance component compare, contain ionone and as the flavor compositions of the γ-decalactone of other fragrance component, reduce the function that tobacco in each starting material adheres to stink and improve, it is large that fragrance reinforced effects becomes.For example, the reduction function of containing the flavor compositions of the embodiment 3A of γ-decalactone, the tobacco of polyester not being adhered to stink is good, but the reduction function that the tobacco of cotton and hair is adhered to stink slightly a little less than.By contrast, the flavor compositions of the embodiment 3B-3G that contains γ-decalactone makes that the arbitrary raw-material tobacco of polyester, cotton and hair is adhered to stink all to be reduced well.
In addition, if contrast does not all contain embodiment 3A and the comparative example 3A of γ-decalactone, the enhancing ratio of flavour intensity is 1.5 times of 3.7 ÷ 2.4 ≒.On the other hand, if contrast does not all contain embodiment 3E and the comparative example 3C of γ-decalactone, the enhancing ratio of flavour intensity is 2.0 times of 5.3 ÷ 2.7 ≒.Like this, compare with the flavor compositions of fragrance component beyond containing ionone and γ-decalactone as other fragrance component, contain ionone and large as the fragrance reinforced effects of the flavor compositions of the γ-decalactone of other fragrance component.
In addition, when flavor compositions only consists of ionone and γ-decalactone, containing ratio at γ-decalactone is 70 to 80 % by weight, the containing ratio of ionone is 20 during to 30 % by weight, especially shows that good reduction tobacco adheres to functional, whole flavour intensity and the fragrant taste (embodiment 3E, embodiment 3G) of inhaling of stink.
In addition, from comparative example 3C, when γ-decalactone is independent, at addition, be under 150ppm, can not manifest reduction tobacco to adhere to the functional of stink.
The known following content of result as shown in Table 4.
As embodiment 3I-3M by flavor compositions inclusion in cyclodextrin and coat coil paper and make cigarette in the situation that, except can obtaining the reinforced effects of other fragrance component that ionone brings, also can obtain function, the fragrant taste of inhaling that good reduction tobacco adheres to stink.
Test 4
The preferred of the flavor compositions that contains ionone verified the glue spread of cigarette.
[preparing cigarette]
By γ-decalactone and β-ionone respectively inclusion in cyclodextrin and coat coil paper, make cigarette (DL-CD+BI-CD=75wt%+25wt%).Cigarette is all used the cigarette identical with embodiment 1A.
Cyclodextrin 25 weight parts of the cyclodextrin of inclusion γ-decalactone 75 weight parts and inclusion β-ionone are mixed with powder type.This mixed powder is scattered in after the 6.0wt% aqueous solution of carboxymethyl cellulose, uses intaglio plate coating machine with 7mm width, to carry out intaglio plate coating at the central part of the wide cigarette coil paper of 27mm.The level of glue spread is as shown in table 5.The concentration of the cyclodextrin of preparation inclusion spices makes it reach target glue spread.Use the coil paper of preparation to prepare cigarette, evaluate wraparound adaptability, the tobacco of cigarette are adhered to stink and the fragrant taste of inhaling.
In contrast, only use the cyclodextrin of inclusion γ-decalactone, in addition, with the above-mentioned coil paper of similarly preparing, use the coil paper of preparation to make cigarette (only DL-CD), evaluate wraparound adaptability, the tobacco of cigarette are adhered to stink and the fragrant taste of inhaling.
[the wraparound adaptability to cigarette]
By cigarette manufacture, be responsible for evaluating.Use the coil paper of preparation and utilize mica wrappingmachine to make cigarette.While observing generation frequency, the wraparound of bad wraparound while making 40000 cigarette continuously, the situation of dispersing, the attachment of cyclodextrin to coil paper paper-feed roll and coil paper contact part of cyclodextrin, comprehensively evaluate adaptability as follows.
Good: wraparound is good, qualified: can wraparound, defective: cannot wraparound.
[sensory evaluation]
1) tobacco adheres to the evaluation of stink
Cigarette while making to burn cigarette is attached to respectively the starting material of regulation, and 12 special valuation officers in company utilize point system to carry out the evaluation that tobacco adheres to stink.The manufacture method of the sample of evaluating is identical with above-mentioned test 3.As starting material, except polyester, cotton and hair, also use wool (JIS standard wool, 5 * 5cm sheet).By special valuation officer, smell each raw-material tobacco of news and adhere to stink, the tobacco which kind of degree evaluation table reveals adheres to stink reduction function.Special valuation officer evaluates each starting material respectively.Mark as described below.
1 minute=do not show (reduce tobacco adhere to stink) functional, 2 minutes=slightly show functional, 3 minutes=show functional, 4 minutes=show stronger functional.
Each raw-material scoring is the arithmetical av of 12 special valuation officers' scoring.Score calculation is to one decimal place.
2) fragrant suction taste evaluation
The point system of utilizing by 4 in company special valuation officers is evaluated the fragrant taste of inhaling to the cigarette sample of making.Mark as described below.
1 minute=(fragrant inhale taste) poor, 2 minutes=can accept, 3 minutes=slightly good, 4 minutes=well.
The scoring of each sample is the arithmetical av of 3 special valuation officers' scoring.Score calculation is to one decimal place.
Test-results is shown in to table 5.
[table 5]
As shown in Table 5, the preferred glue spread that meets the flavor compositions of the functional and fragrant suction taste of the reduction that the wraparound adaptability of cigarette, tobacco are adhered to stink is that 100ppm is above and below 200ppm.
Claims (8)
1. for improving tobacco, adhere to a flavor compositions for stink, it contains: be selected from ionone and other fragrance component in α-ionone, β-ionone and methyl ionone.
2. flavor compositions according to claim 1, wherein, the containing ratio of described ionone is 10 to 50 % by weight.
3. flavor compositions according to claim 2, wherein, the containing ratio of described ionone is 20 to 30 % by weight.
4. flavor compositions according to claim 1, wherein, described other fragrance component be selected from geraniol, Geraniol, rhodinol, anisyl acetate, γ-decalactone, γ-nonyl lactone, 1-ethoxy-2-hydroxy-4-propenyl benzene and formic acid fennel ester more than a kind.
5. flavor compositions according to claim 4, wherein, described other fragrance component only consists of γ-decalactone, and the containing ratio of described γ-decalactone is 70 to 80 % by weight, and the containing ratio of described ionone is 20 to 30 % by weight.
6. a cigarette, it supports the flavor compositions described in the requirement 1 of having the right.
7. cigarette according to claim 6, it is for there being the cigarette of pipe tobacco with coil paper wraparound, and wherein, described coil paper has the cyclodextrin of described flavor compositions to carry out coating or sprayed with inclusion.
8. cigarette according to claim 7, wherein, inclusion is more than 100ppm and below 200ppm in the described flavor compositions of cyclodextrin to the glue spread of coil paper.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/JP2012/055844 WO2013132618A1 (en) | 2012-03-07 | 2012-03-07 | Fragrance composition for reducing lingering tobacco odor, and cigarette |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104160007A true CN104160007A (en) | 2014-11-19 |
| CN104160007B CN104160007B (en) | 2017-10-13 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201280071133.7A Active CN104160007B (en) | 2012-03-07 | 2012-03-07 | Fragrance composition and cigarette for improving tobacco adhesion odor |
Country Status (6)
| Country | Link |
|---|---|
| JP (1) | JP5775962B2 (en) |
| KR (2) | KR101795995B1 (en) |
| CN (1) | CN104160007B (en) |
| RU (1) | RU2580682C1 (en) |
| UA (1) | UA108973C2 (en) |
| WO (1) | WO2013132618A1 (en) |
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| CN104498192A (en) * | 2014-12-15 | 2015-04-08 | 云南中烟工业有限责任公司 | Preparation method and application of florists chrysanthemum extract |
| CN104498185A (en) * | 2014-12-02 | 2015-04-08 | 云南中烟工业有限责任公司 | Carambola extract as well as preparation method and application of carambola extract in cigarettes |
| CN107831228A (en) * | 2017-10-26 | 2018-03-23 | 福建中烟工业有限责任公司 | The method of citronellal, kit and its application in a kind of determination sample |
| CN109414069A (en) * | 2016-07-01 | 2019-03-01 | 日本烟草产业株式会社 | Fragrance extractor |
| CN110144261A (en) * | 2019-04-11 | 2019-08-20 | 杨伟祖 | A kind of cigarette lemon-grass essence |
| CN110484366A (en) * | 2019-07-09 | 2019-11-22 | 河南中烟工业有限责任公司 | A kind of quick-fried pearl fennel essence and preparation method thereof, quick-fried pearl and cigarette |
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| JP6888974B2 (en) * | 2016-01-27 | 2021-06-18 | 学校法人近畿大学 | Compounds with CYP2A13 inhibitory activity and CYP2A13 inhibitors |
| CN106579533A (en) * | 2016-12-15 | 2017-04-26 | 钦州市钦南区科学技术情报研究所 | Essence for tobaccos and preparation method thereof |
| GB201718033D0 (en) * | 2017-11-01 | 2017-12-13 | Nicoventures Holdings Ltd | Flavoured vaporisable formulation |
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| CN104498192A (en) * | 2014-12-15 | 2015-04-08 | 云南中烟工业有限责任公司 | Preparation method and application of florists chrysanthemum extract |
| CN109414069A (en) * | 2016-07-01 | 2019-03-01 | 日本烟草产业株式会社 | Fragrance extractor |
| CN109414069B (en) * | 2016-07-01 | 2022-01-04 | 日本烟草产业株式会社 | Fragrance suction device |
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| CN110144261A (en) * | 2019-04-11 | 2019-08-20 | 杨伟祖 | A kind of cigarette lemon-grass essence |
| CN110484366A (en) * | 2019-07-09 | 2019-11-22 | 河南中烟工业有限责任公司 | A kind of quick-fried pearl fennel essence and preparation method thereof, quick-fried pearl and cigarette |
| CN116726685A (en) * | 2023-06-06 | 2023-09-12 | 四川中烟工业有限责任公司 | Tobacco deodorant |
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Also Published As
| Publication number | Publication date |
|---|---|
| CN104160007B (en) | 2017-10-13 |
| JP5775962B2 (en) | 2015-09-09 |
| KR20170012599A (en) | 2017-02-02 |
| UA108973C2 (en) | 2015-06-25 |
| KR20140126350A (en) | 2014-10-30 |
| HK1199282A1 (en) | 2015-06-26 |
| KR101795995B1 (en) | 2017-11-08 |
| JPWO2013132618A1 (en) | 2015-07-30 |
| RU2580682C1 (en) | 2016-04-10 |
| WO2013132618A1 (en) | 2013-09-12 |
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