CN104106565A - Novel water-emulsion type solvent capable of replacing xylene - Google Patents
Novel water-emulsion type solvent capable of replacing xylene Download PDFInfo
- Publication number
- CN104106565A CN104106565A CN201310494579.7A CN201310494579A CN104106565A CN 104106565 A CN104106565 A CN 104106565A CN 201310494579 A CN201310494579 A CN 201310494579A CN 104106565 A CN104106565 A CN 104106565A
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- CN
- China
- Prior art keywords
- solvent
- emulsion type
- type solvent
- solvent capable
- novel water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 title claims abstract description 21
- 239000002904 solvent Substances 0.000 title claims abstract description 18
- 239000000839 emulsion Substances 0.000 title abstract description 9
- 239000008096 xylene Substances 0.000 title abstract 3
- 239000003814 drug Substances 0.000 claims abstract description 14
- 239000005660 Abamectin Substances 0.000 claims abstract description 7
- 150000003738 xylenes Chemical class 0.000 claims description 10
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 241000723353 Chrysanthemum Species 0.000 claims description 7
- 235000007516 Chrysanthemum Nutrition 0.000 claims description 7
- 229910019142 PO4 Inorganic materials 0.000 claims description 7
- 239000003905 agrochemical Substances 0.000 claims description 7
- 150000002148 esters Chemical class 0.000 claims description 7
- 235000021317 phosphate Nutrition 0.000 claims description 7
- 150000003013 phosphoric acid derivatives Chemical class 0.000 claims description 7
- 239000004094 surface-active agent Substances 0.000 claims description 4
- RRZXIRBKKLTSOM-XPNPUAGNSA-N avermectin B1a Chemical compound C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 RRZXIRBKKLTSOM-XPNPUAGNSA-N 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- OSNIIMCBVLBNGS-UHFFFAOYSA-N 1-(1,3-benzodioxol-5-yl)-2-(dimethylamino)propan-1-one Chemical class CN(C)C(C)C(=O)C1=CC=C2OCOC2=C1 OSNIIMCBVLBNGS-UHFFFAOYSA-N 0.000 claims 1
- 229940079593 drug Drugs 0.000 abstract description 3
- 230000001804 emulsifying effect Effects 0.000 abstract description 2
- VEMKTZHHVJILDY-UXHICEINSA-N bioresmethrin Chemical compound CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)OCC1=COC(CC=2C=CC=CC=2)=C1 VEMKTZHHVJILDY-UXHICEINSA-N 0.000 abstract 1
- 239000000575 pesticide Substances 0.000 abstract 1
- 241000251468 Actinopterygii Species 0.000 description 3
- 239000005946 Cypermethrin Substances 0.000 description 3
- 238000009360 aquaculture Methods 0.000 description 3
- KAATUXNTWXVJKI-UHFFFAOYSA-N cypermethrin Chemical compound CC1(C)C(C=C(Cl)Cl)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 KAATUXNTWXVJKI-UHFFFAOYSA-N 0.000 description 3
- 229960005424 cypermethrin Drugs 0.000 description 3
- 244000144974 aquaculture Species 0.000 description 2
- 230000000711 cancerogenic effect Effects 0.000 description 2
- 231100000357 carcinogen Toxicity 0.000 description 2
- 239000003183 carcinogenic agent Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 206010007269 Carcinogenicity Diseases 0.000 description 1
- 235000016936 Dendrocalamus strictus Nutrition 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 208000002193 Pain Diseases 0.000 description 1
- 230000007670 carcinogenicity Effects 0.000 description 1
- 231100000260 carcinogenicity Toxicity 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 230000036407 pain Effects 0.000 description 1
- 235000015096 spirit Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention provides a novel water-emulsion type solvent capable of replacing xylene, belonging to the field of ecology and agriculture. The objective of the invention is to provide the novel water-emulsion type solvent capable of replacing xylene and dissolving various kinds of pesticides and fishery drugs like pyrethroids, organophosphates and avermectins. According to results of testing at high and low temperatures ranging from -5 DEG C to 50 DEG C, the water-emulsion type solvent shows stable properties, good solubility and a good emulsifying effect.
Description
Technical field
New type water milkiness solvent that can substituted dimethyl benzene of the present invention, belongs to ecology and agriculture field.
Background technology
Files specify Non-environmental Pollution Aquiculture has become minimum standard in this regulation, thereby Water quality standard is supervised by emphasis to make No. 31 " aquaculture quality safety management regulation " according to the Ministry of Agriculture's in August, 2003 distribution unit.Issued fish quality propelling plan simultaneously in August, 2003, the main spirits of this file is: China's culture fishery must be within the shorter 3-4 year, strive for by formulating aquaculture standard, carry out standardized management, improve aquatic product quality detection system, main production area carries out the monitoring regime, carries out Attestation of Aquatic Product Quality system, to can improve the international competitiveness of China's aquatic products comprehensively.In order to make China's aquatic products further reach green, safe, nuisanceless, free of contamination standard, national departments concerned has proposed the solvent that bans use of dimethylbenzene as fishing medicine and agricultural chemicals.Because dimethylbenzene is a kind of carcinogen, be prohibited from using for a long time at cosmetic industry and daily chemical product industry., there is like this solvent of quite large harm, suitable large in the usage amount of cultivation industry.Just take one bottle of common fish insect killing emulsion, 100mL missible oil, has the former medicine of 5%-20%, 10% surfactant, and remaining is all dimethylbenzene, its total amount accounts for the 75%-85% of drug use amount.If things go on like this, the carcinogenicity of dimethylbenzene will have influence on fish.And the mankind have eaten this aquatic products with carcinogen for a long time, healthy will greatly impact.Healthy for the mankind, develops a kind of solvent that can substituted dimethyl benzene and has become a fact too impatient to wait.
Xiantao City Song Tian bio tech ltd associating Hubei Medicine and pharmacy college national innovation funds (numbering: 11C26214202679) and Shiyan City's tackling of key scientific and technical problems major project (numbering: ZD2011029) under the fund project subsidy such as, be devoted to develop can substituted dimethyl benzene new type water milkiness solvent.
In order to solve this difficult problem, we,, through the research of pains, constantly test and put into practice, and have finally succeeded in developing a kind of aqueous emulsion solvent that can substituted dimethyl benzene, through-5
oc-50
obright its stable in properties of high low temperature test chart of C, dissolve and emulsifying effectiveness good, be a kind of good solvent that can substituted dimethyl benzene, the multiple chrysanthemum ester of solubilized class, organic phosphates, Avermectins etc. various agricultural chemicals and fishing medicine.
Summary of the invention
The object of this invention is to provide a kind of new type water milkiness solvent that can substituted dimethyl benzene, the multiple chrysanthemum ester of solubilized class, organic phosphates, Avermectins etc. various agricultural chemicals and fishing medicine.
Technical scheme of the present invention is as follows:
New type water milkiness solvent that can substituted dimethyl benzene, the multiple chrysanthemum ester of solubilized class, organic phosphates, Avermectins etc. various agricultural chemicals and fishing medicine.It is characterized in that its various compositions (percentage by weight) proportioning: DMF 5% to 30%; Methyl alcohol 60-70%, surfactant 5-10%.The chrysanthemum ester class of such solvent-soluble solution 10%-20%, organic phosphates, Avermectin etc. various agricultural chemicals and fishing medicine.Also can be according to the consumption of suitable its formula of adjustment of the height of former medicine content.
Embodiment
Example 1. is prepared the aqueous emulsion solvent of solubilized 5%-10% chrysanthemum ester class, the former medicine of organic phosphates
First DMF 2000mL and 7000mL methyl alcohol are mixed, then add surfactant 1000mL, stir.
Example 2. is prepared 10% aqueous emulsion of cypermethrin
Get above-mentioned joined solvent 1000mL, add 10g cypermethrin, stir and obtain 10% aqueous emulsion of cypermethrin.
Claims (2)
1. a new type water milkiness solvent that can substituted dimethyl benzene, one or more chrysanthemum ester classes of solubilized, organic phosphates, Avermectins etc. various agricultural chemicals and fishing medicine.
2. a kind of new type water milkiness solvent that can substituted dimethyl benzene of claim 1, is characterized in that its various compositions (percentage by weight) proportioning: DMF 5% to 30%; Methyl alcohol 60-70%, surfactant 5-10%; The chrysanthemum ester class of such solvent-soluble solution 10%-20%, organic phosphates, Avermectin etc. various agricultural chemicals and fishing medicine, can be according to the consumption of suitable its formula of adjustment of the height of former medicine content.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310494579.7A CN104106565A (en) | 2013-10-21 | 2013-10-21 | Novel water-emulsion type solvent capable of replacing xylene |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310494579.7A CN104106565A (en) | 2013-10-21 | 2013-10-21 | Novel water-emulsion type solvent capable of replacing xylene |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104106565A true CN104106565A (en) | 2014-10-22 |
Family
ID=51703710
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310494579.7A Pending CN104106565A (en) | 2013-10-21 | 2013-10-21 | Novel water-emulsion type solvent capable of replacing xylene |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104106565A (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1150888A (en) * | 1995-11-13 | 1997-06-04 | 徐建军 | Agricultural chemicals synergist |
| CN102283195A (en) * | 2011-09-13 | 2011-12-21 | 广西田园生化股份有限公司 | Pesticide adjuvant and preparation method thereof |
| CN102428913A (en) * | 2011-11-11 | 2012-05-02 | 山东荣邦化工有限公司 | Microemulsion pesticide and production process thereof |
| CN102885034A (en) * | 2012-09-28 | 2013-01-23 | 王龙华 | Microemulsion pesticide and preparation method thereof |
| WO2013126947A1 (en) * | 2012-02-27 | 2013-09-06 | Huntsman Corporation Australia Pty Limited | Emulsifiable concentrate formulation |
-
2013
- 2013-10-21 CN CN201310494579.7A patent/CN104106565A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1150888A (en) * | 1995-11-13 | 1997-06-04 | 徐建军 | Agricultural chemicals synergist |
| CN102283195A (en) * | 2011-09-13 | 2011-12-21 | 广西田园生化股份有限公司 | Pesticide adjuvant and preparation method thereof |
| CN102428913A (en) * | 2011-11-11 | 2012-05-02 | 山东荣邦化工有限公司 | Microemulsion pesticide and production process thereof |
| WO2013126947A1 (en) * | 2012-02-27 | 2013-09-06 | Huntsman Corporation Australia Pty Limited | Emulsifiable concentrate formulation |
| CN102885034A (en) * | 2012-09-28 | 2013-01-23 | 王龙华 | Microemulsion pesticide and preparation method thereof |
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|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20141022 |