CN104076121A - Preparation method of gel-type CO2 indicator - Google Patents
Preparation method of gel-type CO2 indicator Download PDFInfo
- Publication number
- CN104076121A CN104076121A CN201310110481.7A CN201310110481A CN104076121A CN 104076121 A CN104076121 A CN 104076121A CN 201310110481 A CN201310110481 A CN 201310110481A CN 104076121 A CN104076121 A CN 104076121A
- Authority
- CN
- China
- Prior art keywords
- solution
- indicator
- ethanolic solution
- methyl red
- ethanol solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- CEQFOVLGLXCDCX-WUKNDPDISA-N methyl red Chemical compound C1=CC(N(C)C)=CC=C1\N=N\C1=CC=CC=C1C(O)=O CEQFOVLGLXCDCX-WUKNDPDISA-N 0.000 claims abstract description 18
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229920000609 methyl cellulose Polymers 0.000 claims abstract description 7
- 239000001923 methylcellulose Substances 0.000 claims abstract description 7
- 238000010438 heat treatment Methods 0.000 claims abstract 2
- NUHCTOLBWMJMLX-UHFFFAOYSA-N bromothymol blue Chemical compound BrC1=C(O)C(C(C)C)=CC(C2(C3=CC=CC=C3S(=O)(=O)O2)C=2C(=C(Br)C(O)=C(C(C)C)C=2)C)=C1C NUHCTOLBWMJMLX-UHFFFAOYSA-N 0.000 claims description 15
- 229920003091 Methocel™ Polymers 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 5
- 230000007423 decrease Effects 0.000 claims description 5
- 235000011187 glycerol Nutrition 0.000 claims description 5
- 238000003760 magnetic stirring Methods 0.000 claims description 5
- 238000012545 processing Methods 0.000 claims description 2
- 239000003643 water by type Substances 0.000 claims 1
- 239000000203 mixture Substances 0.000 abstract description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract 14
- 239000000243 solution Substances 0.000 abstract 13
- ZPLCXHWYPWVJDL-UHFFFAOYSA-N 4-[(4-hydroxyphenyl)methyl]-1,3-oxazolidin-2-one Chemical compound C1=CC(O)=CC=C1CC1NC(=O)OC1 ZPLCXHWYPWVJDL-UHFFFAOYSA-N 0.000 abstract 3
- 238000001514 detection method Methods 0.000 abstract 1
- 238000007865 diluting Methods 0.000 abstract 1
- 239000011259 mixed solution Substances 0.000 abstract 1
- 238000002156 mixing Methods 0.000 abstract 1
- 238000003756 stirring Methods 0.000 abstract 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 238000004320 controlled atmosphere Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 235000012055 fruits and vegetables Nutrition 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Landscapes
- Investigating Or Analyzing Non-Biological Materials By The Use Of Chemical Means (AREA)
Abstract
The invention relates to a preparation method of a gel-type CO2 indicator. The preparation method comprises the following steps: preparing a 10% to 90% ethanol solution; dissolving 0.07g to 0.12g of methyl red into 100ml of ethanol solution to obtain a methyl red ethanol solution; dissolving 0.08g to 0.15g of bromothymol blue into 100ml of ethanol solution to obtain a bromothymol blue ethanol solution; mixing 10ml to 55ml of methyl red ethanol solution with 15ml to 50ml of bromothymol blue ethanol solution, and diluting the mixture for 10 times to obtain an indicator solution; and adding glycerinum into 100ml of prepared indicator solution, heating the mixed solution in a water bath at the constant temperature of 55 to 80 DEG C, adding 1.2g to 2.2g of methylcellulose when the solution is at the target temperature, and continuously stirring the solution at a high speed to obtain a uniform methylcellulose solution. While the temperature is lowered, the viscosity of the solution is increased. When a rotor is stationary, the finished product is obtained. The indicator is suitable for rapid detection on CO2 with the content of 0 to 100 percent in an environment.
Description
Technical field
The present invention relates to a kind of indicator product, be specifically related to a kind of gel-type CO
2the preparation method of indicator.
Background technology
When the storage of fruits and vegetables and controlled atmosphere, need to be to CO
2carrying out Real-Time Monitoring, is mainly at present to adopt instrument to the CO in environment
2enter to detect, but instrument cost is too high, and the gas sensing original paper usability of instrument impermanent, needing periodic replacement, this has all improved storage cost, but it does not have universality.Develop a kind of fast, convenience, low price, indicative function be obvious, the CO with broad applicability
2responsive type indicating label is very necessary.
Summary of the invention
The object of the invention is to overcome the deficiency that above-mentioned prior art exists, a kind of gel-type CO is provided
2the preparation method of indicator.
Object of the present invention realizes by following processing step:
Compound concentration is 10%～90% ethanolic solution;
Take 0.07～0.12g methyl red and be dissolved in 100mL ethanolic solution, obtain methyl red ethanolic solution standby;
Take 0.08～0.15g bromthymol blue and be dissolved in 100mL ethanolic solution, obtain bromthymol blue ethanolic solution standby;
Measure 10～55mL methyl red ethanolic solution and mix with 15～50mL bromthymol blue ethanolic solution, dilute 10 times, obtain indicator solution;
Get indicator solution that 100mL makes in beaker, add 3～8mL glycerine, in 55～80 ℃ of thermostat water baths, heat, while arriving rated temperature, drop into 1.2～2.2g methylcellulose, take out beaker and rapidly under magnetic stirring apparatus constantly high-speed stirred make it form even methocel solution.With temperature, slowly decline, solution viscosity increases.Rotor resistance is increasing, when rotor is motionless, takes out, and obtains finished product.
The beneficial effect that the present invention has is:
The present invention can utilize the CO in change color display environment
2content, by CO invisible in pack environment
2gas content turns to visual color index, facilitates user to understand gas content and changes, and has both saved instrument testing cost, has avoided again blindly operation.
Accompanying drawing explanation
Fig. 1 is this gel-type CO
2the standard color comparison card of indicator, indication be CO in environment
2content is the color in 0,1.8%, 4.1%, 8.3%, 12.7%, 26.0%, 50.5%, 84.6% time respectively.
Embodiment
Below in conjunction with specific embodiment, the present invention is described in detail.Following examples will contribute to those skilled in the art further to understand the present invention, but not limit in any form the present invention.It should be pointed out that to those skilled in the art, not departing under the prerequisite of the present invention's conception, can also make some distortion and improvement.These all belong to protection scope of the present invention.
Embodiment 1
Compound concentration is 10% ethanolic solution;
Take 0.07 methyl red and be dissolved in 100mL ethanolic solution, obtain methyl red ethanolic solution standby;
Take 0.15g bromthymol blue and be dissolved in 100mL ethanolic solution, obtain bromthymol blue ethanolic solution standby; Measure 10mL methyl red ethanolic solution and mix with 50mL bromthymol blue ethanolic solution, dilute 10 times, obtain indicator solution;
Get indicator solution that 100mL makes in beaker, add 3mL glycerine, in 55 ℃ of thermostat water baths, heat, while arriving rated temperature, drop into 2.2g methylcellulose, take out beaker and rapidly under magnetic stirring apparatus constantly high-speed stirred make it form even methocel solution.With temperature, slowly decline, solution viscosity increases.Rotor resistance is increasing, when rotor is motionless, takes out, and obtains finished product.
This indicator is applicable to CO in environment
2content is in 0～100% fast detecting.
Embodiment 2
Compound concentration is 90% ethanolic solution;
Take 0.12g methyl red and be dissolved in 100mL ethanolic solution, obtain methyl red ethanolic solution standby;
Take 0.08g bromthymol blue and be dissolved in 100mL ethanolic solution, obtain bromthymol blue ethanolic solution standby;
Measure 55mL methyl red ethanolic solution and mix with 15mL bromthymol blue ethanolic solution, dilute 10 times, obtain indicator solution;
Get indicator solution that 100mL makes in beaker, add 8mL glycerine, in 80 ℃ of thermostat water baths, heat, while arriving rated temperature, drop into 1.2g methylcellulose, take out beaker and rapidly under magnetic stirring apparatus constantly high-speed stirred make it form even methocel solution.With temperature, slowly decline, solution viscosity increases.Rotor resistance is increasing, when rotor is motionless, takes out, and obtains finished product.
Embodiment 3
Compound concentration is 50% ethanolic solution;
Take 0.09g methyl red and be dissolved in 100mL ethanolic solution, obtain methyl red ethanolic solution standby;
Take 0.12g bromthymol blue and be dissolved in 100mL ethanolic solution, obtain bromthymol blue ethanolic solution standby;
Measure 25mL methyl red ethanolic solution and mix with 35mL bromthymol blue ethanolic solution, dilute 10 times, obtain indicator solution;
Get indicator solution that 100mL makes in beaker, add 5mL glycerine, in 80 ℃ of thermostat water baths, heat, while arriving rated temperature, drop into 1.5g methylcellulose, take out beaker and rapidly under magnetic stirring apparatus constantly high-speed stirred make it form even methocel solution.With temperature, slowly decline, solution viscosity increases.Rotor resistance is increasing, when rotor is motionless, takes out, and obtains finished product.
This indicator is applicable to CO in environment
2content is in 0～100% fast detecting.
Above specific embodiments of the invention are described.It will be appreciated that, the present invention is not limited to above-mentioned specific implementations, and those skilled in the art can make various distortion or modification within the scope of the claims, and this does not affect flesh and blood of the present invention.
Claims (1)
1. a gel-type CO
2the preparation method of indicator, is characterized in that, described preparation method comprises following processing step:
(1) ethanolic solution that compound concentration is 10%～90%;
(2) take 0.07～0.12g methyl red and be dissolved in 100mL ethanolic solution, obtain methyl red ethanolic solution standby;
(3) take 0.08～0.15g bromthymol blue and be dissolved in 100mL ethanolic solution, obtain bromthymol blue ethanolic solution standby;
(4) measure 10～55mL methyl red ethanolic solution and mix with 15～50mL bromthymol blue ethanolic solution, dilute 10 times, obtain indicator solution;
(5) get the indicator solution that 100mL step (4) makes, add 3～8mL glycerine, in 55～80 ℃ of waters bath with thermostatic control heating, while arriving rated temperature, drop into 1.2～2.2g methylcellulose, take out and rapidly under magnetic stirring apparatus constantly high-speed stirred make it form even methocel solution.With temperature, slowly decline, solution viscosity increases.Rotor resistance is increasing, when rotor is motionless, takes out, and obtains finished product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310110481.7A CN104076121A (en) | 2013-03-30 | 2013-03-30 | Preparation method of gel-type CO2 indicator |
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|---|---|---|---|
| CN201310110481.7A CN104076121A (en) | 2013-03-30 | 2013-03-30 | Preparation method of gel-type CO2 indicator |
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| CN104076121A true CN104076121A (en) | 2014-10-01 |
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| CN201310110481.7A Pending CN104076121A (en) | 2013-03-30 | 2013-03-30 | Preparation method of gel-type CO2 indicator |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105004715A (en) * | 2015-06-19 | 2015-10-28 | 天津出入境检验检疫局工业产品安全技术中心 | High-sensitivity CO2 identification card |
| CN110412023A (en) * | 2018-04-27 | 2019-11-05 | 大连理工大学 | A kit for rapidly evaluating the maturity of compost and its application method |
| CN110412239A (en) * | 2018-04-27 | 2019-11-05 | 大连理工大学 | A gel test paper for rapid detection of microbial CO2 respiration rate and its application method |
| CN115078342A (en) * | 2021-03-11 | 2022-09-20 | 南京理工大学 | Gas-sensitive film for monitoring chemical aging degree of composite solid propellant and preparation method thereof |
| US12044665B2 (en) | 2019-01-15 | 2024-07-23 | Precision Planting Llc | Soil analysis compositions and methods |
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2013
- 2013-03-30 CN CN201310110481.7A patent/CN104076121A/en active Pending
Patent Citations (7)
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| US6149952A (en) * | 1998-05-15 | 2000-11-21 | Herbert W. Stoltenberg | Method for determining deleterious bacterial growth in packaged food utilizing hydrophilic polymers |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105004715A (en) * | 2015-06-19 | 2015-10-28 | 天津出入境检验检疫局工业产品安全技术中心 | High-sensitivity CO2 identification card |
| CN110412023A (en) * | 2018-04-27 | 2019-11-05 | 大连理工大学 | A kit for rapidly evaluating the maturity of compost and its application method |
| CN110412239A (en) * | 2018-04-27 | 2019-11-05 | 大连理工大学 | A gel test paper for rapid detection of microbial CO2 respiration rate and its application method |
| CN110412239B (en) * | 2018-04-27 | 2021-08-10 | 大连理工大学 | Rapid detection of microbial CO2Gel test paper for respiratory rate and use method thereof |
| US12044665B2 (en) | 2019-01-15 | 2024-07-23 | Precision Planting Llc | Soil analysis compositions and methods |
| CN115078342A (en) * | 2021-03-11 | 2022-09-20 | 南京理工大学 | Gas-sensitive film for monitoring chemical aging degree of composite solid propellant and preparation method thereof |
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| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
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Application publication date: 20141001 |