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CN104046812A - Making method of highly ductile copper alloy wire for automobiles - Google Patents

Making method of highly ductile copper alloy wire for automobiles Download PDF

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Publication number
CN104046812A
CN104046812A CN201410245750.5A CN201410245750A CN104046812A CN 104046812 A CN104046812 A CN 104046812A CN 201410245750 A CN201410245750 A CN 201410245750A CN 104046812 A CN104046812 A CN 104046812A
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China
Prior art keywords
copper alloy
speed
insulation
warming
alloy wire
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CN201410245750.5A
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Chinese (zh)
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CN104046812B (en
Inventor
徐泽军
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Anhui Xinchen Automobile Manufacturing Co Ltd
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Ruizhan Tongling Technologies Co Ltd
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Abstract

The invention discloses a making method of a highly ductile copper alloy wire for automobiles. The highly ductile copper alloy wire comprises 0.4-0.6wt% of Fe, 0.2-0.3wt% of Zn, 0.3-0.5wt% of Mg, 0.15-0.25wt% of Mn, 0.08-0.14wt% of Bi, 0.04-0.06wt% of Hf, 0.02-0.04wt% of In, 0.03-0.06wt% of La, 0.02-0.03wt% of Yb, 0.005-0.015wt% of P, and the balance Cu and inevitable impurities. The addition of a tiny amount of Hf, In, La, Yb and the like reinforces and purifies Cu, so the conductivity and the mechanical strength of copper alloy are guaranteed, and the toughness and plasticity of a product obtained in the invention are improved, thereby the elongation of the copper alloy wire is not lower than 40%.

Description

The preparation method of high expanded copper alloy wire for a kind of automobile
Technical field
The present invention relates to the preparation method of high expanded copper alloy wire for a kind of automobile, belong to copper alloy manufacturing technology field.
Background technology
?copper alloy has the good electricity ﹑ that leads and leads hot property ﹑ ductility and solidity to corrosion, so electric motor of automobile electrical equipment winding coil, electric wire and cable conductor material etc. are made in widespread use.Can not be controlled to oxygen level in traditional production of copper alloy wire process, and in copper, alloying element ratio is unreasonable, and impurity content is too high, and this has a great impact the electroconductibility of copper alloy wire, ductility and intensity.
Summary of the invention
The object of the invention is to overcome the deficiencies in the prior art, the preparation method of a kind of automobile with high expanded copper alloy wire is provided.
The technical solution used in the present invention is as follows:
A preparation method for high expanded copper alloy wire for automobile, comprises the following steps:
(1) copper billet added in smelting furnace and be warming up to fusing at 1140-1180 ℃, being then warming up to 1200-1250 ℃, adding associated alloys food ingredient, stir, after whole fusings, temperature adjustment adds refining agent refining 30-35min to 1160-1220 ℃, after skimming, is incubated 15-25min; Again copper alloy liquid is carried out to stokehold chemistry real-time analysis, the weight percent of each elemental composition in copper alloy liquid is met the following requirements:
Fe 0.4-0.6, Zn 0.2-0.3, Mg 0.3-0.5, Mn 0.15-0.25, Bi 0.08-0.14, Hf 0.04-0.06, In 0.02-0.04, La 0.03-0.06, Yb 0.02-0.03, P 0.005-0.015, surplus is copper and inevitable impurity; After analysis, according to the weight percent of each component in formula, adjust feed supplement;
(2) by copper billet, feed intake the 0.2-0.3% of weight to dropping into the fusing of Sn-Ag-Cu-Ni-Ge alloy block in stove, in alloy block, the mass ratio of Sn, Ag, Cu, Ni, Ge element is 1-2:3-5:0.5-1:0.2-0.4:0.1-0.2, stirs 25-35min; Then temperature adjustment is to 1180-1240 ℃, then adds refining agent refining 20-25min, insulation 15-20min after slagging-off;
(3) continuous casting and rolling becomes copper alloy bar, drawing wire machine to be drawn into copper alloy single line;
(4) copper alloy wire is sent into and in heat treatment furnace, carried out ageing treatment: first with 60-80 ℃/h speed, be warming up to 150-180 ℃, insulation 3-6h, with 70-90 ℃/h speed, be warming up to 360-390 ℃ again, insulation 2-3h, with 50-60 ℃/h speed, be cooled to 220-240 ℃ again, insulation 3-4h, then with 80-100 ℃/h speed, be warming up to 410-430 ℃, insulation 1-2h; Then with 70-80 ℃/h speed, be cooled to 240-260 ℃, insulation 4-5h, then puts into 0-3 ℃ of frozen water and processes 3-5h, and take out and be warming up to 160-190 ℃ with 50-60 ℃/h speed, insulation 2-4h, air cooling is to room temperature.
The preparation method of described refining agent is as follows: a, get the raw material of following weight part: sepiolite 3-5, fluorite 1-2, montmorillonite 2-3, sodium carbonate 3-4, Sodium Silicofluoride 4-6, vanadium diboride 2-2.5, lapis amiridis 1-2, trees ashes 2-3, nano-silicon nitride 1.5-2.5, silane resin acceptor kh-550 1-2; B, sepiolite, fluorite, montmorillonite are mixed to send at 510-540 ℃ and calcine 3-5h, take out and pulverized 200-300 mesh sieve; Add water making beating and make the slurries of 40-50%, then adding concentration is the hydrochloric acid soln adjusting slurries PH=4.5-5.5 of 10-15%, 2000-3000rpm speed lapping 20-30min, it is neutral that the sodium hydroxide solution that is 15-20% by concentration regulates lapping liquid pH value, and spraying is dried to obtain powder, then adds all the other raw materials, 1000-1500rpm high-speed stirring 5-10min, dry, pulverize, cross 300-400 mesh sieve.
Beneficial effect of the present invention:
The present invention adopts elements such as adding micro-Hf, In, La, Yb to strengthen and cleaning action copper, when guaranteeing copper alloy electroconductibility and physical strength, improve toughness and the plasticity of product, tensile strength >=420MPa, electric conductivity >=90%IACS, unit elongation >=40%.
embodiment
A preparation method for high expanded copper alloy wire for automobile, comprises the following steps:
(1) copper billet added in smelting furnace and be warming up to fusing at 1160 ℃, being then warming up to 1220 ℃, adding associated alloys food ingredient, stirring, after all melting, temperature adjustment to 1180 ℃ adds refining agent refining 30min, after skimming, is incubated 20min; Again copper alloy liquid is carried out to stokehold chemistry real-time analysis, the weight percent of each elemental composition in copper alloy liquid is met the following requirements: Fe 0.4-0.6, Zn 0.2-0.3, Mg 0.3-0.5, Mn 0.15-0.25, Bi 0.08-0.14, Hf 0.04-0.06, In 0.02-0.04, La 0.03-0.06, Yb 0.02-0.03, P 0.005-0.015, surplus is copper and inevitable impurity; After analysis, according to the weight percent of each component in formula, adjust feed supplement;
(2) by copper billet feed intake weight 0.2% to dropping into the fusing of Sn-Ag-Cu-Ni-Ge alloy block in stove, in alloy block, the mass ratio of Sn, Ag, Cu, Ni, Ge element is 1:3.5:0.8:0.3:0.1, stirs 30min; Then temperature adjustment to 1220 ℃, then add refining agent refining 20min, insulation 15min after slagging-off;
(3) continuous casting and rolling becomes copper alloy bar, drawing wire machine to be drawn into copper alloy single line;
(4) copper alloy wire is sent into and in heat treatment furnace, carried out ageing treatment: first with 70 ℃/h speed, be warming up to 160 ℃, insulation 4h, then be warming up to 380 ℃ with 80 ℃/h speed, insulation 2h, then with 60 ℃/h speed, be cooled to 240 ℃, insulation 3h, with 100 ℃/h speed, be warming up to 420 ℃ again, insulation 1h; Then with 80 ℃/h speed, be cooled to 250 ℃, insulation 4h, then puts into 1 ℃ of frozen water and processes 4h, and take out and be warming up to 170 ℃ with 60 ℃/h speed, insulation 3h, air cooling is to room temperature.
The preparation method of described refining agent is as follows: a, get the raw material of following weight (kg): sepiolite 4, fluorite 1.5, montmorillonite 2, sodium carbonate 3, Sodium Silicofluoride 5, vanadium diboride 2, lapis amiridis 1.5, trees ashes 2, nano-silicon nitride 2, silane resin acceptor kh-550 2; B, sepiolite, fluorite, montmorillonite are mixed to send at 540 ℃ and calcine 3h, take out and pulverized 200 mesh sieves; Add water making beating and make 4% slurries, then add concentration and be 10% hydrochloric acid soln and regulate slurries PH=5.5,2000rpm speed lapping 25min, it is neutral that the sodium hydroxide solution that is 15% by concentration regulates lapping liquid pH value, and spraying is dried to obtain powder, then adds all the other raw materials, 1000rpm high-speed stirring 8min, dry, pulverize, cross 300 mesh sieves.
The copper alloy wire making is through check, and its salient features is: tensile strength 472Mpa, yield strength is 386Mpa, unit elongation 45%, electric conductivity IACS(20 ℃) 91%.

Claims (2)

1. a preparation method for high expanded copper alloy wire for automobile, is characterized in that comprising the following steps:
(1) copper billet added in smelting furnace and be warming up to fusing at 1140-1180 ℃, being then warming up to 1200-1250 ℃, adding associated alloys food ingredient, stir, after whole fusings, temperature adjustment adds refining agent refining 30-35min to 1160-1220 ℃, after skimming, is incubated 15-25min; Again copper alloy liquid is carried out to stokehold chemistry real-time analysis, the weight percent of each elemental composition in copper alloy liquid is met the following requirements:
Fe 0.4-0.6, Zn 0.2-0.3, Mg 0.3-0.5, Mn 0.15-0.25, Bi 0.08-0.14, Hf 0.04-0.06, In 0.02-0.04, La 0.03-0.06, Yb 0.02-0.03, P 0.005-0.015, surplus is copper and inevitable impurity; After analysis, according to the weight percent of each component in formula, adjust feed supplement;
(2) by copper billet, feed intake the 0.2-0.3% of weight to dropping into the fusing of Sn-Ag-Cu-Ni-Ge alloy block in stove, in alloy block, the mass ratio of Sn, Ag, Cu, Ni, Ge element is 1-2:3-5:0.5-1:0.2-0.4:0.1-0.2, stirs 25-35min; Then temperature adjustment is to 1180-1240 ℃, then adds refining agent refining 20-25min, insulation 15-20min after slagging-off;
(3) continuous casting and rolling becomes copper alloy bar, drawing wire machine to be drawn into copper alloy single line;
Copper alloy wire is sent into and in heat treatment furnace, carried out ageing treatment: first with 60-80 ℃/h speed, be warming up to 150-180 ℃, insulation 3-6h, with 70-90 ℃/h speed, be warming up to 360-390 ℃ again, insulation 2-3h, with 50-60 ℃/h speed, be cooled to 220-240 ℃ again, insulation 3-4h, then with 80-100 ℃/h speed, be warming up to 410-430 ℃, insulation 1-2h; Then with 70-80 ℃/h speed, be cooled to 240-260 ℃, insulation 4-5h, then puts into 0-3 ℃ of frozen water and processes 3-5h, and take out and be warming up to 160-190 ℃ with 50-60 ℃/h speed, insulation 2-4h, air cooling is to room temperature.
2. the preparation method of high expanded copper alloy wire for a kind of automobile according to claim 1, it is characterized in that, the preparation method of described refining agent is as follows: a, get the raw material of following weight part: sepiolite 3-5, fluorite 1-2, montmorillonite 2-3, sodium carbonate 3-4, Sodium Silicofluoride 4-6, vanadium diboride 2-2.5, lapis amiridis 1-2, trees ashes 2-3, nano-silicon nitride 1.5-2.5, silane resin acceptor kh-550 1-2; B, sepiolite, fluorite, montmorillonite are mixed to send at 510-540 ℃ and calcine 3-5h, take out and pulverized 200-300 mesh sieve; Add water making beating and make the slurries of 40-50%, then adding concentration is the hydrochloric acid soln adjusting slurries PH=4.5-5.5 of 10-15%, 2000-3000rpm speed lapping 20-30min, it is neutral that the sodium hydroxide solution that is 15-20% by concentration regulates lapping liquid pH value, and spraying is dried to obtain powder, then adds all the other raw materials, 1000-1500rpm high-speed stirring 5-10min, dry, pulverize, cross 300-400 mesh sieve.
CN201410245750.5A 2014-06-05 2014-06-05 A kind of automobile preparation method of high expanded copper alloy wire Expired - Fee Related CN104046812B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN120280222A (en) * 2025-06-09 2025-07-08 安徽鑫海高导新材料有限公司 Preparation process of ultrafine copper conductor for new energy automobile

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1681360A1 (en) * 2003-09-19 2006-07-19 Sumitomo Metal Industries Limited Copper alloy and method for production thereof
CN1930314A (en) * 2004-03-12 2007-03-14 住友金属工业株式会社 Copper alloy and its manufacturing method
US20070148032A1 (en) * 2005-12-22 2007-06-28 Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.) Copper alloy having excellent stress relaxation property
JP2012502189A (en) * 2008-09-10 2012-01-26 ピーエムエックス・インダストリーズ・インコーポレーテッド White copper alloy with reduced nickel content
CN103695726A (en) * 2013-12-26 2014-04-02 青岛友铭辰生物技术有限公司 Aluminum alloy power transmission line for electrified railways and preparation method of aluminum alloy power transmission line

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1681360A1 (en) * 2003-09-19 2006-07-19 Sumitomo Metal Industries Limited Copper alloy and method for production thereof
CN1930314A (en) * 2004-03-12 2007-03-14 住友金属工业株式会社 Copper alloy and its manufacturing method
US20070148032A1 (en) * 2005-12-22 2007-06-28 Kabushiki Kaisha Kobe Seiko Sho (Kobe Steel, Ltd.) Copper alloy having excellent stress relaxation property
JP2012502189A (en) * 2008-09-10 2012-01-26 ピーエムエックス・インダストリーズ・インコーポレーテッド White copper alloy with reduced nickel content
CN103695726A (en) * 2013-12-26 2014-04-02 青岛友铭辰生物技术有限公司 Aluminum alloy power transmission line for electrified railways and preparation method of aluminum alloy power transmission line

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN120280222A (en) * 2025-06-09 2025-07-08 安徽鑫海高导新材料有限公司 Preparation process of ultrafine copper conductor for new energy automobile
CN120280222B (en) * 2025-06-09 2025-10-14 安徽鑫海高导新材料有限公司 Preparation process of ultrafine copper conductor for new energy automobile

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Effective date of registration: 20201105

Address after: 244000 No.2 workshop, no.3888, west section of Cuihu Sixth Road, Tongling City, Anhui Province

Patentee after: Anhui Xinchen Automobile Manufacturing Co., Ltd

Address before: 244061 Mount Huangshan Road, Tongling economic and Technological Development Zone, Anhui

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