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CN104026134A - Wooden floor bactericidal detergent - Google Patents

Wooden floor bactericidal detergent Download PDF

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Publication number
CN104026134A
CN104026134A CN201410233430.8A CN201410233430A CN104026134A CN 104026134 A CN104026134 A CN 104026134A CN 201410233430 A CN201410233430 A CN 201410233430A CN 104026134 A CN104026134 A CN 104026134A
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CN
China
Prior art keywords
bactericidal
floor
diphenyl
detergent
diethyl
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Application number
CN201410233430.8A
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Chinese (zh)
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CN104026134B (en
Inventor
刘勇
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Shaanxi Kaili Chemical Co., Ltd.
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CHUZHOU SMET COMPOUND MATERIALS Co Ltd
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Priority to CN201410233430.8A priority Critical patent/CN104026134B/en
Publication of CN104026134A publication Critical patent/CN104026134A/en
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Publication of CN104026134B publication Critical patent/CN104026134B/en
Expired - Fee Related legal-status Critical Current
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Abstract

The invention relates to a wooden floor bactericidal detergent belonging to the technical field of cleaning products. The wooden floor bactericidal detergent consists of the following raw materials: water, N-(2,6-dioxo-3-piperidyl)-phthalimide, (2-ethoxy) diisopropylmethylammonium bromidexanthene-9-carboxylic ester, 2-(acetoxy group) benzoic acid, diphenylacetic acid 2-(diethylamino)ethyl ester hydrochloride, 2,3,4,5,6-pentahydroxy-2-hexenoic acid-4-lactone, N,N-diethyl-2-[4-(1,2-diphenyl-2-chlorovinyl) phenoxy] diethylcarbamazine citrate, 2-aminoethanol and diethyl ether. The detergent does not contain irritant surface active materials, the used raw material components are harmless to a human body and are matched and combined according to the properties of each raw material component, and the wooden floor bactericidal detergent has an obvious bactericidal effect, particularly does not have any harm to floor materials in the bactericidal cleaning process and is particularly suitable for wide application in the field of floor cleaning.

Description

The agent of a kind of wood floors sterilizing cleaning
Technical field
The present invention relates to the agent of a kind of wood floors sterilizing cleaning, belong to cleaning supplies technical field.
background technology
Have at present the cleaning agent of bactericidal action, the cationic surfactant that sterilization component is wherein mainly clorox or has bactericidal action is as quaternary ammonium salt.Though clorox has very strong bactericidal effect, there are stronger excitant and sensitization, when use, also can cause article to fade.Cationic surfactant development rapidly, because it has bactericidal effect, the conventional cationic surfactant of China is mainly quaternary ammonium salt, its bactericidal effect is remarkable, but still have the following disadvantages: its bactericidal effect can be subject to the impact of composition in system and weaken, as there is protein or anion in system time, its bactericidal effect can weaken; Cationic surfactant has very low LD50, and toxicity is higher, and skin is had to excitant.
Many employing wood floors in existing house decoration, but after wood floors use a period of time, bacterium easily grows, dirt is not easy to clean, and bactericidal effect is good, to skin, non-irritating sterilizing cleaning agent becomes the active demand on market.
Summary of the invention
The object of the invention is to solve the bactericidal effect that above-mentioned prior art exists unstable, there is irritating deficiency, the agent of good, the non-irritating wood floors sterilizing cleaning of a kind of bactericidal effect is provided.
Technical problem of the present invention, is achieved by following technical proposals:
The agent of a kind of wood floors sterilizing cleaning, special character is to be made up of the raw material of following weight portion proportioning: 70 parts, water, N-(2, 6-dioxo-3-piperidyl)-phthalimide 15-18 part, (2-ethoxy) diisopropyl methyl ammonium bromide cluck ton-9-carboxylate 13-15 part, 2-(acetoxyl group) benzoic acid 10-12 part, diphenyl acetic acid 2-(diethylamino) ethyl ester hydrochloride 8-10 part, 2, 3, 4, 5, 6-penta hydroxy group-2-hexenoic acid-4-lactone 8-10 part, N, N-diethyl-2-[4-(1, 2-diphenyl-2-chlorovinyl) phenoxy group] ethamine citrate 4-6 part, 2-ethylaminoethanol 6-8 part, diethyl ether 2-4 part.
Preparation method of the present invention: add pure water, add while stirring N-(2,6-dioxo-3-piperidyl)-phthalimide, continue to be stirred to and be uniformly dispersed, be then heated to 50-65 DEG C; Slowly add (2-ethoxy) diisopropyl methyl ammonium bromide cluck ton-9-carboxylate, stir and make it to dissolve; After add successively 2-(acetoxyl group) benzoic acid, diphenyl acetic acid 2-(diethylamino) ethyl ester hydrochloride, 2,3,4,5,6-penta hydroxy group-2-hexenoic acid-4-lactone, N, N-diethyl-2-[4-(1,2-diphenyl-2-chlorovinyl) phenoxy group] ethamine citrate, 2-ethylaminoethanol, diethyl ether, stir; Be cooled to 30-35 DEG C, stir and leave standstill 20 minutes, obtain this floor sterilizing cleaning agent.
The agent of described wood floors sterilizing cleaning is used in 10-35 DEG C of temperature range.
This wood floors sterilizing cleaning agent, not containing excitant surface reactive materials such as clorox and quaternary ammonium salts, the raw material components using is harmless, and according to the character matched combined of each raw material components, there is obvious bactericidal effect, especially its in sterilizing cleaning process to flooring board matter without any injury, be particularly suitable for the extensive use in floor-cleaning field.
Embodiment
Below provide the specific embodiment of the present invention, be used for the present invention to be further described.In the present invention, if no special instructions, each raw material is all taking working substance content as 100%.
In following examples and comparative example, raw material introduction:
N-(2,6-dioxo-3-piperidyl)-phthalimide, CAS accession number is 50-35-1;
(2-ethoxy) diisopropyl methyl ammonium bromide cluck ton-9-carboxylate, CAS accession number is 50-34-0;
2-(acetoxyl group) benzoic acid, CAS accession number is 50-78-2;
Diphenyl acetic acid 2-(diethylamino) ethyl ester hydrochloride, CAS accession number is 50-42-0;
2,3,4,5,6-penta hydroxy group-2-hexenoic acid-4-lactone, CAS accession number is 50-81-7;
N, N-diethyl-2-[4-(1,2-diphenyl-2-chlorovinyl) phenoxy group] ethamine citrate, CAS accession number is 50-41-9;
2-ethylaminoethanol, CAS accession number is 141-43-5;
Diethyl ether, CAS accession number is 60-29-7.
Embodiment 1
The wood floors sterilizing cleaning agent of the present embodiment is made up of the raw material of following weight portion proportioning:
Water 70kg, N-(2,6-dioxo-3-piperidyl)-phthalimide 18kg, (2-ethoxy) diisopropyl methyl ammonium bromide cluck ton-9-carboxylate 13kg, 2-(acetoxyl group) benzoic acid 10kg, diphenyl acetic acid 2-(diethylamino) ethyl ester hydrochloride 8kg, 2,3,4,5,6-penta hydroxy group-2-hexenoic acid-4-lactone 10kg, N, N-diethyl-2-[4-(1,2-diphenyl-2-chlorovinyl) phenoxy group] ethamine citrate 4 kg, 2-ethylaminoethanol 8kg, diethyl ether 2kg.
Add pure water 70kg, add while stirring N-(2,6-dioxo-3-piperidyl)-phthalimide 18 kg, continue to be stirred to and be uniformly dispersed, be then heated to 50-65 DEG C; Slowly add (2-ethoxy) diisopropyl methyl ammonium bromide cluck ton-9-carboxylate 13kg, stir and make it to dissolve; After add successively 2-(acetoxyl group) benzoic acid 10 kg, diphenyl acetic acid 2-(diethylamino) ethyl ester hydrochloride 8 kg, 2,3,4,5,6-penta hydroxy group-2-hexenoic acid-4-lactone 10 kg, N, N-diethyl-2-[4-(1,2-diphenyl-2-chlorovinyl) phenoxy group] ethamine citrate 4kg, 2-ethylaminoethanol 8kg, diethyl ether 2 kg, stir; Be cooled to 30-35 DEG C, stir and leave standstill 20 minutes, obtain this floor sterilizing cleaning agent.
The properties of product of the present embodiment:
Sterilizing power: staphylococcus aureus 99.9%, Escherichia coli 99.5%, Candida albicans 99.2%.
Embodiment 2
The wood floors sterilizing cleaning agent of this comparative example is made up of the raw material of following weight portion proportioning:
Water 70kg, N-(2,6-dioxo-3-piperidyl)-phthalimide 15kg, (2-ethoxy) diisopropyl methyl ammonium bromide cluck ton-9-carboxylate 14kg, 2-(acetoxyl group) benzoic acid 11kg, diphenyl acetic acid 2-(diethylamino) ethyl ester hydrochloride 10kg, 2,3,4,5,6-penta hydroxy group-2-hexenoic acid-4-lactone 8kg, N, N-diethyl-2-[4-(1,2-diphenyl-2-chlorovinyl) phenoxy group] ethamine citrate 6 kg, 2-ethylaminoethanol 6kg, diethyl ether 4kg.
Preparation method is with embodiment 1 in this wood floors sterilizing cleaning agent.
The properties of product of the present embodiment:
Sterilizing power: staphylococcus aureus 99.7%, Escherichia coli 99.6%, Candida albicans 99.2%.
Embodiment 3
The wood floors sterilizing cleaning agent of the present embodiment is made up of the raw material of following weight portion proportioning:
Water 70kg, N-(2,6-dioxo-3-piperidyl)-phthalimide 16kg, (2-ethoxy) diisopropyl methyl ammonium bromide cluck ton-9-carboxylate 15kg, 2-(acetoxyl group) benzoic acid 12kg, diphenyl acetic acid 2-(diethylamino) ethyl ester hydrochloride 9kg, 2,3,4,5,6-penta hydroxy group-2-hexenoic acid-4-lactone 9kg, N, N-diethyl-2-[4-(1,2-diphenyl-2-chlorovinyl) phenoxy group] ethamine citrate 5kg, 2-ethylaminoethanol 7kg, diethyl ether 3kg.
Preparation method is with embodiment 1 in this wood floors sterilizing cleaning agent.
The properties of product of the present embodiment:
Sterilizing power: staphylococcus aureus 99.6%, Escherichia coli 99.4%, Candida albicans 99.5%.
Comparative example 1
The wood floors sterilizing cleaning agent of this comparative example is made up of the raw material of following weight portion proportioning:
Water 70kg, N-(2,6-dioxo-3-piperidyl)-phthalimide 18kg, 2-(acetoxyl group) benzoic acid 10kg, diphenyl acetic acid 2-(diethylamino) ethyl ester hydrochloride 8kg, 2,3,4,5,6-penta hydroxy group-2-hexenoic acid-4-lactone 10kg, N, N-diethyl-2-[4-(1,2-diphenyl-2-chlorovinyl) phenoxy group] ethamine citrate 4kg, diethyl ether 2kg.
Add pure water 70kg, add while stirring N-(2,6-dioxo-3-piperidyl)-phthalimide 18kg, continue to be stirred to and be uniformly dispersed, be then heated to 50-65 DEG C; After add successively 2-(acetoxyl group) benzoic acid 10kg, diphenyl acetic acid 2-(diethylamino) ethyl ester hydrochloride 8kg, 2,3,4,5,6-penta hydroxy group-2-hexenoic acid-4-lactone 10kg, N, N-diethyl-2-[4-(1,2-diphenyl-2-chlorovinyl) phenoxy group] ethamine citrate 4kg, diethyl ether 2kg, stir; Be cooled to 30-35 DEG C, stir and leave standstill 20 minutes, obtain this floor sterilizing cleaning agent.
The properties of product of the present embodiment:
Sterilizing power: staphylococcus aureus 80.6%, Escherichia coli 78.4%, Candida albicans 75.5%.
Comparative example 2
The wood floors sterilizing cleaning agent of the present embodiment is made up of the raw material of following weight portion proportioning:
Water 70kg, N-(2,6-dioxo-3-piperidyl)-phthalimide 18kg, (2-ethoxy) diisopropyl methyl ammonium bromide cluck ton-9-carboxylate 13kg, 2-(acetoxyl group) benzoic acid 10kg, 2,3,4,5,6-penta hydroxy group-2-hexenoic acid-4-lactone 10kg, N, N-diethyl-2-[4-(1,2-diphenyl-2-chlorovinyl) phenoxy group] ethamine citrate 4 kg, 2-ethylaminoethanol 8kg.
Its preparation method is with comparative example 1.
The properties of product of this comparative example:
Sterilizing power: staphylococcus aureus 92.9%, Escherichia coli 92.4%, Candida albicans 91.5%.
The floor sterilizing cleaning agent of above embodiment and comparative example is all used in 10-35 DEG C of temperature range.
With embodiment 1-3 and the clean wood floors of comparative example gained finished product, its performance parameter sees the following form.
By 25 times of embodiment 1-3 and comparative example gained finished product clear water dilutions, pick dilution with clean rag, spread upon dirty locating, use clear water wiping, recover the bright and clean of wood floors.
Infiltrating time, for finished product dilution being spread upon behind dirty place, dissolves the dirty routed time completely;
Effect comprises following several situation:
1. represent the dirty removing completely of bursting, floor is completely bright and clean;
2. represent to still have the residual dirt of minute quantity to burst, do not affect floor attractive in appearance;
3. represent to still have a small amount of residual dirt to burst, floor surface is light not;
4. represent to remove a small amount of dirty bursting, still need secondary clean.
Product wiping properties parameter list
Embodiment 1 Embodiment 2 Embodiment 3 Comparative example 1 Comparative example 2
Smear number of times 1 1 1 1 1
Infiltrating time/s 8 12 10 18 18
Wiping effect 1 1 1 3 2

Claims (2)

1. wood floors sterilizing cleaning agent, it is characterized in that being formed by the raw material of following weight portion proportioning: 70 parts, water, N-(2, 6-dioxo-3-piperidyl)-phthalimide 15-18 part, (2-ethoxy) diisopropyl methyl ammonium bromide cluck ton-9-carboxylate 13-15 part, 2-(acetoxyl group) benzoic acid 10-12 part, diphenyl acetic acid 2-(diethylamino) ethyl ester hydrochloride 8-10 part, 2, 3, 4, 5, 6-penta hydroxy group-2-hexenoic acid-4-lactone 8-10 part, N, N-diethyl-2-[4-(1, 2-diphenyl-2-chlorovinyl) phenoxy group] ethamine citrate 4-6 part, 2-ethylaminoethanol 6-8 part, diethyl ether 2-4 part.
2. wood floors sterilizing cleaning as claimed in claim 1 agent, is characterized in that the agent of described wood floors sterilizing cleaning is used in 10-35 DEG C of temperature range.
CN201410233430.8A 2014-05-29 2014-05-29 A kind of wood floors Bactericidal cleaner Expired - Fee Related CN104026134B (en)

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CN104026134B CN104026134B (en) 2015-09-23

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106635436A (en) * 2016-11-30 2017-05-10 四川中塑高分子材料有限公司 Novel cleaning agent for sports floor
CN106635511A (en) * 2016-11-30 2017-05-10 四川中塑高分子材料有限公司 Sports floor cleaner
CN106635435A (en) * 2016-11-30 2017-05-10 四川中塑高分子材料有限公司 An improved type sports floor cleaning agent
CN106635506A (en) * 2016-11-30 2017-05-10 四川中塑高分子材料有限公司 Efficient sports floor cleaning agent
CN106675792A (en) * 2016-11-30 2017-05-17 四川中塑高分子材料有限公司 Antibacterial sports floor cleaning agent
CN106854574A (en) * 2017-01-05 2017-06-16 长沙协浩吉生物工程有限公司 A kind of compound method of wood furniture cleaning agent

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009045443A2 (en) * 2007-10-02 2009-04-09 The University Of Rochester Methods and compositions related to synergistic responses to oncogenic mutations
CN103255002A (en) * 2013-05-21 2013-08-21 苏州富通高新材料科技股份有限公司 Antibacterial floor cleaner and preparation method thereof
CN103555457A (en) * 2013-10-30 2014-02-05 青岛叁鼎卫生制品有限公司 Floor cleaner

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009045443A2 (en) * 2007-10-02 2009-04-09 The University Of Rochester Methods and compositions related to synergistic responses to oncogenic mutations
CN103255002A (en) * 2013-05-21 2013-08-21 苏州富通高新材料科技股份有限公司 Antibacterial floor cleaner and preparation method thereof
CN103555457A (en) * 2013-10-30 2014-02-05 青岛叁鼎卫生制品有限公司 Floor cleaner

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106635436A (en) * 2016-11-30 2017-05-10 四川中塑高分子材料有限公司 Novel cleaning agent for sports floor
CN106635511A (en) * 2016-11-30 2017-05-10 四川中塑高分子材料有限公司 Sports floor cleaner
CN106635435A (en) * 2016-11-30 2017-05-10 四川中塑高分子材料有限公司 An improved type sports floor cleaning agent
CN106635506A (en) * 2016-11-30 2017-05-10 四川中塑高分子材料有限公司 Efficient sports floor cleaning agent
CN106675792A (en) * 2016-11-30 2017-05-17 四川中塑高分子材料有限公司 Antibacterial sports floor cleaning agent
CN106854574A (en) * 2017-01-05 2017-06-16 长沙协浩吉生物工程有限公司 A kind of compound method of wood furniture cleaning agent

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Inventor after: Kang Dongping

Inventor before: Liu Yong

TR01 Transfer of patent right
TR01 Transfer of patent right

Effective date of registration: 20170316

Address after: Five East Road 710399 Shaanxi city of Xi'an province Huxian Fengjing Industrial Park.

Patentee after: Shaanxi Kaili Chemical Co., Ltd.

Address before: 239000 Anhui city of Chuzhou province to two County Road C District Industrial Park weft

Patentee before: Chuzhou Smet Compound Materials Co., Ltd.

CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20150923

Termination date: 20170529