The agent of a kind of wood floors sterilizing cleaning
Technical field
The present invention relates to the agent of a kind of wood floors sterilizing cleaning, belong to cleaning supplies technical field.
background technology
Have at present the cleaning agent of bactericidal action, the cationic surfactant that sterilization component is wherein mainly clorox or has bactericidal action is as quaternary ammonium salt.Though clorox has very strong bactericidal effect, there are stronger excitant and sensitization, when use, also can cause article to fade.Cationic surfactant development rapidly, because it has bactericidal effect, the conventional cationic surfactant of China is mainly quaternary ammonium salt, its bactericidal effect is remarkable, but still have the following disadvantages: its bactericidal effect can be subject to the impact of composition in system and weaken, as there is protein or anion in system time, its bactericidal effect can weaken; Cationic surfactant has very low LD50, and toxicity is higher, and skin is had to excitant.
Many employing wood floors in existing house decoration, but after wood floors use a period of time, bacterium easily grows, dirt is not easy to clean, and bactericidal effect is good, to skin, non-irritating sterilizing cleaning agent becomes the active demand on market.
Summary of the invention
The object of the invention is to solve the bactericidal effect that above-mentioned prior art exists unstable, there is irritating deficiency, the agent of good, the non-irritating wood floors sterilizing cleaning of a kind of bactericidal effect is provided.
Technical problem of the present invention, is achieved by following technical proposals:
The agent of a kind of wood floors sterilizing cleaning, special character is to be made up of the raw material of following weight portion proportioning: 70 parts, water, N-(2, 6-dioxo-3-piperidyl)-phthalimide 15-18 part, (2-ethoxy) diisopropyl methyl ammonium bromide cluck ton-9-carboxylate 13-15 part, 2-(acetoxyl group) benzoic acid 10-12 part, diphenyl acetic acid 2-(diethylamino) ethyl ester hydrochloride 8-10 part, 2, 3, 4, 5, 6-penta hydroxy group-2-hexenoic acid-4-lactone 8-10 part, N, N-diethyl-2-[4-(1, 2-diphenyl-2-chlorovinyl) phenoxy group] ethamine citrate 4-6 part, 2-ethylaminoethanol 6-8 part, diethyl ether 2-4 part.
Preparation method of the present invention: add pure water, add while stirring N-(2,6-dioxo-3-piperidyl)-phthalimide, continue to be stirred to and be uniformly dispersed, be then heated to 50-65 DEG C; Slowly add (2-ethoxy) diisopropyl methyl ammonium bromide cluck ton-9-carboxylate, stir and make it to dissolve; After add successively 2-(acetoxyl group) benzoic acid, diphenyl acetic acid 2-(diethylamino) ethyl ester hydrochloride, 2,3,4,5,6-penta hydroxy group-2-hexenoic acid-4-lactone, N, N-diethyl-2-[4-(1,2-diphenyl-2-chlorovinyl) phenoxy group] ethamine citrate, 2-ethylaminoethanol, diethyl ether, stir; Be cooled to 30-35 DEG C, stir and leave standstill 20 minutes, obtain this floor sterilizing cleaning agent.
The agent of described wood floors sterilizing cleaning is used in 10-35 DEG C of temperature range.
This wood floors sterilizing cleaning agent, not containing excitant surface reactive materials such as clorox and quaternary ammonium salts, the raw material components using is harmless, and according to the character matched combined of each raw material components, there is obvious bactericidal effect, especially its in sterilizing cleaning process to flooring board matter without any injury, be particularly suitable for the extensive use in floor-cleaning field.
Embodiment
Below provide the specific embodiment of the present invention, be used for the present invention to be further described.In the present invention, if no special instructions, each raw material is all taking working substance content as 100%.
In following examples and comparative example, raw material introduction:
N-(2,6-dioxo-3-piperidyl)-phthalimide, CAS accession number is 50-35-1;
(2-ethoxy) diisopropyl methyl ammonium bromide cluck ton-9-carboxylate, CAS accession number is 50-34-0;
2-(acetoxyl group) benzoic acid, CAS accession number is 50-78-2;
Diphenyl acetic acid 2-(diethylamino) ethyl ester hydrochloride, CAS accession number is 50-42-0;
2,3,4,5,6-penta hydroxy group-2-hexenoic acid-4-lactone, CAS accession number is 50-81-7;
N, N-diethyl-2-[4-(1,2-diphenyl-2-chlorovinyl) phenoxy group] ethamine citrate, CAS accession number is 50-41-9;
2-ethylaminoethanol, CAS accession number is 141-43-5;
Diethyl ether, CAS accession number is 60-29-7.
Embodiment 1
The wood floors sterilizing cleaning agent of the present embodiment is made up of the raw material of following weight portion proportioning:
Water 70kg, N-(2,6-dioxo-3-piperidyl)-phthalimide 18kg, (2-ethoxy) diisopropyl methyl ammonium bromide cluck ton-9-carboxylate 13kg, 2-(acetoxyl group) benzoic acid 10kg, diphenyl acetic acid 2-(diethylamino) ethyl ester hydrochloride 8kg, 2,3,4,5,6-penta hydroxy group-2-hexenoic acid-4-lactone 10kg, N, N-diethyl-2-[4-(1,2-diphenyl-2-chlorovinyl) phenoxy group] ethamine citrate 4 kg, 2-ethylaminoethanol 8kg, diethyl ether 2kg.
Add pure water 70kg, add while stirring N-(2,6-dioxo-3-piperidyl)-phthalimide 18 kg, continue to be stirred to and be uniformly dispersed, be then heated to 50-65 DEG C; Slowly add (2-ethoxy) diisopropyl methyl ammonium bromide cluck ton-9-carboxylate 13kg, stir and make it to dissolve; After add successively 2-(acetoxyl group) benzoic acid 10 kg, diphenyl acetic acid 2-(diethylamino) ethyl ester hydrochloride 8 kg, 2,3,4,5,6-penta hydroxy group-2-hexenoic acid-4-lactone 10 kg, N, N-diethyl-2-[4-(1,2-diphenyl-2-chlorovinyl) phenoxy group] ethamine citrate 4kg, 2-ethylaminoethanol 8kg, diethyl ether 2 kg, stir; Be cooled to 30-35 DEG C, stir and leave standstill 20 minutes, obtain this floor sterilizing cleaning agent.
The properties of product of the present embodiment:
Sterilizing power: staphylococcus aureus 99.9%, Escherichia coli 99.5%, Candida albicans 99.2%.
Embodiment 2
The wood floors sterilizing cleaning agent of this comparative example is made up of the raw material of following weight portion proportioning:
Water 70kg, N-(2,6-dioxo-3-piperidyl)-phthalimide 15kg, (2-ethoxy) diisopropyl methyl ammonium bromide cluck ton-9-carboxylate 14kg, 2-(acetoxyl group) benzoic acid 11kg, diphenyl acetic acid 2-(diethylamino) ethyl ester hydrochloride 10kg, 2,3,4,5,6-penta hydroxy group-2-hexenoic acid-4-lactone 8kg, N, N-diethyl-2-[4-(1,2-diphenyl-2-chlorovinyl) phenoxy group] ethamine citrate 6 kg, 2-ethylaminoethanol 6kg, diethyl ether 4kg.
Preparation method is with embodiment 1 in this wood floors sterilizing cleaning agent.
The properties of product of the present embodiment:
Sterilizing power: staphylococcus aureus 99.7%, Escherichia coli 99.6%, Candida albicans 99.2%.
Embodiment 3
The wood floors sterilizing cleaning agent of the present embodiment is made up of the raw material of following weight portion proportioning:
Water 70kg, N-(2,6-dioxo-3-piperidyl)-phthalimide 16kg, (2-ethoxy) diisopropyl methyl ammonium bromide cluck ton-9-carboxylate 15kg, 2-(acetoxyl group) benzoic acid 12kg, diphenyl acetic acid 2-(diethylamino) ethyl ester hydrochloride 9kg, 2,3,4,5,6-penta hydroxy group-2-hexenoic acid-4-lactone 9kg, N, N-diethyl-2-[4-(1,2-diphenyl-2-chlorovinyl) phenoxy group] ethamine citrate 5kg, 2-ethylaminoethanol 7kg, diethyl ether 3kg.
Preparation method is with embodiment 1 in this wood floors sterilizing cleaning agent.
The properties of product of the present embodiment:
Sterilizing power: staphylococcus aureus 99.6%, Escherichia coli 99.4%, Candida albicans 99.5%.
Comparative example 1
The wood floors sterilizing cleaning agent of this comparative example is made up of the raw material of following weight portion proportioning:
Water 70kg, N-(2,6-dioxo-3-piperidyl)-phthalimide 18kg, 2-(acetoxyl group) benzoic acid 10kg, diphenyl acetic acid 2-(diethylamino) ethyl ester hydrochloride 8kg, 2,3,4,5,6-penta hydroxy group-2-hexenoic acid-4-lactone 10kg, N, N-diethyl-2-[4-(1,2-diphenyl-2-chlorovinyl) phenoxy group] ethamine citrate 4kg, diethyl ether 2kg.
Add pure water 70kg, add while stirring N-(2,6-dioxo-3-piperidyl)-phthalimide 18kg, continue to be stirred to and be uniformly dispersed, be then heated to 50-65 DEG C; After add successively 2-(acetoxyl group) benzoic acid 10kg, diphenyl acetic acid 2-(diethylamino) ethyl ester hydrochloride 8kg, 2,3,4,5,6-penta hydroxy group-2-hexenoic acid-4-lactone 10kg, N, N-diethyl-2-[4-(1,2-diphenyl-2-chlorovinyl) phenoxy group] ethamine citrate 4kg, diethyl ether 2kg, stir; Be cooled to 30-35 DEG C, stir and leave standstill 20 minutes, obtain this floor sterilizing cleaning agent.
The properties of product of the present embodiment:
Sterilizing power: staphylococcus aureus 80.6%, Escherichia coli 78.4%, Candida albicans 75.5%.
Comparative example 2
The wood floors sterilizing cleaning agent of the present embodiment is made up of the raw material of following weight portion proportioning:
Water 70kg, N-(2,6-dioxo-3-piperidyl)-phthalimide 18kg, (2-ethoxy) diisopropyl methyl ammonium bromide cluck ton-9-carboxylate 13kg, 2-(acetoxyl group) benzoic acid 10kg, 2,3,4,5,6-penta hydroxy group-2-hexenoic acid-4-lactone 10kg, N, N-diethyl-2-[4-(1,2-diphenyl-2-chlorovinyl) phenoxy group] ethamine citrate 4 kg, 2-ethylaminoethanol 8kg.
Its preparation method is with comparative example 1.
The properties of product of this comparative example:
Sterilizing power: staphylococcus aureus 92.9%, Escherichia coli 92.4%, Candida albicans 91.5%.
The floor sterilizing cleaning agent of above embodiment and comparative example is all used in 10-35 DEG C of temperature range.
With embodiment 1-3 and the clean wood floors of comparative example gained finished product, its performance parameter sees the following form.
By 25 times of embodiment 1-3 and comparative example gained finished product clear water dilutions, pick dilution with clean rag, spread upon dirty locating, use clear water wiping, recover the bright and clean of wood floors.
Infiltrating time, for finished product dilution being spread upon behind dirty place, dissolves the dirty routed time completely;
Effect comprises following several situation:
1. represent the dirty removing completely of bursting, floor is completely bright and clean;
2. represent to still have the residual dirt of minute quantity to burst, do not affect floor attractive in appearance;
3. represent to still have a small amount of residual dirt to burst, floor surface is light not;
4. represent to remove a small amount of dirty bursting, still need secondary clean.
Product wiping properties parameter list
| |
Embodiment 1 |
Embodiment 2 |
Embodiment 3 |
Comparative example 1 |
Comparative example 2 |
| Smear number of times |
1 |
1 |
1 |
1 |
1 |
| Infiltrating time/s |
8 |
12 |
10 |
18 |
18 |
| Wiping effect |
1 |
1 |
1 |
3 |
2 |