CN104003809A - Effect improved compound fertilizer - Google Patents
Effect improved compound fertilizer Download PDFInfo
- Publication number
- CN104003809A CN104003809A CN201410263907.7A CN201410263907A CN104003809A CN 104003809 A CN104003809 A CN 104003809A CN 201410263907 A CN201410263907 A CN 201410263907A CN 104003809 A CN104003809 A CN 104003809A
- Authority
- CN
- China
- Prior art keywords
- fertilizer
- nitrogen
- parts
- composite fertilizer
- percent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003337 fertilizer Substances 0.000 title claims abstract description 176
- 230000000694 effects Effects 0.000 title abstract description 29
- 150000001875 compounds Chemical class 0.000 title abstract description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 134
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 71
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims abstract description 41
- 239000004202 carbamide Substances 0.000 claims abstract description 41
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 claims abstract description 15
- 235000019837 monoammonium phosphate Nutrition 0.000 claims abstract description 15
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims abstract description 12
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 10
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims abstract description 10
- 235000011130 ammonium sulphate Nutrition 0.000 claims abstract description 10
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 claims abstract description 7
- 229910052939 potassium sulfate Inorganic materials 0.000 claims abstract description 7
- 235000011151 potassium sulphates Nutrition 0.000 claims abstract description 7
- -1 sodium tetraphenylborate Chemical compound 0.000 claims abstract description 5
- YWYZEGXAUVWDED-UHFFFAOYSA-N triammonium citrate Chemical compound [NH4+].[NH4+].[NH4+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O YWYZEGXAUVWDED-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000011787 zinc oxide Substances 0.000 claims abstract description 5
- 229910000365 copper sulfate Inorganic materials 0.000 claims abstract description 4
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims abstract description 4
- FGRVOLIFQGXPCT-UHFFFAOYSA-L dipotassium;dioxido-oxo-sulfanylidene-$l^{6}-sulfane Chemical compound [K+].[K+].[O-]S([O-])(=O)=S FGRVOLIFQGXPCT-UHFFFAOYSA-L 0.000 claims abstract description 4
- 239000002131 composite material Substances 0.000 claims description 108
- 229910052698 phosphorus Inorganic materials 0.000 claims description 21
- 239000012747 synergistic agent Substances 0.000 claims description 20
- 239000002994 raw material Substances 0.000 claims description 9
- 239000002689 soil Substances 0.000 abstract description 43
- 230000007062 hydrolysis Effects 0.000 abstract description 10
- 238000006460 hydrolysis reaction Methods 0.000 abstract description 10
- 229910000387 ammonium dihydrogen phosphate Inorganic materials 0.000 abstract description 5
- 239000006012 monoammonium phosphate Substances 0.000 abstract description 5
- 241000108664 Nitrobacteria Species 0.000 abstract description 3
- 230000002829 reductive effect Effects 0.000 abstract description 3
- 239000001103 potassium chloride Substances 0.000 abstract 1
- 235000011164 potassium chloride Nutrition 0.000 abstract 1
- 239000001120 potassium sulphate Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 description 47
- 238000012360 testing method Methods 0.000 description 47
- 239000000618 nitrogen fertilizer Substances 0.000 description 34
- 230000008569 process Effects 0.000 description 28
- 241000209094 Oryza Species 0.000 description 15
- 239000000126 substance Substances 0.000 description 15
- 235000007164 Oryza sativa Nutrition 0.000 description 14
- 235000009566 rice Nutrition 0.000 description 14
- 238000012545 processing Methods 0.000 description 13
- 238000004519 manufacturing process Methods 0.000 description 12
- 229910052700 potassium Inorganic materials 0.000 description 12
- 108010046334 Urease Proteins 0.000 description 11
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 11
- 210000003608 fece Anatomy 0.000 description 9
- 239000010871 livestock manure Substances 0.000 description 9
- 238000002844 melting Methods 0.000 description 9
- 230000008018 melting Effects 0.000 description 9
- GNTDGMZSJNCJKK-UHFFFAOYSA-N divanadium pentaoxide Chemical compound O=[V](=O)O[V](=O)=O GNTDGMZSJNCJKK-UHFFFAOYSA-N 0.000 description 8
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 description 6
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 5
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 5
- 240000008042 Zea mays Species 0.000 description 5
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 5
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 5
- 235000005822 corn Nutrition 0.000 description 5
- 239000011574 phosphorus Substances 0.000 description 5
- 239000011591 potassium Substances 0.000 description 5
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 description 5
- 229910001950 potassium oxide Inorganic materials 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 4
- 241000196324 Embryophyta Species 0.000 description 4
- 238000007792 addition Methods 0.000 description 4
- FFBHFFJDDLITSX-UHFFFAOYSA-N benzyl N-[2-hydroxy-4-(3-oxomorpholin-4-yl)phenyl]carbamate Chemical compound OC1=C(NC(=O)OCC2=CC=CC=C2)C=CC(=C1)N1CCOCC1=O FFBHFFJDDLITSX-UHFFFAOYSA-N 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 238000013461 design Methods 0.000 description 4
- 238000005469 granulation Methods 0.000 description 4
- 230000003179 granulation Effects 0.000 description 4
- 238000011534 incubation Methods 0.000 description 4
- 238000002386 leaching Methods 0.000 description 4
- 235000015097 nutrients Nutrition 0.000 description 4
- 238000012856 packing Methods 0.000 description 4
- 238000012216 screening Methods 0.000 description 4
- 238000010998 test method Methods 0.000 description 4
- 229910021529 ammonia Inorganic materials 0.000 description 3
- 230000033228 biological regulation Effects 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- 235000013305 food Nutrition 0.000 description 3
- 230000012010 growth Effects 0.000 description 3
- 230000008635 plant growth Effects 0.000 description 3
- 230000013278 single fertilization Effects 0.000 description 3
- 210000002700 urine Anatomy 0.000 description 3
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- PNNCWTXUWKENPE-UHFFFAOYSA-N [N].NC(N)=O Chemical compound [N].NC(N)=O PNNCWTXUWKENPE-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 238000005904 alkaline hydrolysis reaction Methods 0.000 description 2
- 235000019270 ammonium chloride Nutrition 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 239000008280 blood Substances 0.000 description 2
- 210000004369 blood Anatomy 0.000 description 2
- 235000013339 cereals Nutrition 0.000 description 2
- 239000003245 coal Substances 0.000 description 2
- 238000013270 controlled release Methods 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 238000009863 impact test Methods 0.000 description 2
- 230000002045 lasting effect Effects 0.000 description 2
- 235000012054 meals Nutrition 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 235000016709 nutrition Nutrition 0.000 description 2
- 230000035764 nutrition Effects 0.000 description 2
- 230000003389 potentiating effect Effects 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000002681 soil colloid Substances 0.000 description 2
- 239000011343 solid material Substances 0.000 description 2
- 239000006228 supernatant Substances 0.000 description 2
- 230000009466 transformation Effects 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- 235000005979 Citrus limon Nutrition 0.000 description 1
- 244000131522 Citrus pyriformis Species 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- NPYPAHLBTDXSSS-UHFFFAOYSA-N Potassium ion Chemical compound [K+] NPYPAHLBTDXSSS-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 235000013877 carbamide Nutrition 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000004737 colorimetric analysis Methods 0.000 description 1
- 239000002361 compost Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000009837 dry grinding Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000009313 farming Methods 0.000 description 1
- FPVGTPBMTFTMRT-NSKUCRDLSA-L fast yellow Chemical compound [Na+].[Na+].C1=C(S([O-])(=O)=O)C(N)=CC=C1\N=N\C1=CC=C(S([O-])(=O)=O)C=C1 FPVGTPBMTFTMRT-NSKUCRDLSA-L 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 230000004720 fertilization Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000008235 industrial water Substances 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 239000010687 lubricating oil Substances 0.000 description 1
- 230000035800 maturation Effects 0.000 description 1
- 239000011785 micronutrient Substances 0.000 description 1
- 235000013369 micronutrients Nutrition 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 235000021049 nutrient content Nutrition 0.000 description 1
- 230000000050 nutritive effect Effects 0.000 description 1
- 239000002674 ointment Substances 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 150000002927 oxygen compounds Chemical class 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229910001414 potassium ion Inorganic materials 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000003044 randomized block design Methods 0.000 description 1
- 230000007115 recruitment Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000000452 restraining effect Effects 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000009331 sowing Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 230000032258 transport Effects 0.000 description 1
- 235000011046 triammonium citrate Nutrition 0.000 description 1
- 239000001393 triammonium citrate Substances 0.000 description 1
- 238000003911 water pollution Methods 0.000 description 1
Landscapes
- Fertilizers (AREA)
Abstract
The invention discloses effect improved compound fertilizer. The effect improved compound fertilizer comprises, by part, 35-65.2 parts of urea with 46 percent of N, 8-40 parts of monoammonium phosphate with 10 percent of N and 50 percent of P2O5, 6.7-30 parts of potassium chloride with 60 percent of K2O or 8-30 parts of potassium sulphate with 50 percent of K2O, 0-15 parts of ammonium sulfate with 21 percent of N and 0.1-1 part of nitrogen controlled synergist (AHE). According to the AHE, the proportion of sodium tetraphenylborate, copper sulfate, zinc oxide, ammonium citrate and potassium thiosulfate is 3: 2: 2: 1: 2-3. The effect improved compound fertilizer reduces the hydrolysis rate of urea in the fertilizer, restrains the activity of nitrobacteria in soil, the 6-8 millesimal of AHE is added into the effect improved compound fertilizer, the nitrogen use efficiency reaches to 44 percent, the nitrogen use efficiency is improved by 23 percent, the nitrogen loss is reduced by 22.6 percent, and the crop is increased by 8-16 percent. One-time fertilize application is carried out in spring, and labor cost is saved.
Description
Technical field
The present invention relates to a kind of synergy chemical fertilizer, is the chemical fertilizer of nitrogenous, phosphorus, potassium and control nitrogen synergistic agent (AHE) for improving crop yield specifically.
Background technology
That composite fertilizer, the compound manure using in China's agricultural at present all belongs to is nitrogenous, phosphorus, three kinds of nutrients of potassium or the composite fertilizer of two kinds of nutrients (State Standard of the People's Republic of China GB15063-2009 < < composite fertilizer-compound manure > >) wherein.In composite fertilizer, nitrogen element is that crop growth is necessary, is also the nutritive element having the call.Nitrogenous source raw material used during manufacture is mainly with nitrogenous chemical fertilizer such as urea, ammonium sulfate, ammonium chloride, monoammonium phosphates, the composite fertilizer utilization rate of nitrogen fertilizer that these fertilizer are raw material production of take is low, its utilization rate of nitrogen fertilizer is only 30%～35% (Zhang Fusuo etc., Chinese staple food crop utilization rate of fertilizer present situation and raising approach soil journal: 2008.45(5): P915-922).The number of utilization rate of fertilizer is direct affects crop yield, the major cause that composite fertilizer utilization rate of nitrogen fertilizer is low has 3 points: the one, in composite fertilizer contained major nitrogen source urea with incorporation of fertilizerin the soil after, farm crop seldom absorb, must be ammonium nitrogen through contained urase hydrolysis in soil, crop just can absorb.Reaction formula is:
Because crop has from less to more the absorption of nitrogen full vegetative period, arrive again the rule of few lasting absorption, only have the conversion of fertilizer nutrient to discharge to meet the regulation of fertilizer requirement of crop could realize stable and high yields, and the speed of the hydrolysis of urea in composite fertilizer absorb requirement with crop nutrition content and does not synchronize.(< < Chinese soil and fertilizer > > " progress of nitrogen fertilizer potentiating agent and effect assessment thereof " the 2011.3.P 1-7 such as He Weiming), the urea at short notice caused ammonia loss by volatilization of hydrolysis accounts for its total amount 10～50%, is that nitrogen utilizes one of low reason (Wu Zhijie etc. (< < release/controlled release principle and application > > Science Press 18,2003).Second reason is: the volatilization loss of the ammonia that nitrated-anti-nitre effect causes, and the volatilization loss of ammonia is except urea, and the loss access of the nitrogen of the ammonium fertilizers such as the ammonium sulfate in composite fertilizer raw material, ammonium chloride, monoammonium phosphate is consistent.If the gaseous oxygen compound of nitrogen is (as NO
x, N
2o etc.) the final product N of anti-nitre effect
2atmosphere escape.Between this loss amount accounts for 30%～55% greatly (Zhu Zhaoliang, China's soil is for nitrogen and fertilizer nitrogen whereabouts progress of research, soil 1985,17:2-9).The 3rd reason is leaching loss: the nitric nitrogen NO that nitrification produces
3-N.Although be the nitrogen that crop can absorb, but because nitric nitrogen is with negative charge, and soil colloid is also with negative charge, so can not adsorbed by soil colloid, movability in soil is large, very easily outflow with water enter in water body loss (the < < release/controlled release principle and application > > Science Press such as Wu Zhijie, 2003:; 17).Above 3 is the major cause that composite fertilizer utilization rate of nitrogen fertilizer is low.Because composite fertilizer utilization rate of nitrogen fertilizer is low, the nitrogen of loss has entered atmosphere and water body with variform, and the atmosphere causing and water pollution, environmental pollution impact are huge.
By the end of 2010, China permits composite fertilizer manufacturing enterprise on the regular payroll just to reach 4400, aggregated capacity quantity of goods produced is over 200,000,000 tons, actual annual production is 5,000 ten thousand tons, composite fertilizer nitrogen content is average more than 15%, pressing utilization rate of nitrogen fertilizer 35% calculates, China is often only by using the purity nitrogen volatilization leaching loss that composite fertilizer brings just to reach 487.5 ten thousand tons, produce 1 ton of purity nitrogen and need 1.33 tons of standard coals, by standard coal price 960 yuan of calculating per ton in 2010, the mark coal losses that only this item China causes because utilization rate of nitrogen fertilizer is low every year reaches 6,480,000 tons, 62.2 hundred million yuans of financial losses, China is every year because the volatilization leaching of the low nitrogen causing of composite fertilizer utilization rate of nitrogen fertilizer is discharged to atmosphere with the exception of this, the Environmental Pollution Loss that water body causes cannot be estimated.
Summary of the invention
The object of the present invention is to provide a kind of synergy composite fertilizer and manufacture method thereof, the present invention adopts the method for the decomposition and inversion thing activity of regulation and control nitrogenous fertilizer, from root, reconciles the decomposition and inversion speed of nitrogen, reaches the object that improves utilization rate of nitrogen fertilizer; Adapt to crop regulation of fertilizer requirement, in the time of volume increase, economize on resources, reduce the pollution of nitrogenous fertilizer to environment.Method of the present invention is by urea melting, then sprinkling pelleting, makes the component of every granulation fertilizer more even, is conducive to farm crop and evenly absorbs each component.
Technical scheme of the present invention is as follows:
A synergy composite fertilizer, it is made by the raw material of following parts by weight:
Containing 35～65.2 parts, the urea of N 46%, containing N10%, P
2o
550% 8～40 parts of monoammonium phosphates, containing K
26.7～30 parts, the Repone K of O 60% or containing K
28～30 parts of the potassium sulfate of O 50%, containing 0～15 part, N21% ammonium sulfate, control nitrogen synergistic agent (AHE) 0.1～1 part;
Above-mentioned control nitrogen synergistic agent AHE is sodium tetraphenylborate: copper sulfate: zinc oxide: ammonium citrate: Potassium Thiosulphate is 3:2:2:1:2～3.
The further scheme of above-mentioned synergy composite fertilizer is for 55.2 parts, the urea containing N 46%, containing N10%, P
2o
550% 24 parts of monoammonium phosphates, containing K
220 parts, the Repone K of O 60%, control nitrogen synergistic agent (AHE) 0.8 part.
The manufacture method of above-mentioned synergy composite fertilizer:
1, raw material preparation:
(1) by nitrogenous 46% urea melting in urea melting device;
(2) by nitrogenous 10%, containing the monoammonium phosphate of Vanadium Pentoxide in FLAKES 50%, pulverized 40 mesh sieves;
(3) by the Repone K containing potassium oxide 60% or containing the potassium sulfate of potassium oxide 50%, pulverized 40 mesh sieves;
(4) control nitrogen synergistic agent AHE(powdery);
2, raw material is mixed fertile
(2), (3), (4), ammonium sulfate are joined to mixer after by above-mentioned formula metering to carry out after homogenizing mixes being transported in tablets press;
3, granulation
The urine having melted through urea melting device (1) is measured and sprayed into tablets press on request, with (2), (3), (4), the ammonium sulfate pulverulent material sprinkling pelleting of homogenizing;
4, dry, cooling, screening, metering, packing
In tablets press, raw meal particle size reaches after requirement, and pellet is transported in drying machine and is dried, and transports material in cooler after dry coolingly, enters storehouse to be checked through sieve apparatus screening is laggard, and metering packing is finished product after the assay was approved.
The invention has the advantages that: the present invention joins control nitrogen synergistic agent AHE in composite fertilizer, make the synergism that utilization rate of nitrogen fertilizer is high as follows: the specificity enzyme-urease activity that 1, suppresses hydrolyze urea, delay the hydrolysis rate of urea in fertilizer, make part hydrolysis of urea be converted into ammonium nitrogen, separately there is part urea still with urea state, to be present in soil, with treat follow-up in plant growth, latter stage hydrolysis becomes ammonium nitrogen, for crop, absorb; 2, be under the effect of control nitrogen synergistic agent AHE, suppress the activity of nitrobacteria in soil, control nitrification process, keep the form that exists of the ammonium nitrogen that contains in the ammonium nitrogen that become by Urea Transformation and fertilizer, stop nitrobacteria by NH
4 +-N changes into NO
3-N, prevents from the volatilization leaching loss of formed nitrogen after the further conversion of ammonium nitrogen from adding control nitrogen synergistic agent AHE6～8 ‰, and utilization rate of nitrogen fertilizer reaches 44%, and utilization rate of nitrogen fertilizer improves 23%, reduces nitrogen loss 22.6%, crop yield 8～16%.3, save manually, reduce costs, synergy composite fertilizer can be realized base fertilizer single fertilization to food crop, in plant growth, later stage need not topdress, and has reduced the farming operation link topdressing, and has saved chemical fertilizer input and artificial input that peasant topdresses, realized and both improved chemical fertilizer utilization ratio, the object of increasing production again, increasing income.4, by the inventive method, be by urea melting, then sprinkling pelleting, make the component of every granulation fertilizer more even, all contain N, P, K is conducive to farm crop and evenly absorbs each component.Simple process, is beneficial to popularization.
accompanying drawing explanation
Fig. 1 is process flow sheet of the present invention.
Below in conjunction with accompanying drawing, the invention will be further described.
By Fig. 1, can see synergy composite fertilizer process flow sheet, described urea melting, pulverized 40 mesh sieves by monoammonium phosphate, Repone K or potassium sulfate; Control nitrogen synergistic agent AHE, ammonium sulfate are meals; Above-mentioned solid material is joined to mixer after by above-mentioned formula metering to carry out after homogenizing mixes being transported in tablets press; The urine having melted is measured on request and is sprayed into tablets press, with the solid materials sprinkling pelleting of homogenizing; Dry, cooling, screening, metering, packing.
Embodiment
Embodiment 1: containing 55.2 parts, the urea of N 46%, containing N10%, P
2o
550% 24 parts of monoammonium phosphates, containing K
220 parts, the Repone K of O 60%, control nitrogen synergistic agent (AHE) 0.8 part.
Synergy composite fertilizer method
(1) by urea melting in urea melting device of 55.2 parts nitrogenous 46%;
(2) by 24 parts nitrogenous 10%, containing the monoammonium phosphate of Vanadium Pentoxide in FLAKES 50%, pulverized 40 mesh sieves;
(3) 20 parts of Repone K containing potassium oxide 60% were pulverized to 40 mesh sieves;
(4) 0.8 part of control nitrogen synergistic agent AHE powdery is got ready;
2, raw material is mixed fertile
By (2), (3), (4), undertaken after homogenizing mixes being transported in tablets press by joining mixer after above-mentioned formula metering;
3, granulation
The urine having melted through urea melting device (1) is measured and sprayed into tablets press on request, with (2), (3), (4) pulverulent material sprinkling pelleting of homogenizing;
4, dry, cooling, screening, metering, packing.
Embodiment 2
Containing 47 parts, the urea of N 46%, containing N10%, P
2o
550% 20 parts of monoammonium phosphates, containing K
220 parts of the potassium sulfate of O 50%, containing 11.5 parts, N21% ammonium sulfate, control nitrogen synergistic agent (AHE) 0.4 part.
Embodiment 3 is containing 36 parts, the urea of N 46%, containing N10%, P
2o
550% 33 parts of monoammonium phosphates, containing K
230 parts, the Repone K of O 60%, control nitrogen synergistic agent (AHE) 0.6 part;
Embodiment 4: containing 62 parts, the urea of N 46%, containing N10%, P
2o
550% 15 parts of monoammonium phosphates, containing K
215 parts of the potassium sulfate of O 50%, containing 7.3 parts, N21% ammonium sulfate, control nitrogen synergistic agent (AHE) 1 part;
Embodiment 2～4 making methods are identical with embodiment 1.
the beneficial effect experiment of fertilizer of the present invention
Effect one: suppress soil urease liveness, postpone Urea Transformation peak period 20 days.
One,
synergy composite fertilizer affects test to soil urease liveness:
1, test objective:
The soil incubation test of the influence degree of soil urease liveness being carried out after being manured into soil for clear and definite synergy composite fertilizer.
2, test materials and method
Test period: 6 days-June 16 April in 2011
test materials: the main fertilizer ratio of synergy composite fertilizer uses embodiment 1(containing 55.2 parts, the urea of N 46%, containing N10%, P
2o
550% 24 parts of monoammonium phosphates, containing K
220 parts, the Repone K of O 60%, nitrogen fertilizer potentiating agent AHE are different), containing N28% wherein blood urea nitrogen account for total nitrogen 89%, containing P
2o
512%, containing K
2o12%); (main fertilizer ratio not containing AHE, contains wherein blood urea nitrogen point total nitrogen 89% of N28%, containing P with embodiment 1 to composite fertilizer
2o
512%, containing K
2o12%); Culture soil is picked up from Jianchang, Yuanbaoshan District battalion town corn field topsoil soils, the rear 1mm sieve of crossing of air-dry grinding, and culture soil physicochemical character is: organic 2.61g/kg, alkali-hydrolyzable nitrogen 57.2mg/kg, rapid available phosphorus 16mg/kg, available potassium 178mg/kg, PH8.2.
test design and method
Synergy composite fertilizer is processed AHE content and is respectively 2 ‰, 4 ‰, 6 ‰, 8 ‰, and other composition is identical with contrast composite fertilizer.Test method is: respectively each is processed to fertilizer and ground 0.149m sieve, take 500g compost and 20.0g and process fertilizer, after mixing, be respectively charged in the polyethylene box of 25cm * 15cm * 12cm, put into fixed temperature and humidity incubator, keep 25 ℃ of temperature, humidity 20% is cultivated.When cultivation the 2nd, 5,10,20,30,40,50,60d, measure the urease activity in culture soil, measuring method: the mensuration NH of urease activity
4 +burst size method (8)
Note: urease activity (NH
3-Nmg/10g soil)
Test-results: show from upper watch test result: urase is as the specificity enzyme of hydrolyze urea, and along with the prolongation of incubation time, each urease activity of processing all shows as from low to high, then declines gradually again.Process 5 composite fertilizers urease activity when cultivating 20d and reach maximum 49.7NH
3-Nmg/10g soil, declines again afterwards, and while cultivating 60d, urease activity drops to 9.8NH
3-Nmg/10g soil, this result shows: urea contained in composite fertilizer is after cultivating 20d, by urase a large amount of hydrolysis rapidly, in soil, urea content also decreases, along with the prolongation of incubation time, be subject to the impact of concentration of substrate, urease activity also declines, and it is too early that the urea in soil is hydrolyzed peak in earlier stage, and hydrolysis of urea amount is excessive, what can cause that the recoverable amount of the nitrogen in soil declines is too fast, thereby causes plant growth later stage nitrogen stress.And in the processing of synergy composite fertilizer, along with the increase of the addition of AHE in fertilizer, the inhibition ability of urase is also being increased, its urease activity maximum of processing of synergy composite fertilizer AHE8 ‰ addition just reaches 48.8NH after cultivating 40d
3-Nmg/10g soil, has processed 5 backward delays 20 days than ordinary compound fertilizer, and this shows that the urea hydrolysis in early stage in culture soil is more slow, has part urea in follow-up conversion, significant to meeting the nitrogen nutrition demand of crop intermediary and later stages growth.
Effect two: suppress nitric nitrogen and transform minimizing 38.5%, reduce nitrogen loss 22.6%.
two, synergy composite fertilizer transforms impact test to soil nitrate-N
1, test objective: for clear and definite synergy composite fertilizer carries out soil incubation test to the influence degree of soil nitrification bacterial activity after being manured into soil.
2, test period: 6 days-September 20 May in 2012.
Test site: Chifeng, Inner Mongol Jie Xiang composite fertilizer company limited saddle support experimental field.
3, test materials and method:
test method: field pipe laying method, husky chimney filter diameter 8cm, high 22cm.
for examination fertilizer: embodiment 1, (AHE8 ‰, N28%, P
2o
512%, K
2o12%), contrast fertilizer: composite fertilizer containing AHE all the other with embodiment 1 together (N28%, P
2o
512%, K
2o12%).
for trying soil physical and chemical property: full N1.12g/kg, alkaline hydrolysis N37mg/kg, available P 11.2mg/kg, quick-acting k173mg/kg, organic 2.9g/kg, ph7.9.
soil nitrate-N measuring method: phenol two yellow acid colorimetrys (9)
4, test is processed: process 1 synergy composite fertilizer
Process 2 composite fertilizers (ck)
Each processes five repetitions, will test fertilizer and grind after 0.149mm sieve, after taking 20.0g and culture soil 200g and mixing, nondestructively pack in husky chimney filter, pour into respectively after tap water 100ml, cover husky chimney filter lid, imbed experimental field topsoil soils 25cm depths, after earthing, carry out mark.After placing into the soil, husky chimney filter respectively sampling in the 10th, 20,30,40,50,60,70,80 days, measures NO
3-N content.Get the mean value calculation content repeating for five times.
Synergy composite fertilizer is to soil NO
3-N transforms affects test-results mg/kg-1
Conclusion (of pressure testing): show from upper watch test result, process 2 composite fertilizer NO
3the formation peak period of-N is at latter 40 days NO of cultivation
3-N content is 426.7mg/kg, and processes 1 synergy composite fertilizer NO after cultivating 40 days
3-N content does not peak, and cultivates the NO that just peaks after 60 days
3-N content is 330mg/kg, and test-results shows: AHE contained in synergy composite fertilizer has restraining effect to soil nitrification bacterium, while cultivating 40 days, processes synergy composite fertilizer than the NO of contrast composite fertilizer
3-N transforms and reduces 38.5%, is cultivating in 80 days, and synergy composite fertilizer is processed NO
3-N transforms maximum contrast composite fertilizer NO
3-N transforms maximum, reduces nitrogen loss 22.6%.
Effect three: utilization rate of nitrogen fertilizer reaches 44.84%, improves utilization rate of nitrogen fertilizer 23.73%
Three,
synergy composite fertilizer nitrogen fertilizer for paddy rice utilization ratio field test
1, test objective: for after clear and definite synergy composite fertilizer is manured into soil, the influence degree to crop utilization rate of nitrogen fertilizer, carries out utilization rate of nitrogen fertilizer test.
2, test period and place:
Test period: in June, 2011-2011 year October
Test site: Wengniute Banner Red Hill town, the Inner Mongol
Soil physical and chemical property experimental field: organic matter: 33.1g/kg, full nitrogen 1.03g/kg, alkali-hydrolyzable nitrogen 54.7mg/kg, available phosphorus 20.2mg/kg, available potassium 168mg/kg, pH value 7.4.
For trying crop varieties: paddy rice, long white No. 19
For trying fertilizer: main fertilizer embodiment 2 ratios of synergy composite fertilizer (except AHE), (containing N26%, P
2o
510%, K
2o10%), the main fertilizer of composite fertilizer embodiment 2 ratios are (containing N26%, P
2o
510%, K
2o10%)
3, test method
Test adopts randomized block design, establishes 6 processing, repeats community area 52m for three times
2, test fertilizer is base manure, does not topdress.After paddy rice maturation, take field sample, measure above-ground plant parts total nitrogen content, measuring method is with H
2sO
4-Catalyst mixtures-distillation method.
4, test is processed:
Process 1: synergy composite fertilizer (containing AHE8 ‰), base fertilizer 750kg/hm
2;
Process 2: synergy composite fertilizer (containing AHE6 ‰), base fertilizer 750kg/hm
2;
Process 3: synergy composite fertilizer (containing AHE4 ‰), base fertilizer 750kg/hm
2;
Process 4: synergy composite fertilizer (containing AHE2 ‰), base fertilizer 750kg/hm
2;
Process 5: composite fertilizer, base fertilizer 750kg/hm
2;
Process 6: nitrogen fertilizer application (CK) not, base fertilizer 0.
Synergy composite fertilizer nitrogen fertilizer for paddy rice utilization ratio field test results table
| Processing number | Process title | Amount of nitrogen (kg/hm 2) | Overground part plant total nitrogen (kg/hm 2) | Utilization rate of nitrogen fertilizer (%) |
| 1 | Synergy composite fertilizer AHE8 ‰ | 210 | 177.18a | 44.84 |
| 2 | Synergy composite fertilizer AHE6 ‰ | 210 | 175.91a | 44.19 |
| 3 | Synergy composite fertilizer AHE4 ‰ | 210 | 150.39b | 32.03 |
| 4 | Synergy composite fertilizer AHE2 ‰ | 210 | 144.01bc | 28.99 |
| 5 | Composite fertilizer | 210 | 117.34c | 21.11 |
| 6 | Nitrogen fertilizer application (CK) not | 0 | 83.11d |
Note: in table, lowercase alphabet shows that between processing, difference reaches 5% conspicuous level.
5, conclusion (of pressure testing):
From upper watch test result, prove: synergy composite fertilizer is respectively processed rice plant over-ground part total nitrogen content all higher than other processing, the highest to process 1 synergy Chemical Mixed Fertilizer paddy rice over-ground part total nitrogen content, and the AHE adding in synergy composite fertilizer amount is proportionate with paddy rice overground part total nitrogen content, the result shows relevant with the control nitrogen ability of wherein contained AHE.The in the situation that of identical amount of nitrogen, synergy Chemical Mixed Fertilizer is processed 1 utilization rate of nitrogen fertilizer and is reached 28.99～44.84%, processes 5 utilization rate of nitrogen fertilizer improve utilization rate of nitrogen fertilizer 7.88～23.73% than composite fertilizer.Test-results shows: in synergy composite fertilizer, as long as control nitrogen synergistic agent AHE addition reaches more than 6 ‰, its utilization rate of nitrogen fertilizer is and significant difference higher than the utilization rate of nitrogen fertilizer of the composite fertilizer of equal nitrogen content all.
Effect four: increasing production of rice 16%
four, synergy composite fertilizer is at rice field fertilization effect.
1, test objective:
For clear and definite synergy composite fertilizer be manured into soil after influence degree to rice yield, by applying the synergy composite fertilizer of different AHE additions, and carry out rice yield impact test.
2, test period: in June, 2011-October.
Experimental cultivar: long white No. 19 of paddy rice
3, test site: Wengniute Banner Red Hill town, the Inner Mongol, experimental field soil physical and chemical property: organic 33.1g/kg, full N1.03g/kg, alkaline hydrolysis N54.7mg/kg, effective P20.2mg/kg, quick-acting K168mg/kg, ph7.4.
4, test materials and method:
For trying fertilizer: main fertilizer embodiment 3 ratios of synergy composite fertilizer, (containing AHE, containing N26%, P
2o
510%, K
2o10%), the main fertilizer of composite fertilizer contains N26%, P with embodiment 3(
2o
510%, K
2o10%).
Test design: test adopts single factors randomized blocks design, synergy composite fertilizer is processed the AHE that adds different amounts; Composite fertilizer is identical with synergy composite fertilizer nutrient content except not adding AHE, and ck is nitrogen fertilizer application not, and test amounts to 6 processing, repeats community area 52 ㎡ for three times.
Table 1: the field test processing list of synergy composite fertilizer on paddy rice:
Process the numbering N fertilizer amount of executing kg.hm
2p
2o
5the fertilizer amount of executing kg.hm
2k
2the O fertilizer amount of executing kg.hm
2fertilizing method
1 synergy composite fertilizer AHE8 ‰ 210 90 90 base manure
2 synergy composite fertilizer AHE6 ‰ 210 90 90 base manure
3 synergy composite fertilizer AHE4 ‰ 210 90 90 base manure
4 synergy composite fertilizer AHE2 ‰ 210 90 90 base manure
5 composite fertilizer 210 90 90 base manure
6 nitrogen fertilizer application (ck) 0 90 90 base manure not
5, test-results
Each fertilizer treatment of table 2 is to the rice yield factor and yield effect test-results
Process numbering number of productive ear grain number per spike setting percentage thousand seed weight yield of kernels amount of increase in production %
（x10
4hm
2) (%) (g) (kghm
2)
1 synergy composite fertilizer 317.5a 110.8ab 89.5ab 25.35ab 8251.6a 16
AHE8‰
2 synergy composite fertilizer 301.6a 105.8bc 85.6b 25.31ab 7699.2b 8.2
AHE6‰
3 synergy composite fertilizer 264.2b 116.7ab 91.3ab 25.71ab 7588.4bc 6.7 AHE4 ‰
4 synergy composite fertilizer 253.8bc 123.9a 93.1a 25.10b 7411.1bc 4.2 AHE2 ‰
5 composite fertilizer 244.7bc 116.2ab 96.2a 25.98ab 7113.3c-
6 nitrogen fertilizer application (ck) 234.1c 95.4c 93.7c 26.11a 5756.1d not
Note: in table,, in same row, between different lowercases represent to process, difference reaches 5% conspicuous level
From table 2 experiment results proved, the synergy composite fertilizer of all AHE of adding is processed and composite fertilizer processing rice yield is all significantly higher than not nitrogen fertilizer application ck processing, wherein process 1A,HE8 ‰ output the highest, compare remarkable volume increase with processing 5 composite fertilizers, amount of increase in production reaches 4.2～16%, identical, supply under nitrogen condition, add each number of productive ear, grain number per spike, yield of kernels of processing of AHE all higher than composite fertilizer, to process, this shows to add after AHE in fertilizer, nitrogen nutrient supply is lasting, under the condition of not topdressing, still than conventional composite fertilizer volume increase.
Effect five: farm crop corn yield increasing 11.3%
five, synergy composite fertilizer corn fertilizing field test
1, test objective: by field test method, define synergy composite fertilizer to the impact of corn yield and single fertilization effect.
2, test site: Anqing town, Songshan District
3, test soil physical and chemical property: organic 18.4g/kg, full nitrogen 1.18g/kg, alkali-hydrolyzable nitrogen 49mg/kg, rapid available phosphorus 21kg/kg, available potassium 173mg/kg, PH7.8.
4, test period: in April, 2012-October
For studying thing: corn.Kind: Zheng Dan 958, mu Basic Seedling 3800 strains, test April 26 sowing time, contrast dressing time July 9.
5, test fertilizer: the main embodiment 4 for fertilizer of synergy composite fertilizer, (containing AHE8 ‰, nitrogenous 29%, containing Vanadium Pentoxide in FLAKES 12%, containing potassium oxide 12%), the main embodiment 4 fertilizer for of contrast fertilizer composite fertilizer, (nitrogenous 29%, containing Vanadium Pentoxide in FLAKES 12%, contain potassium oxide 12%).Urea (nitrogenous 46%).
6, test design: random district group, repeats community area 9X12=108m for three times
2
Test is processed:
Process numbering content rate of fertilizer application and method
Process 1 composite fertilizer CK base fertilizer 30kg/666.7m
2+ urea 20kg/666.7m
2, topdress
Process 2 synergy composite fertilizer base fertilizer 30kg/666.7m
2, do not topdress
Process 3 synergy composite fertilizer base fertilizer 40kg/666.7m
2, do not topdress
Process 4 synergy composite fertilizer base fertilizer 50kg/666.7m
2, do not topdress
Process 5 synergy composite fertilizer base fertilizer 60kg/666.7m
2, do not topdress
7, test-results
Note: each community is got 60 fringe samples and surveyed product, t0.05=2.228, t0.01=3.169
8, conclusion (of pressure testing)
Test-results shows: add the synergy composite fertilizer of control nitrogen synergistic agent AHE, rate of fertilizer application 30kg/666.7m
2above level, all, than contrast volume increase, amount of increase in production is 9.25%～11.33%, and it is the highest that synergy composite fertilizer is processed 4 output, and rate of fertilizer application reaches 50kg/666.7m
2above, output increasing degree is little.Synergy Chemical Mixed Fertilizer base fertilizer single fertilization, does not topdress, and reduces the recruitment of topdressing, the synergy composite fertilizer that belongs to not only saving of labor but also increase production.
Synergy composite fertilizer finished product forms and content sees the following form
Synergy composite fertilizer control nitrogen synergistic agent (AHE) starting material physicochemical character
Sodium tetraphenylborate: molecular formula (C6H5) 4BNa molecular weight 342.24 white solids, odorlessness, deteriorated goods have aniline smell.Water-soluble, for the identification of potassium ion.Contained boron is the necessary micronutrient element of crop growth.The favorable to the people Chemical Co., Ltd. in Chongqing produces.
Copper sulfate: molecular formula: CuSO
45H
2o, molecular weight: 249.68, crystal.The aqueous solution is weakly alkaline.Purposes: main application is sterilant, fodder additives.San Li chemical plant, Shijiazhuang produces.
Zinc oxide: molecular formula is ZnO.Be a kind of white or micro-yellowy fine-powder, be easily dispersed in rubber and latex.Be insoluble in water, dissolve in acid and highly basic.Be widely used in the making of the products such as plastics, silicate product, synthetic rubber, lubricating oil, paint, ointment, tackiness agent, food, battery, fire retardant.Five yuan of chemical plant of Yinchuan of Ningxia Province produce.
Lemon acid amide: be also called Triammonium citrate, white deliquescence powder or crystallization.Soluble in water.During fusing point, there is decomposition.Low toxicity.Structure or molecular formula C6H5O7 (NH4) 3, molecular weight 243.22, ammonium citrate is mainly used in chemical analysis, Treatment of Industrial Water etc. and Lianyun Harbour supernatant Chemical Co., Ltd. produces.
Potassium Thiosulphate: molecular formula: H
2k
2o
4s
2. molecular weight: 208.3401, soluble in water.Main application: reductive agent, toxinicide.Lianyun Harbour supernatant Chemical Co., Ltd. produces.
Claims (2)
1. a synergy composite fertilizer, is characterized in that: it is made by the raw material of following parts by weight:
Containing 35～65.2 parts, the urea of N 46%, containing N10%, P
2o
550% 8～40 parts of monoammonium phosphates, containing K
26.7～30 parts, the Repone K of O 60% or containing K
28～30 parts of the potassium sulfate of O 50%, containing 0～15 part, N21% ammonium sulfate, control nitrogen synergistic agent (AHE) 0.1～1 part;
Above-mentioned control nitrogen synergistic agent AHE is sodium tetraphenylborate: copper sulfate: zinc oxide: ammonium citrate: Potassium Thiosulphate is 3:2:2:1:2～3.
2. synergy composite fertilizer according to claim 1, is characterized in that: it is made by the raw material of following parts by weight:
Containing 55.2 parts, the urea of N 46%, containing N10%, P
2o
550% 24 parts of monoammonium phosphates, containing K
220 parts, the Repone K of O 60%, control nitrogen synergistic agent (AHE) 0.8 part.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410263907.7A CN104003809B (en) | 2014-06-13 | 2014-06-13 | Synergia compound fertilizer material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410263907.7A CN104003809B (en) | 2014-06-13 | 2014-06-13 | Synergia compound fertilizer material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104003809A true CN104003809A (en) | 2014-08-27 |
| CN104003809B CN104003809B (en) | 2015-09-30 |
Family
ID=51364748
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410263907.7A Active CN104003809B (en) | 2014-06-13 | 2014-06-13 | Synergia compound fertilizer material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104003809B (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107129342A (en) * | 2016-02-29 | 2017-09-05 | 李季 | It is a kind of to carry complex fertilizer of the remanent magnetism containing organic matter |
| CN108947647A (en) * | 2018-06-30 | 2018-12-07 | 赤峰杰翔复合肥有限公司 | A kind of synergy beet is compound fertilizer dedicated and preparation method thereof |
| CN111138235A (en) * | 2020-01-13 | 2020-05-12 | 中国农业大学 | Salt ion and pH double sensitive polymer saline-alkali earth slow-release membrane material and preparation method thereof |
| CN112125760A (en) * | 2020-08-19 | 2020-12-25 | 洲际环境科学研究院(广州)有限公司 | Environment-friendly method for reducing nitrification of ammonia nitrogen in soil |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102060614A (en) * | 2010-12-03 | 2011-05-18 | 林超 | Slow-release lose-control ammonium phosphate compound fertilizer and preparation method thereof |
| CN102557815A (en) * | 2010-12-31 | 2012-07-11 | 施可丰化工股份有限公司 | Multifunctional synergist of compound fertilizer |
| CN103333000A (en) * | 2013-06-04 | 2013-10-02 | 张亚彬 | Environment-friendly nitrogen phosphorus and potassium compound fertilizer |
-
2014
- 2014-06-13 CN CN201410263907.7A patent/CN104003809B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102060614A (en) * | 2010-12-03 | 2011-05-18 | 林超 | Slow-release lose-control ammonium phosphate compound fertilizer and preparation method thereof |
| CN102557815A (en) * | 2010-12-31 | 2012-07-11 | 施可丰化工股份有限公司 | Multifunctional synergist of compound fertilizer |
| CN103333000A (en) * | 2013-06-04 | 2013-10-02 | 张亚彬 | Environment-friendly nitrogen phosphorus and potassium compound fertilizer |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107129342A (en) * | 2016-02-29 | 2017-09-05 | 李季 | It is a kind of to carry complex fertilizer of the remanent magnetism containing organic matter |
| CN108947647A (en) * | 2018-06-30 | 2018-12-07 | 赤峰杰翔复合肥有限公司 | A kind of synergy beet is compound fertilizer dedicated and preparation method thereof |
| CN111138235A (en) * | 2020-01-13 | 2020-05-12 | 中国农业大学 | Salt ion and pH double sensitive polymer saline-alkali earth slow-release membrane material and preparation method thereof |
| CN112125760A (en) * | 2020-08-19 | 2020-12-25 | 洲际环境科学研究院(广州)有限公司 | Environment-friendly method for reducing nitrification of ammonia nitrogen in soil |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104003809B (en) | 2015-09-30 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103804097B (en) | A kind of fertilizer containing Antiphytoviral fertilizer additive | |
| CN107892634B (en) | A kind of cotton special liquid meal fertilizer for improving soil and preparation method and application method | |
| CN101633587B (en) | Saline-alkali land improving and fertilizing agent and preparation method thereof | |
| CN104072304A (en) | Bamboo charcoal compound microbial fertilizer and production method thereof | |
| CN107032914A (en) | Biological coat fertilizer of a kind of high-activity humic acid and preparation method thereof | |
| CN104609953A (en) | Microorganism fertilizer with coated straw bits and preparation method of microorganism fertilizer | |
| CN108503466A (en) | A kind of tea tree special bio bacterial manure and the preparation method and application thereof | |
| CN101195542A (en) | Method for producing soluble composite microorganism fertilizer | |
| CN102910987A (en) | Organic fertilizer and preparation method and use method of organic fertilizer | |
| CN104045413A (en) | Special novel cadmium prevention blending fertilizer for rice, and preparation method thereof | |
| CN103804091A (en) | Nutrition modifier rich in selenium for lowering content of heavy metals in food crops and application thereof | |
| CN104003809B (en) | Synergia compound fertilizer material | |
| CN104211479A (en) | Humic acid activated type compound fertilizer and production method thereof | |
| CN106748133B (en) | Fertilizer synergistic wrapping agent containing water-soluble organic matters and microorganisms and preparation method and application thereof | |
| CN108610181A (en) | A kind of vegetables special bio bacterial manure and the preparation method and application thereof | |
| CN104788170B (en) | Alkalescent slow-release compound fertilizer, silicon substrate alkalescent sustained release composite microbe fertilizer and preparation method thereof | |
| CN104446970A (en) | Organic and inorganic microbial fertilizer special for peanuts and preparation method thereof | |
| CN108147897A (en) | Bio-feritlizer | |
| CN104058874A (en) | Composite microbial granulated fertilizer containing medium trace elements and production process of composite microbial granulated fertilizer | |
| CN108975994A (en) | Complex fertilizer and preparation method thereof | |
| CN110922258A (en) | Functional stable bulk blend fertilizer and preparation method and application thereof | |
| CN110683883A (en) | A kind of facility cucumber whole growth period water-soluble fertilizer and its application method and application | |
| CN108083950A (en) | A kind of complex fertilizer and preparation method thereof | |
| CN113185335A (en) | Biological organic fertilizer and preparation method thereof | |
| CN113061065A (en) | A kind of sunflower special fertilizer and its preparation method and application method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |