CL2019001157A1 - Composiciones de revestimientos resistentes a grasa, aceite y agua - Google Patents
Composiciones de revestimientos resistentes a grasa, aceite y aguaInfo
- Publication number
- CL2019001157A1 CL2019001157A1 CL2019001157A CL2019001157A CL2019001157A1 CL 2019001157 A1 CL2019001157 A1 CL 2019001157A1 CL 2019001157 A CL2019001157 A CL 2019001157A CL 2019001157 A CL2019001157 A CL 2019001157A CL 2019001157 A1 CL2019001157 A1 CL 2019001157A1
- Authority
- CL
- Chile
- Prior art keywords
- coatings
- grease
- water
- oil
- compositions
- Prior art date
Links
- 238000000576 coating method Methods 0.000 title abstract 7
- 239000004519 grease Substances 0.000 title abstract 5
- 239000003921 oil Substances 0.000 title abstract 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title abstract 5
- 239000000203 mixture Substances 0.000 title 1
- 239000000463 material Substances 0.000 abstract 4
- 229920000126 latex Polymers 0.000 abstract 2
- 239000004816 latex Substances 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- 239000002245 particle Substances 0.000 abstract 2
- 239000000758 substrate Substances 0.000 abstract 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 1
- 230000004888 barrier function Effects 0.000 abstract 1
- 230000005540 biological transmission Effects 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 229920003048 styrene butadiene rubber Polymers 0.000 abstract 1
- 229920005792 styrene-acrylic resin Polymers 0.000 abstract 1
Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/062—Copolymers with monomers not covered by C09D133/06
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/66—Additives characterised by particle size
- C09D7/67—Particle size smaller than 100 nm
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/66—Additives characterised by particle size
- C09D7/68—Particle size between 100-1000 nm
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/66—Additives characterised by particle size
- C09D7/69—Particle size larger than 1000 nm
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
- D21H19/18—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12 comprising waxes
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/72—Coated paper characterised by the paper substrate
- D21H19/76—Coated paper characterised by the paper substrate the substrate having specific absorbent properties
- D21H19/78—Coated paper characterised by the paper substrate the substrate having specific absorbent properties being substantially impervious to the coating
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
- D21H27/10—Packing paper
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Nanotechnology (AREA)
- Paints Or Removers (AREA)
- Paper (AREA)
- Laminated Bodies (AREA)
Abstract
Aquí se describen los revestimientos que imparten resistencia al aceite, la grasa y el agua a diversos materiales, tal como papel, cartón y materiales poliméricos. Dichos revestimientos pueden aplicarse como revestimientos de barrera a los materiales de sustrato para inhibir y prevenir la transmisión de aceite, grasa y agua; es decir, para evitar que el aceite, el agua, la grasa pase en y/ o a través del material del sustrato. Los revestimientos incluyen un látex polimérico basado en acrílico, un látex de caucho de estireno-butadieno, una solución de resina de estireno-acrílico, una cera de tamaño de partícula grande y, opcionalmente, una cera de tamaño de partícula pequeño. También se describe aquí un proceso de preparación de los revestimientos. También se describen productos a los que se han aplicado los revestimientos para impartir resistencia al aceite, la grasa y/o al agua, y procesos para preparar dichos productos.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201662414838P | 2016-10-31 | 2016-10-31 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CL2019001157A1 true CL2019001157A1 (es) | 2019-07-19 |
Family
ID=62025527
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CL2019001157A CL2019001157A1 (es) | 2016-10-31 | 2019-04-26 | Composiciones de revestimientos resistentes a grasa, aceite y agua |
| CL2019003719A CL2019003719A1 (es) | 2016-10-31 | 2019-12-18 | Revestimiento que proporciona una barrera contra la transmisión de uno o más de aceite, grasa o agua en o a través de un sustrato. (divisional solicitud 201901157) |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CL2019003719A CL2019003719A1 (es) | 2016-10-31 | 2019-12-18 | Revestimiento que proporciona una barrera contra la transmisión de uno o más de aceite, grasa o agua en o a través de un sustrato. (divisional solicitud 201901157) |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US11242461B2 (es) |
| EP (1) | EP3532677A4 (es) |
| CN (1) | CN110073056B (es) |
| BR (1) | BR112019007422B1 (es) |
| CL (2) | CL2019001157A1 (es) |
| CO (1) | CO2019002561A2 (es) |
| WO (1) | WO2018081764A1 (es) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2020508403A (ja) | 2017-02-27 | 2020-03-19 | ウエストロック・エム・ダブリュー・ヴイ・エルエルシー | ヒートシール可能なバリア性板紙 |
| AU2018275247A1 (en) | 2017-05-31 | 2019-12-19 | Armstrong World Industries, Inc. | Flame retardant clear coatings for building panels |
| CN111670281A (zh) * | 2017-11-13 | 2020-09-15 | 太阳化学公司 | 用于纤维素基材的水基涂料 |
| DE102018117071A1 (de) | 2018-07-13 | 2020-01-16 | Mitsubishi Hitec Paper Europe Gmbh | Heißsiegelfähiges Barrierepapier |
| CN109183490B (zh) * | 2018-09-18 | 2020-06-02 | 珠海红塔仁恒包装股份有限公司 | 一种高阻隔涂布白卡纸及其制备方法 |
| MX2021008576A (es) * | 2019-01-17 | 2021-10-26 | Westrock Mwv Llc | Recipientes de carton recubiertos que tienen un recubrimiento de barrera acuosa. |
| CN111945477B (zh) * | 2020-08-14 | 2022-07-05 | 上海紫华薄膜科技有限公司 | 一种离型热封包装纸及其制作方法 |
| ZA202006089B (en) * | 2020-10-01 | 2023-01-25 | Seal Chemistry Pty Ltd | High-release barrier coated paper wrapper for candies and gum which exclude the use of hot wax and a method for preparation thereof |
| ZA202007591B (en) * | 2020-12-07 | 2021-09-29 | Seal Chemistry Pty Ltd | Barrier coated wrapper materials and method for preparation of barrier coated wrapper materials |
| CN113373726B (zh) * | 2021-05-27 | 2022-11-18 | 珠海红塔仁恒包装股份有限公司 | 一种胶乳及其制备方法和应用 |
| EP4194515A1 (en) * | 2021-12-07 | 2023-06-14 | Siegwerk Druckfarben AG & Co. KGaA | Barrier coating for paper substrates |
| CN114456666B (zh) * | 2022-03-30 | 2022-10-28 | 北京化工大学 | 一种耐高温水性光油、其制备方法及用途 |
| EP4528026A1 (en) * | 2023-09-20 | 2025-03-26 | Ahlstrom Oyj | Grease barrier packaging material |
| WO2025061872A1 (en) * | 2023-09-20 | 2025-03-27 | Ahlstrom Oyj | Low moisture vapor transmission rate packaging material |
Family Cites Families (44)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5763100A (en) | 1993-05-10 | 1998-06-09 | International Paper Company | Recyclable acrylic coated paper stocks and related methods of manufacture |
| US5837383A (en) | 1993-05-10 | 1998-11-17 | International Paper Company | Recyclable and compostable coated paper stocks and related methods of manufacture |
| EP0816561B1 (en) | 1996-07-04 | 2002-01-02 | Societe Des Produits Nestle S.A. | A packaging material having a food grade barrier coating |
| FI101990B (fi) | 1996-11-22 | 1998-09-30 | Stora Enso Oyj | Kuumennettava elintarvikevuoka ja sen valmistusmenetelmä |
| AU6120100A (en) * | 1999-06-16 | 2001-01-02 | Vacumet Corp. | Metallized paper with grease resistance |
| CA2323341A1 (en) | 1999-10-15 | 2001-04-15 | Fort James Corporation | A paperboard container having enhanced grease resistance and rigidity and a method of making same |
| WO2003099548A1 (en) * | 2000-03-03 | 2003-12-04 | The Hoffman Group, Ltd. | Composite paperboards and method of making composite paperboards |
| WO2002014426A1 (en) | 2000-08-15 | 2002-02-21 | P.H. Glatfelter Company | Formulation for achievement of oil and grease resistance and release paper properties |
| CA2452121C (en) | 2001-06-29 | 2011-12-06 | Spectra-Kote Corporation | Grease, oil and wax resistant paper composition |
| US6858765B2 (en) * | 2001-10-31 | 2005-02-22 | Mitsui Chemicals, Inc. | Polyolefin wax for coating materials and printing ink composition |
| WO2004035929A1 (en) | 2002-10-15 | 2004-04-29 | Dow Global Technologies Inc. | Method of producing a multilayer coated substrate having improved barrier properties |
| AU2003290358B2 (en) * | 2002-12-27 | 2010-04-01 | Imerys Pigments, Inc. | Paper coating pigments |
| US7320825B2 (en) | 2003-05-27 | 2008-01-22 | International Paper Company | Barrier coatings for oil and grease resistance |
| US7427444B2 (en) | 2003-07-16 | 2008-09-23 | Air Products Polymers, L.P. | Polymer emulsion coatings for cellulosic substrates with improved barrier properties |
| US7737200B2 (en) | 2004-06-23 | 2010-06-15 | University Of Maine System Board Of Trustees | Barrier compositions and articles produced with the compositions |
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| WO2007001694A1 (en) * | 2005-06-24 | 2007-01-04 | Exxonmobil Chemical Patents Inc. | Functionalized propylene copolymer adheside composition |
| US7282273B2 (en) | 2005-10-26 | 2007-10-16 | Polymer Ventures, Inc. | Grease resistance and water resistance compositions and methods |
| WO2007050964A1 (en) | 2005-10-26 | 2007-05-03 | Polymer Ventures, Inc. | Grease and water resistant article |
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| GB0608126D0 (en) * | 2006-04-24 | 2006-06-07 | Imerys Minerals Ltd | Barrier compositions |
| BRPI0811749A2 (pt) | 2007-05-18 | 2014-11-11 | Topchim N V | Composição para o tratamento da superfície de papel, papelão ou semelhante, e, aplicação de composições substrato celulósico. |
| US8771835B2 (en) | 2007-07-03 | 2014-07-08 | Newpage Wisconsin System, Inc. | Substantially biodegradable and compostable high-barrier packaging material and methods for production |
| ES2820336T3 (es) | 2007-12-06 | 2021-04-20 | Retec Int Inc | Revestimiento de barrera de base acuosa de formación rápida de película |
| WO2009114588A1 (en) | 2008-03-12 | 2009-09-17 | Nanopaper, Llc | Grease-resistant films and coatings |
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| CN102292500A (zh) | 2008-11-07 | 2011-12-21 | 芬兰优质纸板公司 | 涂布的可再生纸或纸板及其生产方法 |
| BRPI0923880A2 (pt) | 2008-12-30 | 2015-07-28 | Univ Sheffield Hallam | Material de barreira a base de biopolímero e método para a obtenção do mesmo |
| AR075381A1 (es) * | 2009-02-10 | 2011-03-30 | Unicamp | Uso de particulas de fosfato, polifosfato y metafosfato, de aluminio en aplicaciones de recubrimiento de papeles. |
| US8758567B2 (en) | 2009-06-03 | 2014-06-24 | Hercules Incorporated | Cationic wet strength resin modified pigments in barrier coating applications |
| US9580866B2 (en) * | 2009-06-03 | 2017-02-28 | Solenis Technologies, L.P. | Cationic wet strength resin modified pigments in water-based latex coating applications |
| US20110046284A1 (en) * | 2009-08-24 | 2011-02-24 | Basf Corporation | Novel Treated Mineral Pigments for Aqueous Based Barrier Coatings |
| SE534876C2 (sv) | 2010-03-18 | 2012-01-31 | Stora Enso Oyj | Metod för att förse ett substrat med en barriär genom användning av elektrospinning eller smältspinning av nanofiber |
| US8771812B2 (en) | 2011-05-30 | 2014-07-08 | Basf Se | Paper and cardboard packaging with barrier coating |
| AU2013262912B2 (en) | 2012-05-15 | 2015-06-25 | Mantrose-Haeuser Co., Inc. | Seaweed-based food packaging coating |
| WO2013188630A2 (en) * | 2012-06-15 | 2013-12-19 | Nanopaper, Llc | Additives for papermaking |
| FI124411B (fi) | 2012-07-05 | 2014-08-15 | Upm Kymmene Corp | Elintarvikepakkaus |
| WO2014028203A1 (en) * | 2012-08-14 | 2014-02-20 | Henkel US IP LLC | Moisture and vapor barrier coating compositions |
| EP2951026B1 (en) * | 2013-01-31 | 2018-03-21 | Hewlett-Packard Development Company L.P. | Pre-treatment coating |
| US9701860B2 (en) | 2013-02-19 | 2017-07-11 | Sun Chemical Corporation | Printable radiation curable barrier coatings |
| EP3047068B1 (de) | 2013-09-18 | 2017-08-23 | InnoGEL AG | Verpackungsmaterial mit einer auf stärke basierenden barrierebeschichtung sowie beschichtungsmasse und verfahren zum herstellen desselben |
| WO2015171443A1 (en) | 2014-05-07 | 2015-11-12 | Westrock Mwv, Llc | Paperboard barrier structure and container |
| US9771688B2 (en) | 2015-02-11 | 2017-09-26 | Westrock Mwv, Llc | Oil, grease, and moisture resistant paperboard |
| US9732474B2 (en) | 2015-05-29 | 2017-08-15 | International Paper Company | Hydrophobic coated paper substrate for polymer emulsion topcoats and method for making same |
-
2017
- 2017-10-31 EP EP17865721.9A patent/EP3532677A4/en active Pending
- 2017-10-31 BR BR112019007422-8A patent/BR112019007422B1/pt active IP Right Grant
- 2017-10-31 US US16/341,741 patent/US11242461B2/en active Active
- 2017-10-31 CN CN201780056731.XA patent/CN110073056B/zh active Active
- 2017-10-31 WO PCT/US2017/059164 patent/WO2018081764A1/en not_active Ceased
-
2019
- 2019-03-19 CO CONC2019/0002561A patent/CO2019002561A2/es unknown
- 2019-04-26 CL CL2019001157A patent/CL2019001157A1/es unknown
- 2019-12-18 CL CL2019003719A patent/CL2019003719A1/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| EP3532677A1 (en) | 2019-09-04 |
| BR112019007422A2 (pt) | 2019-07-02 |
| EP3532677A4 (en) | 2020-05-27 |
| BR112019007422B1 (pt) | 2023-02-14 |
| CN110073056B (zh) | 2022-05-17 |
| US20200056052A1 (en) | 2020-02-20 |
| CN110073056A (zh) | 2019-07-30 |
| US11242461B2 (en) | 2022-02-08 |
| WO2018081764A1 (en) | 2018-05-03 |
| CO2019002561A2 (es) | 2019-03-29 |
| CL2019003719A1 (es) | 2020-06-12 |
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