CH240000A - Welding electrode and process for its manufacture. - Google Patents
Welding electrode and process for its manufacture.Info
- Publication number
- CH240000A CH240000A CH240000DA CH240000A CH 240000 A CH240000 A CH 240000A CH 240000D A CH240000D A CH 240000DA CH 240000 A CH240000 A CH 240000A
- Authority
- CH
- Switzerland
- Prior art keywords
- aluminum
- welding electrode
- jacket
- binder
- rod
- Prior art date
Links
- 238000003466 welding Methods 0.000 title claims description 15
- 238000000034 method Methods 0.000 title claims description 5
- 238000004519 manufacturing process Methods 0.000 title claims description 3
- 229910052782 aluminium Inorganic materials 0.000 claims description 14
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 14
- 229910052751 metal Inorganic materials 0.000 claims description 9
- 239000002184 metal Substances 0.000 claims description 9
- 229910000838 Al alloy Inorganic materials 0.000 claims description 8
- 239000011230 binding agent Substances 0.000 claims description 7
- 239000000126 substance Substances 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 4
- 239000003638 chemical reducing agent Substances 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 238000007254 oxidation reaction Methods 0.000 claims description 3
- 239000000155 melt Substances 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims description 2
- 239000012255 powdered metal Substances 0.000 claims 2
- 239000007788 liquid Substances 0.000 claims 1
- 230000004907 flux Effects 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 3
- 239000001301 oxygen Substances 0.000 description 3
- 229910052760 oxygen Inorganic materials 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 239000002923 metal particle Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- ACVYVLVWPXVTIT-UHFFFAOYSA-N phosphinic acid Chemical compound O[PH2]=O ACVYVLVWPXVTIT-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 241001275954 Cortinarius caperatus Species 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000001785 acacia senegal l. willd gum Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000005253 cladding Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 238000005476 soldering Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 150000003609 titanium compounds Chemical class 0.000 description 1
- YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/02—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by mechanical features, e.g. shape
- B23K35/0255—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by mechanical features, e.g. shape for use in welding
- B23K35/0261—Rods, electrodes, wires
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
- B23K35/24—Selection of soldering or welding materials proper
- B23K35/28—Selection of soldering or welding materials proper with the principal constituent melting at less than 950 degrees C
- B23K35/286—Al as the principal constituent
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Nonmetallic Welding Materials (AREA)
Description
Schweisselektrode und Verfahren zu deren Herstellung. Es ist bekannt, dass Aluminium eine sehr grosse Affinität für Sauerstoff besitzt. Die ser Umstand bewirkt, dass sich auf der Ober fläche des Metalles sehr leicht eine dünne, resistende Oxydhaut bildet. Diese Oxydhaut bildet einen ausgezeichneten Schutz gegen Korrosion, aber gibt wesentliche Schwierig keiten beim Löten und Schweissen von Alu minium und Aluminiumlegierungen, insbe sondere beim Lichtbogenschweissen. Für das autogene Schweissen von Aluminium und Aluminiumlegierungen wurden bis jetzt mei stens aus demselben Metall bestehende blanke Stäbe benutzt.
Beim elektrischen Schweissen verwendet man oft Elektroden, die mit einem Mantel (Umkleidung) umgeben sind, der hauptsächlich eine desoxydierende Wirkung ausübt und gleichzeitig geeignete Flussmittel enthält. An diese Flussmittel werden beim Schweissen von Aluminium und aluminium reichen Legierungen ziemlich hohe Anforde rungen gestellt.
Sie sollen nämlich ein gutes Lösungsvermögen für Aluminiumoxyd be- sitzen, frei sein von Zusätzen, die die Schweissnaht verunreinigen und die Korro sionsfestigkeit beeinträchtigen, eine gute La gerbeständigkeit aufweisen und bei ihrer Ver wendung in Pulverform gut an den Elektro den haften bezw. leicht mit Wasser zu einem homogenen Brei angerührt werden können, womit die Elektroden und der zu schwei ssende Teil des Werkstückes gut und gleich mässig bestrichen werden können.
Im allgemeinen genügtes daher bis jetzt nicht, nur in den Mantel des Elektroden stabes Fluss- und Reduktionsmittel einzuver leiben, es war vielfach auch erforderlich, das Werkstück selbst unmittelbar vor dem Schweissen mit diesen Stoffen zu bestreichen, wobei noch besonders zu beachtende Mass nahmen empfohlen wurden. Diese Manipu lationen verursachten Zeitverlust und hatten auch andere Nachteile.
Die Erfindung betrifft eine Schweisselek trode mit einem von einem Mantel umgebe nen, aus Aluminium oder Aluminiumlegie- rung bestehenden Elektrodenstab, die ge kennzeichnet ist durch einen Mantel, der pul verförmiges, mindestens Aluminium enthal tendes Metall, z. B. pulverförmiges Alumi nium oder eine pulverförmige Aluminium legierung, in desoxydiertem Zustand und ein Bindemittel enthält, das die Oxydation der Teilchen des pulverförmigen Metalles ver hindert.
Es wurde gefunden, dass das des oxydierte Aluminium bezw. die desoxydierte Aluminiumlegierung infolge der sehr grossen, sauerstofffreien Oberfläche der Metallteilchen bei der hohen Temperatur des Lichtbogens be gierig Sauerstoff anzieht und dadurch die Bildung eines Oxydfilms auf dem Metall in der Schweissnaht und dem Metall des Werk stückes in der Umgebung der Schweissnaht verhindert, so dass eine einwandfreie Schwei ssung erzielt. wird. Die Verwendung einer der artigen Elektrode hat ausserdem den Vorteil, dass es nicht erforderlich ist, das Werkstück selbst mit einem Flussmittel zu bestreichen und das Werkstück einer Vorwärmung zu unterwerfen, wie dies bisher üblich war.
Die Desoxydierung des Aluminiumstaubes bezw. der pulverförmigen Aluminiumlegie rung kann mittels starker Reduktionsmittel, wie z. B. Wasserstoff, unterphosphoriger Säure (H3PO2), Titantrichlorid und derglei- ehen, vorgenommen -,werden. Das in dieser Weise sauerstofffrei gemachte Metallpulver wird zweckmässig sofort mit einem geeigne ten Bindemittel gemischt und auf den Schweissstab aufgebracht, was nach bekann ten Methoden, z. B. durch Tauchen oder Auf walzen, ;geschehen kann. Das Bindemittel be dingt das feste Anhaften der Masse an den Stab und schützt die Teilchen des Metall pulvers gegen vorzeitige Oxydation durch Einwirkung des Luftsauerstoffes.
Das Bindemittel kann teilweise aus an organischen Stoffen bestehen, die vorzugs weise derart gewählt werden, dass sie beim Abschmelzen des Elektrodenstabes sintern, jedoch ein derart niedriges spezifisches Ge wicht haben, dass sie nicht in die Schweiss naht gelangen. Die organischen Substanzen können während des Schweissprozesses ver brennen und dabei eine reduzierende Atmo sphäre liefern. Besonders geeignet für diesen Zweck sind z. B. Gemische von Asbest mit arabischem Gummi oder mit. Tylose.
Erwünschtenfalls kann der Elektroden mantel noch Substanzen enthalten, die einen bestimmten Einfluss auf die Eigenschaften des Metalls haben, z. B. Magnesium-, Man gan-, Kupfer-, Lithium-, Silicium- und Titan verbindungen.
Welding electrode and process for its manufacture. It is known that aluminum has a very high affinity for oxygen. This fact causes a thin, resistant oxide skin to easily form on the surface of the metal. This oxide skin provides excellent protection against corrosion, but there are significant difficulties in soldering and welding aluminum and aluminum alloys, especially in arc welding. For the autogenous welding of aluminum and aluminum alloys, bare rods consisting mostly of the same metal have been used until now.
In electrical welding, electrodes are often used that are surrounded by a jacket (cladding) which mainly has a deoxidizing effect and at the same time contains suitable flux. When welding aluminum and aluminum-rich alloys, these fluxes are subject to fairly high demands.
Namely, they should have a good dissolving power for aluminum oxide, be free of additives that contaminate the weld seam and impair the corrosion resistance, have good storage stability and, when used in powder form, adhere well to the electrodes or. can easily be mixed with water to a homogeneous paste, with which the electrodes and the part of the workpiece to be welded can be coated well and evenly.
In general, it is therefore not sufficient until now to only incorporate flux and reducing agents into the jacket of the electrode rod; in many cases it was also necessary to coat the workpiece with these substances directly before welding, whereby special measures to be observed were recommended . These manipulations caused a loss of time and also had other disadvantages.
The invention relates to a Schweisselek electrode with an electrode rod surrounded by a jacket, made of aluminum or aluminum alloy, which is characterized by a jacket, the powdery metal containing at least aluminum, z. B. powdered aluminum or a powdered aluminum alloy, in the deoxidized state and contains a binder that prevents the oxidation of the particles of the powdery metal ver.
It was found that the oxidized aluminum bezw. The deoxidized aluminum alloy, due to the very large, oxygen-free surface of the metal particles, greedily attracts oxygen at the high temperature of the arc, thereby preventing the formation of an oxide film on the metal in the weld seam and the metal of the workpiece in the vicinity of the weld seam, so that a flawless weld achieved. becomes. The use of such an electrode also has the advantage that it is not necessary to coat the workpiece itself with a flux and to subject the workpiece to preheating, as was customary up to now.
The deoxidation of aluminum dust respectively. the powdery aluminum alloy tion can by means of strong reducing agents such. B. hydrogen, hypophosphorous acid (H3PO2), titanium trichloride and the like, made - are. The metal powder made oxygen-free in this way is expediently immediately mixed with a suitable th binder and applied to the welding rod, which after well-known methods such. B. by dipping or rolling on, can happen. The binding agent causes the mass to adhere firmly to the rod and protects the particles of the metal powder against premature oxidation due to the action of atmospheric oxygen.
The binder can partly consist of organic substances, which are preferably chosen such that they sinter when the electrode rod melts, but have such a low specific weight that they do not get into the weld seam. The organic substances can burn during the welding process and create a reducing atmosphere. Particularly suitable for this purpose are, for. B. Mixtures of asbestos with or with arabic gum. Gypsies.
If desired, the electrode coat can also contain substances that have a certain influence on the properties of the metal, eg. B. Magnesium, Mangan, copper, lithium, silicon and titanium compounds.
Claims (1)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL240000X | 1944-02-04 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CH240000A true CH240000A (en) | 1945-11-30 |
Family
ID=19780484
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH240000D CH240000A (en) | 1944-02-04 | 1944-03-06 | Welding electrode and process for its manufacture. |
Country Status (1)
| Country | Link |
|---|---|
| CH (1) | CH240000A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102006003191A1 (en) * | 2006-01-24 | 2007-11-15 | Airbus Deutschland Gmbh | Additional material in particular for improving the quality of a joining seam formed during the thermal joining of two metallic components |
-
1944
- 1944-03-06 CH CH240000D patent/CH240000A/en unknown
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102006003191A1 (en) * | 2006-01-24 | 2007-11-15 | Airbus Deutschland Gmbh | Additional material in particular for improving the quality of a joining seam formed during the thermal joining of two metallic components |
| DE102006003191B4 (en) * | 2006-01-24 | 2011-03-17 | Airbus Operations Gmbh | Additional material for the thermal joining of two metallic components and a corresponding use of a filler material |
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