CH146865A - Process for the preparation of a complex compound containing phosphorus, tungsten and molybdenum. - Google Patents
Process for the preparation of a complex compound containing phosphorus, tungsten and molybdenum.Info
- Publication number
- CH146865A CH146865A CH146865DA CH146865A CH 146865 A CH146865 A CH 146865A CH 146865D A CH146865D A CH 146865DA CH 146865 A CH146865 A CH 146865A
- Authority
- CH
- Switzerland
- Prior art keywords
- molybdenum
- compound containing
- tungsten
- complex compound
- preparation
- Prior art date
Links
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 title claims description 6
- 150000001875 compounds Chemical class 0.000 title claims description 6
- 229910052698 phosphorus Inorganic materials 0.000 title claims description 6
- 239000011574 phosphorus Substances 0.000 title claims description 6
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 title claims description 4
- 229910052750 molybdenum Inorganic materials 0.000 title claims description 4
- 239000011733 molybdenum Substances 0.000 title claims description 4
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 title claims description 3
- 229910052721 tungsten Inorganic materials 0.000 title claims description 3
- 239000010937 tungsten Substances 0.000 title claims description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 4
- 150000003839 salts Chemical class 0.000 claims description 4
- 229910019142 PO4 Inorganic materials 0.000 claims description 3
- 239000007795 chemical reaction product Substances 0.000 claims description 3
- 239000000975 dye Substances 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- MEFBJEMVZONFCJ-UHFFFAOYSA-N molybdate Chemical compound [O-][Mo]([O-])(=O)=O MEFBJEMVZONFCJ-UHFFFAOYSA-N 0.000 claims description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 3
- 239000010452 phosphate Substances 0.000 claims description 3
- 230000002378 acidificating effect Effects 0.000 claims description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 2
- 239000004922 lacquer Substances 0.000 claims description 2
- VLAPMBHFAWRUQP-UHFFFAOYSA-L molybdic acid Chemical compound O[Mo](O)(=O)=O VLAPMBHFAWRUQP-UHFFFAOYSA-L 0.000 claims description 2
- CMPGARWFYBADJI-UHFFFAOYSA-L tungstic acid Chemical compound O[W](O)(=O)=O CMPGARWFYBADJI-UHFFFAOYSA-L 0.000 claims description 2
- 239000002966 varnish Substances 0.000 claims description 2
- ODYQTICKLUOBBB-UHFFFAOYSA-N 3,4,5-trimethyl-6-(2-methylbenzenecarboximidoyl)benzene-1,2-diamine Chemical compound CC1=CC=CC=C1C(=N)C1=C(C)C(C)=C(C)C(N)=C1N ODYQTICKLUOBBB-UHFFFAOYSA-N 0.000 claims 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical class Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 description 2
- 229940010552 ammonium molybdate Drugs 0.000 description 2
- 235000018660 ammonium molybdate Nutrition 0.000 description 2
- 239000011609 ammonium molybdate Substances 0.000 description 2
- PBYZMCDFOULPGH-UHFFFAOYSA-N tungstate Chemical compound [O-][W]([O-])(=O)=O PBYZMCDFOULPGH-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- VSOYJNRFGMJBAV-UHFFFAOYSA-N N.[Mo+4] Chemical compound N.[Mo+4] VSOYJNRFGMJBAV-UHFFFAOYSA-N 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- NNBFNNNWANBMTI-UHFFFAOYSA-M brilliant green Chemical compound OS([O-])(=O)=O.C1=CC(N(CC)CC)=CC=C1C(C=1C=CC=CC=1)=C1C=CC(=[N+](CC)CC)C=C1 NNBFNNNWANBMTI-UHFFFAOYSA-M 0.000 description 1
- GRWZHXKQBITJKP-UHFFFAOYSA-L dithionite(2-) Chemical compound [O-]S(=O)S([O-])=O GRWZHXKQBITJKP-UHFFFAOYSA-L 0.000 description 1
- GRWZHXKQBITJKP-UHFFFAOYSA-N dithionous acid Chemical compound OS(=O)S(O)=O GRWZHXKQBITJKP-UHFFFAOYSA-N 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- IYDGMDWEHDFVQI-UHFFFAOYSA-N phosphoric acid;trioxotungsten Chemical compound O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.O=[W](=O)=O.OP(O)(O)=O IYDGMDWEHDFVQI-UHFFFAOYSA-N 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- 125000003698 tetramethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
Landscapes
- Inorganic Compounds Of Heavy Metals (AREA)
- Paints Or Removers (AREA)
Description
Verfahren zur Herstellung einer komplexen Phosphor, Wolfrain und 31olybdäli enthaltenden Verbindung. Es wurde gefunden, dass man eine wert volle, komplexe Phosphor, Wolfram und Molybdän enthaltende Verbindung erhalten kann, wenn man ein Gemisch der Farbstoffe, Salz des Tetrainethyldiaiiii nobenzophenonimids von der Formel
EMI0001.0007
und Salz des Teti,a-äthyl-di-p-amino-triphenyl- karbinols von der Formel
EMI0001.0010
mit einem Phosphat,
einem Phosphorwol frainat und einem reduzierten Molybdat behandelt, derart, dass die basischen Reste des Phos phates, Phosphorwolframates und des redu zierten l#lolybdate8, sowie die sauren Reste der Farbstoffbasen nicht in das Endprodukt eintreten, sondern in Lösung bleiben.
Das Endprodukt ist ein bisher nicht bekannter Farblack der Verbindungen von Tetramethyldiaminobeiizoplieiioniniids und Tetraäthyl-di-p-amiriotriplieiiylkat-biiiol mit Resten der Phosphorsäure, Wolframsäure und Molybdäiisäure und eine leuchtende, gelblich- grüne Nüance von grosser Brillanz und vor züglicher Echtheit besitzt.
<I>Beispiel:</I> 4,2 Teile salzsaures Salz des Tetramethyl- diaminoberizopheimoiiimids (Aurainin O# Farb- stofftabellen Schultz-Julius <B>1923,</B> Nr. 493) und 2,4 Teile Sulfat des Teti#aäthyl-di-p-aiiiitio- triphenylkarbitiols (Diamantgrün <B>G),</B> Schultz- Julius<B>1923,</B> Nr. 499 werden in Wasser<B>1: 100</B> gelöst.
Zu dieser Lösung gibt man nachein ander 5,2 Teile reduziertes molybdänsaures Ammonium,<B>1:</B> 20 gelöst (hergestellt durch Reduktion von Ammoniummolybdat mit Hydro- sulfit) <B>0,8</B> Gewichtsteile Natriumphosphat (Na2 HP04 +12 aq), <B>1: 10</B> gelöst,<B>10</B> Gewichts teile phosphorwolframsaures Natrium,<B>1:10</B> gelöst ferner 4 Volumteile Salzsäure von 20' Bä. im Verhältnis<B>1: 1</B> mit Wasser verdünnt.
Man kocht auf und isoliert den entstehenden Farblack in der üblichen Weise.
Das erwähnte reduzierte molybdänsaure Ammonium kann zum Beispiel in der folgen den Weise gewonnen werden<B>-</B> Zu<B>50</B> Gewichtsteilen Ammoniummolybdat, <B>1: 10</B> gelöst, werden bei Zimmertemperatur <B>2,5</B> Gewichtsteile Hydrosulfit als Pulver ge geben. Man lässt das Gemisch 1/2 Stunde lang stehen, bringt dann langsam zum Kochen, kocht etwa '/2 Stunde lang, bis der Geruch nach Schwefelwasserstoff verschwunden ist und stellt diese Lösung auf<B>1000</B> Volum- teile ein.
Process for the preparation of a complex compound containing phosphorus, Wolfrain and 31olybdali. It has been found that a valuable, complex compound containing phosphorus, tungsten and molybdenum can be obtained if a mixture of the dyes, salt of Tetrainethyldiaiiii nobenzophenonimids of the formula
EMI0001.0007
and salt of teti, a-ethyl-di-p-amino-triphenylcarbinol of the formula
EMI0001.0010
with a phosphate,
treated with a phosphorus tungstate and a reduced molybdate in such a way that the basic residues of the phosphate, phosphorus tungstate and the reduced l # lolybdate8, as well as the acidic residues of the dye bases do not enter the end product, but remain in solution.
The end product is a hitherto unknown color varnish of the compounds of tetramethyldiaminobeiizoplieiioniniids and tetraethyl-di-p-amiriotriplieiiylkat-biiiol with residues of phosphoric acid, tungstic acid and molybdic acid and a bright, yellowish-green shade of great brilliance and excellent authenticity.
<I> Example: </I> 4.2 parts of hydrochloric acid salt of tetramethyl diaminoberizopheimoiiimids (Aurainin O # color table Schultz-Julius <B> 1923, </B> No. 493) and 2.4 parts of sulfate of Teti # aäthyl-di-p-aiiiitio- triphenylcarbitiols (diamond green <B> G), </B> Schultz-Julius <B> 1923, </B> No. 499 are in water <B> 1: 100 </B> solved.
To this solution are added 5.2 parts of reduced ammonium molybdenum, <B> 1: </B> 20 dissolved (produced by reducing ammonium molybdate with hydrosulfite) <B> 0.8 </B> parts by weight of sodium phosphate ( Na2 HP04 +12 aq), <B> 1:10 </B> dissolved, <B> 10 </B> parts by weight of sodium phosphotungstic acid, <B> 1:10 </B> also dissolved 4 parts by volume of hydrochloric acid of 20 ' Bä. Diluted with water in a ratio of <B> 1: 1 </B>.
It is boiled and the resulting colored lacquer is isolated in the usual way.
The aforementioned reduced molybdenum acid ammonium can be obtained, for example, in the following manner <B> - </B> To <B> 50 </B> parts by weight of ammonium molybdate, <B> 1:10 </B>, are dissolved at room temperature Give <B> 2.5 </B> parts by weight of hydrosulphite as a powder. The mixture is left to stand for 1/2 hour, then slowly brought to the boil, boiled for about 1/2 hour until the smell of hydrogen sulfide has disappeared and this solution is adjusted to <B> 1000 </B> parts by volume.
Claims (1)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE146865X | 1927-11-14 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CH146865A true CH146865A (en) | 1931-05-15 |
Family
ID=5671625
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CH146865D CH146865A (en) | 1927-11-14 | 1928-11-10 | Process for the preparation of a complex compound containing phosphorus, tungsten and molybdenum. |
Country Status (1)
| Country | Link |
|---|---|
| CH (1) | CH146865A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2825673A (en) * | 1954-04-27 | 1958-03-04 | Josef Troxler | Thermal insulating covering for a pipe |
-
1928
- 1928-11-10 CH CH146865D patent/CH146865A/en unknown
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2825673A (en) * | 1954-04-27 | 1958-03-04 | Josef Troxler | Thermal insulating covering for a pipe |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CH146865A (en) | Process for the preparation of a complex compound containing phosphorus, tungsten and molybdenum. | |
| DE1644534A1 (en) | Anthraquinone dye and process for its preparation | |
| AT115045B (en) | Process for the production of complex tungsten and molybdenum compounds. | |
| DE523464C (en) | Process for the production of colored lakes | |
| DE508811C (en) | Process for the preparation of yellow monoazo dyes | |
| DE179020C (en) | ||
| CH132487A (en) | Process for the preparation of a phosphotungsten molybdenum compound. | |
| AT135676B (en) | Process for the production of lightfast chrome yellow. | |
| DE518214C (en) | Process for the preparation of 1-oxy-4-halogenanthraquinone-2-sulfonic acids | |
| DE488199C (en) | Process for the production of colored lacquers | |
| DE2417253C2 (en) | Liquid dye preparations of a reactive dye | |
| DE544998C (en) | Process for the preparation of mixed halogenated dyes of the 4íñ5íñ8íñ9-dibenzpyrenquinone series | |
| CH126124A (en) | Process for the representation of a colored lacquer. | |
| CH141868A (en) | Process for the preparation of a complex compound containing phosphorus, tungsten and molybdenum. | |
| DE423319C (en) | Process for the production of easily soluble blue-green dyes | |
| AT136364B (en) | Process for the production of chromium-containing dyes. | |
| CH215063A (en) | Process for the production of a copper-containing trisazo dye. | |
| CH128372A (en) | Process for the representation of a colored lacquer. | |
| CH184484A (en) | Process for the preparation of an azo dye. | |
| CH157339A (en) | Process for the preparation of the sulfamic acid of 2-aminoanthrahydroquinone-9.10-disulfuric acid ester. | |
| CH154032A (en) | Process for the preparation of a disazo dye. | |
| CH122907A (en) | Process for the preparation of a developer dye. | |
| CH154036A (en) | Process for the preparation of a disazo dye. | |
| CH127453A (en) | Process for the production of a colored lacquer. | |
| CH128374A (en) | Process for the representation of a colored lacquer. |