CA3121954C - Immersion nozzle - Google Patents
Immersion nozzleInfo
- Publication number
- CA3121954C CA3121954C CA3121954A CA3121954A CA3121954C CA 3121954 C CA3121954 C CA 3121954C CA 3121954 A CA3121954 A CA 3121954A CA 3121954 A CA3121954 A CA 3121954A CA 3121954 C CA3121954 C CA 3121954C
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- Canada
- Prior art keywords
- lateral protrusions
- pair
- lateral
- immersion nozzle
- protrusions
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/04—Continuous casting of metals, i.e. casting in indefinite lengths into open-ended moulds
- B22D11/0408—Moulds for casting thin slabs
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/10—Supplying or treating molten metal
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D41/00—Casting melt-holding vessels, e.g. ladles, tundishes, cups or the like
- B22D41/50—Pouring-nozzles
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Continuous Casting (AREA)
- Casting Support Devices, Ladles, And Melt Control Thereby (AREA)
Abstract
It is intended to provide a flat immersion nozzle capable of stabilizing a molten steel discharge flow to stabilize an in-mold bath surface, i.e., reduce the fluctuation of the in-mold bath surface. Provided is an immersion nozzle having a flat portion whose inner bore has a thickness Tn and a width Wn greater than the thickness Tn, wherein two lateral protrusions 1 each protruding in a thickness direction are provided on each of opposed walls of the flat portion extending in a width direction. The lateral protrusions 1 are arranged at axial symmetrical positions with respect to a longitudinal central axis of the width-directionally extending walls, in pairs, such that each of them extends obliquely downwardly in the width direction, wherein two pairs of the lateral protrusions are arranged, respectively, on the opposed width-directionally extending walls, in opposed relation.
Description
DESCRIPTION TITLE OF INVENTION Immersion nozzle TECHNICALFIELD
[0001] The present invention relates to an immersion nozzle for use in continuous casting to pour molten steel from tundish into a mold,and more particularly to an immersion nozzle,such as those used for continuous casting of a thin slab, a medium-thick slab or the like, which is flat in terms of transverse cross-section (cross-section in a direction perpendicular to a vertical direction) near a dischargeport of the immersion nozzle. BACKGROUNDART
[0002] In a continuous casting process for forming a slab having a given shape by continuously subjecting molten steel to cooling and solidification, molten steel is poured into a mold via an immersion nozzle for continuous casting (hereinafter also referred to simply as "immersion nozzle") installed with respect to the bottom of a tundish.
[0003] Generally, theimmersion nozzleis composed of a bottomed tubular body which has an upper end serving as an inlet of molten steel, and a molten steel flow passage (inner bore) internally formed to extend downwardly from the molten steel inlet, wherein a pair of discharge ports communicated with the molten steel flow passage (inner bore) are formed in a lateral wall of a lower portion of the tubular body in opposed relation to each other. The immersion nozzle is used in a state in which the lower portion thereof is immersed in molten steel in a mold. This is intended to prevent scattering of poured molten steel, and further block contact of the molten steel with the atmosphere, thereby preventing oxidation thereof. Further, the use of the immersion nozzle is intended to allow the flow of molten steel in the mold to be straightened, thereby preventing impurities such as slag or non-metal inclusions floating on the surface of the molten - 1- Date Re$ue/Date Received 2021*06-02CA 03121954 2021-06-02 steel from being entrained into the molten steel.
[0004] In recent years, there has been a growing tendency toward manufacturing thinned slabs such as a thin slab and a medium-thick slab during continuous casting. In order to cope with a thin mold for this type of continuous casting, the immersion nozzle needs to be flattened. For example, the below-mentioned Patent Document 1 discloses a flat immersion nozzle in which a discharge port is provided in a short-side lateral wall; and in the below-incntioncd Patent Document 2 discloses a flat immersion nozzle in which a discharge port is further provided in a lower end wall. Generally, such a flat immersion nozzle is configured such that the width of an inner bore thereof is increased between a molten steel inlet thereof and the discharge port in a direction from the molten steel inlet toward a mold.
[0005] However, when the inner bore has a region where it is increased in terms of width, and flattened, the flow of molten steel inside the immersion nozzle becomes more likely to be disordered, and thusa dischargeflow toward the mold also becomes more likely tobe disordered. Resulting turbulence of the molten steel flow becomes a factor causing defective quality of slabs, an increase indanger during casting operation, etc.,suchasan increasein fluctuation of thesurface of (molten steel) bath in the mold (in-mold bath surface), entrainment of a mold powder into a slab, or unevenness in temperature. Therefore, it is necessary to stabilize a molten steel flow inside the immersion nozzle anda molten steel flow during discharge.
[0006] With a view to stabilizing the above molten steel flows, for example, the bdow-mentioned Patent Document 3 discloses an immersion nozzle formed with at least two bending facets extending from a point (center) on a plane in a lower region of an inner bore toward a lower edge of a discharge port. The Patent [Document 3 also discloses an immersion nozzle comprising a flow divider for dividing a molten steel flow into two streams. In the flat immersion nozzle disclosed in the Patent Document 3, the stability of the molten steel flow inside the immersion nozzle are enhanced, as compared with the immersion nozzles disclosed in the Patent Documents 1 and 2, in which there is not any means to change a flow direction/pattem in an internal space thereof. [0007] -2- Date Re?ue/Date Received 2021-06-02CA 03121954 2021-06-02 However the means to divide the molten steel flow in a right-left direction is still likely to cause a situation where die fluctuation of die molten steel discharge flow between right and left discharge posts is increased, and thereby the fluctuation of the in-mold bath surface is increased.
[0008] Under die above background, die present inventors have invented a flat immersion nozzle disclosed in die below-mentioned Patent Document 4, thereby contributing to stabilizing an in¬ mold bath surface, etc. CITATION LIST |PatentDocument]
[0009] Patent Document 1: JP-A Hl1-005145 Patent Document 2: JP-AHl1-047897 Patent Document 3: JP-A2001-501132 Patent Document 4: WO-A 2017/081934 SUMMARYOF INVENTION [Technical Problem]
[0010] However, the present inventors hasfound that,in continuous casting earned out under casting conditions, particularly, a condition of a molten steel flow rate of about 0.04 (t / (min*cm2)) or more, as measured with reference to the position of minimum cross-sectional area in a region around an upper end of1he immersion nozzle wherea transverse cross-section ofdie inner bore is a circular shape, even die flat immersion nozzle disclosed in the Patent Document 4 is still insufficient in terms of the intended effects such as stabilization of an in-mold bath surfice.
[0011] Therefore, a problem to be solved by the present invention is to provide a flat immersion nozzle capable of stabilizing an in-mold bath surfice, i.e., reducing die fluctuation of the in-mold bath surface. [Solution to Technical Problem] [0012] -3- Date Re$ue/Date Received 2021-06-02In the flat immersion nozzle disclosed in the Patent Document 4, primarily, a protrusion (protruding portion) is provided in a central region of an inner bore (inner hole) of the nozzle, as a basic configuration, and optionally a protrusion having a protruding thickness equal to or less than that of the central protrusion is provide beside the central protrusion to finely adjust a discharge flow direction, a discharge flow/pattem, or the like. Differently, in the present invention, symmetrical lateral (laterally-offset) protrusions are provided, wherein a space having no protrusion is defined between the lateral protrusions, as a basic configuration, and optionally a protrusion having a protruding length less than that of each of the lateral protrusion is provided.
[0013] In the structure of the flat immersion nozzle disclosed in the Patent Document 4, the molten steel flow inside the inner bore is guided such that the flow rate thereof becomes laiger in a lateral direction (which means a width direction of a flat portion of the nozzle, this is also applied to the following description) than in a central and vertically downward direction. In this case, the flow velocity of molten steel discharged from the discharge port tends to be increased, and, under the condition that a molten steel flow rate per unit time or per unit area is relatively large, the fluctuation of the in-mold bath surface is likely to be increased. Differently, in the structure of the flat immersion nozzle of the present invention, the molten steel flow inside the inner bore is guided, while being adjusted to increase the flow rate thereof in the central and vertically downward direction, thereby relatively reducing the flow rate thereof in the lateral direction. In other words, the ratio of the flow rate in the central and vertically downward direction / the flow rate in the lateral direction is relatively increased as compared with that in the structure of the flat immersion nozzle disclosed in the Patent Document 4. It should be noted here that the above adjustment is made in relation to the ratio of the flow rate in the central and vertically downward direction / the flow rate in the lateral direction, but is not necessarily made to establish the relationship of the central and vertically downward direction > the flow rate in the lateral direction.
[0014] The present invention intended to obtain the above flow pattern provides a flat immersion nozzle having features described in the following sections 1 to 8. 1. An immersion nozzle having a flat portion whose inner bore has a thickness (Tn) and a width 4 Date Re^ue/Date Received 2023-09-18(Wn) greater than the thickness (Tn), and which comprises opposed short-side lateral walls, and a first opposed long-side wall and a second opposed long-side wall extending in a width direction of the flat portion, wherein a pair of discharge ports are provided, respectively, in lower parts of the short-side lateral walls, the immersion nozzle comprising: a first pair of lateral protrusions provided on the first opposed long-side wall,and arranged at axial symmetrical positions with respect to a longitudinal central axis of the first opposed longside wall and a second pair of lateral protrusions provided on the second opposed long-side wall, and arrangedat axial symmetrical positions with respect to a longitudinal central axis of the second opposed long-side wall, each of the first pair of lateral protrusions and the second pair of lateral protrusions extending obliquely downwardly in the width direction and protruding in a thickness direction of the flat portion, wherein lateral protrusions of the first pair of lateral protrusions and lateral protrusions of the second pair of lateral protrusions are each spaced apart from each other in the width direction, wherein the first pair of lateral protrusions are arranged on the first opposed long-side wall and the second pair of lateral protrusions are arranged on the second opposed long-side wall in opposed relation, and wherein two sets of opposed lateral protrusions in the first pair of lateral protrusions and the second pair of lateral protrusions have a same value falling within a range of 0.18 to 0.90 in terms of a total protruding length (Ts) in the thickness direction, expressed as an index on the basis of 1 indicative of a thickness of the inner bore at a position where the two sets of opposed lateral protrusions are provided; and wherein a center region is defined by a region extending in the width direction between inner¬ most comers of center-side ends of thefirst pair of lateral protrusions and the second pair of lateral protrusions, extending in the thickness direction between side walls of the inner bore, and extending a length of the immersion nozzle in a longitudinal direction, wherein the center region does not have a continuous protrusion with a protruding length in the thickness direction that is equal to or greater than that of the first pair of lateral protrusions on the first opposed long-side wall and the second pair of lateral protrusions on the second opposed long-side wall. 2.The immersion nozzle as in section 1, which further comprises a first center protrusion provided on the first opposed long-side wall at a position between the lateral protrusions of the first pair of 5 Date Re^ue/Date Received 2023-09-18lateral protrusions and a second central protrusion provided on the second opposed long-side wall at a position between the lateral protrusions of the second pair of lateral protrusions, wherein the first central protrusion and the second central protrusion have a thickness¬ directional protruding length that is less than that of the lateral protrusions of the first pair of lateral protrusions and the lateral protrusions of the second pair of lateral protrusions, respectively, and wherein the first central protrusion and the second central protrusion have a value of less than 0.40 in terms of a total protruding length (Tp) in the thickness-direction, expressed as an index on the basis of1indicative of the thickness of the inner bore at the position where the opposed lateral protrusions are provided. 3. The immersion nozzle as in section 2, wherein an upper end surface of thefirst central protrusion and the second central protrusion have a shape selected from the group consisting of a shape extending horizontally in the width direction, a curved shape having a top at a midpoint thereof, and an upwardly protruding shape including a bending point. 4. The immersion nozzle as in section 2, wherein an upper end surface of at least one of: - the lateral protrusions of the first pair of lateral protrusions and the lateral protrusions of the second pair of lateral protrusions; and - the first central protrusion and the second central protrusion have a shape extending horizontally in a direction toward a center of the inner bore, a planar shape extending obliquely downwardly in the direction toward the center of the inner bore, or a curved shape extending obliquely downwardly in the direction toward the center of the inner bore. 5. The immersion nozzle as in any one of sections 2 to 4, wherein at least one of: - the lateral protrusions of the first pair of lateral protrusions and the lateral protrusions of the second pair of lateral protrusions; and - the first central protrusion and the second central protrusion; have a shape in which the thickness-directional protruding length thereof is constant, or becomes shorter linearly, curvilinearly or stepwisely in a direction toward a center of the first opposed long-side wall or the second opposed long-side wall. 6 Date Re^ue/Date Received 2023-09-186. The immersion nozzle as in any one of sections 2 to 5, wherein one of: - the lateral protrusions of the first pair of lateral protrusions and the lateral protrusions of the second pair of lateral protrusions; and - the lateral protrusions of the first pair of lateral protrusions combined with the first central protrusion and the lateral protrusions of the second pair of lateral protrusions combined with the second central protrusion is provided plurally in an up-down direction. 7. The immersion nozzle as in any one of sections 1 to 6, which comprises a protrusion provided around a center of a bottom of the inner bore to protrude upwardly. 8. The immersion nozzle as in any one of sections 1 to 7, which is used for continuous casting carried out under conditions including a molten steel flow rate of 0.04 (t / (min-cm2)) or more, as measured with reference to a position of minimumcross-sectional area in aregion around an upper end of the immersion nozzle where a transverse cross-section of the inner bore hasacircular shape.
[0015] In the present invention, the terms "width Wn" and "thickness Tn" of the inner bore means, respectively, a width (length in a long-side direction) and a thickness (length in a short-side direction) at positions of upper ends of the pair of discharge ports provided in the short-side lateral wall of the immersion nozzle. [Effect of Invention]
[0016] The flat immersion nozzle of the present invention can control a molten steel flow to gradually increase/reduce the flow rate thereof in a continuous manner, without fixedly or completely separating the direction of the molten steel flow over the range from a central region to a lateral region inside the immersion nozzle, thereby ensuring an appropriate balance of molten steel flows within the immersion nozzle. Thus, even in continuous casting carried out under casting conditions, particularly, a condition of a molten steel flow rate of about 0.04(t I (min-cm2)) or more, as measured with reference to the position of minimum cross-sectional area in a region around an upper end of the immersion nozzle where a transverse cross-section of the inner bore is a circular shape, wherein the continuous casting tends to cause a situation where a high-speed or - 6a - Date Re^ue/Date Received 2023-09-18high-volume molten steel flow is generated on the side of each of the lateral discharge ports, it Date Re^ue/Date Received 2023-09-18CA 03121954 2021-06-02 discharged from the discharge ports to stabilize the in-mold bath surface or the like, i.e., reduce the fluctuation of the in-mold bath surface or the like. Then, since the fluctuation of the in-mold bath surface is suppressed, it becomes possible to reduce entrainment of a mold powder or the like into the mold,and promote floating of in-molten steelinclusions, thereby improving quality ofslabs. Further,since an excessivemoltensteel flow toward lateral walls of the mold is suppressed, it becomes possible to reduce a risk of the occurrence of accident such as breakout. BRIEF DESCRIPTION OF DRAWINGS
[0017] FIG. 1is a conceptual diagram showing an example of an immersion nozzle of the present invention (an immersion nozzle according to a first embodiment of the present invention), which is provided with two pairs of lateral protrusions, wherein FIG. 1(a) is a schematic sectional view taken along a vertical plane passing through the center of a short side of a flat portion of the immersion nozzle,and FIG. 1(b)is a schematic sectional view taken along a vertical plane passing through the center of a long side of theflat portion (taken along the line A-Ain FIG. 1(a)). FIG. 2 is a conceptual diagram showing another example of the immersion nozzle of the present invention (an immersion nozzle according to a second embodiment of the present invention), which is provided with the two pairs of lateral protrusions (lower lateral protrusions) in FIG. 1 and two pairs of upper lateral protrusions each at a position on the upper side of a respective one of the two pairs of lower lateral protrusions, wherein FIG. 2(a) is a schematic sectional view taken along a vertical plane passing through the center of a short side of a flat portion of theimmersion nozzle,and FIG. 2(b) is a schematic sectionalview takenalongavertical planepassingthrough the center of along side of the flat portion (taken along the lineA-Ain FIG. 2(a)). FIG. 3isa conceptual diagram showing yet another example of the immersion nozzle of the presentinvention (an immersion nozzleaccordingto a third embodiment of the present invention), which is provided with the two pairs of lateral protrusions in FIG, 1 and two central protrusions each at a position between a respective one of the two pairs of lateral protrusions, wherein FIG. 3(a) isa schematicsectional view taken along a vertical plane passing through the centerof a short side of a flat portion of the immersion nozzle, and FIG. 3(b) is a schematic sectional view taken along a vertical plane passing through the center of a long side of theflat portion (taken along die -7- Date Re?ue/Date Received 2021-06-02CA 03121954 2021-06-02 line A-A in FIG. 3(a)). FIG. 4isa conceptual diagram showing still another example of the immersion nozzle of the present invention (an immersion nozzle according to a fourth embodiment of the present inventian), which is provided with the two pairs of lateral protrusions (lower lateral protrusions) and dietwocentral protrusionsinFIG.3andtwo pair of upperlateralprotrusions each ata position on the upper side of a respective one of the pair of lower lateral protrusions, wherein FIG. 4(a) is a schematicsectional view taken along a vertical plane passing through the center of a short side of a flat portion ofdie immersion nozzle, and FIG. 4(b) is a schematic sectional view taken along a vertical plane passing through the center of a long side of the flat portion (taken along the line A-Ain FIG.4(a)). FIG. 5isa schematic sectional view taken along thevertical plane passing through the center of the short side in FIG. 3 or 4, enlargedly showing a region where the central protrusion is provided between the pair of lateral protrusions, wherein a central part of the central protrusion is convexed upwardly to form a linear reverse-V or chevron shape, and a central part of a bottom protrusion isconvexed upwardly to form a linear reverse-V or chevron shape. FIG. 6 is a schematic top view of an inner bore of the immersion nozzle in FIG. 5, showing arelationshipbetween a set of opposedlateralprotrusionsandaset of opposed central protrusions. FIG. 7is a schematic sectional view taken along a vertical plane passing through the center of a short side of a flat portion of a modification of the immersion nozzle in FIG. 5, wherein an upper end ofdie central protrusion lias a curved surface FIG. 8 is a schematic sectional view taken along a vertical plane passing through die center of a short side of a flat portion of a modification of the immersion nozzle in FIG. 5, wherein die upper end ofdie central protrusion Im a flat surface FIG. 9is a schematic sectional view taken along a vertical plane passing through the center of a long side of a flat portion of a modification of the immersion nozzle in FIG. 3 or 4, wherein an upper surface ofdie lateral protrusion ordie central protrusion is configured to extend obliquely downwardly in a direction toward thecenter of the inner bore. FIG. 10 is a schematic top view showing a modification of the immersion nozzle in FIG. 5, where the protruding length of the upper surface of each of the lateral protrusion and the central protrusion is constant (an inner bore-side edge of each of the lateral protrusion and the central protrusion is parallel to an width-directionally extending wall of the flat portion. -8- Date Re5ue/Date Received 2021-06-02CA 03121954 2021-06-02 FIG. 11 is a schematic top view showing a modification of the immersion nozzle in FIG. 5, wherethe protrudinglength of the upper surface of the centra] protrusion islinearly reduced toward a central region of the width-directionally extending wall. FIG. 12 is a schematic top view showing a modification of the immersion nozzle in FIG. 5, where the protruding length of the upper surface of the central protrusion is curvilinearly reduced toward the central region of the width-directionally extending wall. FIG. 13 is a schematic top view showing a modification of the immersion nozzle in FIG. 5, wheredie protruding length ofdieupper surfaces ofthe lateral protrusion andthe central protrusion islinearly and continuously reduced toward die central region of the width-directionally extending wall. FIG. 14is a schematic sectional view taken along a vertical plane passing through the center of a short side of a flat portion of a modification of the immersion nozzle in FIG. 5, where the bottom protrusion has aflat upper surface. FIG. 15is a schematic sectional view taken along a vertical plane passing through die center of a short side of a flat portion of a modification of the immersion nozzle in FIG. 5, where the bottom protrusion has a curved upper surface. FIG. 16is a schematic sectional view taken along a vertical plane passing through die center of a short side of a flat portion of a modification of the immersion nozzle in FIG. 5, where the bottom protrusion is formed such that an upper surface thereof has a convex part on a central region thereof, anddie diameter thereof gradually increases toward die bottom of die inner bore. FIG. 17is a schematic sectional view taken along a vertical plane passing through die center of a short side of a flat portion of a modification of the immersion nozzle in FIG. 5, where die bottom protrusion is also provided with a molten steel discharge port FIG. 18 is a conceptual diagram showing a mold and the fluctuation of an in-mold bath surface (molten steel surface), wherein FIG. 18(a)isa schematic top view of the vicinity of a bath surface (inner surface) of a mold, and FIG. 18(b) is a schematic sectional view (one half in a longitudinal direction) of die vicinity of the bath surface (inner surface) of the mold, taken along a vertical plane passing through the center of a short side of the mold. FIG. 19is a graph showing the fluctuation (maximum value, average ofright and left regions) of the in-mold bath surface (molten steel surface) in Inventive Example 3 in Table1. -9- Date Reyue/Date Received 2021-06-02CA 03121954 2021-06-02 DESCRIPTION OF EMBODIMENTS
[0018] Molten steel flows toward width-directional ends can be formed to a certain degree by providing the flow dividing means as disclosed in the aforementioned Patent Document 3. However, such fixed and complete flow dividing is likely to generate molten steel flows separated in each region, i.e., in each small area, of an inner bore, leading to a situation where the flow direction and the flow velocity vary in each position of the inner bore. Particularly, when the flow direction or the flow rate changesduetomolten steel flow rate control or thelike, significant turbulence is likely to occur in a discharge flow from the inside of an immersion nozzle into a mold,a bath surface, etc.
[0019] Therefore, in the present invention, for example, as shown in a first embodiment thereof illustrated inFIG.1, a pair of lateral protrusions 1are first provided on one of opposed (long-side) walls extending in a width direction of a flat portion of an immersion nozzle 10, axially symmetrically with respect to a central axis of the width-directionally extending wall (see FIG. 1(a), etc.; the pair of lateral protrusions will hereinafter be also referred to simply as "axial symmetrical lateral protrusions"). Each of the pair of lateral protrusions 1 is configured such that an upper surface thereof is extends from a center-side end of the lateral protrusions 1 obliquely downwardly in the width direction of the flat portion, i.e., obliquely downwardly toward a respective one of a pair of discharge ports 4. Such an indined surface makes it possible to gently change the flow velocity and flow pattern of molten steel from the inside of an inner bore 3 or the discharge port 4, while suppressing the occurrence of a vortex flow or the like, thereby optimizing the flow velocity and flow pattern of the molten steel.
[0020] The pair of axial symmetrical lateral protrusions are also provided on the other width* directionally extending wall across the inner bore, in plane-symmetrical relation with respect to a thickness direction of the flat portion (see FIG. 1(b); each of two sets of the lateral protrusions arranged in plane-symmetrical relation will hereinafter be also referred to simply as "planesymmetrical lateral protrusions"). In the present invention, for example, as shown in FIG. 6,the total length Ts in the thickness direction of the plane-symmetrical lateral protrusions is set in the - 10- Oate Re?ue/Date Received 2021-06-02CA 03121954 2021-06-02 range of 0.18 to 0.90, when expressed as an index on the basis of 1 indicative of the thickness Tn of theinner bore ata position where theplane-symmetrical lateral protrusionsareprovided. That is, there is a space allowing molten steel to pass therethrough, between the plane-symmetrical lateral protrusions. By providing the space having such a spacing, theflow direction and flow velocity of molten steel passing therethrough is gently controlled without fixedly and completely separating a molten steel flow in the inner bore. This makes it possible to mitigate a situation where molten steel flows toward the discharge ports with a clear boundary.
[0021] Further, by adjusting the position,length, direction,etc., of each lateral protrusion,itbecomes possible to avoid a molten steel flow concentrating on around the center or lateral sides, and diverge the molten steel flow into two directions toward width-directional ends, i.c., the discharge ports, and a direction toward the central region, while giving adequate balance to the diverged flows. In addition,differently fromsimpledivergence,since respective regions aroundthe lateral protrusions arc spatially communicated with each other, the molten steel flow will be diverged, while forming a moderate boundary therebetween, and uniforming flow under gentle mixing, instead of a completely divided state.
[0022] The position, length, direction, etc., of each lateral protrusion can be appropriately adjusted, as mentioned above. For example, in a second embodiment illustrated in FIG. 2, in addition to the two pairs of lateral protrusions (assigned with the reference code la in FIG. 2; each of the lateral protrusions la will hereinafter be referred to as "lower lateral protrusion"), two pairs of lateral protrusions (assigned with the reference code lb in FIG. 2; each of the lateral protrusions lb will hereinafter be referred to as "upper lateral protrusion") are provided, respectively, above the two pairs of lower lateral protrusions.
[0023] Further, in the present invention,a protrusion (central protrusion) having a protruding length less than that of each of the axial symmetrical lateral protrusions may be provided between the axial symmetrical lateral protrusions, as in third and fourth embodiments illustrated FIGS. 3 and 4. More specifically, in the third embodiment illustrated FIG. 3, the central protrusion Ip is provided between the axial symmetrical lateral protrusions1 illustratedin FIG.1,and, in the fourth - 11- Oate Re?ue/Date Received 2021-06-02CA 03121954 2021-06-02 embodimentillustrated FIG. 4,the central protrusion Ipis provided betweendie axial symmetrical lower lateral protrusions1illustrated in FIG. 2.
[0024] Tins structure brings out an effect opposite to that of a structure in which a protrusion (protrusion portion) having a protruding length greater than that of each of the axial symmetrical lateral protrusions is provided in the Patent Document 4 to allow the flow rate of a molten steel flow towardthe lateral ends to become greaterthan that of a molten steel flow toward between the axial symmetrical lateral protrusions, i.e., an effect of increasing the ratio of the flow rate of the molten steel flow toward between the axial symmetrical lateral protrusions (centtai region) / the flow rate of the molten steel flow toward the lateral ends. In continuous casting having a relatively large molten steel flow rate (about 0.04 (t / (min-cm2))or more), itis effective to increase the ratio of the flow rate of the molten steel flow toward between the axial symmetrical 1ateral protrusions (central region) I theflow rate of the molten steel flow toward die lateral ends.
[0025] The balance of the molten steel flows to the central region and the lateral ends can be optimized by adjusting the magnitude of the molten steel flow velocity (molten steel flow rate per unit tine or per unit sectional area), a drawing speed, the size and shape of a mold, an immersion depth, a nozzle structure such as the area of the discharge port, etc. Specifically,it is possible to employ a method of adjusting die width-directional or downward angle, width-directional length, protruding length, etc., of each lateral protrusion, a method of selecting the presence or absence of die central protrusion between the axial symmetric lateral protrusion, a method of adjusting die protruding length (height) of the central protrusion, a method of adjusting the shape of an upper end surface of the central protrusion, etc. For example, with regard tothe protruding length of the central protrusion, as exemplified in FIG. 6, the protruding length Tp/2 thereof is set to be less than the protruding length Ts/2 of the lateral protrusion 1, wherein a total protruding length Tp expressed as an index on the basis of 1 indicative ofdie thicknessof theinnerboreatthe positionwherethe plane-symmetrical or opposed lateral protrusions are provided. In other words, Tp <Ts, wherein Tp/Tn 0.40.
[0026] Further, tire upper end surface of the central protrusion may be formed in a shape extending horizontally in thewidth direction, asshown in FIG. 8, oracurved shape having atopat amidpoint - 12- Oate Re?ue/Date Received 2021-06-02CA 03121954 2021-06-02 thereof, as shown in FIG. 5, or an upwardly protruding shape including a bending point, as shown in FIG. 7. These shapes make it possible to further change the flow velocity andflow pattern of molten steel, thereby optimizing the flow velocity and flow pattern.
[0027] Further,an upper endsurface of the lateral protrusion or thecentral protrusion may be formed in a shape extendingfroma topthereofat a boundary with the width-directionally extending (longside) wall of the flat portion of the immersion nozzle, obliquely downwardly in a direction toward a thickness-directional center of the flat portion of the immersion nozzle, i.e., a direction toward the center of the inner bore (toward aspace). Thisinclination makesit possible tofurther change the flow velocity and flow pattern of mol ten steel, thereby optimizing the flow vdocity and flow pattern.
[0028] Further, the protruding length of the upper end of the lateral protrusion or the central protrusion may beformedto beconstant, asshown in FIG.10,or may be formed tobecome shorter in a direction toward the center of the width-directionally extending (long-side) wall of the flat portion of theimmersion nozzle,as shown in FIGS.11 to13. Theseinclinationsmake it possible to furflier change the flow velocity and flow pattern of molten steel, thereby optimizing the flow velocity and flow pattern.
[0029] In the flat immersion nozzle, the discharge port in each of the short-side lateral walls is configured to have an opening which is long in the longitudinal direction. Thus, the discharge flow velocity is likely to be reduced in an upper region of the discharge port, and, particularly in the vicinity of an upper edge of the discharge port, a backflow phenomenon that molten sted is sucked into the immersion nozzle is often observed. Therefore, in the present invention, for example, as shown in FIGS. 2 and 4, in addition to the aforementioned axial symmetrical and plain-symmettical lower protrusions la, one or more sets of axial symmetrical and plainsymmetrical protrusions (upper protrusions) lb may be provided thereabove. The axial symmetrical and plain-symmetrical upper protrusions lb may be formed in a similar optimizing configuration to that of the axial symmetrical and plain-symmetrical lower protrusions la.
[0030] The axial symmetrical and plain-symmetrical upper protrusions lb have a function of - 13- Oate Re?ue/Date Received 2021-06-02CA 03121954 2021-06-02 suppressing, particularly, decrease of die flow velocity in the upper region of the discharge port, or turbulence of a molten steel flow such as the backflow in the vicinity of the upper edge of the discharge port, to complement a function of uniforming the distribution of flow velocity in respective longitudinal positionsof thedischarge port, anda function ofadjusting flow ratebalance toward an upper limit. A central protrusion may be provided between the axial symmetrical protrusions lb in a similar manner to the central protrusion between dieaxial symmetrical protrusions la.
[0031] A bottom 5 of the immersion nozzle may be formed as a wall serving simply as a partition wall with respect toa moldwithout forming any dischargeport arounddie center thereof,as shown in FIG. 14, or may be formed in a configuration comprising a protrusion provided around die center thereof to protrude upwardly, as shown in FIGS. 1 to 5, 7, 8, 15 and 16. Further, a discharge port 6 may be additionally in the bottom 5, as shown in FIG. 17. Sucha protrusion of the bottom is useful in changing the flow direction/pattem, flow velocity, etc., when changing a molten steel flew directed toward the ventral region to directions toward the discharge ports.
[0032] Next, die present invention will be described with reference to examples. [0033] [Example A] ExampleA is a result of water model experiments, showing a relationship between the ratio Ts/Tn or TpTTn of die protrusion length Ts of the opposed lower lateral protrusions la toward a space of theinner bore of die immersion nozzle or die protrusion length Tp of the opposed central protrusions Ip toward the space of die space of the inner bore (die total length of die planesymmetrical protrusions) to the thickness (length in the short-side direction) Tn of the inner bore of the immersion nozzle, and a degree of fluctuation of the in-mold bath surface (in-mold uneven flow index, in-mold bath surface fluctuation height), with respect to each immersion nozzle according to the second embodiment of the present invention illustrated in FIG. 2, which is provided with the two-stage axial symmetrical and plane-symmetrical lateral protrusions la, lb wherein the central protrusion Ip is not provided between each of die two pairs of lower lateral protrusions la,andaccording todie fourth embodiment of the presentinvention illustrated in FIG. 4, which is provided with the two-stage axial symmetrical and plane-symmetrical lateral - 14- Oate Re?ue/Date Received 2021-06-02CA 03121954 2021-06-02 protrusions la,1b are provided, wherein the central protrusion Ip is not provided between each of the two pairs of lower lateral protrusions la.
[0034] Specifications of the immersion nozzles are as follows. • Overall length * Molten steel inlet • Widtli of inner bore (Wn) at upper edge of discharge port 1 1165 mm :cp 86 mm :255mm • Thickness of inner bore (Tn) at upper edge of discharge port :34 mm • Height of upper edge of discharge port from nozzle lower edge face :146.5 mm • Height of central protrusion (from nozzle 1owcr edge face ) :155 mm: * Thickness of wall of immersion nozzle : about 25 mm • Thickness of (central top of) bottom of iminersion nozzle :height 100 mm * Upperlateral protrusion (lb) : Length in width direction of immersion nozzle- 25 mm (In each of right and left upper lateral protrusions) RatioTs/Tn 0.74 Inclination angle toward discharge port = 45 degrees Posture of upper end surface in width direction and thickness direction of immersion nozzle= horizontal Distance between right and left upper lateral protrusions = 100 mm No center protrusion ’ Lowerlateral protrusion (la) : Length in width direction of immersion nozzle= 40mm (In each of right and left lower lateral protrusions) Ratio Ts/Tn = 0.1 to 1.0 (no space) Inclination angle toward discharge port = 45 degrees Posture of upper end surface in width direction and thickness direction of immersion nozzle = horizontal Distance between right and left left lateral protrusions = 60 mm Ratio Tp/Tnofcentralprotrusions= 0 (nocentral protrusions) to 0.7 - 15- Oate Re?ue/Date Received 2021-06-02CA 03121954 2021-06-02
[0035] Conditions of a mold anda fluid are as follows. * Width of mold : 1650 mm * Thickness of mold : 65 mm (Central top: 185 mm) * Immersion depth (from upper edge of discharge port to water level): 83 mm • Fluid supply speed : 0.065 t (min-cm2) *Valueconverted to molten steel
[0036] Here, when an in-mold uneven flow index expressed on the basis of 1indicative ofa state in which thereisno uneven flowsatisfies the following relationship: 0.8Sin-mold uneven flow index <1.2, and anin-mold bathsurfacefluctuationheight (mm)is equal toor less than 15mm, an effect capable of solving the problem addressed by the present invention was deemed to be obtained. This was used as evaluation criterion. The in-mold unevenflow index meansa result obtained by measuring aflow velocity at aset bath surface (at an under-water position of 30 mm from a set upper surface of water) around each of the right and left discharge ports of the immersion nozzle in a mold, in the water model experiment, and expressing the right and left flow velocities as a ratio (absolute value), i.e., an absolute value of the left flow velocity I the right flow velocity (or the right flow velocity / the left flow velocity), and the in-mold bath surface fluctuation height means a maximum value of Sw in HG.18.
[0037] Aresult of evaluation is shown in Table1. - 16- Oate Re$ue/Date Received 2021*06-02CA. 03121954 2021-06-02 x 03 GO o O* bp Comp arative le rH 3“^ 0.4 Tp< Ts »15 X p. p a 1 1 1 * © © VA Am »15 X r -I|. o a os 0.95 0.4 TP< Ts so <n X Comp arative Examp le 00 © V JO 28 X Comp arative Examp le t** 6'0 o V » ,a A X £ I S £ - a » 8 r- 1 0.4 Tp <Ts i- cr H o Inve ntive mple SO 0.25 Tp <Ts •M © o P g CS Ji a « 8 m o Tp <Ts CM i—H o Comp native le M> 0.5 0.7 Tp> Ts rH X Hp g M« J! cr 0.4 Tp <Ts Os o Inve ntive Exa mple 0.25 Tp <Ts xr 0 Inve ntive mple CM © Ha VHm m o Qt & EF » O g i | o a £ 00 o 0.4 A& Hm CM CM X Comp arative le Tp> Ts 00 X g g Ci ® 1 I t o Tp <Ts CM o Comp arative Examp le ro 0.4 Tp> Ts 32 X Comp arative le 0.25 A M 24 X & g & o0|§ I CO VHA Hm i-H QO X Ts/Tn Tp/Tn ’X3 •S aQ3 -s »£5 Sg ** £* gCp hn OilMaximum surfacebath fluctuation Swvalue (mm) Evaluation* DateRe?ue/Date Received 2021-06-02CA 03121954 2021-06-02
[0038] As seal in Table 1, when the ratio of Ts to Tn (Ts/Tn) regarding the lateral protrusions is in the range of 0.18 to 0.90, the in-mold uneven flow index and the in-mold bath surface fluctuation height can satisfy the criterion. Further, in thecase of the center protrusions are provided, when the protruding length thereof is less than that of the lateral protrusions, and the ratio of Tp to Tn (Tp/Tn) is 0.4 or less, the in¬ mold uneven flow index and the in-mold bath surface fluctuation height can satisfy the criterion. [0039] [Example B] ExampleB isa result of water model experiments, showing a degree of in-mole bath surface fluctuation when the upper end surface of each of tire lower lateral protrusion la and the central protrusion lp is formed in a planar shape extending obliquely downwardly toward the center of the inner bore, as shown in FIG. 9, in the forth embodiment of the present invention illustrated in FIG.4.
[0040] Here, theratioTs/Tn regarding thelower lateral protrusionsand the ratioTp/Tn regarding the central protrusions were set, respectively, to 0.74 and 0.18, and two cases where the inclination angle (0 in FIG. 9) of each of the lower lateral protrusion and the central protrusion toward the center of theinner bore was set to 0 degree (horizontal) and 45 degrees were compared with each other. The remaining conditions are the same as those of Example A.
[0041] A result is shown in FIG. 19. The vertical axis of FIG. 19 represents an average value of maximum baft surface fluctuation values Sw (mm) around the right and left discharge ports, in both the cases w here the inclination angle is O degree and 45 degrees.
[0042] FIG. 19shows that, in both the cases where the inclination angle is 0 degree and 45 degrees, the in-mold bath surface fluctuation height is significantly smaller than 15 mm as the criterion, and, in the case where the inclination angle is 45 degrees, the in-mold baft surface fluctuation height is reduced to 2.0 (mm), which is about 1/2 of 3.75 (mm) in the case where the inclination angle is 0 degree. - 18- Oate Re$ue/Date Received 2021*06-02CA 03121954 2021-06-02 LIST OF REFERENCE SIGNS [0043] 10: immersion nozzle 1: lateral protrusion la: lower lateral protrusion lb: upper lateral protrusion Ip: central protrusion 2: molten steel inlet 3: inns’bore (molten steel flow passage) 4: dischargeport (short side wall) 5: bottom 6: dischargeport (bottom) 7: bath surface 20: mold Wn: width of inner bore of immersion nozzle (length in long-side direction) Wp: width between opposite ends of lateral protrusion Wc: width of central protrusion Th: thickness of inner fore of immersion nozzle (length in short-side direction) Ts: protruding length of opposed lateral protrusions toward space (total protruding length of opposed ones) Tp: protruding length of opposed central protrusions toward space (total protruding length of opposed ones) ML: width erf mold (long side) Ms: thickness of mold (short side, lateral end) Me: thickness of mold (short side, central region) Sw: fluctuation range of in-mold bath surface (size between topand bottom) - 19- Oate Re$ue/Date Received 2021*06-02
Claims
CLAIMS 1. An immersion nozzle having a flat portion whose inner bore has a thickness (Tn) and a width (Wn) greater than the thickness (Tn), and which comprises opposed short-side lateral walls, and a first opposed long-side wall and a second opposed long-side wall extending in a width direction of the flat portion, wherein a pair of discharge ports are provided, respectively, in lower parts of the short-side lateral walls, the immersion nozzle comprising: a first pair of lateral protrusions provided on the first opposed long-side wall, and arranged at axial symmetrical positions with respect to a longitudinal central axis of the first opposed longside wall and a second pair of lateral protrusions provided on the second opposed long-side wall, and arranged at axial symmetrical positions with respect to a longitudinal central axis of the second opposed long-side wall, each of the first pair of lateral protrusions and the second pair of lateral protrusions extending obliquely downwardly in the width direction and protruding in a thickness direction of the flat portion, wherein lateral protrusions of the first pair of lateral protrusions and lateral protrusions of the second pair of lateral protrusions are each spaced apart from each other in the width direction, wherein the first pair of lateral protrusions are arranged on the first opposed long-side wall and the second pair of lateral protrusions are arranged on the second opposed long-side wall in opposed relation, and wherein two sets of opposed lateral protrusions in the first pair of lateral protrusions and the second pair of lateral protrusions have a same value falling within a range of 0.18 to 0.90 in terms of a total protruding length (Ts) in the thickness direction, expressed as an index on the basis of 1 indicative of a thickness of the inner bore at a position where the two sets of opposed lateral protrusions are provided; and wherein a center region is defined by a region extending in the width direction between inner¬ most comers ofcenter-side ends of the first pair of lateral protrusions and the second pair of lateral protrusions, extending in the thickness direction between side walls of the inner bore, and extending a length of the immersion nozzle in a longitudinal direction, wherein the center region does not have a continuous protrusion with a protruding length in the thickness direction that is equal to or greater than that of the first pair of lateral protrusions on the first opposed long-side wall and the second pair of lateral protrusions on the second opposed long-side wall. -20- Date Recue/Date Received 2023-09-182. The immersion nozzle as claimed in claim 1, which further comprises a first center protrusion provided on the first opposed long-side wall at a position between the lateral protrusions of the first pair of lateral protrusions and a second central protrusion provided on the second opposed long-side wall at a position between the lateral protrusions of the second pair of lateral protrusions, wherein the first central protrusion and the second central protrusion have a thickness¬ directional protruding length that is less than that of the lateral protrusions of the first pair of lateral protrusions and the lateral protrusions of the second pair of lateral protrusions, respectively, and wherein the first central protrusion and the second central protrusion have a value of less than 0.40 in terms of a total protruding length (Tp) in the thickness-direction, expressed as an index on the basis of 1 indicative of the thickness of the inner bore at the position where the opposed lateral protrusions are provided. 3. The immersion nozzle as claimed in claim 2, wherein an upper end surface of the first central protrusion and the second central protrusion have a shape selected from the group consisting of a shape extending horizontally in the width direction, a curved shape having a top at a midpoint thereof, and an upwardly protruding shape including a bending point. 4. The immersion nozzle as claimed in claim 2, wherein an upper end surface of at least one of: - the lateral protrusions of the first pair of lateral protrusions and the lateral protrusions of the second pair of lateral protrusions; and - the first central protrusion and the second central protrusion have a shape extending horizontally in a direction toward a center of the inner bore, a planar shape extending obliquely downwardly in the direction toward the center of the inner bore, or a curved shape extending obliquely downwardly in the direction toward the center of the inner bore. 5. The immersion nozzle as claimed in any one of claims 2 to 4, wherein at least one of: - the lateral protrusions of the first pair of lateral protrusions and the lateral protrusions of the second pair of lateral protrusions; and - the first central protrusion and the second central protrusion; -21 - Date Recue/Date Received 2023-09-18have a shape in which the thickness-directional protruding length thereof is constant, or becomes shorter linearly, curvilinearly or stepwisely in a direction toward a center of the first opposed long-side wall or the second opposed long-side wall. 6. The immersion nozzle as claimed in any one of claims 2 to 5, wherein one of: - the lateral protrusions of the first pair of lateral protrusions and the lateral protrusions of the second pair of lateral protrusions; and - the lateral protrusions of the first pair of lateral protrusions combined with the first central protrusion and the lateral protrusions of the second pair of lateral protrusions combined with the second central protrusion is provided plurally in an up-down direction. 7. The immersion nozzle as claimed in any one of claims 1 to 6, which comprises a protrusion provided around a center of a bottom of the inner bore to protrude upwardly. 8. The immersion nozzle as claimed in any one of claims 1 to 7, which is used for continuous casting carried out under conditions including a molten steel flow rate of 0.04 (t I (min-cm2)) or more, as measured with reference to a position of minimum cross-sectional area in a region around an upper end of the immersion nozzle where a transverse cross-section of the inner bore has a circular shape. -22- Date Recue/Date Received 2023-09-18
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2019-007948 | 2019-01-21 | ||
| JP2019007948A JP7134105B2 (en) | 2019-01-21 | 2019-01-21 | immersion nozzle |
| PCT/JP2020/001078 WO2020153195A1 (en) | 2019-01-21 | 2020-01-15 | Immersion nozzle |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA3121954A1 CA3121954A1 (en) | 2020-07-30 |
| CA3121954C true CA3121954C (en) | 2025-03-11 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA3121954A Active CA3121954C (en) | 2019-01-21 | 2020-01-15 | Immersion nozzle |
Country Status (9)
| Country | Link |
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| US (1) | US20220134420A1 (en) |
| EP (1) | EP3915696A4 (en) |
| JP (1) | JP7134105B2 (en) |
| CN (1) | CN113226594B (en) |
| BR (1) | BR112021010225A2 (en) |
| CA (1) | CA3121954C (en) |
| TW (1) | TWI731561B (en) |
| WO (1) | WO2020153195A1 (en) |
| ZA (1) | ZA202103504B (en) |
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| JP2025005211A (en) * | 2023-06-27 | 2025-01-16 | 黒崎播磨株式会社 | Submerged Entry Nozzle |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| UA51734C2 (en) | 1996-10-03 | 2002-12-16 | Візувіус Крусібл Компані | Immersed cup for liquid metal passing and method for letting liquid metal to path through it |
| JPH115145A (en) | 1997-04-22 | 1999-01-12 | Toshiba Ceramics Co Ltd | Integrated immersion nozzle and method for manufacturing the same |
| JPH1147897A (en) | 1997-07-31 | 1999-02-23 | Nippon Steel Corp | Immersion nozzle for continuous casting of thin-wall wide slabs |
| KR100423947B1 (en) * | 2001-09-21 | 2004-03-22 | 조선내화 주식회사 | submerged entry nozzle for continous casting |
| JP4076516B2 (en) * | 2004-04-07 | 2008-04-16 | 品川白煉瓦株式会社 | Immersion nozzle for continuous casting of steel |
| CN2810819Y (en) * | 2005-07-01 | 2006-08-30 | 鞍山钢铁集团公司 | Submerged nozzle of medium-thin plate continuous-casting mold |
| CN101932395B (en) * | 2008-03-27 | 2012-12-05 | 黑崎播磨株式会社 | Immersion nozzle for continuous casting |
| JP5047854B2 (en) * | 2008-03-27 | 2012-10-10 | 黒崎播磨株式会社 | Immersion nozzle for continuous casting |
| CN201329417Y (en) * | 2008-11-27 | 2009-10-21 | 中钢集团洛阳耐火材料研究院有限公司 | Multi-port submerged nozzle for sheet billet continuous casting |
| CN101733373A (en) * | 2009-12-23 | 2010-06-16 | 重庆大学 | Submerged nozzle for sheet billet continuous casting crystallizer |
| CN201823911U (en) * | 2010-10-19 | 2011-05-11 | 维苏威高级陶瓷(苏州)有限公司 | Submerged nozzle of thin blank plate |
| CN201979058U (en) * | 2011-01-29 | 2011-09-21 | 中钢集团洛阳耐火材料研究院有限公司 | Submerged entry nozzle for thin slab billet continuous casting |
| JP2012183544A (en) | 2011-03-03 | 2012-09-27 | Kurosaki Harima Corp | Immersion nozzle |
| JP5645736B2 (en) * | 2011-03-31 | 2014-12-24 | 黒崎播磨株式会社 | Immersion nozzle for continuous casting |
| BR112013032763B1 (en) * | 2011-07-06 | 2023-09-26 | Refractory Intellectual Property Gmbh & Co. Kg | NOZZLE FOR GUIDING A CAST METAL |
| ES2609983T3 (en) * | 2013-06-20 | 2017-04-25 | Refractory Intellectual Property Gmbh & Co. Kg | Submerged refractory inlet nozzle |
| JP6577841B2 (en) | 2015-11-10 | 2019-09-18 | 黒崎播磨株式会社 | Immersion nozzle |
-
2019
- 2019-01-21 JP JP2019007948A patent/JP7134105B2/en active Active
-
2020
- 2020-01-15 CN CN202080007527.0A patent/CN113226594B/en active Active
- 2020-01-15 CA CA3121954A patent/CA3121954C/en active Active
- 2020-01-15 US US17/424,301 patent/US20220134420A1/en active Pending
- 2020-01-15 BR BR112021010225-6A patent/BR112021010225A2/en not_active Application Discontinuation
- 2020-01-15 WO PCT/JP2020/001078 patent/WO2020153195A1/en not_active Ceased
- 2020-01-15 EP EP20744229.4A patent/EP3915696A4/en active Pending
- 2020-01-21 TW TW109102107A patent/TWI731561B/en active
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2021
- 2021-05-24 ZA ZA2021/03504A patent/ZA202103504B/en unknown
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| Publication number | Publication date |
|---|---|
| CA3121954A1 (en) | 2020-07-30 |
| EP3915696A4 (en) | 2022-09-14 |
| JP2020116591A (en) | 2020-08-06 |
| CN113226594B (en) | 2023-03-14 |
| BR112021010225A2 (en) | 2021-08-24 |
| ZA202103504B (en) | 2022-07-27 |
| CN113226594A (en) | 2021-08-06 |
| EP3915696A1 (en) | 2021-12-01 |
| JP7134105B2 (en) | 2022-09-09 |
| US20220134420A1 (en) | 2022-05-05 |
| TWI731561B (en) | 2021-06-21 |
| WO2020153195A1 (en) | 2020-07-30 |
| TW202035036A (en) | 2020-10-01 |
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