CA2245560C - Detergent particles comprising metal-containing bleach catalysts - Google Patents

Detergent particles comprising metal-containing bleach catalysts Download PDF

Info

Publication number: CA2245560C
Authority: CA; Canada
Prior art keywords: preferred; composite particle; bleach catalyst; oac; sodium
Prior art date: 1996-02-08
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

CA002245560A

Other languages

English (en)

French (fr)

Other versions

CA2245560A1 (en

Inventor

Fiona Susan Macbeath

Barry Rowland

Michael Crombie Addison

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Procter and Gamble Co

Original Assignee

Procter and Gamble Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1996-02-08

Filing date

1997-01-31

Publication date

2001-09-11

1997-01-31 Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co

1997-08-14 Publication of CA2245560A1 publication Critical patent/CA2245560A1/en

2001-09-11 Application granted granted Critical

2001-09-11 Publication of CA2245560C publication Critical patent/CA2245560C/en

2017-01-31 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

239000007844 bleaching agent Substances 0.000 title claims abstract description 89
239000003599 detergent Substances 0.000 title claims abstract description 84
239000003054 catalyst Substances 0.000 title claims abstract description 83
229910052751 metal Inorganic materials 0.000 title claims abstract description 28
239000002184 metal Substances 0.000 title claims abstract description 28
239000002245 particle Substances 0.000 title claims description 53
239000000203 mixture Substances 0.000 claims abstract description 176
239000000463 material Substances 0.000 claims abstract description 34
239000011246 composite particle Substances 0.000 claims abstract description 29
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 26
238000010348 incorporation Methods 0.000 claims abstract description 6
239000011572 manganese Substances 0.000 claims description 24
229910017052 cobalt Inorganic materials 0.000 claims description 21
239000010941 cobalt Substances 0.000 claims description 21
GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 21
229910052748 manganese Inorganic materials 0.000 claims description 13
229920000159 gelatin Polymers 0.000 claims description 12
235000019322 gelatine Nutrition 0.000 claims description 12
PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 10
239000001828 Gelatine Substances 0.000 claims description 9
229910052723 transition metal Inorganic materials 0.000 claims description 7
150000003624 transition metals Chemical class 0.000 claims description 7
WLDGDTPNAKWAIR-UHFFFAOYSA-N 1,4,7-trimethyl-1,4,7-triazonane Chemical compound CN1CCN(C)CCN(C)CC1 WLDGDTPNAKWAIR-UHFFFAOYSA-N 0.000 claims description 6
XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 6
150000001720 carbohydrates Chemical class 0.000 claims description 4
235000014633 carbohydrates Nutrition 0.000 claims description 4
239000010949 copper Substances 0.000 claims description 4
229910052742 iron Inorganic materials 0.000 claims description 4
108010010803 Gelatin Proteins 0.000 claims description 3
229910052802 copper Inorganic materials 0.000 claims description 3
239000008273 gelatin Substances 0.000 claims description 3
235000011852 gelatine desserts Nutrition 0.000 claims description 3
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 2
RGHNJXZEOKUKBD-SQOUGZDYSA-M D-gluconate Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O RGHNJXZEOKUKBD-SQOUGZDYSA-M 0.000 claims description 2
ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 2
RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
YRNNKGFMTBWUGL-UHFFFAOYSA-L copper(ii) perchlorate Chemical compound [Cu+2].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O YRNNKGFMTBWUGL-UHFFFAOYSA-L 0.000 claims description 2
229940050410 gluconate Drugs 0.000 claims description 2
NGLYWWPBKJFWRP-UHFFFAOYSA-L iron(2+) N-pyridin-2-ylpyridin-2-amine diperchlorate Chemical compound [Fe+2].[O-]Cl(=O)(=O)=O.[O-]Cl(=O)(=O)=O.C=1C=CC=NC=1NC1=CC=CC=N1.C=1C=CC=NC=1NC1=CC=CC=N1.C=1C=CC=NC=1NC1=CC=CC=N1 NGLYWWPBKJFWRP-UHFFFAOYSA-L 0.000 claims description 2
229910052750 molybdenum Inorganic materials 0.000 claims description 2
239000011733 molybdenum Substances 0.000 claims description 2
229910052719 titanium Inorganic materials 0.000 claims description 2
239000010936 titanium Substances 0.000 claims description 2
229910001914 chlorine tetroxide Inorganic materials 0.000 claims 4
VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 claims 2
ITWBWJFEJCHKSN-UHFFFAOYSA-N 1,4,7-triazonane Chemical compound C1CNCCNCCN1 ITWBWJFEJCHKSN-UHFFFAOYSA-N 0.000 claims 1
KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims 1
GTUTUHMILJYQNJ-UHFFFAOYSA-N [Co+2].N(=C=S)C1=C(C(=NC=C1)NC1=NC=CC=C1)N=C=S Chemical compound [Co+2].N(=C=S)C1=C(C(=NC=C1)NC1=NC=CC=C1)N=C=S GTUTUHMILJYQNJ-UHFFFAOYSA-N 0.000 claims 1
229910052707 ruthenium Inorganic materials 0.000 claims 1
WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims 1
229910052721 tungsten Inorganic materials 0.000 claims 1
239000010937 tungsten Substances 0.000 claims 1
102000004190 Enzymes Human genes 0.000 description 49
108090000790 Enzymes Proteins 0.000 description 49
229940088598 enzyme Drugs 0.000 description 49
-1 manganese cations Chemical class 0.000 description 46
QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 30
229920000642 polymer Polymers 0.000 description 29
108010065511 Amylases Proteins 0.000 description 28
102000013142 Amylases Human genes 0.000 description 28
235000019418 amylase Nutrition 0.000 description 28
235000002639 sodium chloride Nutrition 0.000 description 27
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 23
150000003839 salts Chemical class 0.000 description 22
238000000034 method Methods 0.000 description 21
239000000243 solution Substances 0.000 description 21
239000004094 surface-active agent Substances 0.000 description 21
108091005804 Peptidases Proteins 0.000 description 20
102000035195 Peptidases Human genes 0.000 description 20
229940025131 amylases Drugs 0.000 description 19
238000004851 dishwashing Methods 0.000 description 19
229910052708 sodium Inorganic materials 0.000 description 19
239000011734 sodium Substances 0.000 description 18
239000004365 Protease Substances 0.000 description 17
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 17
150000001875 compounds Chemical class 0.000 description 17
239000002270 dispersing agent Substances 0.000 description 17
239000003446 ligand Substances 0.000 description 17
229910052760 oxygen Inorganic materials 0.000 description 17
229910019142 PO4 Inorganic materials 0.000 description 16
239000001301 oxygen Substances 0.000 description 16
239000010452 phosphate Substances 0.000 description 16
VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 16
229910052783 alkali metal Inorganic materials 0.000 description 14
229910000069 nitrogen hydride Inorganic materials 0.000 description 14
235000021317 phosphate Nutrition 0.000 description 14
QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 13
125000000217 alkyl group Chemical group 0.000 description 13
125000000129 anionic group Chemical group 0.000 description 13
238000004061 bleaching Methods 0.000 description 13
238000004140 cleaning Methods 0.000 description 13
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 12
MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 12
239000002253 acid Substances 0.000 description 12
239000000460 chlorine Substances 0.000 description 12
229910052801 chlorine Inorganic materials 0.000 description 12
239000012933 diacyl peroxide Substances 0.000 description 12
239000004615 ingredient Substances 0.000 description 12
239000004382 Amylase Substances 0.000 description 11
LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 11
150000001340 alkali metals Chemical class 0.000 description 11
KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 11
229910052681 coesite Inorganic materials 0.000 description 11
229910052906 cristobalite Inorganic materials 0.000 description 11
229910052682 stishovite Inorganic materials 0.000 description 11
229910052905 tridymite Inorganic materials 0.000 description 11
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 10
150000007942 carboxylates Chemical class 0.000 description 10
239000001257 hydrogen Substances 0.000 description 10
229910052739 hydrogen Inorganic materials 0.000 description 10
230000000087 stabilizing effect Effects 0.000 description 10
108090001060 Lipase Proteins 0.000 description 9
102000004882 Lipase Human genes 0.000 description 9
DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 9
239000012190 activator Substances 0.000 description 9
125000004432 carbon atom Chemical group C* 0.000 description 9
238000007046 ethoxylation reaction Methods 0.000 description 9
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 9
229920001296 polysiloxane Polymers 0.000 description 9
QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 8
239000004367 Lipase Substances 0.000 description 8
239000004115 Sodium Silicate Substances 0.000 description 8
238000005260 corrosion Methods 0.000 description 8
230000007797 corrosion Effects 0.000 description 8
235000019421 lipase Nutrition 0.000 description 8
238000002360 preparation method Methods 0.000 description 8
108010084185 Cellulases Proteins 0.000 description 7
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ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 7
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150000001412 amines Chemical class 0.000 description 7
230000000694 effects Effects 0.000 description 7
238000005187 foaming Methods 0.000 description 7
230000001590 oxidative effect Effects 0.000 description 7
229920001451 polypropylene glycol Polymers 0.000 description 7
229910052700 potassium Inorganic materials 0.000 description 7
239000011591 potassium Substances 0.000 description 7
229960003975 potassium Drugs 0.000 description 7
NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 7
238000001694 spray drying Methods 0.000 description 7
235000019698 starch Nutrition 0.000 description 7
LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 6
IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 6
102000003992 Peroxidases Human genes 0.000 description 6
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 6
229910052910 alkali metal silicate Inorganic materials 0.000 description 6
239000012736 aqueous medium Substances 0.000 description 6
238000009472 formulation Methods 0.000 description 6
239000003112 inhibitor Substances 0.000 description 6
229920005646 polycarboxylate Polymers 0.000 description 6
229910052911 sodium silicate Inorganic materials 0.000 description 6
MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 6
239000002689 soil Substances 0.000 description 6
238000003756 stirring Methods 0.000 description 6
OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 5
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 5
KRKNYBCHXYNGOX-UHFFFAOYSA-K Citrate Chemical compound [O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O KRKNYBCHXYNGOX-UHFFFAOYSA-K 0.000 description 5
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230000015572 biosynthetic process Effects 0.000 description 5
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241000894007 species Species 0.000 description 5
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 4
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VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 description 3
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HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 3
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UIIMBOGNXHQVGW-UHFFFAOYSA-M sodium bicarbonate Substances [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 1
229940001593 sodium carbonate Drugs 0.000 description 1
239000011780 sodium chloride Substances 0.000 description 1
239000001509 sodium citrate Substances 0.000 description 1
229940079842 sodium cumenesulfonate Drugs 0.000 description 1
FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
235000019795 sodium metasilicate Nutrition 0.000 description 1
PFUVRDFDKPNGAV-UHFFFAOYSA-N sodium peroxide Chemical compound [Na+].[Na+].[O-][O-] PFUVRDFDKPNGAV-UHFFFAOYSA-N 0.000 description 1
229940048086 sodium pyrophosphate Drugs 0.000 description 1
159000000000 sodium salts Chemical class 0.000 description 1
QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 description 1
KVCGISUBCHHTDD-UHFFFAOYSA-M sodium;4-methylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1 KVCGISUBCHHTDD-UHFFFAOYSA-M 0.000 description 1
QEKATQBVVAZOAY-UHFFFAOYSA-M sodium;4-propan-2-ylbenzenesulfonate Chemical compound [Na+].CC(C)C1=CC=C(S([O-])(=O)=O)C=C1 QEKATQBVVAZOAY-UHFFFAOYSA-M 0.000 description 1
MZSDGDXXBZSFTG-UHFFFAOYSA-M sodium;benzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC=CC=C1 MZSDGDXXBZSFTG-UHFFFAOYSA-M 0.000 description 1
238000007711 solidification Methods 0.000 description 1
230000008023 solidification Effects 0.000 description 1
239000002904 solvent Substances 0.000 description 1
239000000600 sorbitol Substances 0.000 description 1
238000001179 sorption measurement Methods 0.000 description 1
238000011105 stabilization Methods 0.000 description 1
238000003860 storage Methods 0.000 description 1
125000003107 substituted aryl group Chemical group 0.000 description 1
238000006467 substitution reaction Methods 0.000 description 1
KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 1
239000005720 sucrose Substances 0.000 description 1
150000003445 sucroses Chemical class 0.000 description 1
150000003871 sulfonates Chemical class 0.000 description 1
229910052717 sulfur Inorganic materials 0.000 description 1
239000000271 synthetic detergent Substances 0.000 description 1
238000012360 testing method Methods 0.000 description 1
150000004685 tetrahydrates Chemical class 0.000 description 1
235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
239000004753 textile Substances 0.000 description 1
DHCDFWKWKRSZHF-UHFFFAOYSA-L thiosulfate(2-) Chemical compound [O-]S([S-])(=O)=O DHCDFWKWKRSZHF-UHFFFAOYSA-L 0.000 description 1
GTZCVFVGUGFEME-UHFFFAOYSA-N trans-aconitic acid Natural products OC(=O)CC(C(O)=O)=CC(O)=O GTZCVFVGUGFEME-UHFFFAOYSA-N 0.000 description 1
125000001425 triazolyl group Chemical group 0.000 description 1
ITMCEJHCFYSIIV-UHFFFAOYSA-M triflate Chemical compound [O-]S(=O)(=O)C(F)(F)F ITMCEJHCFYSIIV-UHFFFAOYSA-M 0.000 description 1
UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 1
150000004684 trihydrates Chemical class 0.000 description 1
125000000026 trimethylsilyl group Chemical group [H]C([H])([H])[Si]([*])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
WUUHFRRPHJEEKV-UHFFFAOYSA-N tripotassium borate Chemical compound [K+].[K+].[K+].[O-]B([O-])[O-] WUUHFRRPHJEEKV-UHFFFAOYSA-N 0.000 description 1
AQLJVWUFPCUVLO-UHFFFAOYSA-N urea hydrogen peroxide Chemical compound OO.NC(N)=O AQLJVWUFPCUVLO-UHFFFAOYSA-N 0.000 description 1
235000013311 vegetables Nutrition 0.000 description 1
230000002087 whitening effect Effects 0.000 description 1
239000000811 xylitol Substances 0.000 description 1
HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
235000010447 xylitol Nutrition 0.000 description 1
229960002675 xylitol Drugs 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3935—Bleach activators or bleach catalysts granulated, coated or protected
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0039—Coated compositions or coated components in the compositions, (micro)capsules
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0084—Antioxidants; Free-radical scavengers
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3905—Bleach activators or bleach catalysts
- C11D3/3932—Inorganic compounds or complexes

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Inorganic Chemistry (AREA)
Biochemistry (AREA)
Detergent Compositions (AREA)

CA002245560A 1996-02-08 1997-01-31 Detergent particles comprising metal-containing bleach catalysts Expired - Fee Related CA2245560C (en)

Applications Claiming Priority (3)

Application Number	Priority Date	Filing Date	Title
GB9602578.8		1996-02-08
GB9602578A GB2309976A (en)	1996-02-08	1996-02-08	Bleach catalyst particles for inclusion in detergents
PCT/US1997/001462 WO1997029174A1 (en)	1996-02-08	1997-01-31	Detergent particles comprising metal-containing bleach catalysts

Publications (2)

Publication Number	Publication Date
CA2245560A1 CA2245560A1 (en)	1997-08-14
CA2245560C true CA2245560C (en)	2001-09-11

Family

ID=10788356

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA002245560A Expired - Fee Related CA2245560C (en)	1996-02-08	1997-01-31	Detergent particles comprising metal-containing bleach catalysts

Country Status (8)

Country	Link
EP (1)	EP0891410A4 (es)
JP (1)	JP3171855B2 (es)
CN (1)	CN1214726A (es)
AR (1)	AR005720A1 (es)
BR (1)	BR9707402A (es)
CA (1)	CA2245560C (es)
GB (1)	GB2309976A (es)
WO (1)	WO1997029174A1 (es)

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
WO1997036986A1 (de) *	1996-04-01	1997-10-09	Henkel Kommanditgesellschaft Auf Aktien	Reinigungsmittel mit oligoamminaktivatorkomplexen für persauerstoffverbindungen
DE19620411A1 (de) *	1996-04-01	1997-10-02	Henkel Kgaa	Übergangsmetallamminkomplexe als Aktivatoren für Persauerstoffverbindungen
WO2000042150A1 (en) *	1999-01-14	2000-07-20	The Procter & Gamble Company	Detergent compositions comprising a pectate lyase and a metal bleach catalyst
MXPA01007217A (es) *	1999-01-14	2002-04-24	Procter & Gamble	Composiciones detergentes que contienen un pectato liasa y un sistema blanqueador.
WO2001009276A1 (en) *	1999-07-28	2001-02-08	Ciba Specialty Chemicals Holding Inc.	Water-soluble granules of salen-type manganese complexes
GB0020846D0 (en)	2000-08-23	2000-10-11	Unilever Plc	Ligands for bleaching compositions and synthesis thereof
US6833343B2 (en) *	2001-03-30	2004-12-21	Kao Corporation	Bleaching detergent formulation
GB2374082A (en) *	2001-04-04	2002-10-09	Procter & Gamble	Particles for a detergent product
GB0202783D0 (en) *	2002-02-06	2002-03-27	Unilever Plc	Granule and composition containing same
GB0212984D0 (en) *	2002-06-06	2002-07-17	Unilever Plc	Preserved enhancement of bleaching catalysts together
KR20040033166A (ko) *	2002-10-11	2004-04-21	주식회사 엘지생활건강	표백활성화제의 제조 방법
US7060818B2 (en)	2003-02-21	2006-06-13	Carnegie Mellon University	Synthesis of macrocyclic tetraamido compounds and new metal insertion process
ES2314833T3 (es)	2006-07-27	2009-03-16	Evonik Degussa Gmbh	Particulas envueltas de percarbonato de sodio.
DE502006001853D1 (de)	2006-07-27	2008-11-27	Evonik Degussa Gmbh	Umhüllte Natriumpercarbonatpartikel
SI1882732T1 (sl)	2006-07-27	2010-08-31	Evonik Degussa Gmbh	OplaĹˇÄŤeni delci natrijevega perkarbonata
DE102006036896A1 (de) *	2006-08-04	2008-02-07	Henkel Kgaa	Wasch- oder Reinigungsmittel mit größenoptimierten Bleichwirkstoffteilchen
SI2080544T1 (sl)	2007-12-19	2011-04-29	Evonik Degussa Gmbh	Postopek za pripravo prevlečenih delcev natrijevega perkarbonata
MX2013000792A (es) *	2010-07-20	2013-02-27	Procter & Gamble	Particulas con una pluralidad de recubrimientos.
CA2968344C (en) *	2014-12-08	2023-03-14	Kinnos Inc.	Additive compositions for pigmented disinfection and methods thereof

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Publication number	Priority date	Publication date	Assignee	Title
DE1961076A1 (de) *	1969-12-05	1971-06-09	Henkel & Cie Gmbh	Aktivatorkombination fuer Perverbindungen sowie fuer diese enthaltende Bleich-,Wasch- und Reinigungsmittel
US4536183A (en) *	1984-04-09	1985-08-20	Lever Brothers Company	Manganese bleach activators
GB8629837D0 (en) *	1986-12-13	1987-01-21	Interox Chemicals Ltd	Bleach activation
DE3843195A1 (de) *	1988-12-22	1990-06-28	Hoechst Ag	Verfahren zur herstellung eines lagerstabilen, leicht loeslichen bleichaktivator-granulats
GB8908416D0 (en) *	1989-04-13	1989-06-01	Unilever Plc	Bleach activation
GB8915781D0 (en) *	1989-07-10	1989-08-31	Unilever Plc	Bleach activation
EP0458398B1 (en) *	1990-05-21	1997-03-26	Unilever N.V.	Bleach activation
DE4040654A1 (de) *	1990-12-19	1992-06-25	Henkel Kgaa	Granulat mit umhuelltem bleichaktivator
US5480575A (en) *	1992-12-03	1996-01-02	Lever Brothers, Division Of Conopco, Inc.	Adjuncts dissolved in molecular solid solutions
ES2110223T5 (es) *	1993-02-22	2001-05-01	Quest Int	Composicion resistente a la humedad.
GB9305598D0 (en) *	1993-03-18	1993-05-05	Unilever Plc	Bleach catalyst composition
GB9407299D0 (en) *	1994-04-13	1994-06-08	Procter & Gamble	Detergent compositions
US5480577A (en) *	1994-06-07	1996-01-02	Lever Brothers Company, Division Of Conopco, Inc.	Encapsulates containing surfactant for improved release and dissolution rates
ES2145315T3 (es) *	1994-12-09	2000-07-01	Procter & Gamble	Composicion para lavavajillas automaticos que contiene particulas de peroxidos de diacilo.

1996
- 1996-02-08 GB GB9602578A patent/GB2309976A/en not_active Withdrawn
1997
- 1997-01-31 CN CN 97193437 patent/CN1214726A/zh active Pending
- 1997-01-31 EP EP97904083A patent/EP0891410A4/en not_active Withdrawn
- 1997-01-31 BR BR9707402A patent/BR9707402A/pt not_active Application Discontinuation
- 1997-01-31 CA CA002245560A patent/CA2245560C/en not_active Expired - Fee Related
- 1997-01-31 WO PCT/US1997/001462 patent/WO1997029174A1/en not_active Ceased
- 1997-01-31 JP JP52856297A patent/JP3171855B2/ja not_active Expired - Fee Related
- 1997-02-05 AR ARP970100460A patent/AR005720A1/es unknown

Also Published As

Publication number	Publication date
CA2245560A1 (en)	1997-08-14
GB9602578D0 (en)	1996-04-10
GB2309976A (en)	1997-08-13
EP0891410A1 (en)	1999-01-20
CN1214726A (zh)	1999-04-21
EP0891410A4 (en)	1999-12-01
WO1997029174A1 (en)	1997-08-14
JPH11504067A (ja)	1999-04-06
BR9707402A (pt)	1999-04-06
AR005720A1 (es)	1999-07-14
JP3171855B2 (ja)	2001-06-04

Publication	Publication Date	Title
US5703034A (en)	1997-12-30	Bleach catalyst particles
US5902781A (en)	1999-05-11	Bleach catalyst plus enzyme particles
CA2245560C (en)	2001-09-11	Detergent particles comprising metal-containing bleach catalysts
US5939373A (en)	1999-08-17	Phosphate-built automatic dishwashing composition comprising catalysts
CA2265825C (en)	2002-06-11	Low foaming automatic dishwashing compositions
EP0821722B1 (en)	2000-07-26	Preparation and use of composite particles containing diacyl peroxide
EP0796317B1 (en)	2000-03-01	Automatic dishwashing composition containing particles of diacyl peroxides
JP3299979B2 (ja)	2002-07-08	低発泡性自動食器洗浄組成物
EP0925342B1 (en)	2000-08-23	Automatic dishwashing compositions containing low foaming nonionic surfactants in conjunction with enzymes
US6093343A (en)	2000-07-25	Detergent particles comprising metal-containing bleach catalysts
EP0717102A1 (en)	1996-06-19	Liquid automatic dishwashing detergent composition containing diacyl peroxides
US5877134A (en)	1999-03-02	Low foaming automatic dishwashing compositions
US6013613A (en)	2000-01-11	Low foaming automatic dishwashing compositions
EP0677576A2 (en)	1995-10-18	Automatic dishwashing composition containing bleach activators
CA2236466C (en)	2006-02-14	Bleach catalyst particles
CA2240818C (en)	2006-06-27	Phosphate built automatic dishwashing compositions comprising catalysts
MXPA98003551A (es)	1998-11-16	Particulas de catalizador de blanqueo
CA2240955A1 (en)	1997-06-26	Bleach catalyst plus enzyme particles
CA2546759A1 (en)	1997-06-26	Low-foaming granular automatic diswashing detergent comprising metal-containing bleach catalyst
HK1003389B (en)	2000-11-24	Automatic dishwashing composition containing particles of diacyl peroxides

Legal Events

Date	Code	Title	Description
1998-08-05	EEER	Examination request
2003-01-31	MKLA	Lapsed