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CA2007022C - Coaxial filter cigarette - Google Patents

Coaxial filter cigarette

Info

Publication number
CA2007022C
CA2007022C CA002007022A CA2007022A CA2007022C CA 2007022 C CA2007022 C CA 2007022C CA 002007022 A CA002007022 A CA 002007022A CA 2007022 A CA2007022 A CA 2007022A CA 2007022 C CA2007022 C CA 2007022C
Authority
CA
Canada
Prior art keywords
filter
wrapper
rod portion
coaxial
inner core
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CA002007022A
Other languages
French (fr)
Other versions
CA2007022A1 (en
Inventor
Werner Schneider
Horst Borowski
Erwin Kausch
Rolf Kutting
Meinhard Meyer
Knut Moller
Bernd-Henrik Muller
Erhard Rittershaus
Gert Rudolph
Adolf Schluter
Wolfgang Wiethaup
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
British American Tobacco Germany GmbH
Original Assignee
British American Tobacco Germany GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by British American Tobacco Germany GmbH filed Critical British American Tobacco Germany GmbH
Publication of CA2007022A1 publication Critical patent/CA2007022A1/en
Application granted granted Critical
Publication of CA2007022C publication Critical patent/CA2007022C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D1/00Cigars; Cigarettes
    • AHUMAN NECESSITIES
    • A24TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
    • A24DCIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
    • A24D3/00Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
    • A24D3/04Tobacco smoke filters characterised by their shape or structure

Landscapes

  • Cigarettes, Filters, And Manufacturing Of Filters (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Networks Using Active Elements (AREA)

Abstract

A coaxial filter cigarette with a rod portion having an inner core of material glowing substantially free of residue, in particular tobacco material, a sheath or wrapper for the inner core, an outer shell of tobacco and/or non-tobacco material coaxially surrounding the inner core or its sheath, respec-tively, a sheath or wrapper for the outer shell, and with a filter portion having a filter core, an air-impermeable sheath or wrapper for the filter core, a filter shell and a sheath or wrapper for the filter shell comprises a zone of the main heat source which is located in the inner core of the rod portion and a zone in which the major part of the aerosol reaching the mouth of the smoker is produced and which is located in the outer shell of the rod portion; the filter portion greatly reduces the combustion gases originating from the inner core of the rod portion and substantially reduces the smoke par-ticles originating from the inner core, whereas the aerosol produced in the outer shell of the rod portion is influenced only slightly or not at all.

Description

Z(~070Z2 COAXIAL FILTER CIGARETTE

BACKGROUND OF THE INVENTION

1. Field of the Invention The invention relates to a coaxial filter cigarette comprising a rod portion having an inner core of a material glowing sub-stantially free of residue, in particular tobacco material, a sheath or wrappe-r for the inner core, an outer shell of a tobacco and/or non-tobacco material coaxially surrounding the inner core or its sheath or wrapper respectively and a sheath or wrapper for the outer shell as well as a filter portion.
2. Description of the Prior Art A number of publications on so-called "coaxial smokable ar-ticles" exists, i.e. in particular coaxial cigars or cigar-ettes having an inner core which is surrounded by a shell or jacket of tobacco material. The basic principle of such a coaxial cigarette is known, for example, from French Patent Specification No. 998,556; here the inner core consists of tobacco of lower quali~y which is surrounded by an annular shell of tobacco of high quality. This makes it possible to achieve savings as regards the costs of the tobacco materials used.

Further designs of such coaxial cigarettes are disclosed in French Patent Specification No. 1,322,254, United States Patent No. 3,614,956, United States Patent No. 4,219,031, British Patent Specification No. 2,070,409, British Patent No. 1, 086,443 and German Offenlegungsschrift No. 3,602,846.
Furthermore, United States Patent No. 3,356,094 discloses .. , a coaxial cigarette having an inner hollow tube and an aero-sol production zone with a narrow outlet; the making of this coaxial cigarette is, however, very complicated and thus ex-pensive; moreover, the various components are separated from each other so that an unusual smoke pattern results.

Finally, a coaxial filter cigarette of the aforementioned type is known from the Canadian Patent Specification No. 588, 319 and comprises a rod portion and a filter portion; the rod portion contains an inner core of a material glowing substantially free of residue, in particular tobacco material, a sheath or wrapper for the inner core, an outer shell of a tobacco and/or non-tobacco material coaxially sur-rounding the inner core or its sheath or wrapper, respective-ly, and a sheath or wrapper for the outer core.

The filter portion comprises a filter core, an~air-impermeable sheath or wrapper for the filter core, a filter shell and a sheath or wrapper for the filter shell.

The basic principle of this coaxial filter cigarette resides in a distinction in the radial direction between two regions, that is the zone of the main heat source on the one hand and the zone in which the major part of the aerosol reaching the mouth of the smoker is produced on the other hand. The heat generating zone is in the outer shell and the aerosol produc-ing zone is in the inner core of the rod portion.

In such a design of a coaxial filter cigarette the desired reduction of the secondary stream (smoke) is problematical and can be achieved only with great expenditure of time and expense. Moreover, such a coaxial filter cigarette has an inflammatory potential similar to that of a conventional cigarette.

, - 3 -. . .

SlJMMARY OF THE INVENTION

The invention therefore has as its object the provision of a coaxial filter cigarette of the specified kind in which the aforementioned disadvantages do not occur.

In particular, a coaxial filter cigarette is to be proposed, in which the smoke reaching S the mouth of the smoker has a high proportion of flavour-relevant components and a very low proportion of undesirable combustion products; at the same time the secondary stream (smoke) on the one hand and the infl~mm~tion potential on the other are to be reduced compared with con~elltional cigarettes.

For solving these objects, the invention therefore proposes in a coaxial a coaxial filter 10 cigarette col~lplising: a rod portion defined by an outer wrapper; an inner core di;,~oscd coaxially within said rod portion defined by a coaxially disposed inner Wl~ lel, a main heat source disposed within said inner core, said main heat source being a material which glows substantially residue-free; an outer shell defined by a space created between the outer wrapper and said inner wrapper, said outer shell15 being filled with an aerosol producing material consi~ g of at least one of the group conc;~ e of tobacco and non-tobacco materials; additives for controlling combustion hltelllliAed with said main heat source; a filter portion disposed at one end of the rod portion, with a single coaxial filter element having a filter core with an air impermeable wrapper and a filter shell; said filter core removing greater than 95%
20 of smoke received into said filter core generated through combustion of said rod portion, and said filter shell removing a maxillluln of 60% of said smoke flowing into said filter shell.

VLS-.jj 4 ~, . -~00702Z
-The advantages achieved with the invention are due to the fact that in a coaxial rod the zone of the main heat source on the one hand and the zone in which the greater part of the aero-sol reaching the mouth of the smoker on the other hand are specially separated. In contrast to the coaxial filter clga-rette according to the Canadian Patent Specification No. 585,319 the aerosol is produced in the outer shell and the heat in the inner core of the rod portion of the ciga-rette.

Both the rod por-tion and the adjoining filter portion, i.e.
the materials used therein in conjunction with their speci-fications determining the flow dynamics, are so designed that a substantial separation of the streams in the outer shell and in the core is ensured.

The filter portion is so constructed that the smoke particles originating from the inner core of the rod portion are sub-stantially reduced, whereas the aerosol produced in the outer shell of the rod portion is only slightly or not at all di-minished.

Due to the spatial arrangement of the heat generation in the inner core of the rod portion, the secondary stream (smoke) can be substantially reduced by relatively simple construc-tional measures because the combustion products are shielded by the outer shell of the rod portion and thus given off lar-gely via the main stream (smoke).

At the same time a reduction of the ignition or inflammation potential of the cigarette is achieved because the heat gene-ration zone is located in the inner core of the rod portion and thus likewise shielded by the outer shell. The tempera-tures at the surface of the cigarette are thus comparatively ~, low and consequently even on longer contact between the peri-pheral surface of the cigarette and a combustible material no ignition or inflammation can occur.

If in a filterless coaxial cigarette the heat generation zone were located in the inner core, a high proportion of carbon monoxide (CO) or undesirable smoke components, respectively, would pass from the combustion zone into the mouth of the smoker; in addition, on sealing the end of the inner core of the rod portion, no reaction of the combustion zone would follow after the smoker had taken a draw.

These disadvantages can be avoided by a configuration of the filter portion which is adapted to the configuration of the rod portion and so designed that the smoke particles origi-nating from the inner core of the rod portion are substan-tially reduced, whereas the aerosol produced in the outer shell of the rod portion is only slightly or not at all in-fluenced.

If the mixture used for the rod portion supplies only amounts of gaseous smoke so small that an additional reduction by ven-tilation/diffusion is not necessary, a relatively simple co-axial filter element having a suitable sheath or wrapper and an associated tipping paper can be used. The tipping paper can be air-impermeable, porous in nature and/or can be provided with a ventilation zone, which is preferably produced by laser beams and extends in the peripheral direction of the filter portion.

If the tipping paper is porous or preperforated, the sheath paper or wrapper of the single filter element must also be porous. In all other cases, the sheath paper or wrapper may have any desired form.

, ,~

Z(~070Z2 For most uses, however, such a mouth-side filter element is combined with a rod-side diffusion and ventilation ele-ment (passage filter element) to ensure an optimum adapta-tion to the smoke products and aerosols produced by the rod portion.

Thus, in these cases the diffusion and ventilation element (passage filter element) serves to reduce the gas components which are produced by the combustion occurring in the inner core of the rod portion, whilst the filter element combined therewith traps ~he smoke particles originating from the inner core of the rod portion and practically does not in-fluence the aerosoIs produced in the outer shell of the rod portion.

BRIEF DESCRIPTION OF THE DRAWINGS

The invention will be described in detail hereinafter with the aid of examples of embodiment with reference to the attached schematic drawings, wherein:
ig. 1 shows an axial section through a coaxial filter cigarette, ig. 2 is a illustration corresponding to Fig. 1 of a further embodiment of the filter portion of such a coaxial filter cigarette, ig. 3 is a section through the rod-side diffusion and ventilation element of the filter portion accord-in to Fig. 2 and ig. 4 in an illustration corresponding to Fig. 1 of a further embodiment of the filter portion.

DESCRIPTION OF THE PREFERRED EMBODIMENTS

The coaxial filter cigarette shown in Fig. 1 and denoted generally by the reference numeral 10 comprises a rod por-tion 12 to which a coaxial filter portion 13 is attached by the usual assembly techniques. The rod portion 12 includes an inner core 14 having a sheath or wrapper 16 and an outer shell 18 with a sheath or wrapper 20.

In the embodiment according to Fig. 1 the filter portion 13 comprises a s~ngle coaxial filter element 15 with a fil-ter core 22 having a sheath or wrapper 24 and with a filter shell 26 having sheath or wrapper 28.

The coaxial filter element 15 can be ventilated as will be explained below; the ventilation means is indicated by a line of punctiform ventilation openings or holes 30 which extend over the periphery of the coaxial filter èlement 15, as well as through the tipping paper (not shown).

The coaxial rod portion serves for smoke and vapour gener-ation and has a length of 25 to 85 mm and a diameter of 7 to 9 mm, i.e. the usual dimensions of conventional cigarettes.

The inner core 14 of the rod portion 12 has a diameter of 2 to 6 mm and consists of tobacco or another allowable material which decomposes under the action of heat. Additives for con-trolling the combustion are added to the material of the inner core 14 and ensure that the heat generation zone of the rod portion 12 is located in the inner core 14.

The air-impermeable sheath 16 of the inner core 14 of the rod portion 12 consists of paper, a foil of tobacco material or another suitable air-impermeable material and comprises at ,~ - 8 -':

least one passage for sucking air into the interior of the inner core 14 in order in this manner to control the combus-tion in the heat generating zone in the inner core 14. In accordance with the desired draw number, the air suction passage(s) must extend from the ignition side at least over a part of the length of the rod portion 12.

Various alternatives are available for implementing said air suction passage; the inner core 14 may, for example, be form-ed by an extruda~e or a compact with impressed channels; as alternative, the material of the inner core 14 may be formed as open-pore body; also, the sheath 16 of the inner core 14 can be made double-walled with continuous inner passages;
finally, the sheath 16 of the inner core 14 of the rod por-tion 12 can contain rod-like bulges as spacers at the inner side.

The sheath 16 of the inner core 14 may be embossed, corru-gated or grooved so that free flow passages are formed in the longitudinal direction of the coaxial filter cigarette 10.

The outer shell 18 of the rod portion 12 consists of tobacco, other materials made from tobacco, materials decomposing under the action of heat (and/or of materials which are thermally stable at temperatures up to 500 or 600C) which can be crumbled under mechanical action, and/or of combi-nations of such materials, and contains additives for con-trolling the thermal processes and the combination of aro-matics and flavourings, referred to as "casing", which is generally present in solutions and contain sugar, moisten-ing agents and similar substances.

Both the additives for controlling the thermal processes and the casing materials are preferably present in high v concentration, i.e. in total concentrations of more than 5% with respect to the material weight of the outer shell 18 of the rod portion 12.

Alternatively or additionally, the outer shell 18 may con-tain further materials which on being heated to a tempera-ture of about 500C are largely transferred into the vapour and/or aerosol state without undesirable components being released.

The outer sheath.20 of the outer shell 18 of the rod por-tion 12 is either air-impermeable or has a very low air permeability of less than 25 ISO units, it consists of a cigarette paper, preferably with a heat-insulating coating, or of a heat-insulating material, it also contains addi-tives for controlling the combustion.

The outer sheath 20 of the outer shell 18 of the rod por-tion 12 may possibly be provided with segment perforations for controlling the temperature gradients in the outer shell 18, the use and/or the configuration of these segment perfo-rations depends on the other materials employed.

If the mixture in the rod portion 12 furnishes such small amounts of smoke gas that an additional reduction of the amounts of gaseous smoke by ventilation/diffusion is not necessray, the filter portion 13 can consist (see the em-bodiment in Fig. 1) of a single coaxial filter element 15 having an outer diameter which corresponds to the outer diameter of the rod portion 12, i.e. is about 7 to 9 mm.
The length of said single coaxial filter element 15 lies in the range from 10 to 40 mm.

The diameter of the filter core 22 lies in the range from , .
2 to 6 mm, i.e. corresponds substantially to the diameter of the inner core 14 of the rod portion 12; in accordance with a preferred embodiment said diameter is about 2 mm larger than the diameter of the inner core 14.

The filter efficiency of the filter core 22 should be more than 95% of the smoke streaming into the filter core 22.
The filter core 22 may consist of the usual filter materials, preferably cellulose acetate.

The sheath of the filter core 22 is air-impermeable and may consis-t of paper, polyethylene or preferably also cel-lulose acetate.

The filter shell 26 has a filter efficiency of 0 to 60% for the smoke entering the filter shell 26, in particular a fil-ter efficiency of 10 to 30%, and may consist of the known filter materials but also of tobacco.

According to a preferred embodiment the filter shell 26 is made from cellulose acetate.

If only the coaxial filter element 15 is used, a suitable sheath 28 is employed in combination with a tipping paper which is air-impermeable, porous and/or is provided with a ventilation zone 30 preferably produced with laser beams and extending in the peripheral direction.

The sheath or wrapper 28 of the filter shell 26, generally a paper wrapper, must be porous as well only when the tipp-ing paper serving to attach the filter element 15 to the rod portion 12 is porous or preperforated. In all other cases the air permeability of the sheath 28 of the filter shell 26 may be selected as desired.

~,...
.~ .

However, as a rule the mlxture in the rod portion 12 produces such large amounts of gaseous smoke that the coaxial filter element 15 alone is not sufficient; in such a case the embodi-ment according to Fig. 2 may be employed, in which the filter element 15 is combined with the structure explained above and having a rod-side diffusion and ventilation element 32. In this case, the air permeability of the sheath 28 of the outer shell 26 of the filter portion 15 may be selected as desired;
the sheath 28 may either be provided with an air-impermeable tipping paper or the same tipping paper as in the diffusion and ventilation-element 32 (still to be explained) may be used; in the first case two different tipping papers are necessary for the two filter elements, whilst in the second case a single unitary tipping paper may be employed for the entire filter portion 13.

The rod-side diffusion and ventilation element 32 has a length of 10 to 40 mm and a diameter which corresponds to the dia-meter of the outer shell 18 of the rod portion 12, i.e. lies in the range from about 7 to 9 mm.

The diffusion and ventilation element 32 may be formed as fibre filter having the lowest packing density which can still be processed or as holl~w element of a plastic material; in Fig. 2 such a hollow element 32 with a cavity 33 is indicat-ed. The hollow element 32 may contain usual chamber filter materials or other pourable or granulate material which is suitable for reducing the components of the gas phase of the resulting smoke.

When an air-impermeable material is used to make the hollow element 32, the outer surface of said hollow element 32 must have an adequate number of perforations; the total perfor-ation area must be at least 10% of the outer area of the , hollow element 32; the walls of outer passages 34 (still to be explained) in any case must be impermeable and not perfo-rated.

In the ventilation and diffusion element 32 at least four outer passages 34 are provided which on their inside are air-impermeable and have a rectangular form, the longer side of the rectangle is perpendicular to the outer surface of the ventilation and diffusion element 32 as can be seen in Fig. 3.

The decisive cri-~erion for the shape of the outer passages 34 is as great as possible a cross-sectional area with as small as possible a proportion of the outer surface of the element 32.

The radial depth of the passages 34 must not be larger than the radius of the outer shell 18 of the rod portion 12 minus the radius of the inner core 14 of the rod portion 12.

The mouth-side end face of the hollow element 32, i.e. the end face directed towards the filter element 15, is configur-ed so that the stream from the outer passages 34 is conduct-ed into the filter shell 26 of the adjacent coaxial filter element 15, whereas the-stream from the cavity of the hollow element 32 is conducted into the filter core 22 of the ad-joining filter element 15.

In a possible realisation of the described embodiment, the ventilation and diffusion element 32 and in particular its separation function between the filter element 15 and the rod portion 12 can be implemented by a corresponding partial sealing of the mouth-side end face of the filter element 32, for example, by using a specially shaped filter element with a diaphragm, as is known fundamentally from German Patent , Z~070Z2 . .
.
Specification No. 3,400,004, or by using an additional inter-mediate element (not shown in Fig. 2) having the following properties:

The intermediate element has a length of 3 to 7 mm, a diameter corresponding to the outer diameter of the filter element 15, outer passages corrsponding to the outer passages 34 of the hollow element 32, and a hollow inner tube having a diameter which is at least 1 mm smaller than the diameter of the"fil-ter core 22 of the filter element 15. This intermediate ele-ment must consis,t, of an air-impermeable material.

The sheath or wrapper 28 of the hollow element 32 has a very high air-permeability of at least 10000 ISO units, this desired high air permeability can be achieved also if no sheath 28 at all is employed.

For attaching the filter portion 13 to the rod portion 12, a tipping paper of low air permeability in the range from 20 to 150 ISO units is used and should at the same time en-sure a high diffusion of gases with low molecular weight (e.g. CO).

If desired, the filter ~ortion 13 according to Fig. 2 may also be provided with a ventilation zone 30 which is spaced about 2 to 5 mm from the mouth-side end of the element 32 and ensures that the filter portion 13 has a ventilation degree of 5 to 80%.

Fig. 4 shows a further embodiment of the filter portion 13 which consists in this case of a mouth-side filter element 36 and a rod-side passage filter element 38.

The mouth-side filter element 36 has a length of 6 to 24 mm, ,~

. . .

Z(~070ZZ

a diameter of 7 to 9 mm corresponding to the diameter of the rod portion 12, and consists of a material having the usual filter properties, preferably cellulose acetate.

The filter material of the filter element 36 has a specific draw resistance of preferably less than 150 Pa/cm.

If the filter element 36 is longer than 10 mm a ventilation zone 30 may be provided, ensuring a ventilation degree of 5 to 80%. The ventilation zone should be spaced at least 10 mm from the mouth-side end of the filter element 36 and thus of the filter portion 13 to ensure that the lips of the smoker cannot close the ventilation perforations.

The rod-side passage filter element 38 has a length of 10 to 34 mm and comprises likewise outer passages 34, as are provided in the embodiment according to Fig. 2.

The sheath 28 and the tipping paper (not illustrated) of the filter element 13 also have the properties described with re-spect to the embodiment shown in Fig. 2.

The rod-side passage filter element 38 is filled with the usual filter materials, especially cellulose acetate, the specifications of which are selected in dependece upon the length of the passage filter element 38 in such a manner that the smoke particles given off from the inner core 14 of the rod portion 12 are filtered to at least 95%.

,,

Claims (10)

1. A coaxial filter cigarette comprising:
a rod portion defined by an outer wrapper;
an inner core disposed coaxially within said rod portion defined by a coaxially disposed inner wrapper;
a main heat source disposed within said inner core, said main heat source being a material which glows substantially residue-free;
an outer shell defined by a space created between the outer wrapper and said inner wrapper, said outer shell being filled with an aerosol producing material consisting of at least one of the group consisting of tobacco and non-tobacco materials;
additives for controlling combustion intermixed with said main heat source;
a filter portion disposed at one end of the rod portion, with a single coaxial filter element having a filter core with an air impermeable wrapper and a filter shell;
said filter core removing greater than 95% of smoke received into said filter core generated through combustion of said rod portion, and said filter shell removing a maximum of 60% of said smoke flowing into said filter shell.
2. A coaxial filter cigarette according to claim 1, wherein said wrapper of the inner core of the rod portion is air-impermeable but has at least one passage for sucking air into the inner core.
3. A coaxial filter cigarette according to claim 1, wherein said outer shell of the rod portion contains additives for controlling the thermal processes.
4. A coaxial filter cigarette according to claim 1, wherein said wrapper of the outer shell of the rod portion has a very low air permeability of at the most 25 ISO
units.
5. A coaxial filter cigarette according to claim 1, wherein said wrapper of the outer shell of the rod portion contains additives for controlling the combustion.
6. A coaxial filter cigarette according to claim 1, wherein a rod-side diffusion and ventilation element having a wrapper with outer passages is disposed between said coaxial filter element and the rod portion.
7. A coaxial filter cigarette according to claim 6, wherein the filter portion comprises a further intermediate element having outer passages and a hollow inner tube, the diameter of which is at least 1 mm smaller than the diameter of the filter core.
8. A coaxial filter cigarette according to claim 6, wherein said wrapper of said diffusion and ventilation element is air permeable.
9. A coaxial filter cigarette according to claim 1, wherein said filter shell removes
10-30% of said smoke flowing into said filter shell.
CA002007022A 1989-01-17 1990-01-03 Coaxial filter cigarette Expired - Fee Related CA2007022C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DEP3901226.3 1989-01-17
DE3901226A DE3901226C1 (en) 1989-01-17 1989-01-17

Publications (2)

Publication Number Publication Date
CA2007022A1 CA2007022A1 (en) 1990-07-17
CA2007022C true CA2007022C (en) 1996-09-03

Family

ID=6372241

Family Applications (1)

Application Number Title Priority Date Filing Date
CA002007022A Expired - Fee Related CA2007022C (en) 1989-01-17 1990-01-03 Coaxial filter cigarette

Country Status (9)

Country Link
EP (1) EP0378788B1 (en)
JP (1) JP2594657B2 (en)
AT (1) ATE96288T1 (en)
AU (1) AU621451B2 (en)
CA (1) CA2007022C (en)
DE (2) DE3901226C1 (en)
DK (1) DK173403B1 (en)
FI (1) FI89552C (en)
MY (1) MY105180A (en)

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Also Published As

Publication number Publication date
JPH02234661A (en) 1990-09-17
FI900155A0 (en) 1990-01-11
FI900155L (en) 1990-07-18
EP0378788B1 (en) 1993-10-27
HK1005842A1 (en) 1999-01-29
DE3901226C1 (en) 1990-07-26
JP2594657B2 (en) 1997-03-26
ATE96288T1 (en) 1993-11-15
FI89552C (en) 1993-10-25
DK7390A (en) 1990-07-18
AU4850190A (en) 1990-07-26
FI89552B (en) 1993-07-15
AU621451B2 (en) 1992-03-12
DE58906030D1 (en) 1993-12-02
DK173403B1 (en) 2000-09-25
MY105180A (en) 1994-08-30
EP0378788A1 (en) 1990-07-25
DK7390D0 (en) 1990-01-11
CA2007022A1 (en) 1990-07-17

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