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CA1336364C - High damping capacity, two-phase fe-mn-al-c alloy - Google Patents

High damping capacity, two-phase fe-mn-al-c alloy

Info

Publication number
CA1336364C
CA1336364C CA000605033A CA605033A CA1336364C CA 1336364 C CA1336364 C CA 1336364C CA 000605033 A CA000605033 A CA 000605033A CA 605033 A CA605033 A CA 605033A CA 1336364 C CA1336364 C CA 1336364C
Authority
CA
Canada
Prior art keywords
alloy
cast iron
phase
alloys
damping capacity
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CA000605033A
Other languages
French (fr)
Inventor
Chi-Meen Wan
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Famcy Steel Corp
Original Assignee
Famcy Steel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US07/218,695 external-priority patent/US4875933A/en
Application filed by Famcy Steel Corp filed Critical Famcy Steel Corp
Application granted granted Critical
Publication of CA1336364C publication Critical patent/CA1336364C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/06Ferrous alloys, e.g. steel alloys containing aluminium
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C38/00Ferrous alloys, e.g. steel alloys
    • C22C38/04Ferrous alloys, e.g. steel alloys containing manganese

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Heat Treatment Of Steel (AREA)
  • Manufacture Of Alloys Or Alloy Compounds (AREA)
  • Laminated Bodies (AREA)

Abstract

Carbon steels and other hot-and cold-workable ferrous alloys generally have poor damping capacity as compared to that cast iron(gray cast iron, malleable cast iron and ductile cast iron). This is because the graphite in cast irons helps to absorb the damping force and depresses the damping wave. But cast iron can not be rolled into strip or sheet. By controlling the correlated concentrations of manganese, aluminum and carbon, Fe-Mn-Al-C based alloys are made to be a .alpha.+.gamma. two-phase alloy steel with different .alpha. and .gamma. volume fractions. With particular ferrite volumes, workable Fe-Mn-Al-C based alloys have equivalent and better damping capacity than that of cast irons especially in the high frequency side. Such alloys suppress the vibration noise that comes from machine rooms, motors, air conditioners, and etc.
Chromium and other minor amount of elements can be added to this alloy system to improve the corrosion resistance.

Description

1 ~36364 HIGH DAMPING CAPACITY, TWO-PHASE Fe-Mn-Al-C ALLOY

BACKGROUND:
For the past years alpha-gamma two-phase alloys have been developed by adding molybdenum and cobalt to the Fe-Ni-Cr alloy syætem for the purpose of making alloys having both better stress corrosion and hydrogen embrittlement resistance.
But none of these alloys was designed for the purpose of higher damping capacity. The iron-base materials that have been used for high damping capacity are the cast irons. The graphite in gray cast irons is the most important factor for absorbing the high frequency vibration wave. But cast irons generally are not workable, making them of limited value in highdamping applications.
DESCRIPTION OF THE DRAWING
In the drawing:
Figure 1 depicts the damping capacity curve for an alloy of the invention; and Figure 2 depicts the damping capacity curve for ductile iron.
DETAILED DESCRIPTION OF THE INVENTION:
In Fe-Mn-Al-C alloys, manganese and carbon are gamma-phase formers and aluminum is an alpha-phase former. By suitable compositonal arrangement, Fe-Mn-~l-C alloys can be designed to be fully gamma phase, such as Fe-29Mn-7~1-lC.
Reduction of the manganese or carbon or both of them and the ~_ increase of aluminum can promote the appearance of alpha phase, and make the alloy an alpha+gamma two-phase ~teel. The volume fraction of alpha phase can be controlled by changing the amount of manganese or aluminum or carbon or other ferrite-forming elements.

la 60538-1062 The invention provides a ferrite-austenite two-phase alloy characterized by high damping capa~ity having a composition consisting essentially of about 10 to 45 wt%
manganese, about 4 to 15 wt% aluminum, 0 to about 12 wt%
chromium, about 0.01 to 0.7 wt% carbon and at least one of 0 to 4.0 wt% molybdenum, 0 to 4.0 wt% copper, 0 to 2.0 wt%
nickel, 0 to 3.5 wt% niobium, 0 to 500 ppm boron, 0 to 0.2 wt%
nitrogen, 0 to 3.5 wt% titanium, 0 to 2.0 wt% cobalt, 0 to 3.5 wt% vanadium, 0 to 3.5 wt% tungsten, 0 to 2.0 wt%
zirconium, and 0 to 2.5 wt% silicon and the balance essentially iron, said manganese and carbon as austenite formers being correlated relative to aluminum as a ferrite former such as to provide a two-phase alloy containing by volume about 25~ to 75~
ferrite and the balance essentially austenite, said alloy being characterized by a damping capa~ity substantially equivalent to that of ductile iron.

B

E~ample 1. -2- 1 3 3 6 3 6 4 This example illustrates the effect of the element compositions on the change of oc volume fraction in the E`e-Mn-Al-C based alloys. Manganese and car~on are austenite phase stabilizers and aluminum is a ferrite phase former. The effect of the carbon content on the fe~Tite fraction of the Fe-Mn-Al-C based alloys is shown in Table I. in which the chemical composition of aIuminum and manganese are essentially constant and the carbon content decreases from 0.6 wt% to 0.11 wt~o.With the decreasing of carbon content, the ferrite phase volume fractions of the alloys increases from 0% to 36%. With the change of manganese, carbon and alt~minum contents, the volume fractions of ferrite phase and balanced y phase is controlled to be from 25% to 76%. Within this ferrite fraction range, excellent damping capacity is always found in the Fe-Mn-Al-C based alloy.
Table I
\ composition Mn Al C ferrite vol%
alloy ~ t%) (wt%) (wt%) 1 26.0 7.4 0.5 0 2 26.3 7.6 0.34 11.9 3 25.8 7.4 0.11 36.0 E Y~rnPIe 2.
This example illustrates the good damping capacity of the said a+~ two-phase Fe-Mn-Al-C based alloys which have been measured and determined with comparison to ductile cast iron. The test sample of the invention contained 19.7Mn-5.84Al-5.74Cr-0.19C. The ferrite volume fraction is about 6~to balanced with y phase. The damping capacity curves of the d~rnping capacity tests of the Fe-~In-Al-C
based alloy and ductile cast iron are shown in Fig. 1 and Fig. 2. It is seen that the damping capacities of the two alloys are almost equivalent.

-3- 1 3:36364 ~E~ample 3.
-- This e~ample illustrates the good workability of a+y two-phase Fe-Mn-Al-C based alloys. The alloys listed in Table II were cast into ingot; homogenized at 1200C; cut and hot forged at 1200C; further ~nne~led at 1150C and descaled. The alloys were cold rolled into 2.0 mm thick strip and annealed. The fernte v~lume percentages of these strips were measured and are listed in Table III. The mechanical properties of these annealed strips are also listed in Table III. It is seen that the alloys of the invention have good workablility and excellent mechanical propertIes.
Table ll.
alloyno. I Mn ~ Al I C I Cr I Other #109 25.1 6.7 0.287 5.6 200ppmN2 #108 30.3 6.3 0.244 5.8 #320 21.6 6.8 0.11 0 ----#317 20.0 6.1 0.4 5.5 0.92Mo #129 33.4 10.3 0.47 2.1 0.2Ti #116 29.5 10.2 0.4 0 0.1Nb Table lll Isample no. 0.2% proof ultimate tensile % elongation hardness ferrite stress(ksi) stress (ksi) (Rb) %

~108 39 94 44 80 28 7r320 41 98 43 82 67 tr317 44 101 41 83 75 .t 129 61 112 38 86 65 tr 116 59 109 37 85 73

Claims (13)

1. A ferrite-austenite two-phase alloy characterized by high damping capacity having a composition consisting essentially of about 10 to 45 wt% manganese, about 4 to 15 wt%
aluminum, 0 to about 12 wt% chromium, about 0.01 to 0.7 wt%
carbon and at least one of 0 to 4.0 wt% molybdenum, 0 to 4.0 wt% copper, 0 to 2.0 wt% nickel, 0 to 3.5 wt% niobium, 0 to 500 ppm boron, 0 to 0.2 wt% nitrogen, 0 to 3.5 wt%
titanium, 0 to 2.0 wt% cobalt, 0 to 3.5 wt% vanadium, 0 to 3.5 wt% tungsten, 0 to 2.0 wt% zirconium, and 0 to 2.5 wt%
silicon and the balance essentially iron, said manganese and carbon as austenite formers being correlated relative to aluminum as a ferrite former such as to provide a two-phase alloy containing by volume about 25% to 75% ferrite and the balance essentially austenite, said alloy being characterized by a damping capacity substantially equivalent to that of ductile iron.
2. The alloy of claim 1 containing 0 to 4.0 wt%
molybdenum.
3. The alloy of claim 1 containing 0 to 4.0 wt% copper.
4. The alloy of claim 1 containing 0 to 2.0 wt% nickel.
5. The alloy of claim 1 containing 0 to 3.5 wt% niobium.
6. The alloy of claim 1 containing 0 to 500 ppm boron.
7. The alloy of claim 1 containing 0 to 0.2 wt%
nitrogen.
8. The alloy of claim 1 containing 0 to 3.5 wt%
titanium.
9. The alloy of claim 1 containing 0 to 2.0 wt% cobalt.
10. The alloy of claim 1 containing 0 to 3.5 wt% vanadium
11. The alloy of claim 1 containing 0 to 3.5 wt%
tungsten.
12. The alloy of claim 1 containing 0 to 2.0 wt%
zirconium.
13. The alloy of claim 1 containing 0 to 2.5 wt% silicon.
CA000605033A 1988-07-08 1989-07-07 High damping capacity, two-phase fe-mn-al-c alloy Expired - Fee Related CA1336364C (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US07/218,695 US4875933A (en) 1988-07-08 1988-07-08 Melting method for producing low chromium corrosion resistant and high damping capacity Fe-Mn-Al-C based alloys
US218,695 1988-07-08
US341,117 1989-04-20
US07/341,117 US4966636A (en) 1988-07-08 1989-04-20 Two-phase high damping capacity F3-Mn-Al-C based alloy

Publications (1)

Publication Number Publication Date
CA1336364C true CA1336364C (en) 1995-07-25

Family

ID=26913151

Family Applications (1)

Application Number Title Priority Date Filing Date
CA000605033A Expired - Fee Related CA1336364C (en) 1988-07-08 1989-07-07 High damping capacity, two-phase fe-mn-al-c alloy

Country Status (7)

Country Link
EP (1) EP0380630B1 (en)
JP (1) JPH03500305A (en)
AT (1) ATE114736T1 (en)
AU (1) AU610429B2 (en)
CA (1) CA1336364C (en)
DE (1) DE68919672T2 (en)
WO (1) WO1990000629A1 (en)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR960006453B1 (en) * 1993-10-22 1996-05-16 최종술 Fe-Mn vibration damping alloy steel and its manufacturing method
CN1043253C (en) * 1995-08-18 1999-05-05 赵学胜 Al-Mn-Si-N series austenitic stainless acid-resisting steel
DE10259230B4 (en) * 2002-12-17 2005-04-14 Thyssenkrupp Stahl Ag Method for producing a steel product
US20090165897A1 (en) * 2005-02-02 2009-07-02 Corus Staal Bv Austenitic steel having high strength and formability, method of producing said steel and use thereof
EP2008971A4 (en) 2006-04-20 2010-08-04 Asahi Glass Co Ltd CORE SILICA-ENVELOPE AND METHOD FOR MANUFACTURING SAME
WO2013064202A1 (en) * 2011-11-03 2013-05-10 Tata Steel Nederland Technology B.V. Method of manufacturing a duplex steel sheet having enhanced formability
WO2013178887A1 (en) * 2012-05-31 2013-12-05 Arcelormittal Investigación Desarrollo Sl Low-density hot- or cold-rolled steel, method for implementing same and use thereof
DK3265102T3 (en) 2015-03-06 2025-10-13 Atea Pharmaceuticals Inc BETA-D-2'-DEOXY-2'ALPHA-FLUORO-2'-BETA-C-SUBSTITUTED-2-MODIFIED-N6-SUBSTITUTED PURIN NUCLEOTIDES FOR HCV TREATMENT
CN104674109B (en) * 2015-03-11 2017-01-18 北京科技大学 Low-density Fe-Mn-Al-C system cold-rolled automobile steel plate and preparation method
KR101910744B1 (en) * 2017-07-26 2018-10-22 포항공과대학교 산학협력단 Medium-entropy alloys with excellent cryogenic properties

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA655825A (en) * 1963-01-15 Ciba Limited Unsaturated aliphatic amino-diols and process for their manufacture
DE1239857B (en) * 1959-06-23 1967-05-03 United States Steel Corp Use of an austenitic steel alloy for forgeable components
AU8261182A (en) * 1981-04-22 1982-10-28 Unisearch Limited Oxidation and corrosion-resistant febase-al-mn alloys
JPS60248866A (en) * 1984-05-24 1985-12-09 Yamato Metal Kogyo Kk Stainless steel for cryogenic service having excellent sea water resistance

Also Published As

Publication number Publication date
AU3981589A (en) 1990-02-05
ATE114736T1 (en) 1994-12-15
EP0380630A1 (en) 1990-08-08
EP0380630A4 (en) 1990-12-27
AU610429B2 (en) 1991-05-16
DE68919672T2 (en) 1995-04-06
DE68919672D1 (en) 1995-01-12
WO1990000629A1 (en) 1990-01-25
EP0380630B1 (en) 1994-11-30
JPH03500305A (en) 1991-01-24

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