CA1340065C - Copolymeres de greffe et melanges de ceux-ci avec des polyolefines - Google Patents

Copolymeres de greffe et melanges de ceux-ci avec des polyolefines

Info

Publication number: CA1340065C
Authority: CA; Canada
Prior art keywords: blend; weight; polymer; polypropylene; trunk
Prior art date: 1988-03-29
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

CA000593171A

Other languages

English (en)

Inventor

William James Work

Newman Bortnick

Casmir Stanislaus Ilenda

Roger Kenneth Graham

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Rohm and Haas Co

Original Assignee

Rohm and Haas Co

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1988-03-29

Filing date

1989-03-09

Publication date

1998-09-29

1989-03-09 Application filed by Rohm and Haas Co filed Critical Rohm and Haas Co

1996-08-28 Priority to CA000617058A priority Critical patent/CA1340066C/fr

1998-09-29 Application granted granted Critical

1998-09-29 Publication of CA1340065C publication Critical patent/CA1340065C/fr

2015-09-29 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

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229920000578 graft copolymer Polymers 0.000 title claims abstract description 151
229920000098 polyolefin Polymers 0.000 title claims abstract description 111
229920000642 polymer Polymers 0.000 claims abstract description 152
239000000178 monomer Substances 0.000 claims abstract description 94
239000002904 solvent Substances 0.000 claims abstract description 47
239000003999 initiator Substances 0.000 claims abstract description 35
CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims abstract description 34
229920002959 polymer blend Polymers 0.000 claims abstract description 32
239000007787 solid Substances 0.000 claims abstract description 27
229930195733 hydrocarbon Natural products 0.000 claims abstract description 25
150000002430 hydrocarbons Chemical class 0.000 claims abstract description 25
239000011159 matrix material Substances 0.000 claims abstract description 25
239000004215 Carbon black (E152) Substances 0.000 claims abstract description 24
238000010438 heat treatment Methods 0.000 claims abstract description 12
230000001965 increasing effect Effects 0.000 claims abstract description 9
238000004519 manufacturing process Methods 0.000 claims abstract description 6
-1 polyethylene Polymers 0.000 claims description 210
239000004743 Polypropylene Substances 0.000 claims description 156
229920001155 polypropylene Polymers 0.000 claims description 139
229920001577 copolymer Polymers 0.000 claims description 52
239000012141 concentrate Substances 0.000 claims description 51
150000003254 radicals Chemical class 0.000 claims description 44
238000000034 method Methods 0.000 claims description 40
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 37
238000006243 chemical reaction Methods 0.000 claims description 36
230000004907 flux Effects 0.000 claims description 36
239000000654 additive Substances 0.000 claims description 35
230000008569 process Effects 0.000 claims description 34
239000004698 Polyethylene Substances 0.000 claims description 30
JHPBZFOKBAGZBL-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylprop-2-enoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)=C JHPBZFOKBAGZBL-UHFFFAOYSA-N 0.000 claims description 29
229920000573 polyethylene Polymers 0.000 claims description 28
239000000835 fiber Substances 0.000 claims description 26
VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical group COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 24
230000000996 additive effect Effects 0.000 claims description 24
239000000243 solution Substances 0.000 claims description 23
125000000217 alkyl group Chemical group 0.000 claims description 22
239000004604 Blowing Agent Substances 0.000 claims description 17
239000003381 stabilizer Substances 0.000 claims description 16
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 15
125000003118 aryl group Chemical group 0.000 claims description 14
125000002877 alkyl aryl group Chemical group 0.000 claims description 13
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 11
150000001336 alkenes Chemical class 0.000 claims description 11
238000002156 mixing Methods 0.000 claims description 11
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239000003086 colorant Substances 0.000 claims description 9
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LEDIWWJKWAMGLD-UHFFFAOYSA-N bis(2-methylundecan-2-yl) disulfide Chemical group CCCCCCCCCC(C)(C)SSC(C)(C)CCCCCCCCC LEDIWWJKWAMGLD-UHFFFAOYSA-N 0.000 claims description 7
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239000005077 polysulfide Substances 0.000 claims description 6
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125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 6
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 5
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239000007983 Tris buffer Substances 0.000 claims description 4
125000006350 alkyl thio alkyl group Chemical group 0.000 claims description 4
238000003490 calendering Methods 0.000 claims description 4
238000007665 sagging Methods 0.000 claims description 4
238000010128 melt processing Methods 0.000 claims description 2
125000000864 peroxy group Chemical group O(O*)* 0.000 claims description 2
125000000547 substituted alkyl group Chemical group 0.000 claims 13
SNVLJLYUUXKWOJ-UHFFFAOYSA-N methylidenecarbene Chemical compound C=[C] SNVLJLYUUXKWOJ-UHFFFAOYSA-N 0.000 claims 12
125000003107 substituted aryl group Chemical group 0.000 claims 12
BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims 4
235000012438 extruded product Nutrition 0.000 claims 4
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238000010101 extrusion blow moulding Methods 0.000 claims 1
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238000001816 cooling Methods 0.000 abstract description 11
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LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 72
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239000011347 resin Substances 0.000 description 44
JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 32
PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 32
229920001903 high density polyethylene Polymers 0.000 description 22
239000004700 high-density polyethylene Substances 0.000 description 22
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239000000463 material Substances 0.000 description 21
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238000001125 extrusion Methods 0.000 description 16
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239000004926 polymethyl methacrylate Substances 0.000 description 16
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 15
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238000006116 polymerization reaction Methods 0.000 description 15
238000002360 preparation method Methods 0.000 description 15
238000012360 testing method Methods 0.000 description 15
CWPKTBMRVATCBL-UHFFFAOYSA-N 3-[1-[1-[(2-methylphenyl)methyl]piperidin-4-yl]piperidin-4-yl]-1h-benzimidazol-2-one Chemical compound CC1=CC=CC=C1CN1CCC(N2CCC(CC2)N2C(NC3=CC=CC=C32)=O)CC1 CWPKTBMRVATCBL-UHFFFAOYSA-N 0.000 description 14
238000000465 moulding Methods 0.000 description 14
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 12
239000002253 acid Substances 0.000 description 12
230000006872 improvement Effects 0.000 description 12
239000000047 product Substances 0.000 description 12
239000000454 talc Substances 0.000 description 12
229910052623 talc Inorganic materials 0.000 description 12
239000004417 polycarbonate Substances 0.000 description 11
239000013256 coordination polymer Substances 0.000 description 10
238000002347 injection Methods 0.000 description 10
239000007924 injection Substances 0.000 description 10
229920000915 polyvinyl chloride Polymers 0.000 description 10
239000004800 polyvinyl chloride Substances 0.000 description 10
229920002302 Nylon 6,6 Polymers 0.000 description 9
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238000010561 standard procedure Methods 0.000 description 9
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 8
229920000219 Ethylene vinyl alcohol Polymers 0.000 description 8
230000008901 benefit Effects 0.000 description 8
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150000002148 esters Chemical class 0.000 description 8
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150000007513 acids Chemical class 0.000 description 7
238000002425 crystallisation Methods 0.000 description 7
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UFRKOOWSQGXVKV-UHFFFAOYSA-N ethene;ethenol Chemical compound C=C.OC=C UFRKOOWSQGXVKV-UHFFFAOYSA-N 0.000 description 7
239000004715 ethylene vinyl alcohol Substances 0.000 description 7
238000005259 measurement Methods 0.000 description 7
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239000003607 modifier Substances 0.000 description 7
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229920000638 styrene acrylonitrile Polymers 0.000 description 7
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239000006260 foam Substances 0.000 description 6
239000000499 gel Substances 0.000 description 6
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229910052751 metal Inorganic materials 0.000 description 6
239000002184 metal Substances 0.000 description 6
230000004580 weight loss Effects 0.000 description 6
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
229920002292 Nylon 6 Polymers 0.000 description 5
239000004952 Polyamide Substances 0.000 description 5
239000004793 Polystyrene Substances 0.000 description 5
235000015107 ale Nutrition 0.000 description 5
230000015572 biosynthetic process Effects 0.000 description 5
230000007423 decrease Effects 0.000 description 5
239000005038 ethylene vinyl acetate Substances 0.000 description 5
229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 description 5
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238000003856 thermoforming Methods 0.000 description 5
238000012546 transfer Methods 0.000 description 5
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 4
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229920001778 nylon Polymers 0.000 description 4
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238000012545 processing Methods 0.000 description 4
IOVGROKTTNBUGK-SJCJKPOMSA-N ritodrine Chemical compound N([C@@H](C)[C@H](O)C=1C=CC(O)=CC=1)CCC1=CC=C(O)C=C1 IOVGROKTTNBUGK-SJCJKPOMSA-N 0.000 description 4
239000000126 substance Substances 0.000 description 4
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 3
HGBBKKWVSQBIMM-UHFFFAOYSA-N 2-pyrrolidin-1-yl-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)pyridine Chemical compound O1C(C)(C)C(C)(C)OB1C1=CC=C(N2CCCC2)N=C1 HGBBKKWVSQBIMM-UHFFFAOYSA-N 0.000 description 3
NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 3
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XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 3
239000004676 acrylonitrile butadiene styrene Substances 0.000 description 3
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JPNZKPRONVOMLL-UHFFFAOYSA-N azane;octadecanoic acid Chemical class [NH4+].CCCCCCCCCCCCCCCCCC([O-])=O JPNZKPRONVOMLL-UHFFFAOYSA-N 0.000 description 2
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KDGNCLDCOVTOCS-UHFFFAOYSA-N (2-methylpropan-2-yl)oxy propan-2-yl carbonate Chemical compound CC(C)OC(=O)OOC(C)(C)C KDGNCLDCOVTOCS-UHFFFAOYSA-N 0.000 description 1
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RIPYNJLMMFGZSX-UHFFFAOYSA-N (5-benzoylperoxy-2,5-dimethylhexan-2-yl) benzenecarboperoxoate Chemical compound C=1C=CC=CC=1C(=O)OOC(C)(C)CCC(C)(C)OOC(=O)C1=CC=CC=C1 RIPYNJLMMFGZSX-UHFFFAOYSA-N 0.000 description 1
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125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
229920003048 styrene butadiene rubber Polymers 0.000 description 1
229920001909 styrene-acrylic polymer Polymers 0.000 description 1
150000003440 styrenes Chemical class 0.000 description 1
239000000725 suspension Substances 0.000 description 1
238000003786 synthesis reaction Methods 0.000 description 1
CXOHVCKJGLFRKZ-AATRIKPKSA-N tert-butyl (e)-but-2-eneperoxoate Chemical compound C\C=C\C(=O)OOC(C)(C)C CXOHVCKJGLFRKZ-AATRIKPKSA-N 0.000 description 1
OPQYOFWUFGEMRZ-UHFFFAOYSA-N tert-butyl 2,2-dimethylpropaneperoxoate Chemical compound CC(C)(C)OOC(=O)C(C)(C)C OPQYOFWUFGEMRZ-UHFFFAOYSA-N 0.000 description 1
CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 1
229920001169 thermoplastic Polymers 0.000 description 1
239000012745 toughening agent Substances 0.000 description 1
230000007704 transition Effects 0.000 description 1
MGMXGCZJYUCMGY-UHFFFAOYSA-N tris(4-nonylphenyl) phosphite Chemical compound C1=CC(CCCCCCCCC)=CC=C1OP(OC=1C=CC(CCCCCCCCC)=CC=1)OC1=CC=C(CCCCCCCCC)C=C1 MGMXGCZJYUCMGY-UHFFFAOYSA-N 0.000 description 1
235000013311 vegetables Nutrition 0.000 description 1
239000003039 volatile agent Substances 0.000 description 1
238000003466 welding Methods 0.000 description 1
239000002023 wood Substances 0.000 description 1

Landscapes

Compositions Of Macromolecular Compounds (AREA)

CA000593171A 1988-03-29 1989-03-09 Copolymeres de greffe et melanges de ceux-ci avec des polyolefines Expired - Fee Related CA1340065C (fr)

Priority Applications (1)

Application Number	Priority Date	Filing Date	Title
CA000617058A CA1340066C (fr)	1988-03-29	1996-08-28	Copolymeres de greffe et leurs melanges avec des polyolefines

Applications Claiming Priority (4)

Application Number	Priority Date	Filing Date
US17464888A	1988-03-29	1988-03-29
US174,648		1988-03-29
US3155089A	1989-03-01	1989-03-01
US31550		1989-03-01

Related Child Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000617058A Division CA1340066C (fr)	1988-03-29	1996-08-28	Copolymeres de greffe et leurs melanges avec des polyolefines

Publications (1)

Publication Number	Publication Date
CA1340065C true CA1340065C (fr)	1998-09-29

Family

ID=27791108

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CA000593171A Expired - Fee Related CA1340065C (fr)	1988-03-29	1989-03-09	Copolymeres de greffe et melanges de ceux-ci avec des polyolefines

Country Status (1)

Country	Link
CA (1)	CA1340065C (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
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CN114685985A (zh) *	2022-04-11	2022-07-01	海信（山东）冰箱有限公司	高强度高耐磨易成型pa66材料及其制备方法、冰箱门铰链
CN114801341A (zh) *	2022-04-14	2022-07-29	长园电子（东莞）有限公司	一种耐穿刺绝缘双层热缩管及其制备方法
EP4134229A1 (fr)	2010-01-27	2023-02-15	SIG Technology AG	Composite pour emballage, emballage obtenu avec le composite et methode pour plier ledit composite
CN116373193A (zh) *	2023-02-24	2023-07-04	无锡恩捷新材料科技有限公司	隔离膜的生产工艺

1989
- 1989-03-09 CA CA000593171A patent/CA1340065C/fr not_active Expired - Fee Related

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
EP4134229A1 (fr)	2010-01-27	2023-02-15	SIG Technology AG	Composite pour emballage, emballage obtenu avec le composite et methode pour plier ledit composite
CN114685985A (zh) *	2022-04-11	2022-07-01	海信（山东）冰箱有限公司	高强度高耐磨易成型pa66材料及其制备方法、冰箱门铰链
CN114685985B (zh) *	2022-04-11	2024-01-23	海信冰箱有限公司	高强度高耐磨易成型pa66材料及其制备方法、冰箱门铰链
CN114801341A (zh) *	2022-04-14	2022-07-29	长园电子（东莞）有限公司	一种耐穿刺绝缘双层热缩管及其制备方法
CN116373193A (zh) *	2023-02-24	2023-07-04	无锡恩捷新材料科技有限公司	隔离膜的生产工艺
CN116373193B (zh) *	2023-02-24	2024-02-09	无锡恩捷新材料科技有限公司	隔离膜的生产工艺

Publication	Publication Date	Title
US4957974A (en)	1990-09-18	Graft copolymers and blends thereof with polyolefins
US5229456A (en)	1993-07-20	Graft copolymers and blends thereof with polyolefins
US5128410A (en)	1992-07-07	Graft copolymers and blends thereof with polyolefins
JP2859439B2 (ja)	1999-02-17	液晶ポリマーブレンド，その製法およびブレンドから製造した製品
US6967225B2 (en)	2005-11-22	Scratch-resistant polypropylene composition
US5109066A (en)	1992-04-28	Polyolefin compositions with improved impact strength
US5202380A (en)	1993-04-13	Polyolefin compositions with improved impact strength
EP0431733B1 (fr)	1994-04-06	Compositions de polyoléfine à résistance au choc améliorée
US5506307A (en)	1996-04-09	Modifier for polypropylene imparting improved melt strength
US5147932A (en)	1992-09-15	Polyolefin compositions with improved impact strength
CA1340065C (fr)	1998-09-29	Copolymeres de greffe et melanges de ceux-ci avec des polyolefines
US6093772A (en)	2000-07-25	Immiscible polymer compatibiliser system
CN103917566A (zh)	2014-07-09	基于接枝聚烯烃的聚合物
US6921792B2 (en)	2005-07-26	Chemically modified polyolefin elastomer composition and method for preparing the same
CA1340066C (fr)	1998-09-29	Copolymeres de greffe et leurs melanges avec des polyolefines
AU625059B2 (en)	1992-07-02	Graft copolymers and blends thereof with polyolefins
KR960006624B1 (ko)	1996-05-22	열가소성 수지 조성물
JPH02261811A (ja)	1990-10-24	グラフト共重合体およびそれとポリオレフィンとの混合物
JP3010516B2 (ja)	2000-02-21	改質プロピレン系重合体の製造法
HU211069B (en)	1995-10-30	Process for producing grafted copolymers, composition of said copolymers and polyolefins and method for improvement of quality and compatibility polyolefins
JPH03122168A (ja)	1991-05-24	ブロー成形法及びブロー成形品
JPH03124769A (ja)	1991-05-28	熱可塑性樹脂フィルムの製造法
JPH0229696B2 (fr)	1990-07-02

Legal Events

Date	Code	Title	Description
2003-09-29	MKLA	Lapsed