CA1201080A - Methode de conversion de la biomasse en hydrocarbure - Google Patents
Methode de conversion de la biomasse en hydrocarbureInfo
- Publication number
- CA1201080A CA1201080A CA000443162A CA443162A CA1201080A CA 1201080 A CA1201080 A CA 1201080A CA 000443162 A CA000443162 A CA 000443162A CA 443162 A CA443162 A CA 443162A CA 1201080 A CA1201080 A CA 1201080A
- Authority
- CA
- Canada
- Prior art keywords
- process according
- biomass
- crystalline aluminosilicate
- aluminosilicate zeolite
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims abstract description 41
- 239000002028 Biomass Substances 0.000 title claims abstract description 26
- 229930195733 hydrocarbon Natural products 0.000 title claims abstract description 14
- 150000002430 hydrocarbons Chemical class 0.000 title claims abstract description 14
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000010457 zeolite Substances 0.000 claims abstract description 20
- 239000003054 catalyst Substances 0.000 claims abstract description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 229910021536 Zeolite Inorganic materials 0.000 claims abstract description 15
- 229910000323 aluminium silicate Inorganic materials 0.000 claims abstract description 9
- 239000002245 particle Substances 0.000 claims abstract description 7
- 239000007787 solid Substances 0.000 claims abstract description 5
- 230000003635 deoxygenating effect Effects 0.000 claims abstract description 3
- 239000002923 metal particle Substances 0.000 claims abstract description 3
- 239000000463 material Substances 0.000 claims description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 5
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 5
- 150000002739 metals Chemical class 0.000 claims description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 4
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 4
- 239000011148 porous material Substances 0.000 claims description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims description 3
- 239000000377 silicon dioxide Substances 0.000 claims description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 2
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 2
- 229910052804 chromium Inorganic materials 0.000 claims description 2
- 239000011651 chromium Substances 0.000 claims description 2
- 229910017052 cobalt Inorganic materials 0.000 claims description 2
- 239000010941 cobalt Substances 0.000 claims description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 2
- 229910052802 copper Inorganic materials 0.000 claims description 2
- 239000010949 copper Substances 0.000 claims description 2
- 229910052742 iron Inorganic materials 0.000 claims description 2
- 229910052750 molybdenum Inorganic materials 0.000 claims description 2
- 239000011733 molybdenum Substances 0.000 claims description 2
- 229910052680 mordenite Inorganic materials 0.000 claims description 2
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- 229910052763 palladium Inorganic materials 0.000 claims description 2
- 229910052707 ruthenium Inorganic materials 0.000 claims description 2
- 239000010936 titanium Substances 0.000 claims description 2
- 229910052719 titanium Inorganic materials 0.000 claims description 2
- 229910052725 zinc Inorganic materials 0.000 claims description 2
- 239000011701 zinc Substances 0.000 claims description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims 2
- 239000010815 organic waste Substances 0.000 claims 1
- 229910052697 platinum Inorganic materials 0.000 claims 1
- 238000006243 chemical reaction Methods 0.000 description 15
- 239000007788 liquid Substances 0.000 description 11
- 239000000446 fuel Substances 0.000 description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 239000004215 Carbon black (E152) Substances 0.000 description 5
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000006392 deoxygenation reaction Methods 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- 239000011269 tar Substances 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 239000003638 chemical reducing agent Substances 0.000 description 2
- 239000000571 coke Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 238000002309 gasification Methods 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 229920002488 Hemicellulose Polymers 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 235000013431 Pinus clausa Nutrition 0.000 description 1
- 235000000773 Pinus glabra Nutrition 0.000 description 1
- 241001502813 Pinus glabra Species 0.000 description 1
- 241000209504 Poaceae Species 0.000 description 1
- 241000219000 Populus Species 0.000 description 1
- 206010037660 Pyrexia Diseases 0.000 description 1
- AUVLKSYQHWCRNS-UHFFFAOYSA-N acetylene;ethane Chemical group CC.C#C AUVLKSYQHWCRNS-UHFFFAOYSA-N 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 238000004939 coking Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 238000005984 hydrogenation reaction Methods 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 239000013528 metallic particle Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- -1 piatinum Chemical compound 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 230000003389 potentiating effect Effects 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000010517 secondary reaction Methods 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G1/00—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
- C10G1/04—Production of liquid hydrocarbon mixtures from oil-shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal by extraction
- C10G1/047—Hot water or cold water extraction processes
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA000443162A CA1201080A (fr) | 1983-12-13 | 1983-12-13 | Methode de conversion de la biomasse en hydrocarbure |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CA000443162A CA1201080A (fr) | 1983-12-13 | 1983-12-13 | Methode de conversion de la biomasse en hydrocarbure |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CA1201080A true CA1201080A (fr) | 1986-02-25 |
Family
ID=4126739
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA000443162A Expired CA1201080A (fr) | 1983-12-13 | 1983-12-13 | Methode de conversion de la biomasse en hydrocarbure |
Country Status (1)
| Country | Link |
|---|---|
| CA (1) | CA1201080A (fr) |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1268717A4 (fr) * | 2000-03-23 | 2004-03-17 | Univ West Virginia | Procede de transformation d'un dechet agricole en combustible liquide, et dispositif associe |
| EP1889870A1 (fr) * | 2006-08-16 | 2008-02-20 | BIOeCON International Holding N.V. | Suspension stable d'une biomasse comprenant des particules inorganiques |
| WO2008109877A1 (fr) * | 2007-03-08 | 2008-09-12 | Virent Energy Systems, Inc. | Synthèse de combustibles et de produits chimiques liquides à partir d'hydrocarbures oxygénés |
| WO2008009643A3 (fr) * | 2006-07-17 | 2009-04-23 | Bioecon Int Holding Nv | Pyrolise catalytique d'une fine biomasse particulaire et procédé permettant de réduire la taille des particules de la biomasse solide |
| EP2071005A1 (fr) * | 2007-12-03 | 2009-06-17 | BIOeCON International Holding N.V. | Procédé pour la désoxygénation sélective de biomasse |
| WO2009071541A3 (fr) * | 2007-12-03 | 2009-07-23 | Bioecon Int Holding Nv | Procédé de production de bio-huiles et d'eau douce à partir de biomasse aquatique |
| US20110144396A1 (en) * | 2009-12-15 | 2011-06-16 | Conocophillips Company | Process for converting biomass to hydrocarbons and oxygenates |
| US8231857B2 (en) | 2005-12-21 | 2012-07-31 | Virent, Inc. | Catalysts and methods for reforming oxygenated compounds |
| US8350108B2 (en) | 2008-08-27 | 2013-01-08 | Virent, Inc. | Synthesis of liquid fuels from biomass |
| RU2472840C2 (ru) * | 2007-03-08 | 2013-01-20 | Вайрент, Инк. | Синтез жидкого топлива и химических реактивов из кислородсодержащих углеводородов |
| US8366907B2 (en) | 2010-08-02 | 2013-02-05 | Battelle Memorial Institute | Deoxygenation of fatty acids for preparation of hydrocarbons |
| US8834587B2 (en) | 2006-12-20 | 2014-09-16 | Virent, Inc. | Method of producing gaseous products using a downflow reactor |
| US9085735B2 (en) | 2013-01-02 | 2015-07-21 | American Fuel Producers, LLC | Methods for producing synthetic fuel |
| US10118159B2 (en) | 2013-09-06 | 2018-11-06 | Reliance Industries Limited | Catalyst composition and a catalytic process for conversion of biomass to crude bio oil |
-
1983
- 1983-12-13 CA CA000443162A patent/CA1201080A/fr not_active Expired
Cited By (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1268717A4 (fr) * | 2000-03-23 | 2004-03-17 | Univ West Virginia | Procede de transformation d'un dechet agricole en combustible liquide, et dispositif associe |
| US8231857B2 (en) | 2005-12-21 | 2012-07-31 | Virent, Inc. | Catalysts and methods for reforming oxygenated compounds |
| WO2008009643A3 (fr) * | 2006-07-17 | 2009-04-23 | Bioecon Int Holding Nv | Pyrolise catalytique d'une fine biomasse particulaire et procédé permettant de réduire la taille des particules de la biomasse solide |
| EP1889870A1 (fr) * | 2006-08-16 | 2008-02-20 | BIOeCON International Holding N.V. | Suspension stable d'une biomasse comprenant des particules inorganiques |
| WO2008020046A3 (fr) * | 2006-08-16 | 2008-07-17 | Bioecon Int Holding Nv | Suspensions stables de biomasse comprenant des particules inorganiques |
| US8808408B2 (en) * | 2006-08-16 | 2014-08-19 | Kior, Inc. | Stable suspensions of biomass comprising inorganic particulates |
| US8715377B2 (en) * | 2006-08-16 | 2014-05-06 | Kior, Inc. | Stable suspensions of biomass comprising inorganic particulates |
| US20100275507A1 (en) * | 2006-08-16 | 2010-11-04 | Bioecon International Holding N.V. | Stable suspensions of biomass comprising inorganic particulates |
| US20130000182A1 (en) * | 2006-08-16 | 2013-01-03 | Kior Inc. | Stable suspensions of biomass comprising inorganic particulates |
| US8834587B2 (en) | 2006-12-20 | 2014-09-16 | Virent, Inc. | Method of producing gaseous products using a downflow reactor |
| US8367882B2 (en) | 2007-03-08 | 2013-02-05 | Virent, Inc. | Synthesis of liquid fuels and chemicals from oxygenated hydrocarbons |
| US8455705B2 (en) | 2007-03-08 | 2013-06-04 | Virent, Inc. | Synthesis of liquid fuels and chemicals from oxygenated hydrocarbons |
| US9217114B2 (en) | 2007-03-08 | 2015-12-22 | Virent, Inc. | Synthesis of liquid fuels and chemicals from oxygenated hydrocarbons |
| US8933281B2 (en) | 2007-03-08 | 2015-01-13 | Virent, Inc. | Synthesis of liquid fuels and chemicals from oxygenated hydrocarbons |
| RU2472840C2 (ru) * | 2007-03-08 | 2013-01-20 | Вайрент, Инк. | Синтез жидкого топлива и химических реактивов из кислородсодержащих углеводородов |
| US8362307B2 (en) | 2007-03-08 | 2013-01-29 | Virent, Inc. | Synthesis of liquid fuels and chemicals from oxygenated hydrocarbons |
| EP2698416A3 (fr) * | 2007-03-08 | 2014-12-17 | Virent, Inc. | Synthèse de combustibles et de produits chimiques liquides à partir d'hydrocarbures oxygénés |
| WO2008109877A1 (fr) * | 2007-03-08 | 2008-09-12 | Virent Energy Systems, Inc. | Synthèse de combustibles et de produits chimiques liquides à partir d'hydrocarbures oxygénés |
| WO2009071495A3 (fr) * | 2007-12-03 | 2009-08-13 | Bioecon Int Holding Nv | Processus pour la désoxygénation sélective de biomasse |
| WO2009071541A3 (fr) * | 2007-12-03 | 2009-07-23 | Bioecon Int Holding Nv | Procédé de production de bio-huiles et d'eau douce à partir de biomasse aquatique |
| EP2071005A1 (fr) * | 2007-12-03 | 2009-06-17 | BIOeCON International Holding N.V. | Procédé pour la désoxygénation sélective de biomasse |
| US20100294643A1 (en) * | 2007-12-03 | 2010-11-25 | Kior Inc. | Process for the selective de-oxygenation of biomass |
| US8350108B2 (en) | 2008-08-27 | 2013-01-08 | Virent, Inc. | Synthesis of liquid fuels from biomass |
| US20110144396A1 (en) * | 2009-12-15 | 2011-06-16 | Conocophillips Company | Process for converting biomass to hydrocarbons and oxygenates |
| US8846992B2 (en) * | 2009-12-15 | 2014-09-30 | Philips 66 Company | Process for converting biomass to hydrocarbons and oxygenates |
| US8882990B2 (en) | 2010-08-02 | 2014-11-11 | Battelle Memorial Institute | Deoxygenation of fatty acids for preparation of hydrocarbons |
| US8388829B2 (en) | 2010-08-02 | 2013-03-05 | Battelle Memorial Institute | Deoxygenation of fatty acids for preparation of hydrocarbons |
| US8366907B2 (en) | 2010-08-02 | 2013-02-05 | Battelle Memorial Institute | Deoxygenation of fatty acids for preparation of hydrocarbons |
| US9085735B2 (en) | 2013-01-02 | 2015-07-21 | American Fuel Producers, LLC | Methods for producing synthetic fuel |
| US10118159B2 (en) | 2013-09-06 | 2018-11-06 | Reliance Industries Limited | Catalyst composition and a catalytic process for conversion of biomass to crude bio oil |
| US10391474B2 (en) | 2013-09-06 | 2019-08-27 | Reliance Industries Limited | Process for preparation of hydrocarbon fuel from waste rubber |
| EP3685917A1 (fr) | 2013-09-06 | 2020-07-29 | Reliance Industries Limited | Composition de catalyseur et procédé catalytique permettant de convertir une biomasse en bio-huile brute |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| MKEX | Expiry |