CA1245978A - Producing sour natural gas - Google Patents

Abstract

A B S T R A C T

A sour natural gas is produced via a well system comprising a vertical well section and a horizontal drainhole section extending through the reservoir formation. Formation plugging due to in-situ precipitation of sulphur during production operations is avoided by adequately sizing the horizontal drainhole section in the reservoir, thereby establishing near-wellbore pressures in the reservoir above the sulphur saturation pressure, without sacrificing production rates.

Description

~2~5~t~

K_9452 CAN

PRODUCING SOUR NATURAL GAS

The invention relates to the production of sour natural gas.
More particularly, it relates to a method of producing a sour natural gas from a subterranean reservoir formation while preventing plugging of the reservoir formation due to in-situ precipitation of sulphur.
Sour natural gas is able to hold a limited amount of sulphur in solution. The amount of dissolved sulphur increases with the pressure, temperature and hydrogen sulphide content of the gas.
Elemental sulphur comes out of solution when either the pressure or temperature of the fluid drops below the saturation values. Such a change in conditions may easily occur when gas is produced in a production well.
In sour gas production operations via a conventional vertical well, significant amounts of elemental sulphur may be separated from the produced fluid. Depending on the distribution and severity of the pressure and temperature reduction throughout the flow circuit, sulphur deposition is possible in the formation and/or well bore. For instance, the quantities of sulphur which could potentially separate in a 100,000 m3/day sour gas producer at an

2~ isothermal pressure draw-down from 408 to 375 bar - which could for the greater part occur in the producing formation - may cause the separation of some 1100 kg/day of sulphur.
One of the worst consequences of sulphur deposition is that which takes place in the producing reservoir. Not only can this reduce production, but in extreme cases it can permanently shut off flow into the wellbore, leadlng to abandonment and the drilling of a replacement well. Formaeion plugging of this kind becomes more serious as the rock permeability becomes lower. Under these conditions, even the deposition of liquid sulphur in the pores can sig~ificantly reduce productivity since the viscosity of the liquid sulphur is much higher than that of the sour gas der.se fluid phase.

71~3 To produce sour natural gas at a commercial rate of say 100.000 m3/day via a conventional vertical production well the velocity of the gas through the pores of the reservoir formation at the proximity of the well bore is inherently high. Due to the high gas velocity required to produce at commercial rates the reservoir pressure in the proximity of the well bore easily drops below the sulphur saturation pressure, creating conditions favourable for separation of elemental sulphur.
In field operations preventive and remedial methods have been developed and routinely used to cope with the problem of sulphur deposition in well tubulars. However, no practical, effectlve methods exist which prevent or remove sulphur deposits formed in the reservoir.
Object of the invention is to provide a method of producing sour natural gas, wherein deposition of sulphur in the reservoir and in the well bore traversing the payzone is avoided without sacrificing production rates.
In accordance with the invention this object is ac~omplished by a sour gas production method wherein a well system is drilled and completed into the reservoir formation, which system comprises a substantially vertical well section extending from the reservoir formation to the surface and a substantially horizontal drainhole section traversing the reservoir formation along a predetermined distance. After completing the well system gas production is established at such a production rate that at least in the interior of said drainhole section the pressure is above the sulphur saturation pressure.
In a preferred embodiment of the invention the length of said drainhole section is sized in conjunction with a desired production rate of the well system and the thickness of the reservoir formation.
Instead of providing the well system with a single substantially horizontal drainhole section it may be provided with a plurality of substantially horizontal drainhole sections as well.

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The invention will now be explained in more detail with reference to the accompanying drawings in which:
Figure 1 shows a conventional vertical gas producing well and a well system comprising a substantially horizontal drainhole section producing from the same sour gas reservoir formation, Figure 2 shows a diagram in which the ratio (~P /~Ph) of the pressure draw-down of a gas flowing into the vertical well and that of the gas flowing into the horlzontal drainhole is plotted against the dimensionless horizontal length (L/h) of the drainhole, and Figure 3 shows a sour gas producer well system comprising two horizontal drainhole sections drilled from a single vertical well section.
In Figure 1 there is shown a subterranean sour gas reservoir formation 1 with an average thickness h and having substantially horizontal upper and lower exterior boundaries.
At the left side of Figure 1 there is shown a conventional, vertical gas producer well 2 traversing the reservoir formation 1 in a substantially orthogonal direction thereby forming an inflow region 3 extending along the thickness of the reservoir formation 1. As illustrated by arrows I during production gas flows via the permeable wall of the well bore at the inflow region 3 from the reservoir formation 1 into tha well 2.
At the right side of Figure 1 there is shown a well system 4 according to the invention traversing the same reservoir formation 1. The well system 4 comprises a vertical well section 5 extending from the earth surface 6 into the reservoir formation 1, a deviated section 6 and a substantially horizontal drainhole section 7.
The drainhole section 7 has a length L and comprises a permeable wall via which gas flows (see arrows II) from the reservoir formation 1 into the well system 4.
As will be explained hereinbelow the length L of the permeable drainhole section 7 in the reservoir formation 1 is an important parameter with regard to avoiding in-situ precipitation of sulphur

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in the pores of the resarvoir formation 1 in the proximity of the well bore In-situ precipitation of sulphur in the formation is controlled by the difference between the pressure deep in the reservoir (P ) and that in the borehole during production (Pb).
This pressure difference, commonly called "draw-down" ~P, is a function of the well, fluid and rock -haracteristics~ For the conventional vertical well 2 the draw-down ~P can be derived from Darcy's law for the radial flow of gas:

Q- sc- ~ re ~P = p _ p2 _ Qn - (1) sc w v e bv draw-down, vertical hole bar P = Reservoir pressure at the exterior boundary, bar Pb = Borehole pressure, vertical hole, bar P = Pressure at standard conditions, bar ~ = Gas production rate at standard conditions, cm3/sec.
15 T = Absolute reservoir temperature, K
T = Absolute temperature at standard conditions, K
z = Gas compressibility factor at the average pressure in the drainage system considered ~ =-Viscosity of gas under reservoir conditions 9 CP
K = Rock permeability, D
h = Net formation thickness, cm r = Radius of exterior boundary, cm r = Well bore radius, cm w Equation (l) is applicable to isotropic formations, unimpaired by skin damage and penetrated by a conventional, vertical well.
Based on equations used by Giger et al (Giger, F.M., Reiss, L.H. and Jourdan, A.P., "The Reservoir Engineering Aspects of Horizontal Drilling", SPE 13024, September 1984), the following relationship between the draw-down ~Ph and the various well, fluid and rock characteristics can be derived for the inflow of gas into the horizontal drainhole section 7:

-/ Q.Psc.T.z.~ ~ L 1 ~ ~ h l ~ h e Pe T C.~.K.L L h Qn ( 2 Lre ) 2~r ~ ( ) where ~Ph = Pe Pbh L = Length of horizontal drainhole section, cm P = Reservoir pressure at the exterior boundary, bar Pbh = Borehole pressure, horizontal drainhole, bar Ps = Pressure at standard conditions, bar Q = Gas production rate at standard conditions, cm3/sec.
T = Absolute reservoir temperature K
T = Absolute temperature at standard conditions, K
z = Gas compressibility fator at the average pressure in the drainage system considered ~ = Viscosity of gas under reservoir conditions, cP
K = Rock permeability, D
h = Net formation thickness, cm re = Radius of exterior boundary, cm r = Well bore radius, cm In the following example it is assumed that sour gas containing 80%
~2S is produced.
When considering the methane - hydrogen sulphide - sulphur equilibrium, the following saturation sulphur contents were determined for various pressure and temperature conditions:

- 6 - ~2 GAS COMPOSITION: CH4 20%, H2S 80%
.
Pressure Temperature Sulphur Content Bar C g/m3 408 121.1 40.0 408 65.6 19.2 20~ 121.1 6.4 204 65.6 4.6 .
It may be seen that a decrease in temperature from 121 C to 66 C
more than halves the saturation sulphur content of the 408 bar gas.
A pressure reduction to 204 bar further reduces the sulphur content to almost one tenth of the original value. It is evident that the pressure effect is more dominant than the temperature effect.
It is further assumed that the gas is produced at a rate of 100,000 m3/d from a low permeability reservoir (10 mD) which has a Pe of 412.5 bar and a static temperature of 124 C. The other characteristics are assumed to be:

Net formation thickness, 15 m Radius of exterior boundary, 400 m Well bore radius, 0.11 m Gas compressibility factor, 0.7 Viscosity of gas under reservoir conditions, 0.075 cP
Pressure P at standard conditlons l bar sc Temperature T c at standard conditions 288 K

Using equatlon (1), the draw-down ~P in the vertical well 2 for the given conditions is calculated to be 18.1 bar, indicating that the borehole pressure drops from 412.5 to 394.4 bar, well below the saturation pressure (408 bar). This implies that sulphur separation in the formation is expectable.
Then a 350 m horizontal drainhole section is considered, assuming the same formation, fluid and well character$stics as for the vertical well example.

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Under the assumed well conditions, the draw-down for the horiæontal drainhole is calculated using equation (2~ to be only 3.5 bar, indicating a borehole pressure of 409 bar, just above the saturation pressure (408 bar). Therefore, no sulphur separation ln the formation is to be expected. However, as the difference between borehole and saturation pressure is only marginal (1 bar), a longer horizontal hole should be chosen. It may be calculated that for a horizontal length of 450 m, the borehole pressure drops to 409.7 bar, almost 2 bar above the saturation pressure.
In order to easily compare the pressure draw-down of a vertical well with that of a horizontal well producing at the same rate from the same reservoir, the ratio of equations (1) and (2) can be written in a more convenient form as follows:

p2 _ p2 Qn -e bv w (3) e bh 1 ~ ~r Qn ( e ) ~ h Qn h _ L L 2~r 2 r w Equation (3) shows that for a given reservoir where Pe, r , h and r remain the same and Q is not changed, the pressure draw-down for a horizontal hole decreases as the horizontal length L increases. The effect of L on the draw-down is further illustrated in Figure 2, where the draw-down ratio ~P /~Ph is plotted as a function of the dimensionless horizontal length (L/h). This graph can be used to estimate the minimum length of the horizontal section required to achieve a given maximum allowable draw-down.
~ igure 2 further illustrates that the horizontal wellbore length L i~ the reservoir is the dominating parameter with regard to establishing minimum draw-down; and that under the assumed well conditions a horizontal hole 40 times longer than the reservoir thickness exhibits pressure draw-downs ten times less than those in a vertical hole through the same reservoir, producing at the same rate.
By extending the horizontal length of a drain hole it is not only possible to avoid in-situ sulphur separation but also to achieve this at increased production rates. By applying equation (2) with the assumed well and reservoir conditions it can be demonstrated that if the horizontal hole length is extended by about 25~, the production rate can be increased by about 20~ at the same draw-down.
Furthermore, as illustrated in Fig. 3, modern horizontal well drilling techniques enable operators to drill more than one horizontal hole from a single vertical well. This can be considered as an alternative if further extension of a single horizontal well is desirable but technically not possible. The total production capacity of the well system is controlled by the sum of the lengths Ll and L2 of both horizontal sections.
This all implies that from a single horizontal well system considerably higher production rates are possible than from a single vertical well without inducing in-situ sulphur separation.
Moreover, production of sour natural gas via a well system according to the invention instead of via conventional vertical wells has the advantage of enhanced safety, because a reduced number of surfac production points (well heads) and surface flow-lines are required to produce sour gas at the desired rates.

Claims (7)

C L A I M S

1. Method of producing a sour natural gas from a subterranean reservoir formation in which the gas pressure is above the sulphur saturation pressure, the method comprising:
- completing a well system into said formation, said well system comprising a substantially vertical well section extending from the reservoir formation to the surface and a substantially horizontal drainhole section traversing the reservoir formation along a predetermined distance, and - establishing gas production via the well system at such a production rate that at least in the interior of said drainhole section the pressure of the produced fluid is above the sulphur saturation pressure.

2. The method of claim 1, wherein the length (L) of the horizontal drainhole section is determined in conjunction with a desired production rate of the well system and the thickness of the reservoir formation.

3. The method of claim 2, comprising first determining a maximum acceptable difference (.DELTA.Ph)A between the gas pressure at the exterior boundary of the reservoir (Pe) and that in the interior of the drainhole section (Pbh)to maintain the gas pressure (Pbb)in said interior above the sulphur saturation pressure, subsequently calculating the difference .DELTA.Ph between Pe and Pb for various values of said length (L) on the basis of the relationship:

(2) where .DELTA.Ph = Pe - Pbh L = Length of the drainhole section, cm Pe = Reservoir pressure at the exterior boundary, bar Pbh = Borehole pressure, horizontal drainhole, bar Psc = Pressure at standard conditions, bar Q = Gas production rate at standard conditions, cm3/sec.
T = Absolute reservoir temperature °K
Tsc = Absolute temperature at standard conditions, °K
z = Gas compressibility factor at the average pressure in the drainage system u = Viscosity of gas under reservoir conditions, cP
K = Rock permeability, D
h = Net formation thickness, cm re = Radius of exterior boundary, cm rw = Well bore radius, cm and then determining a length (L) for which .DELTA.Ph < (.DELTA.Ph)A.

4. The method of claim 2, wherein the length of the substantially horizontal drainhole section is at least 30 times the reservoir thickness.

5. The method of claim 1, wherein the well system comprises a single substantially vertical well section and a plurality of substantially horizontal drainhole sections arranged in fluid communication with the vertical well section and traversing the reservoir formation in various directions.

6. The method of claim 5, wherein the accumulated lengths of said substantially horizontal drainhole sections is at least 30 times the thickness of the reservoir formation.

7. The method of claim 1, wherein the sour natural gas comprises about 20% weight methane and about 80% weight hydrogen sulphide.