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BRPI0922066A8 - “processos para a fabricação de metilmercaptopropionaldeído, bem como da metionina ou do hidroxianálogo da metionina” - Google Patents

“processos para a fabricação de metilmercaptopropionaldeído, bem como da metionina ou do hidroxianálogo da metionina”

Info

Publication number
BRPI0922066A8
BRPI0922066A8 BRPI0922066A BRPI0922066A BRPI0922066A8 BR PI0922066 A8 BRPI0922066 A8 BR PI0922066A8 BR PI0922066 A BRPI0922066 A BR PI0922066A BR PI0922066 A BRPI0922066 A BR PI0922066A BR PI0922066 A8 BRPI0922066 A8 BR PI0922066A8
Authority
BR
Brazil
Prior art keywords
methionine
acrolein
methylmercaptopropionaldehyde
processes
manufacturing
Prior art date
Application number
BRPI0922066A
Other languages
English (en)
Inventor
Devaux Jean-François
Dubois Jean-Luc
Original Assignee
Arkema France
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Arkema France filed Critical Arkema France
Publication of BRPI0922066A2 publication Critical patent/BRPI0922066A2/pt
Publication of BRPI0922066A8 publication Critical patent/BRPI0922066A8/pt
Publication of BRPI0922066B1 publication Critical patent/BRPI0922066B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
    • C07C319/14—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides
    • C07C319/18—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides by addition of thiols to unsaturated compounds
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23K—FODDER
    • A23K20/00—Accessory food factors for animal feeding-stuffs
    • A23K20/10—Organic substances
    • A23K20/142—Amino acids; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23K—FODDER
    • A23K50/00—Feeding-stuffs specially adapted for particular animals
    • A23K50/70—Feeding-stuffs specially adapted for particular animals for birds
    • A23K50/75—Feeding-stuffs specially adapted for particular animals for birds for poultry
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
    • C07C319/02—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of thiols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
    • C07C319/02—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of thiols
    • C07C319/08—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of thiols by replacement of hydroxy groups or etherified or esterified hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C319/00—Preparation of thiols, sulfides, hydropolysulfides or polysulfides
    • C07C319/14—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides
    • C07C319/20—Preparation of thiols, sulfides, hydropolysulfides or polysulfides of sulfides by reactions not involving the formation of sulfide groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/51—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition
    • C07C45/52—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by pyrolysis, rearrangement or decomposition by dehydration and rearrangement involving two hydroxy groups in the same molecule

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Zoology (AREA)
  • Animal Husbandry (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Birds (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Proteomics, Peptides & Aminoacids (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

PROCESSOS PARA A FABRICAÇÃO DE METILMERCAPTOPROPIONALDEÍDO, BEM COMO DA METIONINA OU DO HIDROXIANÁLOGO DA METIONINA. A presente invenção tem por objeto um processo para a fabricação de metilmercaptopropionaldeíido (MMP), que compreende pelo menos os seguintes etapas: (a) a desidratação da glicerina a acroleína, a partir de uma solução aquosa de glicerina na presença de um catalisador ácido; (b) a purificação da corrente aquosa proveniente do etapa (a) para se obter uma corrente de acroleína que contém menos de 15% em massa de água, em relação à acroleína; (c) a reação da corrente de acroleína obtida no etapa (b) com metilmercaptano, na presença de um catalisador; (d) eventualmente a purificação do produto obtido no etapa (c). O processo da invenção pode, por outro lado, compreender uma reação do produto obtido nas etapas (c) ou (d) com o ácido cianídrico, ou com cianeto de sódio, no decurso de uma etapa (e), seguido por uma transformação posterior para produzir a metionina, ou um hidroxianálogo da metionina, que pode, eventualmente, ser então purificada. À utilização, por outro lado, de metilmercaptano e/ou de ácido cianídrico provenientes de biomassa, como matérias-primas no processo de acordo com a invenção, permite obter MMP, metionina, ou um hidroxianálogo da metionina, constituídos por 100% de carbono orgânico proveniente de recursos renováveis.
BRPI0922066-6A 2008-11-20 2009-11-19 “processos para a fabricação de metilmercaptopropionaldeído, bem como da metionina ou do hidroxianálogo da metionina” BRPI0922066B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
FR0857886 2008-11-20
FR0857886A FR2938535B1 (fr) 2008-11-20 2008-11-20 Procede de fabrication de methylmercaptopropionaldehyde et de methionine a partir de matieres renouvelables
PCT/FR2009/052220 WO2010058129A2 (fr) 2008-11-20 2009-11-19 Procede de fabrication de methylmercaptopropionaldehyde et de methionine a partir de matieres premieres renouvelables

Publications (3)

Publication Number Publication Date
BRPI0922066A2 BRPI0922066A2 (pt) 2015-12-15
BRPI0922066A8 true BRPI0922066A8 (pt) 2017-08-08
BRPI0922066B1 BRPI0922066B1 (pt) 2018-02-06

Family

ID=40716953

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0922066-6A BRPI0922066B1 (pt) 2008-11-20 2009-11-19 “processos para a fabricação de metilmercaptopropionaldeído, bem como da metionina ou do hidroxianálogo da metionina”

Country Status (10)

Country Link
US (1) US8735631B2 (pt)
EP (1) EP2361239B1 (pt)
JP (1) JP2012509304A (pt)
CN (2) CN106496081A (pt)
BR (1) BRPI0922066B1 (pt)
ES (1) ES2634448T3 (pt)
FR (1) FR2938535B1 (pt)
MY (1) MY156282A (pt)
SG (1) SG171773A1 (pt)
WO (1) WO2010058129A2 (pt)

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FR2939791B1 (fr) 2008-12-16 2011-01-14 Adisseo France Sas Procede de preparation d'acroleine a partir de glycerol ou de glycerine brute
FR2961507B1 (fr) * 2010-06-17 2016-03-04 Adisseo France Sas Procede de preparation d'acroleine a partir de glycerol ou de glycerine
JP5524736B2 (ja) * 2010-06-29 2014-06-18 住友化学株式会社 メチオニンの製造方法
FR2966456B1 (fr) * 2010-10-26 2013-03-15 Adisseo France Sas Procede d'obtention d'acroleine par deshydratation catalytique de glycerol ou de glycerine
DE102011081828A1 (de) * 2011-08-30 2013-02-28 Evonik Degussa Gmbh Verfahren zur Umsetzung von Methylmercaptopropionaldehyd aus Roh-Acrolein und Roh-Methylmercaptan
CN102633698B (zh) * 2012-04-28 2014-07-30 重庆紫光天化蛋氨酸有限责任公司 甲硫醇和丙烯醛合成的粗甲硫基代丙醛的处理方法和系统
CN104045590B (zh) * 2012-04-28 2016-06-29 宁夏紫光天化蛋氨酸有限责任公司 甲硫醇和丙烯醛合成的粗甲硫基代丙醛的处理系统
EP2679579A1 (de) * 2012-06-27 2014-01-01 Evonik Industries AG Integriertes Verfahren zur Herstellung von Acrolein und 3-Methylmercaptopropionaldehyd
CN102796033B (zh) * 2012-09-03 2014-02-26 浙江新和成股份有限公司 一种清洁的d，l-蛋氨酸制备方法
CU24499B1 (es) 2014-11-28 2021-02-04 Haldor Topsoe As Proceso para preparar ésteres de ácido láctico y ácido 2-hidroxi-3-butenoico a partir de azúcares
CA2983397C (en) * 2015-04-30 2023-04-04 Haldor Topsoe A/S A process for the preparation of methionine alpha-hydroxy analogues from sugars and derivatives thereof.
CN113354544B (zh) * 2021-06-30 2023-03-31 中国科学院山西煤炭化学研究所 一种选择性断裂c-n键制备二氨基二苯基甲烷的方法
CN114057617B (zh) * 2021-12-09 2025-03-18 宁夏紫光天化蛋氨酸有限责任公司 3-甲硫基丙醛的制备方法
DE102024102614A1 (de) * 2024-01-30 2025-07-31 Obrist Technologies Gmbh Verfahren zur Herstellung eines nachhaltigen Energieträgers

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GB913836A (en) 1960-06-21 1962-12-28 Distillers Co Yeast Ltd Improvements in and relating to the synthesis of hydrogen cyanide
FR1526335A (fr) 1966-04-21 1968-05-24 Ncr Co Dispositifs semi-conducteurs photosensibles et leur procédé de fabrication
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FR2882053B1 (fr) * 2005-02-15 2007-03-23 Arkema Sa Procede de deshydratation du glycerol en acrolene
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Also Published As

Publication number Publication date
WO2010058129A3 (fr) 2010-07-15
BRPI0922066B1 (pt) 2018-02-06
CN102282119A (zh) 2011-12-14
EP2361239B1 (fr) 2017-06-28
CN106496081A (zh) 2017-03-15
EP2361239A2 (fr) 2011-08-31
FR2938535B1 (fr) 2012-08-17
US8735631B2 (en) 2014-05-27
JP2012509304A (ja) 2012-04-19
BRPI0922066A2 (pt) 2015-12-15
WO2010058129A2 (fr) 2010-05-27
SG171773A1 (en) 2011-07-28
FR2938535A1 (fr) 2010-05-21
MY156282A (en) 2016-01-29
ES2634448T3 (es) 2017-09-27
US20110229626A1 (en) 2011-09-22

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Legal Events

Date Code Title Description
B06F Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]
B15K Others concerning applications: alteration of classification

Ipc: C07C 45/52 (2006.01), C07C 47/22 (2006.01), C07C 3

B07A Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]
B21F Lapse acc. art. 78, item iv - on non-payment of the annual fees in time

Free format text: REFERENTE A 14A ANUIDADE.

B24J Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12)

Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2749 DE 12-09-2023 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013.