BRPI0715856A2 - formulations for the controlled release of agrochemical active substances - Google Patents

Abstract

Patent of Invention: "FORMULATIONS FOR CONTROLLED RELEASE OF AGROCHEMICAL ACTIVE SUBSTANCES". The present invention relates to compositions which have been found for the controlled release of agrochemical active substances containing at least one agrochemical active substance, cellulose ester and calcium carbonate.

Description

Report of the Invention Patent for "FORMULATIONS FOR CONTROLLED RELEASE OF AGRICULTURAL ACTIVE SUBSTANCES".

The present invention relates to novel formulations for the controlled release of agrochemical active substances, processes for their preparation and their use to combat harmful insects.

Many systems for the controlled release of agrochemical or pharmaceutical active substances have been described in the literature. These are designed for different types and periods of applications and are based on different support materials or die to achieve controlled release.

Thus, WO 99/55774 describes systems for controlled release of agrochemical active substances - among others, in which as a support material cellulose esters are employed. However, no means for controlling release is described, especially not of the type and mode of the present invention.

New compositions have now been found containing

- at least one agrochemical active substance

- at least one cellulose ester - calcium carbonate (Ca2CO3).

In addition, it has been found that the compositions according to the invention can be prepared by mixing

- at least one agrochemical active substance

- at least one cellulose ester - calcium carbonate (Ca2CO3)

and granulating by melt extrusion.

It has further been found that the compositions according to the invention are very suitable for application of the agrochemical active substances they contain. Surprisingly it was found that the release of the substances

The active substances contained in the compositions according to the invention may be adjusted by the calcium carbonate content. In addition, the compositions may be well manipulated. Thus, despite the high glazing point of the support materials employed, they do not present any agglomeration. In addition, they are biodegradable.

The compositions according to the invention are generally suitable for all solid agrochemical active substances at room temperature. Preferred active substances according to the invention are solid active substances at room temperature of the insecticide or fungicide classes. Particularly preferred according to the invention are room temperature solid active substances of the class of nicotinyls, carbamates, ketoenols or fungicides-conazole. Most particularly preferred according to the invention are imidacloprid, methiocarb, tebuconazole and spirotetramate. The fraction of active substance in the compositions according to the invention is generally 0.1 to 20 wt%, preferably 0.5 to 15 wt% and particularly preferably 1 to 10 wt%.

Preferred according to the invention are cellulose esters, particularly preferred is cellulose acetate propionate (CAP). Most particularly preferred is CAP with an acetyl content of 0.3 to 3 wt% and a propionyl content of 40 to 50 wt%. CAP of this type is obtainable in commerce. The cellulose ester fraction in the compositions according to the invention is generally 30 to 90 wt%, preferably 35 to 85 wt% and particularly preferred 40 to 80 wt%.

Compositions according to the invention furthermore contain calcium carbonate. The calcium carbonate fraction in the compositions according to the invention is generally 5 to 50 wt.%, Preferably 10 to 40 wt.% And particularly preferred 15 to 30 wt.%. Surprisingly it has been found that by calcium carbonate content it is possible to influence the rate at which the agrochemical active substance contained in the compositions according to the invention is released. With this, the active substance with rising calcium carbonate fractions is released faster into the environment.

In a preferred embodiment the compositions according to the invention contain at least one solid emulsifier at room temperature. In a particularly preferred embodiment, the compositions according to the invention contain at least one solid non-ionic emulsifier at room temperature of the class of polyoxyethylene-polyoxypropylene block copolymers, alcohol ethoxylates or polystyrylphenols. In a very particular embodiment, the compositions according to the invention contain a nonionic emulsifier of the formula (I) HO (CH 2 CH 2 O) x (CCH 3 HCH 2 O) y (CH 2 CH 2 O) 2H (I)

where χ = 75,

y = 30 and ζ = 75,

where the values for x, y and ζ represent average values. Corresponding polymers are commercially obtainable. The emulsifier fraction in the compositions according to the invention is generally 1 to 25 wt%, preferably 2 to 20 wt% and particularly preferably 3 to 15 wt%.

The compositions according to the invention may contain other formulation aids, for example, possibly substances from the groups of emulsifiers, anionic and nonionic surfactants, foaming inhibitors, preservatives, antioxidants. , dyes and / or inert fillers.

As nonionic surfactants or dispersing aids, all such substances commonly employed in agrochemical compositions are suitable. Preferably, polyethylene oxide-polypropylene oxide block copolymers, linear alcohol polyethylene glycol ethers, ethylene oxide and / or propylene oxide fatty acid reaction products, as well as polyvinyl alcohol, polyvinyl pyridine are mentioned. - Rolidone, mixed polyvinyl alcohol and polyvinylpyrrolidone polymers as well as (meth) acrylic acid and (meth) acrylic acid copolymers, as well as alkyl ethoxylates and alkylaryl ethoxylates, which may optionally be phosphated and eventually neutralized with bases, with sorbitol ethoxylates are mentioned as examples as well as polyoxyalkylene amine derivatives.

Anionic surfactants are all substances of this type usually employed in agrochemical compositions. Preferred are alkali and alkaline earth metal salts of alkyl sulfonic acids or alkylarylsulfonic acids.

Another preferred group of anionic surfactants or dispersing aids are polystyrenesulfonic acid salts, polyvinylsulfonic acid salts, naphthalosulfonic formaldehyde acid condensation salts, naphthaline sulfonic acid condensation salts, phenolsulfonic acid salts. and formaldehyde as well as salts of lignosulfonic acid.

As foam-inhibiting substances all substances employable for this purpose in agrochemical compositions are suitable. Preferred are silicone oils and magnesium stearate.

Preservatives are considered to be all substances employable for this purpose in agrochemical compositions of this type. Examples are Preventol® (Bayer AG) and Proxel®. As antioxidants are considered all substances

generally for this purpose in agrochemical compositions. Preferred is butylhydroxytoluene.

Colorants are considered to be all substances usually employed for this purpose in agrochemical compositions. Titanium dioxide, carbon black, zinc oxide and blue pigments as well as permanent red FGR are mentioned.

Suitable inert fillers are all substances usually employed for this purpose in agrochemical compositions. Preferred are inorganic particles such as carbonates, silicates and oxides as well as organic substances such as urea-formaldehyde condensates. As examples are mentioned kaolin, rutile, silicon dioxide, so-called highly dispersed silicic acids, silica gel, as well as natural and synthetic silicates in addition to talc.

The compositions according to the invention are suitable - with good plant compatibility, advantageous warm animal toxicity and good environmental friendliness - for the protection of plants and plant parts, for increased crop yields. improving crop product quality and combating animal plagues, particularly insects, tetanic, helminths, nematodes and molluscs, which occur in agriculture, horticulture, forestry, gardens and leisure facilities. They may preferably be employed as plant protection agents. They are active against normal and resistant sensitive types as well as against all or individual stages of development. To the above mentioned pests belong:

From the order of the Anoplura (Phthiraptera), for example, Damalinia spp., Haematopinus spp., Linognathus spp., Pediculus spp., Trichodectes spp.

From the Arachnida class, for example, Acarus siro, Aceria sheldeni, Aculops spp., Aculus spp., Amblyomma spp., Argas spp., Boophilus spp., Brevipalpus spp., Bryobia praetiosa, Chorioptes spp., Dermanyssus gallinae, Eotetranychus spp., Epitrimerus pyri, Eutetranychus spp., Eriophyes spp., Hemitarsonemus spp., Hyalomma spp., Latodectus mactans, Metatetranychus spp., Oligonychus spp., Ornithodoros spp. Phyllocoptruta oleivora, Polyphagotarsonemus latus, Psoroptes spp., Rhipicephalus spp., Rhizoglyphus spp., Sarcoptes spp., Scorpio maurus, Stenotarsonemus spp., Tarsonemus spp., Tetranychus spp., Vasiciates

From the Bivalva class, for example, Dreissena spp ..

From the order of the Chilopoda, for example, Geophilus spp.

ra spp.

Of the order Coleoptera, for example, Acanthoscelides obtectus, Adoretus spp., Agelastica alni, Agriotes spp., Amphimallon solstitialis, Anobium punctatum, Anoplophora spp., Anthonomus spp., Apogonia spp., Atomaria spp. Attagenus spp., Bruchidius obtectus, Bruchus spp., Ceuthorhynchus spp., Cleonus mendicus, Conoderus spp., Cosmopolists spp., Costelytra zealandica, Curculio spp., Cryptorhynchus lapathi, Dermestes spp., Diabrotiea spp. Faustinus cubae, Gibbium psyloides, Heteronyehus arator, Hylamorpha elegans, Hylotrupes bajulus, Fake Hypera, Hypothenemus spp. , Migdolus spp., Monoehamus spp., Naupactus xanthographus, Niptus hololeucus, Oryetes rhinoceros, Oryzaephilus suinamensis, Otiorrhynehus sulcatus, Oxyeetonia jucunda, Phaedon cochleariae, Phyllophaia japon. Premnotrypes spp., Psylliodes c-hrysocephala, Ptinus spp., Rhizobius ventralis, Rhizopertha dominica, Sitophilus spp., Sphenophorus spp., Symphyletes spp., Tenebrrio molitor, Tribolium spp. Tyehius spp., Xylotreehus spp., Zabrus spp.

From the order of the Collembola, for example, Onyehiurus armatus.

From the order of the Dermaptera, for example, Forfieula aurieularia.

From the order of the Diplopoda, for example, Blaniulus guttulatus.

From the order of the Diptera, for example Aedes spp., Anopheles spp., Bibio hortulanus, Calliphora erythrocephala, Ceratitis capitata, Chrysonia spp., Coehliomyia spp., Cordylobia anthropophaga, Culex spp., Cute-rebra spp., Daeus oleae , Dermatobia hominis, Drosophila spp., Fannia spp., Gastrophilus spp., Hylemyia spp., Hyppobosca spp., Hypoderma spp., Lueiomyza spp., Musca spp., Nezara spp., Oestrus spp. Oseinella frit, Pegomyia hyoscyami, Phorbia spp., Stomoxys spp., Tabanus spp., Tannia spp., Tipula paludosa, Wohlfahrtia spp.

From the Gastropoda class, for example, Arion spp., Biomphalia spp., Bulinus spp., Deroceras spp., Galba spp., Lymnaea spp., Oncomeania spp., Suceinea spp.

Of the helminth class, for example Ancylostoma duodenale, Ancylostoma ceylanicum, Acylostoma braziliensis, Aneylostoma spp., Ascaris lubicoides, Ascaris spp., Brugia malayi, Bunugomum spp., Chabertia spp., Clonorehis spp. Dicrocoelium spp, Dictyocau- ius filaria, Diphyllobothrium latum, Dracunculus medinensis, Echinococcus granulosus, Echinococcus multilocularis, Enterobius vermicularis, Faeiola spp., Haemonehus spp. spp., Opisthorehis spp., Onchoeerea volvulus, Ostertagia spp., Paragonimus spp., Schistosomen spp., Strongyloides fuelleborni, Strongyloides stercoralis, Stronyloides spp., Taenia saginata Trichinella pseudopsiralis, Trichostronulus spp., Triehuris trichuria, Wuehereria bancrofti. In addition, protozoa such as Eimeria can be combated.

Of the order Heteroptera, for example Anasa tristis, Antestiopsis spp., Blissus spp., Calocoris spp., Campylomma livida, Cavelerius spp., Cimex spp., Creontiades dilutus, Dasynus piperis, Dichelops furcatus, Diconocysdispercus spp. ., Euschistus spp., Eurygaster spp., Heliopeltis spp., Horcia nobilellus, Leptocorisa spp., Leptoglossus phyllopus, Lygus spp., Maeropes excavatus, Miridae, Nezara spp., Oebalus spp. Piezodorus spp., Psallus seriatus, Pseudaeysta persea, Rhodnius spp., Sahlbergella singularis, Seotinophora spp., Stephanitis nashi, Tibraea spp., Triatoma spp.

From the order of Homoptera, for example, Acyrthosipon spp., Aeenolamia spp., Agonoseena spp., Aleurodes spp., Aleurolobus barodensis, Aleurothrixus spp., Amrasea spp., Anuraphis cardui, Aonidiella spp. spp., Arboridia apicalis, Aspidiella spp., Aspidiotus spp., Atanus spp., Aulacorthum solani, Bemisia spp., Brachyeaudus heliehrysii, Brachycolus spp. ., Chatosiphon fragaefolii, Chionaspis tegalensis, Chlorita onukii, Chromaphis juglandicola, Chrysomphalus ficus, Cieadulina mbila, Coccomytilus halli, Coceus spis., Cryptomyzus ribis, Dalbulus spp., Dialeurodes spp. Doralis spp., Drosieha spp., Dysaphis spp., Dysmicoccus spp., Empoasea spp., Eriosoma spp., Erythroneura spp. Idioscopus spp., Laodelphax striatellus, Leeanium spp., Lepidosaphes spp., Lipaphis erysimi, Maerosiphum spp., Mahanarva fimbriata, Melanaphis sacchari, MeteaIfieIIa spp. photettix spp., Nilaparvata lugens, Oneometopia spp., Orthezia praelonga, Parabemisia myricae, Paratrioza spp., Parlatoria spp., Pemphigus spp. Pinnaspis aspidistrae, Planococcus spp., Protopulvaria pyriformis, Pseudaulacaspis pentagona, Pseudococcus spp., Psylla spp., Pteromalus spp., Pyrilla spp., Quadraspidiotus spp. Seaphoides titanus, Schizaphis graminum, Selenaspidus articulatus, Sogata spp., Sogatella furcifera, Sogatodes spp., Stictoeephala festina, Tenalaphara malayensis, Tinocallis caryaefoliae, Tomaspis spp., Toxoptera spp. aporariorum, Trioza spp., Typhloeyba spp., Unaspis spp., Viteus vitifolii.

From the order of the Hymenoptera, for example Diprion spp., Hopocamppa spp., Lasius spp., Monomorium pharaonis, Vespa spp.

From the order of the Isopoda, for example Armadillidium vulgare, Oniscus asellus, Porcellio scaber.

From the order of the Isoptera, for example, Reticulitermes spp., Odontotmes spp ..

From the order of the Lepidoptera, for example, Acronieta major, Aedia leucomelas, Agrotis spp., Alabama argillacea, Anticarsia spp., Barathra brasicae, Bucculatrix thurberiella, Bupalus piniarius, Capua reticulana, Carpoeapsa pomonella spp., Cheimat sp. ., Choristomura fumiferana, Clysia ambiguella, Cnaphalocerus spp., Earias island, Ephestia kuehniella, Euproetis chrysorrhoea, Euxoa spp., Feltia spp., Heliothis spp. , Laphygma spp., Lithocolletis blancardella, Lithophane antennata, Loxagrotis albicosta, Lymantria spp., Malaeosoma neustria, Mamestra brassicae, Mocis repanda, Mythimna seppata, Oriama oryzae, Panacea flammea, Pectinophis pectinophilus, Oulema oryzae ., Plutella xylostelia, Prodenia spp., Pseudoplasia spp., Pseudoplusia includens, Pyrausta nubilalis, Spodoptera spp., Thermia gemmatalis, Tinea pe llionella, Tineola bisselliella, Tortrix viridana, Trochoplusia spp.

From the order of Orthoptera, for example, Acheta domesticus, Blatta orientalis, Blattella germaniea, Gryllotalpa spp., Leueophaea maderae, Loeusta spp., Melanoplus spp., Periplaneta americana, Schistocerea greek.

From the order of the Siphonaptera, for example Ceratophyllus spp.,

Xenopsylla cheopis.

From the order of the Symphyla, for example, Seutigerella immaculata.

From the order of the Thysanoptera, for example, Baliothrips biformis, Enneothrips flavens, Frankliniella spp., Heliothrips spp., Hereinothrips femoralis, Kakothrips spp., Rhipiphorothrips cruentatus, Scirtothrips spp., Taeniot-hrips cardamoni.

From the order of the Thysanura, for example, Lepisma saccharina.

Phytoparasitic nematodes include, for example, Anguina spp., Aphelenchoides spp., Belonoaimus spp., Bursaphelenchus spp., Dithylenchus dipsaci, Globodera spp., Heliocotylenchus spp., Heterodera spp., Longidorus spp. spp., Radopholus similis, Rotylenchus spp., Trichodorus spp., Tylenchorhynchus spp., Tylenchulus spp., Tylenchulus semipenetrans, Xiphinema spp.

If the active substance combinations according to the invention contain at least one fungicidal active substance, then they are suitable for the control of phytopathogenic fungi such as plasmodiophoromycetes, oomycetes, citridiomycetes, zygomycetes, ascomycetes, basidomycetes, deuteromycetes. , etc.

As an example, but not limiting, are mentioned some fungal disease causers that fall under the generic terms mentioned above:

diseases caused by true downy mildew pathogens such as

Blumeria types, such as Blumeria graminis; Podosphaera types, such as Podosphaera leucotricha; Sphaerotheca types, such as, for example, Sphaerotheca fuliginea; Uncinula types, such as Uncinula necator; diseases caused by rust disease pathogens such as

Gymnosporangium type, such as for example, Gymnosporangium sabinae

Hemileia types, such as, for example, Hemileia vastatrix; Phakopsora types, such as, for example, Phakopsora pachyrhizi and Phakopsora meibomiae;

Puccinia types, such as for example, Puccinia recondita or Puccinia triticina;

Uromyces types, such as, for example, appendicular Uromyces

Tus;

diseases caused by pathogens of oomycete group disease such as, for example,

Bremia types such as, for example, Bremia lactucae; Peronospora types such as, for example, Peronospora pisi or P. brassicae;

Phytophthora types such as, for example, Phytophthora infest ns;

Plasmopara types such as, for example, Plasmopara viticola; Pseudoperonospora types such as, for example, Pseudoperonospora humuli or Pseudoperonospora cubensis;

Pythium types such as, for example, Pythium ultimum; leaf spot disease and wilt disease, caused for example by

Alternaria types such as, for example, Alternaria solani; Cercospora types such as, for example, Cercospora beticola; Cladiosporum types such as, for example, Cladiosporium eu- cumerinum;

Cochliobolus types such as, for example, Cochliobolus sativus (conidia form: Drechslera, sin: Helminthosporium); Colletotrichum types such as, for example, Colletotrichum Imiduthanium;

Cycloconium types such as, for example, Cycloconium oleaginous

on one;

Diaporthe types such as, for example, Diaporthe citri; Elsinoe types such as, for example, Elsinoe fawcettii; Gloeosporium types such as, for example, Gloeosporium Iaeti-

color;

Glomerella types such as, for example, Glomerella cingulata; Guignardia types such as, for example, Guignardia bidwelli; Leptosphaeria types such as, for example, Leptosphaeria ma-

culans;

Magnaporthe types such as, for example, Magnaporthe grisea; Mycosphaerella types such as, for example, Mycosphaerella

graminicola;

Phaeosphaeria types such as, for example, Phaeosphaeria

nodorum;

Pyrenophora types such as, for example, Pyrenophora teres; Ramularia types such as, for example, Ramularia collo-cygni; Rhynchosporium types such as, for example, Rhynchosporium

secalis;

Septoria types such as, for example, Septoria apii;

Typhula types such as, for example, Typhula incarnata; Venturia types such as, for example, Venturia inaequalis; root and stem diseases caused, for example, by Corticium types such as, for example, Corticium graminearum; Fusarium types such as, for example, Fusarium oxysporum;

Gaeumannomyces types such as, for example, Gaeumannomyces graminis; Rhizoctonia types such as, for example, Rhizoctonia solani; Tapesia types such as, for example, Tapesia acuformis; Thielaviopsis types such as, for example, basic Thielaviopsis

over there;

diseases of the ears and panicles (including ears of

), caused for example by

Alternaria types such as, for example, Alternaria spp .; Aspergillus types such as, for example, Aspergillus flavus; Cladosporium types such as, for example, Cladosporium spp .; Claviceps types such as, for example, Claviceps purpurea;

Fusarium types such as, for example, Fusarium culmorum; Gibberella types such as, for example, Gibberella zeae; Monographella types such as, for example, Monographella ni-

valis;

diseases caused by jellyfish fungi such as,

for example,

Sphacelotheca types such as, for example, Sphacelotheca

liana;

Tilletia types such as, for example, Tilletia caries; Urocystis types such as, for example, Urocystis occulta;

Ustilago types such as, for example, Ustilago nuda; fruit rot caused by, for example, Aspergillus types such as, for example, Aspergillus flavus; Botrytis types such as, for example, Botrytis cinerea; Penicillium types such as, for example, Penicillium expansum;

Sclerotinia types such as, for example, Sclerotinia sclerotiorum; Verticilium types such as, for example, Verticilium alboatrum; rot and wilting from seeds and soil, as well as sprout diseases caused by, for example, Fusarium types such as, for example, Fusarium culmorum;

Phytophthora types such as, for example, Phytophthora cactus-

rum; Pythium types such as, for example, Pythium ultimum; Rhizoctonia types such as, for example, Rhizoctonia solani; Sclerotium types such as, for example, Sclerotium rolfsii; cancroses, vesicles and witches' brooms caused by

example by

Nectria types such as, for example, Nectria galligena; Withering caused for example by Monilinia types such as, for example, Monilinia laxa; deformations of leaves, flowers and fruits caused for example by

per

Taphrina types such as, for example, Taphrina deformans; degenerative diseases of woody plants caused by e-

example by

Esca types such as, for example, Phaeomoniella clamydospo-

frog;

inflorescence and seed diseases caused by

example by

Botrytis types such as, for example, Botrytis cinerea; plant tuber diseases, caused for example by Rhizoctonia types such as, for example, Rhizoctonia solani;

diseases caused by bacterial pathogens such as for example

Xanthomonas types such as, for example, Xanthomonas campestris pv. oryzae;

Pseudomonas types such as, for example, Pseudomonas s-

yringae pv. lachrymans;

Erwinia types such as, for example, Erwinia amylovora; Preferably, the soybean diseases mentioned below can be combated:

fungal diseases in leaves, stalks, broad beans and seeds caused

for example by

black leaf spot by Alternaria (Alternaria spec. atrans tenuissima), anthracnoses (Colletotrichum gloeosporoides dematium var. truncatum), brown spot (Septoria glycines), leaf spotting and burning by Cercospora (Cercospora kikuchii), leaf burning by Choanephora (Choanephora) infundibulifera trispora (syn.)), leaf spot by Dactulophora (Dactuliophora glycines), hairy downy mildew (Peronospora manshurica), burning by Drechslera (Drechslera glycini), leaf spot by Frogeye (Cercospora sojina), leaf spot by Lula (Leptosphaerulina trifolii), leaf spot by Phyllostica (Phyllosticta soyaecola), powdery mildew (Microsphaera diffusa), leaf spot by Pyrenochaeta (P-yrenochaeta glycines), shoot burning, foliage and base by Rhizoctonia (Rhizoctonia) solani), rust (Phakopsora pachyrhizi), crust (S-phaceloma glycines), leaf blight by Stemphylium (Stemphylium botr-yosum), target spot (Corynespora cassiicola) ;

fungal diseases in roots and stem bases, caused for example by

black root rot (Calonectria crotalariae), black rot (Macrophomina phaseolina), burning or withering by Fusarium, root rot, and pod and stem rot (Fusarium oxysporum, Fusarium orthoceras, Fusarium semitectum, Fusarium equiseti), root rot by Mycoleptodiscus (Mycoleptodiscus terrestris), neocosmospora (Neocosmospora vasinfecta), pod and stem burning (Diaporthe phaseolorum), stem cancer (Diaporthe phaseolorum var. caulivora), Phytophthora rot (Phytophthora megasperitude) rot stem mulch (Phialophora gregata), Pythium rot (Pythium aphanidermatum, Pythium irregular, Pythium debaryanum, Pythium myriotylum, Pythium ultimum), Rhizoctonia root rot, stem wilting, and Rhizococcus wetness , stem wasting by Sclerotinia (Sclerotinia sclerotiorum), "Sclerotinia southern blight" (Sclerotinia rolfsii), root rot by Thielaviopsis (Thielaviopsis ba) sicola). The compositions according to the invention, in addition to the substances

Agrochemical active substances already mentioned above may contain as active components other active substances such as insecticides, baits, sterilizers, bactericides, acaricides, nematicides, fungicides, growth regulating substances, herbicides, "antidotes", fertilizers or semi-chemicals.

Particularly favorable mixing components are, for example: Fungicides:

Nucleic acid synthesis inhibitors:

benalaxyl, benalaxyl-M, bupirimate, chiralaxyl, clozilacon, dimyrimol, etirimol, furalaxyl, himexazole, mefenoxam, metalaxyl, metalaxyl-M, ofurace, oxadixil, oxolinic acid

mitosis and cell division inhibitors

benomyl, carbendazim, dietofencarb, etaboxam, fuberidazole, pencicurone, thiabendazole, thiophanate methyl, zoxamide

respiratory chain inhibitors - diflumetorim complex I

respiratory chain inhibitors - Il boscalida complex, carboxin, fenfuram, flutolanil, furametpir, furmeciclox, mepronil, oxicarboxin, pentiopirad, tifluzamide

respiratory chain inhibitors - complex azoxystrobin, ciazofamid, dimoxystrobin, enestrobin, famoxadone,

fenamidone, fluoxastrobin, cresoxim-methyl, metominostrobin, orisastrobin, piraclostrobin, picoxystrobin, dinocap uncoupling trifloxistrobin, fluazinam ATP production inhibitors

fentin acetate, fentin chloride, fentin hydroxide, silicon dioxide,

fam

amino acid and protein biosynthesis inhibitors andoprim, blasticidin-S, cyprodinil, casugamycin, casugamycin hydrochloride hydrate, mepanipyrim, pyrimethanil signal transduction inhibitors fenpiclonil, fludioxonil, quinoxifen lipid synthesis synthesis membranes , procimidone, vinclozolin ampropylphos, potassium ampropylphos, edifenphos, etridiazole, iprobenphos (PPIs), isoprothiolan, pyrazophos

tolclofos-methyl, biphenyl

iodocarb, propamocarb, propamocarb hydrochloride, propamocarbon carb phosphate

inhibitors of ergosterol fenexamide biosynthesis,

azaconazole, bitertanol, bromuconazole, cyproconazole, diclobutras-

zol, diphenoconazole, diniconazole, diniconazole-M, epoxiconazole, etaconazole, fenarimol, fenbuconazole, fluquinconazole, flurprimidol, flusilazole, flutriafol, furoconazole, furconazole-cis, hexaconazole, imazalil, imazalyl sulfate, imibencozazole, ipibonazole, ipibonazole, myclobutanil, nuarimol, oxpoconazole, paclobutrazol, penconazole, prochloraz perforazole, propiconazole, protioconazole, pyrifenox, simeconazole, tetraconazole, triadimephon, triadimenol, triflumizole, triforin, triticonazole, uniconazole, viniconicon, voriconazole

aldimorf, dodemorf, dodemorf acetate, fenpropidine, fenpropimorph, spiroxamine, tridemorf, naphthyphine, pyributicarb, terbinafine

cell wall synthesis inhibitors

bentiavalicarb, bialaphos, dimetomorf, flumorf, iprovalicarb, mandipropamide, polyoxins, polyoxorim, validamycin A melanin biosynthesis inhibitors capropamid, diclocimet, phenoxanil, phthalide, pyrokylon, tricyclazole

acibenzolar-S-methyl resistance induction, probenazole, thiadinil multiple activity compounds

captafol, captan, chlorothalonyl, copper salts such as: copper hydroxide, copper naphthenate, copper oxychloride, copper sulfate, copper oxide, copper oxine and mixtures bordeaux, diclofluanide, dithianone, dodine, dodine, ferbam, folpet, fluorfolpet, guazatin, guazatin acetate, iminoctadine, iminoctadine albesylate, iminoctadine triacetate, mancoper, mancozeb, maneb, meth, zinc, propineb, sulfur and sulfur preparations containing calcium polysulfide, , tolylfluanide, zineb, ziram Other fungicides

amibromdol, bentiazole, betoxazin, capsimycin, carvone, quinomethionate, chloropicrin, cufraneb, ciflufenamide, cimoxanil, dazomet, debab, dichlomenzine, dichlorophen, dichloran, difenzoquat, difenzoquat methylsulfaminum, difluenamide , fluorimide, fosyl aluminum, fosyl calcium, fosyl sodium, hexachlorobenzene, 8-hydroxyquinoline sulfate, irumamycin, metasulfocarb, metrafenone, methyl isothiocyanate, mildiomycin, natamycin, nickel dimethyl dithiocarbamate, nitrotalisopropyl oxocitrile oxyphentiine, pentachlorophenol and salts, 2-phenylphenol and salts, piperalin, propanosine sodium, proquinazid, piribencarb, pyrrolenitrine, quintozen, keyboardophthalam, tecnazen, triazoxide, triclamide, valifenal, zarylamide,

2- (2 - {[6- (3-chloro-2-methylphenoxy) -5-fluorpyrimidin-4-yl] oxy} phenyl) -2- (methoxyimino) -N-methylacetamide,

2 - [[[[[[1- [3- (1-fluor-2-phenylethyl) oxy] phenyl] ethylidene] amino] oxy] methyl] alpha- (methoxyimino) -N-methyl-alphaE-benzacetamide,

cis -1- (4-chlorophenyl) -2- (1H-1,2,4-triazol-1-yl) cycloheptanol,

1 - [(4-methoxyphenoxy) methyl] -2,2-dimethylpropyl-1H-imidazole-1-acid

carboxylic,

2,3,5,6-tetrachloro-4- (methylsulfonyl) pyridine, 2-butoxy-6-iodo-3-propyl-benzopyran-4-one,

2-chloro-N- (2,3-dihydro-1,1,3-trimethyl-1H-inden-4-yl) -3-pyridincarboxamide,

3,4,5-trichloro-2,6-pyridindicarbonitrile,

3,4-dichloro-N- (2-cyanophenyl) isothiazol-5-carboxamide (Isothianyl) 3- [5- (4-chlorophenyl) -2,3-dimethylisoxazolidin-3-yl] pyridine,

5-chloro-6- (2,4,6-trifluorphenyl) -N - [(1 R) -1,2,2-trimethylpropyl] [1,2,4] triazolo [1,5-a] pyrimidin-7 -amine, 5-chloro-7- (4-methylpiperidin-1-yl) -6- (2,4,6-

trifluorphenyl) [1,2,4] triazolo [1,5-a] pyrimidine,

5-chloro-N - [(1 R) -1,2-dimethylpropyl] -6- (2,4,6-trifluorphenyl) - [1,2,4] triazolo [1,5-a] pyrimidin-7 the mine,

methyl 2 - [[[cyclopropyl [(4-methoxyphenyl) imino] methyl] thio] methyl] -phaphae

(methoxymethylene) benzoacetate,

methyl 1- (2,3-dihydro-2,2-dimethyl-1H-inden-1-yl) -1H-imidazole-5-

carboxylate,

N- (3 ', 4'-Dichloro-5-fluorbiphenyl-2-yl) -3- (difluoromethyl) -1-methyl-1H-1

pyrazol-4-carboxamide,

N- (3-ethyl-3,5,5-trimethyl-cyclohexyl) -3-formylamino-2-hydroxy

benzamide,

N- (4-chloro-2-nitrophenyl) -N-ethyl-4-methyl-benzenesulfonamide, N- (4-chlorobenzyl) -3- [3-methoxy-4- (prop-2-yn-1-

yloxy) phenyl] propanamide,

N - [(4-chlorophenyl) (cyano) methyl] -3- [3-methoxy-4- (prop-2-yn-1-

yloxy) phenyl] propanamide,

N- (5-bromo-3-chloropyridin-2-yl) methyl-2,4-dichloronicotinamide, N- [1- (5-bromo-3-chloropyridin-2-yl) ethyl] -2,4-dichloronicotinamide, (2S) -N- [2- [4 - [[3- (4-chlorophenyl) -2-propynyl] oxy] -3-methoxyphenyl] ethyl] -3-

methyl-2 - [(methylsulfonyl) amino] butanamide,

N - {(Z) - [(cyclopropylmethoxy) imino] [6- (difluoromethoxy) -2,3-difluorphenyl] methyl} -2-benzacetamide,

N- {2- [1,1'-bi (cyclopropyl) -2-yl] phenyl} -3- (difluoromethyl) -1-methyl-1H-pyrazol-4-carboxamide,

N- {2- [3-chloro-5- (trifluoromethyl) pyridin-2-yl] ethyl} -2-

(trifluoromethyl) benzamide,

N-ethyl-N-methyl-N '- {2-methyl-5- (trifluoromethyl) -4- [3- (trimethylsilyl) propoxy] phenyl} imidoformamide, acid-1 H - [(4-methoxyphenoxy) methyl] - 2,2-dimethylpropyl] -1H-imidazole

1-carbothioic,

2-amino-4-methyl-N-phenyl-5-thiazolcarboxamide, 2,4-dihydro-5-methoxy-2-methyl-4 - [[[[1- [3- (trifluoromethyl) phenyl] ethyliden] amino] oxy] methyl] phenyl] -3H-1,2 (CASE

No. 185336-79-2),

N- (6-Methoxy-3-pyridinyl) cyclopropane carboxamide, Bactericides:

Bronopol, dichlorophene, nitrapirin, nickel dimethyl dithiocarbamate, casugamycin, octylinone, furan carboxylic acid, oxytetracycline, pro-benazole, streptomycin, keyophthalam, copper sulfate and other copper preparations.

Insecticides / acaricides / nematicides:

Acetylcholinesterase (AchE) Carbamate Inhibitors,

for example alanicarb, aldicarb, aldoxycarb, alixicarb, amino carb, bendiocarb, benfuracarb, bufencarb, butacarb, butocarboxim, butoxycarboxim, carbaryl, carbofuran, carbosulfan, cloetocarb, dimethylan, ethiofencarb, phenobucate, phenobuccarbate , isoprocarb, methamil, methomyl, metolcarb, oxamyl, pirimicarb, promecarb, propoxur, thiodicarb, thiopanox, trimetacarb, xylylcarb, triazamatos, Organophosphates,

for example acetate, azametiphos, azinphos (-methyl, ethyl), bromophos-ethyl, bromfenvinphos (-methyl), butathiophos, cadusaphos, carbofenothione, chloridexyphos, chlorophenvinphos, chloromorphs, chloropyrifos (-methyl / ethyl), coumaphos, coumaphos, cyanophos, chlorophenvinphos, demeton-S-methyl, demeton-S-methylsulfone, dialiphos, diazinone, diclofentiona, dichlorvos / DDVP, dichrotophos, dimethoate, dimethylvinphos, dioxabenzophos, disulfotone, EPN, etione, etphophos, miphenophosphorus fenitrothione, fensulfothione, fentiona, flupirazofos, phonophos, formothione, fosmetilano, fostiazato, heptenofos, iodofenfos, iprobenfos, isazofos, isofensos, isopropyl O-salicylate, isoxationa, malation, mecarbam, methaphid, methaphid, methaphid , naled, ometoate, oxideme-methyl, paration (methyl / ethyl), phentoate, phorate, fosalone, fosmet, phosphatone, phosphocarb, foxima, pyrimiphos (methyl / ethyl), profenofos, propafos, propetamfos protiofos protoato piraclofos pyridafention a, pyridathione, quinalphos, sebufos, sulfotep, sulprofos, tebupirimfos, temephos, terbufos, tetrachlorovinfos, thiometone, triazofos, trichlorphon, vamidothione.

Sodium Channel Modulators / Voltage-Dependent Sodium Channel Blocker Pyrethroids,

for example acrinatrine, allethrin (d-cis-trans, d-trans), beta-cyfluthrin, bifentrin, bioalethrin, bioalethrin-S cyclopentyl isomer, bioetanometrine, biopermetrine, biorresmethrin, clovaportrin, cis-cypermethrin, cis-reserethrin , cis-permethrin, clocitrin, cycloprotrin, cyfluthrin, cyhalothrin, cypermethrin (alpha-, beta-, theta-, zeta-), cyphenothrin, deltamethrin, empenthrin (1R-isomer), sphenvalerate, etophenprox, fenfluthrin, fenpropatrin, , fenvalerate, flubrocitrinate, flucitrinate, flufenprox, flumethrin, fluvalinate, fubfenprox, gamma-cyhalothrin, imiprotrin, cadetrin, lambda-cyhalothrin, metofluthrin, permethrin (eis, trans-), phenothrin (1R, trans-isomer) pralethrin, profluthrin, pro- trifenbute, pyresmethrin, resmetrin, RU 15525, silafluofen, dew fluvalinate, tefluthrin, teralethrin, tetramethrin (1R isomer), tralomethrin, transflutrin, ZXI 8901, pyrethrin (pyrethrum) DDT

Oxadiazines, for example indoxacarb

semicarbazone,

e.g. metaflumizon (BAS3201)

Acetylcholine Receptor Agonists / Antagonists

Chloronicotinils,

for example acetamipride, clotianidine, dinotefuran, nitenpiram, nitiazine, thiaclopride, thiamethoxam

Nicotines, bensultap, cartap Acetylcholine Receptor Modulators Spinosinas, e.g. spinosad,

GABA Controlled Chloride Channel Antagonists Organochlorines, for example, camfechlor, clordane, endosulfan, gamma-HCH, heptachlor HCH1, lindane, methoxychlor Fiproles,

e.g. acetoprole, etiprole, fipronil, pirafluprole, pyriprole, vaniliprole Chloride channel activators

Mectins1

for example abamectin, emamectin, emamectin benzoate, ivermectin, lepimectin, milbemycin

Juvenile hormone mimetics, for example diofenolan, epofenonane, phenoxycarb, hydroprene,

quinoprene, methoprene, pyriproxyfen, triprene Ecdysone Agonists / Disruptors Diacylhydrazines,

e.g. chromafenozide, halofenozide, methoxyphenozide, tebufenozide Chitin biosynthesis inhibitors

Benzoylureas,

for example bistriflurone, clofluazurone, diflubenzurone, fluazurone, flucicloxurone, flufenoxurone, hexaflumurone, lufenurone, novalurone, noviflumuroin, penflurone, teflubenzurone, triflumurone Buprofezin

Cyromazines

Oxidative phosphorylation inhibitors, ATP disruptors Diafentiurone

Organic tin compounds, for example azocyclotine, cyhexatin, fenbutatin oxides

Oxidative phosphorylation decouplers by breaking the proton gradient H

Pyrroles, for example chlorophenapyr Dinitrophenols,

for example, binapacrila, dinobutone, dinocap, DNOC, meptildinocap METI-I1 Electron Transport Inhibitors

for example, phenazaquin, fenpyroximate, pyrimidifene, pyridene, tebufenpyrad, tolfenpyrad Hydramethylnone Dicofol

Iado-Il Rotenona Electron Transport Inhibitors

Iado-Ill Electron Transport Inhibitors Acequinocyl, fluacripirima Insect Intestinal Membrane Microbial Disruptors

Bacillus thuringiensis strains Tetronic acid fat synthesis inhibitors,

e.g. spirodiclofen, tetramic acid spiromesifen,

cis-3- (2,5-dimethylphenyl) -4-hydroxy-8-methoxy-1-azaspiro [4.5] dec-3-en-2-one Carboxamides, e.g. flonicamide Octopaminergic agonists,

for example amitraz

Magnesium-stimulated ATPase inhibitors, propargite

nereistoxin analogs for example thiocyclam hydrogen oxalate, thiosultap-sodium

Ryanodine receptor agonists, benzoic acid dicarboxamides, for example anubanamide flubendiamide,

for example rinaxipyr (3-bromo-N- {4-chloro-2-methyl-6-one

[(methylamino) carbonyl] phenyl} -1- (3-chloropyridin-2-yl) -1H-pyrazol-5-carboxamide) Azadiractin biological products, hormones or pheromones, Bacillus spec., Beauveria spec., codlemone, Metarhrizium spec., Paecilomyces spec., thuringiensin, Verticillium spec.

Active substances with unknown or unspecified mechanisms of effect Gas absorption agents,

for example aluminum phosphites, methyl bromides, fluorides

sulfuryl

Devouring inhibitors, eg cryolite, flonicamid, pimetrozine Mite growth inhibitors,

for example, clofentezine, ethoxazoles, hexithiazox Amidoflumet, benclothiaz, benzoxime, biphenazate, bromopropyl, buprofezin, cinomethionate, chlorodimeform, chlorobenzylate, chloropicrin, clothiazoben, cycloprene, ciflumetofen, dibenzaminofenanfluenzin, dicyanulfin, gossiplure, hydramethylnone, japonilure, methoxadiazone, petroleum, piperonyl butoxides, potassium oleate, pyridalyl, sulfluramide, tetradifone, tetrasul, triaratene, verbutin.

It is also possible to mix it with other known active substances such as herbicides, fertilizers, growth regulators, antidotes, semi-chemicals, or also with agents for enhancing plant properties.

The active substances according to the invention, in use as insecticides, may furthermore be present in their usual commercial formulations as well as in the application forms prepared from such formulations in admixture with synergists. Synergists are compounds whereby the effect of the active substances according to the invention is increased, without the added synergist having to be properly activated.

The active substances according to the invention may furthermore, in their use as insecticides, be present in their usual commercial formulations as well as in the application forms prepared from such formulations in admixture with inhibiting substances which prevent decomposition of the active substance after application in the environment of plants, on the surface of plant parts or in plant tissues.

The active substance content of the application forms according to the invention may vary within wide limits. The concentration of active substances in the application forms may be from 0.00000001 to 95% by weight of active substance, preferably from 0.00001 to 20% by weight.

The application takes place in the usual way adapted to one of the application forms.

According to the invention all plants can be treated.

In a preferred embodiment, plant types and plant varieties found in native form or obtained by traditional biological reproduction methods such as cross-breeding or fusion of protoplasts are treated. In another preferred embodiment, transgenic plants and plant species which have been obtained by genetic engineering methods possibly in combination with conventional methods (genetically modified organisms) are treated.

Particularly preferably according to the invention are cultivated plants, in each case commercially obtainable or in use. Under cultivars should be understood plants with new properties ("Traits") grown either by traditional cultivation, mutagenesis or by recombinant DNA techniques. These can be species, biotypes or genotypes.

Depending on the species of plants or cultivars, their location and development conditions (soils, climate, growing season, nutrients), due to the treatment according to the invention, superadditive (synergistic) effects may also arise. Thus, for example, reduced application amounts and / or increased spectrum of action and / or increased efficacy of the substances and compositions employed according to the invention enable better plant growth, greater drought tolerance or higher content. water or salt in the soil, more abundant flowering, easier harvesting, acceleration of maturation, higher yield, improved quality and / or higher nutritional value of final products, increased storage stability and / or improved processability of harvested products. , which outweigh the expected effects.

Preferred transgenic plants or cultivars (obtained by genetic engineering) to be treated in accordance with the invention include all plants that have received genetic material by modification of genetic technology, which gives these plants particularly valuable properties (" Traits "). Examples of such properties are better plant growth, higher tolerance to lower or higher temperatures, greater tolerance to drought or soil water or salt content, more abundant flowering, easier harvesting, faster at maturity, higher productivity, better quality and / or higher nutrient value of the crop product, greater storage stability and / or better processability of the crop products. Other particularly emphasized examples of such properties are: better plant defense against animal and microbial pests such as insects, mites, phytopathogenic fungi, bacteria and / or viruses and also higher plant tolerance against certain herbicidal active substances . Examples of transgenic plants include important crop plants such as cereals (wheat and rice), maize, soybean, potatoes, sugar beet, tomatoes, peas and other vegetables, cotton, tobacco, rapeseed, as well as fruit (with fruits: apples, pears, citrus and grapes), with emphasis on corn, soybeans, potatoes, cotton, tobacco and rapeseed. As traits are emphasized in particular the high defense of plants against insects, tetanic, nematodes and snails through plant toxins, in particular those obtained from Bacillus thuringiensis genetic material (for example, by CrylA (a), CrylA (b), CrylA (c), CryIIA1 CrylllA, CrylllB2, Cry9c, Cry2Ab, Cry3Bb and CryIF genes and combinations thereof (hereinafter "Bt plants"). As traits, the high defense of plants against fungi, bacteria and viruses is also particularly emphasized by systemic resistance (SAR), systemin, phytoalexin, elicitors as well as resistant genes and corresponding proteins and toxins. . As traits are also particularly emphasized the high tolerance of plants to certain herbicidal active substances, for example imidazolinones, sulfonylureas, glyphosates or phosphinothricin (eg the gene "PAT"). The genes that confer, in each case, the desired properties (traits) may be present in transgenic plants, also in combination with each other. Examples for "Bt plants" are corn cultivars, cotton cultivars, soybean cultivars and potato cultivars, which are marketed under the trademark YIELD GARD® (eg corn, cotton, soybean), KnockOut® (eg corn), StarLink® (eg maize), Bollgard® (cotton), Nucoton® (cotton) and NewLeaf® (potatoes). Examples of herbicide-resistant plants include maize varieties, cotton varieties, soybean varieties marketed under the trade name Roundup Ready® (glyphosate tolerant eg maize, cotton, soybean), Liberty Link® (tolerant to phosphinothricin, eg rapeseed), IMI® (tolerant to imidazolinones) and STS® (tolerant to sulfonylureas, eg maize). Herbicide-resistant plants (usually grown for herbicide tolerance) also include varieties marketed under the name Clearfield® (eg maize). Of course, this also applies to crops to be developed or placed on the market in the future with such genetic or other traits to be developed in the future.

The mentioned plants may be particularly advantageously treated with the compounds according to the invention. The preferred ranges given above for the active substances are also suitable for the treatment of these plants. Particular emphasis is given to the treatment of plants with the compounds specifically mentioned in the present text.

The following examples serve to elucidate the invention without limiting it. Examples

Preparation Examples The compositions according to the invention were prepared from

follow:

Example 1 Example 2 Example 3 Example 4 Active substance Imidachloprid Imidachloprid Imidachloprid Imidachloprid active substance / wt% 5 5 5 5 Cellulose ester CAP CAP CAP CAP Cellulose ester / wt% 70 55 75 60 CaCO3 / wt% 15 30 15 30 Emulsifier (I) / wt% 10 10 5 5

Active Substance Release

For the example formulation, the release of the active substance was determined after introduction of the formulation in water:

Release of active substance in% After 48 h After 168 h Example 1 18 26 Example 2 29 38 Example 3 7 13 Example 4 12 20

Claims (8)

1. Composition containing - at least one agrochemical active substance - at least one cellulose ester - calcium carbonate (Ca2CC> 3) · A composition according to claim 1 further containing at least one solid emulsifier at room temperature. Composition according to Claim 1 or 2, containing imidaclopride, methiocarb, tebuconazole or spirotetramate as an agrochemical active substance. Composition according to claim 1 or 2, containing - imidaclopride as an agrochemical active substance. Composition according to claim 1, containing - 0.1 to 20% by weight of agrochemical active substance - 30 to 90% by weight of cellulose ester - 5 to 50% by weight of calcium carbonate. Composition according to claim 5, containing 1 to 25% by weight of a solid emulsifier at room temperature. A process for combating harmful insects, comprising applying a composition as defined in one or more of claims 1 to 6. Use of a composition as defined in one or more of claims 1 to 6 for the control of harmful insects.