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BRPI0507938A - processo para a preparação de borracha de nitrila hidrogenada de baixo peso molecular - Google Patents

processo para a preparação de borracha de nitrila hidrogenada de baixo peso molecular

Info

Publication number
BRPI0507938A
BRPI0507938A BRPI0507938-1A BRPI0507938A BRPI0507938A BR PI0507938 A BRPI0507938 A BR PI0507938A BR PI0507938 A BRPI0507938 A BR PI0507938A BR PI0507938 A BRPI0507938 A BR PI0507938A
Authority
BR
Brazil
Prior art keywords
molecular weight
nitrile rubber
hydrogenated nitrile
hydrogenated
low molecular
Prior art date
Application number
BRPI0507938-1A
Other languages
English (en)
Inventor
Frederic Guerin
Original Assignee
Lanxess Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lanxess Inc filed Critical Lanxess Inc
Publication of BRPI0507938A publication Critical patent/BRPI0507938A/pt
Publication of BRPI0507938B1 publication Critical patent/BRPI0507938B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F236/12—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated with nitriles
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00—Chemical modification of rubber
    • C08C19/02—Hydrogenation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
    • C08C19/00—Chemical modification of rubber
    • C08C19/08—Depolymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/42—Nitriles

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

PROCESSO PARA A PREPARAçãO DE BORRACHA DE NITRILA HIDROGENADA DE BAIXO PESO MOLECULAR. A presente invenção refere-se a polímeros de borracha de nitrila hidrogenada, que têm pesos moleculares mais baixos e distribuições de peso molecular mais estreitas do que aquelas conhecidas na técnica anterior, são preparadas por uma processo realizado na presença de hidrogênio e opcionalmente pelo menos uma co-olefina. De acordo com o processo, o substrato é simultaneamente submetido a uma reação de metátese e uma reação de hidrogenação. A reação ocorre na presença de um catalisador a base de alquiledeno de ósmio ou rutênio. A borracha de nitrila hidrogenada produzida tem um peso molecular (Mw) na faixa de 20.000 a 250.000. uma viscosidade Mooney (ML 1+4 em 100 graus C) na faixa de 1 a 50, e uma MWD de menos de 2,6. A borracha de nitrita hidrogenada obtida é usada em indústrias automotivas, elétricas, de engenharia mecânica e de construção de navios.
BRPI0507938A 2004-02-23 2005-02-22 processo para a preparação de borracha de nitrila hidrogenada de baixo peso molecular BRPI0507938B1 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CA002462005A CA2462005A1 (en) 2004-02-23 2004-02-23 Process for the preparation of low molecular weight hydrogenated nitrile rubber
PCT/CA2005/000255 WO2005080456A1 (en) 2004-02-23 2005-02-22 Process for the preparation of low molecular weight hydrogenated nitrile rubber

Publications (2)

Publication Number Publication Date
BRPI0507938A true BRPI0507938A (pt) 2007-07-17
BRPI0507938B1 BRPI0507938B1 (pt) 2016-01-12

Family

ID=34865994

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0507938A BRPI0507938B1 (pt) 2004-02-23 2005-02-22 processo para a preparação de borracha de nitrila hidrogenada de baixo peso molecular

Country Status (11)

Country Link
US (1) US7585920B2 (pt)
EP (1) EP1720920B1 (pt)
JP (1) JP4611371B2 (pt)
KR (1) KR101236031B1 (pt)
CN (1) CN100526353C (pt)
BR (1) BRPI0507938B1 (pt)
CA (1) CA2462005A1 (pt)
MX (1) MXPA06009368A (pt)
PL (1) PL1720920T3 (pt)
TW (1) TWI347328B (pt)
WO (1) WO2005080456A1 (pt)

Families Citing this family (29)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA2350280A1 (en) 2001-06-12 2002-12-12 Bayer Inc. Low molecular weight hydrogenated nitrile rubber
US6841623B2 (en) 2001-06-29 2005-01-11 Bayer Inc. Low molecular weight nitrile rubber
ES2370416T5 (es) * 2005-05-20 2016-04-25 Bridgestone Corporation Método para preparar polímeros de bajo peso molecular
DE102006008521A1 (de) 2006-02-22 2007-08-23 Lanxess Deutschland Gmbh Verwendung von Katalysatoren mit erhöhter Aktivität für die NBR-Metathese
DE102006040569A1 (de) * 2006-08-30 2008-03-06 Lanxess Deutschland Gmbh Verfahren zum Metathese-Abbau von Nitrilkautschuken
DE102007039525A1 (de) * 2007-08-21 2009-02-26 Lanxess Deutschland Gmbh Verfahren zum Metathese-Abbau von Nitrilkautschuk
EP2143489A1 (de) * 2008-07-08 2010-01-13 Lanxess Deutschland GmbH Katalysator-Systeme und deren Verwendung für Metathese-Reaktionen
EP2147721A1 (de) * 2008-07-08 2010-01-27 Lanxess Deutschland GmbH Katalysator-Systeme und deren Verwendung für Metathese-Reaktionen
EP2289623A1 (en) 2009-08-31 2011-03-02 LANXESS Deutschland GmbH Metathesis of nitrile rubbers in the presence of transition metal catalysts
WO2011023771A1 (en) 2009-08-31 2011-03-03 Lanxess Deutschland Gmbh Vulcanizable polymer composition comprising a low molecular weight optionally hydrogenated nitrile rubber
EP2289621A1 (en) * 2009-08-31 2011-03-02 LANXESS Deutschland GmbH Process for the preparation of low molecular weight hydrogenated nitrile rubber
EP2289620A1 (en) * 2009-08-31 2011-03-02 LANXESS Deutschland GmbH Process for the preparation of hydrogenated nitrile rubber
WO2011079439A1 (en) * 2009-12-30 2011-07-07 Zannan Scitech Co., Ltd. Highly active metathesis catalysts selective for romp and rcm reactions
WO2013056400A1 (en) 2011-10-21 2013-04-25 Lanxess Deutschland Gmbh Catalyst compositions and their use for hydrogenation of nitrile rubber
WO2013056463A1 (en) 2011-10-21 2013-04-25 Lanxess Deutschland Gmbh Catalyst compositions and their use for hydrogenation of nitrile rubber
WO2013056459A1 (en) * 2011-10-21 2013-04-25 Lanxess Deutschland Gmbh Catalyst compositions and their use for hydrogenation of nitrile rubber
WO2013056461A1 (en) 2011-10-21 2013-04-25 Lanxess Deutschland Gmbh Catalyst compositions and their use for hydrogenation of nitrile rubber
CN104271607B (zh) * 2012-04-28 2017-05-24 阿朗新科德国有限责任公司 丁腈橡胶的氢化
WO2013159365A1 (en) 2012-04-28 2013-10-31 Lanxess Deutschland Gmbh Hydrogenation of nitrile rubber
EP2676969B1 (en) 2012-06-22 2016-06-01 University Of Waterloo Tandem metathesis and hydrogenation of diene-based polymers in latex
EP2676971B1 (en) 2012-06-22 2015-04-08 University Of Waterloo Hydrogenation of a diene-based polymer latex
CN105542037B (zh) * 2014-10-29 2017-08-25 中国石油化工股份有限公司 一种不饱和共聚物的加氢方法
TWI566835B (zh) 2014-12-25 2017-01-21 財團法人工業技術研究院 烯烴複分解觸媒及低分子量丁腈橡膠之製備方法
CN107540765B (zh) * 2016-06-24 2020-06-09 中国石油天然气股份有限公司 一种丁腈橡胶用阻燃型增塑剂的制备方法
JP2021532208A (ja) 2018-07-23 2021-11-25 アランセオ・ドイチュランド・ゲーエムベーハー 水素化ニトリルゴムを製造するための方法及びそのｈｎｂｒ組成物
EP4045549A4 (en) * 2019-10-14 2023-11-22 Bridgestone Americas Tire Operations, LLC Anionic dispersion polymerization process to make random copolymer rubber
CN114262394B (zh) * 2020-09-16 2023-08-18 浙江赞昇新材料有限公司 液体氢化丁腈橡胶及其制备方法和应用
JP7648878B2 (ja) * 2021-02-26 2025-03-19 横浜ゴム株式会社 ホース用ゴム組成物及びホース
EP4617291A1 (en) * 2022-11-08 2025-09-17 Asahi Kasei Kabushiki Kaisha Hydrogenated conjugated diene polymer, and hydrogenated conjugated diene polymer manufacturing method

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19907519A1 (de) * 1999-02-22 2000-08-31 Basf Ag Verfahren zur Herstellung von substituierten Olefinen
CA2350280A1 (en) * 2001-06-12 2002-12-12 Bayer Inc. Low molecular weight hydrogenated nitrile rubber
US6673881B2 (en) * 2001-06-12 2004-01-06 Bayer Inc. Process for the preparation of low molecular weight hydrogenated nitrile rubber
CA2413636A1 (en) * 2002-12-05 2004-06-05 Bayer Inc. Adhesive compositions
CA2413607A1 (en) * 2002-12-05 2004-06-05 Bayer Inc. Process for the preparation of low molecular weight hydrogenated nitrile rubber

Also Published As

Publication number Publication date
KR101236031B1 (ko) 2013-02-21
EP1720920A1 (en) 2006-11-15
EP1720920A4 (en) 2010-07-28
US7585920B2 (en) 2009-09-08
CN1922224A (zh) 2007-02-28
PL1720920T3 (pl) 2012-11-30
JP4611371B2 (ja) 2011-01-12
TWI347328B (en) 2011-08-21
JP2007534797A (ja) 2007-11-29
MXPA06009368A (es) 2007-01-26
EP1720920B1 (en) 2012-06-13
US20080214741A1 (en) 2008-09-04
TW200604222A (en) 2006-02-01
WO2005080456A1 (en) 2005-09-01
KR20070032278A (ko) 2007-03-21
BRPI0507938B1 (pt) 2016-01-12
CN100526353C (zh) 2009-08-12
CA2462005A1 (en) 2005-08-23

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Legal Events

Date Code Title Description
B07A Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]
B06A Patent application procedure suspended [chapter 6.1 patent gazette]
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 10 (DEZ) ANOS CONTADOS A PARTIR DE 12/01/2016, OBSERVADAS AS CONDICOES LEGAIS.

B21F Lapse acc. art. 78, item iv - on non-payment of the annual fees in time
B24J Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12)

Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2450 DE 19-12-2017 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013.