BRPI0418874A - apparatus and process for converting sulfur compounds into a hydrocarbon stream, and apparatus for contacting the hydrocarbon stream containing alkali sulfur compounds - Google Patents
apparatus and process for converting sulfur compounds into a hydrocarbon stream, and apparatus for contacting the hydrocarbon stream containing alkali sulfur compoundsInfo
- Publication number
- BRPI0418874A BRPI0418874A BRPI0418874-8A BRPI0418874A BRPI0418874A BR PI0418874 A BRPI0418874 A BR PI0418874A BR PI0418874 A BRPI0418874 A BR PI0418874A BR PI0418874 A BRPI0418874 A BR PI0418874A
- Authority
- BR
- Brazil
- Prior art keywords
- sulfur compounds
- alkali
- hydrocarbon stream
- converting
- section
- Prior art date
Links
- 239000003513 alkali Substances 0.000 title abstract 8
- 229930195733 hydrocarbon Natural products 0.000 title abstract 8
- 150000002430 hydrocarbons Chemical class 0.000 title abstract 8
- 239000004215 Carbon black (E152) Substances 0.000 title abstract 7
- 150000003464 sulfur compounds Chemical class 0.000 title abstract 5
- 238000000034 method Methods 0.000 title abstract 3
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 abstract 3
- 238000000605 extraction Methods 0.000 abstract 3
- 239000003518 caustics Substances 0.000 abstract 2
- 229910000037 hydrogen sulfide Inorganic materials 0.000 abstract 2
- 239000011230 binding agent Substances 0.000 abstract 1
- 229910052979 sodium sulfide Inorganic materials 0.000 abstract 1
- GRVFOGOEDUUMBP-UHFFFAOYSA-N sodium sulfide (anhydrous) Chemical compound [Na+].[Na+].[S-2] GRVFOGOEDUUMBP-UHFFFAOYSA-N 0.000 abstract 1
- 150000004763 sulfides Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G19/00—Refining hydrocarbon oils in the absence of hydrogen, by alkaline treatment
- C10G19/02—Refining hydrocarbon oils in the absence of hydrogen, by alkaline treatment with aqueous alkaline solutions
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G19/00—Refining hydrocarbon oils in the absence of hydrogen, by alkaline treatment
- C10G19/08—Recovery of used refining agents
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G53/00—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more refining processes
- C10G53/02—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more refining processes plural serial stages only
- C10G53/12—Treatment of hydrocarbon oils, in the absence of hydrogen, by two or more refining processes plural serial stages only including at least one alkaline treatment step
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/20—Characteristics of the feedstock or the products
- C10G2300/201—Impurities
- C10G2300/202—Heteroatoms content, i.e. S, N, O, P
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/20—Characteristics of the feedstock or the products
- C10G2300/201—Impurities
- C10G2300/207—Acid gases, e.g. H2S, COS, SO2, HCN
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
APARELHO E PROCESSO PARA CONVERTER COMPOSTOS DE ENXOFRE EM UMA CORRENTE DE HIDROCARBONETO, E, APARELHO PARA CONTATAR A CORRENTE DE HIDROCARBONETO CONTENDO COMPOSTOS DE ENXOFRE COM áLCALI. São descritos um aparelho e um processo para extrair compostos de enxofre de uma corrente de hidrocarboneto. Uma seção de pré-lavagem para converter sulfeto de hidrogênio em um sal de sulfeto pela reação com um álcali, de tal forma que o cáustico se comunique com uma seção de extração disposta diretamente acima da seção de pré-lavagem para converter mercaptanas em mercaptídeos pela reação com álcali. O produto de hidrocarboneto sai da seção de extração através de um aglomerador que evitar que o álcali saia com a corrente de produto de hidrocarboneto. Uma seção de pré-lavagem para converter sulfeto de hidrogênio em sulfeto de sódio pela reação com um álcali, tal como solução cáustica, prepara a corrente de hidrocarboneto para extração. O álcali gasto é continuamente retirado e álcali regenerado é continuamente adicionado à seção de pré-lavagem.Apparatus and process for converting sulfur compounds into a hydrocarbon stream, and apparatus for contacting hydrocarbons containing alkali sulfur compounds. An apparatus and method for extracting sulfur compounds from a hydrocarbon stream is described. A prewash section for converting hydrogen sulfide to a sulfide salt by reaction with an alkali such that the caustic communicates with an extraction section disposed directly above the prewash section for converting mercaptans to mercaptides by reaction with alkali. The hydrocarbon product exits the extraction section through a binder that prevents alkali from escaping with the hydrocarbon product stream. A prewash section for converting hydrogen sulfide to sodium sulfide by reaction with an alkali, such as caustic solution, prepares the hydrocarbon stream for extraction. Spent alkali is continuously removed and regenerated alkali is continuously added to the prewash section.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/US2004/017110 WO2005121279A1 (en) | 2004-06-02 | 2004-06-02 | Apparatus and process for extracting sulfur compounds from a hydrocarbon stream |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BRPI0418874A true BRPI0418874A (en) | 2007-11-27 |
| BRPI0418874B1 BRPI0418874B1 (en) | 2013-09-10 |
Family
ID=34958072
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0418874-8B1A BRPI0418874B1 (en) | 2004-06-02 | 2004-06-02 | apparatus and process for converting sulfur compounds into a hydrocarbon stream, and apparatus for contacting the alkali sulfur-containing hydrocarbon stream with |
Country Status (9)
| Country | Link |
|---|---|
| JP (1) | JP4800303B2 (en) |
| KR (1) | KR101013472B1 (en) |
| CN (1) | CN1961060B (en) |
| AU (2) | AU2004320621B2 (en) |
| BR (1) | BRPI0418874B1 (en) |
| CA (1) | CA2567701C (en) |
| ES (1) | ES2345375B2 (en) |
| RU (1) | RU2352610C2 (en) |
| WO (1) | WO2005121279A1 (en) |
Families Citing this family (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7772449B2 (en) * | 2007-08-01 | 2010-08-10 | Stone & Webster Process Technology, Inc. | Removal of acid gases and sulfur compounds from hydrocarbon gas streams in a caustic tower |
| CN101371967B (en) * | 2007-08-24 | 2011-03-30 | 宁波中一石化科技有限公司 | Liquid gas sweetening alkali liquor oxidized regeneration method and apparatus |
| US8028975B2 (en) | 2008-11-14 | 2011-10-04 | Uop Llc | Separation vessel or part thereof, and process relating thereto |
| US8173856B2 (en) | 2010-06-30 | 2012-05-08 | Uop Llc | Process for reducing corrosion |
| US8597501B2 (en) * | 2010-06-30 | 2013-12-03 | Uop Llc | Process for removing one or more sulfur compounds from a stream |
| FR2983205B1 (en) * | 2011-11-24 | 2015-03-20 | Ifp Energies Now | IMPROVED PROCESS FOR THE EXTRACTION OF SULFUR COMPOUNDS USING A FIRST DISCONTINUOUSLY OPERATING PRETREATMENT REACTOR FOLLOWING A SECOND PISTON-TYPE PRETREATMENT REACTOR |
| CN102492464A (en) * | 2011-12-02 | 2012-06-13 | 甘肃蓝科石化高新装备股份有限公司 | Gasoline desulfuration and deodorization process |
| US9181501B2 (en) | 2012-08-17 | 2015-11-10 | Uop Llc | Method and apparatus for removing H2S and moisture from fractionator overhead naphtha |
| US9328294B2 (en) | 2012-09-04 | 2016-05-03 | Uop Llc | Process and apparatus for extracting sulfur compounds in a hydrocarbon stream |
| US8813976B2 (en) * | 2012-12-10 | 2014-08-26 | Uop Llc | Process and apparatus for extracting |
| US9845539B2 (en) | 2012-12-21 | 2017-12-19 | Sulfurcycle Intellectual Property Holding Company Llc | Treatment of hydrogen sulfide |
| US20140197109A1 (en) * | 2013-01-15 | 2014-07-17 | Uop, Llc | Process for removing one or more disulfide compounds |
| US9157032B2 (en) * | 2013-02-19 | 2015-10-13 | Uop Llc | Process for oxidizing one or more thiol compounds |
| US9283496B2 (en) | 2013-06-18 | 2016-03-15 | Uop Llc | Process for separating at least one amine from one or more hydrocarbons, and apparatus relating thereto |
| US9327211B2 (en) | 2013-06-18 | 2016-05-03 | Uop Llc | Process for removing carbonyl sulfide in a gas phase hydrocarbon stream and apparatus relating thereto |
| US9284493B2 (en) | 2013-06-18 | 2016-03-15 | Uop Llc | Process for treating a liquid hydrocarbon stream |
| US9126879B2 (en) | 2013-06-18 | 2015-09-08 | Uop Llc | Process for treating a hydrocarbon stream and an apparatus relating thereto |
| RU2522155C1 (en) * | 2013-07-04 | 2014-07-10 | Андрей Владиславович Курочкин | Supercritical separator |
| US9522861B2 (en) * | 2013-11-18 | 2016-12-20 | Uop Llc | Methods and apparatuses for producing low sulfur propane and butane |
| US10233081B2 (en) | 2014-06-25 | 2019-03-19 | New Sky Energy Intellectual Property Holding Company, Llc | Method to prepare one or more chemical products using hydrogen sulfide |
| FR3063497B1 (en) * | 2017-03-01 | 2019-04-05 | Axens | IMPROVED METHOD FOR REGENERATING AN ALKALINE SOLUTION USED IN A PROCESS FOR EXTRACTING SULFUR COMPOUNDS COMPRISING A WASHING STEP |
| FR3063496B1 (en) * | 2017-03-01 | 2019-04-05 | Axens | IMPROVED METHOD FOR REGENERATING AN ALKALINE SOLUTION USED IN A PROCESS FOR EXTRACTING SULFUR COMPOUNDS WITH NO WASHING STEP |
| KR20250073388A (en) * | 2022-11-14 | 2025-05-27 | 미츠이 케미칼즈 아사히 라이프 마테리알즈 가부시키가이샤 | Water/organic solvent separation device and water/organic solvent separation method |
Family Cites Families (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1943744A (en) * | 1928-10-03 | 1934-01-16 | Rosenstein Ludwig | Process of removing mercaptans from hydrocarbons |
| US2228028A (en) * | 1939-06-19 | 1941-01-07 | Shell Dev | Process for the removal of mercaptans from hydrocarbon distillates |
| US2337467A (en) * | 1942-12-11 | 1943-12-21 | Standard Oil Dev Co | Refining mineral oils |
| US2431770A (en) * | 1943-12-31 | 1947-12-02 | Standard Oil Co | Sweetening process |
| US2727850A (en) * | 1953-04-20 | 1955-12-20 | Standard Oil Co | Sweetening process |
| US3471027A (en) * | 1968-05-03 | 1969-10-07 | Dorr Oliver Inc | Trunnion valve for continuous rotary filter |
| US3574093A (en) * | 1969-01-22 | 1971-04-06 | Universal Oil Prod Co | Combination process for treatment of hydrocarbon streams containing mercapto compounds |
| US3708421A (en) * | 1971-09-20 | 1973-01-02 | C Rippie | Process to remove mercaptan sulfur from sour oils |
| JPS5946554B2 (en) * | 1977-01-28 | 1984-11-13 | 日本石油化学株式会社 | How to remove hydrogen sulfide |
| US4861459A (en) * | 1987-01-16 | 1989-08-29 | Uop Inc. | Low pressure mixing process for atomizing fluids |
| IN168808B (en) * | 1987-05-08 | 1991-06-08 | Pennwait Corp | |
| US6824750B2 (en) * | 2000-02-16 | 2004-11-30 | Shell Oil Company | Vertical extending liquid/liquid contacting column |
| RU2173330C1 (en) * | 2000-04-24 | 2001-09-10 | Ахмадуллина Альфия Гариповна | Method of decaptanization of hydrocarbon stock |
| CN1147341C (en) * | 2001-02-27 | 2004-04-28 | 袁惠新 | Separator for mixture of non soluble liquids |
| US6623627B1 (en) * | 2001-07-09 | 2003-09-23 | Uop Llc | Production of low sulfur gasoline |
| US6749741B1 (en) * | 2001-12-20 | 2004-06-15 | Uop Llc | Apparatus and process for prewashing a hydrocarbon stream containing hydrogen sulfide |
| US7326333B2 (en) * | 2001-12-20 | 2008-02-05 | Uop Llc | Apparatus and process for extracting sulfur compounds from a hydrocarbon stream |
| US6735913B2 (en) * | 2002-08-01 | 2004-05-18 | Sanders & Associates Geostructural Engineering, Inc. | Block wall system |
-
2004
- 2004-06-02 AU AU2004320621A patent/AU2004320621B2/en not_active Ceased
- 2004-06-02 RU RU2006146978/04A patent/RU2352610C2/en not_active IP Right Cessation
- 2004-06-02 CA CA2567701A patent/CA2567701C/en not_active Expired - Fee Related
- 2004-06-02 BR BRPI0418874-8B1A patent/BRPI0418874B1/en not_active IP Right Cessation
- 2004-06-02 WO PCT/US2004/017110 patent/WO2005121279A1/en not_active Ceased
- 2004-06-02 KR KR1020107015219A patent/KR101013472B1/en not_active Expired - Lifetime
- 2004-06-02 CN CN200480043223.0A patent/CN1961060B/en not_active Expired - Fee Related
- 2004-06-02 JP JP2007515017A patent/JP4800303B2/en not_active Expired - Fee Related
- 2004-06-06 ES ES200650083A patent/ES2345375B2/en not_active Expired - Lifetime
-
2010
- 2010-07-29 AU AU2010206024A patent/AU2010206024B2/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| CN1961060B (en) | 2010-09-01 |
| CN1961060A (en) | 2007-05-09 |
| AU2010206024B2 (en) | 2012-08-16 |
| CA2567701C (en) | 2015-03-24 |
| WO2005121279A1 (en) | 2005-12-22 |
| KR20100087049A (en) | 2010-08-02 |
| ES2345375B2 (en) | 2012-05-25 |
| AU2004320621B2 (en) | 2010-08-26 |
| KR101013472B1 (en) | 2011-02-14 |
| BRPI0418874B1 (en) | 2013-09-10 |
| AU2010206024A1 (en) | 2010-08-19 |
| AU2004320621A1 (en) | 2005-12-22 |
| ES2345375A1 (en) | 2010-09-21 |
| CA2567701A1 (en) | 2005-12-22 |
| RU2006146978A (en) | 2008-07-20 |
| JP4800303B2 (en) | 2011-10-26 |
| RU2352610C2 (en) | 2009-04-20 |
| JP2008523163A (en) | 2008-07-03 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B08F | Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette] |
Free format text: REFERENTE A 3A ANUIDADES |
|
| B08G | Application fees: restoration [chapter 8.7 patent gazette] | ||
| B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
| B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] |
Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 02/06/2004, OBSERVADAS AS CONDICOES LEGAIS. |
|
| B21F | Lapse acc. art. 78, item iv - on non-payment of the annual fees in time | ||
| B24J | Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12) |
Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2412 DE 28-03-2017 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013. |