BRPI0409005A - processo para a hidrogenação catalìtica de metilolalcanais - Google Patents
processo para a hidrogenação catalìtica de metilolalcanaisInfo
- Publication number
- BRPI0409005A BRPI0409005A BRPI0409005-5A BRPI0409005A BRPI0409005A BR PI0409005 A BRPI0409005 A BR PI0409005A BR PI0409005 A BRPI0409005 A BR PI0409005A BR PI0409005 A BRPI0409005 A BR PI0409005A
- Authority
- BR
- Brazil
- Prior art keywords
- sup
- group
- methylolalcanals
- carbon atoms
- catalytically hydrogenating
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 3
- 125000004432 carbon atom Chemical group C* 0.000 abstract 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical class OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- 238000005984 hydrogenation reaction Methods 0.000 abstract 2
- 125000003710 aryl alkyl group Chemical group 0.000 abstract 1
- 125000003118 aryl group Chemical group 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000009903 catalytic hydrogenation reaction Methods 0.000 abstract 1
- 239000007791 liquid phase Substances 0.000 abstract 1
- -1 methylol group Chemical group 0.000 abstract 1
- 150000003512 tertiary amines Chemical class 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
- C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
- C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
- C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
- C07C29/141—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group with hydrogen or hydrogen-containing gases
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
- C07C31/18—Polyhydroxylic acyclic alcohols
- C07C31/20—Dihydroxylic alcohols
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
Abstract
"PROCESSO PARA A HIDROGENAçãO CATALìTICA DE METILOLALCANAIS". A invenção refere-se a um processo para a hidrogenação catalítica de metilolalcanais da fórmula (I) em que R¬ 1¬ e R¬ 2¬ são, cada um, independentemente, um outro grupo metilol ou um grupo alquila tendo de 1 a 22 átomos de carbono, ou um grupo alquila tendo de 1 a 22 átomos de carbono, ou um grupo arila ou aralquila tendo de 6 a 33 átomos de carbono, na fase líquida sobre um catalisador de hidrogenação. O processo da invenção e caracterizado pelo fato de que um valor de pH variando entre 6,3 a 7,8 é ajustado na alimentação de hidrogenação por adição de pelo menos uma amina terciária.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10317543A DE10317543A1 (de) | 2003-04-16 | 2003-04-16 | Verfahren zur Hydrierung von Methylolalkanalen |
| PCT/EP2004/003951 WO2004092097A1 (de) | 2003-04-16 | 2004-04-14 | Verfahren zur hydrierung von methylolalkanalen |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BRPI0409005A true BRPI0409005A (pt) | 2006-03-28 |
Family
ID=33103458
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0409005-5A BRPI0409005A (pt) | 2003-04-16 | 2004-04-14 | processo para a hidrogenação catalìtica de metilolalcanais |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US7439406B2 (pt) |
| EP (1) | EP1620377B2 (pt) |
| JP (1) | JP4800925B2 (pt) |
| KR (1) | KR101013318B1 (pt) |
| CN (1) | CN100334051C (pt) |
| AT (1) | ATE399749T1 (pt) |
| BR (1) | BRPI0409005A (pt) |
| DE (2) | DE10317543A1 (pt) |
| ES (1) | ES2307007T5 (pt) |
| MX (1) | MXPA05010270A (pt) |
| MY (1) | MY140112A (pt) |
| WO (1) | WO2004092097A1 (pt) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102006009838A1 (de) * | 2006-03-01 | 2007-09-06 | Basf Ag | Verfahren zur Hydrierung von Methylolalkanalen |
| DE102006009839A1 (de) * | 2006-03-01 | 2007-09-06 | Basf Ag | Verfahren zur Hydrierung von Methylolalkanalen zu mehrwertigen Alkoholen mit geringem Acetalgehalt |
| US7388116B2 (en) * | 2006-06-06 | 2008-06-17 | Basf Aktiengesellschaft | Hydrogenation of methylolalkanals |
| TW200842132A (en) * | 2007-04-20 | 2008-11-01 | Chi Mei Corp | Apparatus for hydrogenation and method for hydrogenating conjugated diene polymer by employing the apparatus |
| JP2011524451A (ja) | 2008-06-16 | 2011-09-01 | ビーエーエスエフ ソシエタス・ヨーロピア | ポリマー製造のための、c11ジオール、又はc11ジオール混合物の使用 |
| DE102008031338B4 (de) * | 2008-07-02 | 2012-09-13 | Oxea Gmbh | Verfahren zur Herstellung von Neopentylglykol |
| US8853465B2 (en) | 2010-05-12 | 2014-10-07 | Basf Se | Process for preparing neopentyl glycol |
| RU2012153379A (ru) | 2010-05-12 | 2014-06-20 | Басф Се | Способ получения неопентилгликоля |
| CN103449970B (zh) * | 2012-05-28 | 2015-10-14 | 北京三聚环保新材料股份有限公司 | 一种新戊二醇的制备方法 |
| US8710278B1 (en) | 2013-01-31 | 2014-04-29 | Eastman Chemical Company | Process for producing polyols |
| US9056824B2 (en) | 2013-01-31 | 2015-06-16 | Eastman Chemical Company | Preparation of hydroxy aldehydes |
| KR101529828B1 (ko) * | 2013-07-26 | 2015-06-17 | 주식회사 엘지화학 | 메틸올알칸알의 제조방법 |
| TW201536734A (zh) | 2014-03-12 | 2015-10-01 | Basf Se | 甲酸鹽的分解 |
| CN105727958A (zh) * | 2014-12-11 | 2016-07-06 | 中国石油化工股份有限公司 | 羟基新戊醛加氢制新戊二醇的催化剂及其制备方法 |
| KR102359896B1 (ko) * | 2017-10-12 | 2022-02-07 | 주식회사 엘지화학 | 디메틸올부탄알의 제조방법 및 이를 이용한 트리메틸올프로판의 제조방법 |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE754868A (fr) | 1969-08-16 | 1971-02-15 | Basf Ag | Procede pour la mise en oeuvre de reactions exothermiques entreun gaz et un liquide |
| BE758910A (fr) | 1969-11-15 | 1971-05-13 | Basf Ag | Preparation de dimethyl-2, 2-propanediol-1, 3 |
| DE2040501C3 (de) | 1970-08-14 | 1984-01-05 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Durchführung von exothermen Reaktionen zwischen einem Gas und einer Flüssigkeit |
| DE2507461C3 (de) | 1975-02-21 | 1986-05-07 | Basf Ag, 6700 Ludwigshafen | Verfahren zur Herstellung von 2,2- Dimethylolalkanalen |
| DE3027890A1 (de) | 1980-07-23 | 1982-03-04 | Basf Ag, 6700 Ludwigshafen | Hydrierkatalysatoren fuer die herstellung von propandiolen und verfahren zur herstellung von propandiolen mit solchen katalysatoren |
| US4851592A (en) * | 1987-10-27 | 1989-07-25 | Eastman Kodak Company | Triethylamine catalyzed neopentyl glycol production utilizing a gas sparged reactor |
| US5146012A (en) * | 1991-04-26 | 1992-09-08 | Aristech Chemical Corporation | Manufacture of neopentyl glycol (III) |
| US5532417A (en) * | 1991-04-26 | 1996-07-02 | Aristech Chemical Corporation | Manufacture of neopentyl glycol (IV) |
| JPH05117187A (ja) * | 1991-04-26 | 1993-05-14 | Aristech Chem Corp | ネオペンチルグリコールの製造方法 |
| US5185478A (en) * | 1991-06-17 | 1993-02-09 | Aristech Chemical Corporation | Manufacture of neopentyl glycol (IIA) |
| DE69213169T2 (de) | 1991-06-17 | 1997-01-23 | Aristech Chemical Corp., Pittsburgh, Pa. | Herstellung von neopentylglycol (iia) |
| DE69218309T3 (de) * | 1991-06-28 | 2000-07-13 | Aristech Chemical Corp., Pittsburgh | Herstellung von Neopentylglykol (IV) |
| JP3557237B2 (ja) * | 1994-02-03 | 2004-08-25 | 住友化学工業株式会社 | ヒドロキシピバルアルデヒドの製造方法 |
| WO1995032171A1 (de) | 1994-05-19 | 1995-11-30 | Basf Aktiengesellschaft | Verfahren zur herstellung von alkoholen |
| DE19542036A1 (de) | 1995-11-10 | 1997-05-15 | Basf Ag | Verfahren zur Herstellung von Polyalkoholen |
| DE19653093A1 (de) | 1996-12-20 | 1998-06-25 | Basf Ag | Verfahren zur Herstellung von Polyalkoholen |
| FI102474B1 (fi) | 1996-12-30 | 1998-12-15 | Neste Oy | Menetelmä moniarvoisten alkoholien valmistamiseksi |
| JP2000026356A (ja) * | 1998-07-10 | 2000-01-25 | Mitsubishi Gas Chem Co Inc | ヒドロキシピバルアルデヒドの製造方法 |
| DE10001257A1 (de) | 2000-01-14 | 2001-07-19 | Bayer Ag | Verfahren zur Herstellung von Trimethylolalkanen |
-
2003
- 2003-04-16 DE DE10317543A patent/DE10317543A1/de not_active Withdrawn
-
2004
- 2004-04-12 MY MYPI20041329A patent/MY140112A/en unknown
- 2004-04-14 KR KR1020057019502A patent/KR101013318B1/ko not_active Expired - Fee Related
- 2004-04-14 EP EP04727249.7A patent/EP1620377B2/de not_active Expired - Lifetime
- 2004-04-14 AT AT04727249T patent/ATE399749T1/de not_active IP Right Cessation
- 2004-04-14 US US10/553,195 patent/US7439406B2/en not_active Expired - Fee Related
- 2004-04-14 BR BRPI0409005-5A patent/BRPI0409005A/pt not_active Application Discontinuation
- 2004-04-14 MX MXPA05010270A patent/MXPA05010270A/es active IP Right Grant
- 2004-04-14 JP JP2006505124A patent/JP4800925B2/ja not_active Expired - Fee Related
- 2004-04-14 CN CNB2004800098837A patent/CN100334051C/zh not_active Expired - Lifetime
- 2004-04-14 DE DE502004007493T patent/DE502004007493D1/de not_active Expired - Lifetime
- 2004-04-14 WO PCT/EP2004/003951 patent/WO2004092097A1/de not_active Ceased
- 2004-04-14 ES ES04727249.7T patent/ES2307007T5/es not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| CN100334051C (zh) | 2007-08-29 |
| MY140112A (en) | 2009-11-30 |
| ES2307007T5 (es) | 2017-07-31 |
| JP2006523644A (ja) | 2006-10-19 |
| EP1620377A1 (de) | 2006-02-01 |
| JP4800925B2 (ja) | 2011-10-26 |
| US20060205985A1 (en) | 2006-09-14 |
| CN1774410A (zh) | 2006-05-17 |
| KR101013318B1 (ko) | 2011-02-09 |
| ES2307007T3 (es) | 2008-11-16 |
| US7439406B2 (en) | 2008-10-21 |
| MXPA05010270A (es) | 2005-11-17 |
| WO2004092097A1 (de) | 2004-10-28 |
| EP1620377B2 (de) | 2017-03-08 |
| KR20050114274A (ko) | 2005-12-05 |
| DE10317543A1 (de) | 2004-11-04 |
| ATE399749T1 (de) | 2008-07-15 |
| DE502004007493D1 (de) | 2008-08-14 |
| EP1620377B1 (de) | 2008-07-02 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B07A | Application suspended after technical examination (opinion) [chapter 7.1 patent gazette] | ||
| B09B | Patent application refused [chapter 9.2 patent gazette] |
Free format text: INDEFIRO O PEDIDO DE ACORDO COM O(S) ARTIGO(S) 8O E 11 DA LPI |
|
| B09B | Patent application refused [chapter 9.2 patent gazette] |
Free format text: MANTIDO O INDEFERIMENTO UMA VEZ QUE NAO FOI APRESENTADO RECURSO DENTRO DO PRAZO LEGAL. |