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BR9917328A - Catalisador para homo e co-polimerização de etileno - Google Patents

Catalisador para homo e co-polimerização de etileno

Info

Publication number
BR9917328A
BR9917328A BR9917328-0A BR9917328A BR9917328A BR 9917328 A BR9917328 A BR 9917328A BR 9917328 A BR9917328 A BR 9917328A BR 9917328 A BR9917328 A BR 9917328A
Authority
BR
Brazil
Prior art keywords
catalyst
homo
polymerization
ethylene
compound
Prior art date
Application number
BR9917328-0A
Other languages
English (en)
Other versions
BR9917328B1 (pt
Inventor
Chung Byung Yang
Original Assignee
Samsung General Chemicals Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Samsung General Chemicals Co filed Critical Samsung General Chemicals Co
Publication of BR9917328A publication Critical patent/BR9917328A/pt
Publication of BR9917328B1 publication Critical patent/BR9917328B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Patente de Invenção: "CATALISADOR PARA HOMO E CO-POLIMERIZAçãO DE ETILENO". A presente invenção refere-se à um catalisador para homo-polimerização ou co-polimerização de etileno, ou mais particularmente à um catalisador de titânio complexo sólido para homo-polimerização ou co-polimerização de etileno, sendo o referido catalisador produzido preparando-se uma solução de magnésio reagindo-se por contato um composto halogenado de magnésio com álcool; reagindo-se a referida solução com um composto de éster tendo pelo menos um grupo hidróxi e um composto de silício tendo um grupo alcóxi e a seguir reagindo-se a referida solução com uma mistura de um composto de titânio e um composto de silício. O catalisador da presente invenção tem alta atividade com superior sensibilidade ao hidrogênio.
BRPI9917328-0A 1999-05-27 1999-10-23 catalisador para homo e co-polimerização de etileno. BR9917328B1 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
KR10-1999-0019192A KR100524293B1 (ko) 1999-05-27 1999-05-27 에틸렌 중합 및 공중합용 촉매
PCT/KR1999/000639 WO2000073356A1 (en) 1999-05-27 1999-10-23 A catalyst for ethylene homo- and co-polymerization

Publications (2)

Publication Number Publication Date
BR9917328A true BR9917328A (pt) 2002-02-26
BR9917328B1 BR9917328B1 (pt) 2009-08-11

Family

ID=19588064

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI9917328-0A BR9917328B1 (pt) 1999-05-27 1999-10-23 catalisador para homo e co-polimerização de etileno.

Country Status (10)

Country Link
US (1) US6855663B1 (pt)
EP (1) EP1194455B1 (pt)
JP (1) JP3533202B2 (pt)
KR (1) KR100524293B1 (pt)
CN (1) CN1160376C (pt)
AT (1) ATE274529T1 (pt)
BR (1) BR9917328B1 (pt)
CA (1) CA2374419A1 (pt)
DE (1) DE69919753T2 (pt)
WO (1) WO2000073356A1 (pt)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100546499B1 (ko) * 1999-05-27 2006-01-26 삼성토탈 주식회사 에틸렌 중합 및 공중합용 촉매
KR100353960B1 (ko) * 2000-05-31 2002-09-27 삼성종합화학주식회사 에틸렌 중합체 및 공중합체의 제조방법
KR100387734B1 (ko) 2000-06-17 2003-06-18 삼성종합화학주식회사 올레핀 중합용 촉매 및 중합방법
KR100389477B1 (ko) * 2000-11-09 2003-06-27 삼성종합화학주식회사 에틸렌 중합체 및 공중합체 제조방법
KR100424011B1 (ko) * 2000-12-18 2004-03-24 삼성아토피나주식회사 에틸렌 중합체 및 공중합체 제조방법
KR100413031B1 (ko) * 2000-12-21 2003-12-31 주식회사 신안에스엔피 Ｌｃｄ 유리 연마장치 및 그를 이용한 ｌｃｄ 유리 연마방법
KR100496776B1 (ko) * 2001-06-21 2005-06-22 삼성토탈 주식회사 에틸렌 중합 및 공중합용 촉매
KR100530794B1 (ko) * 2001-06-21 2005-11-23 삼성토탈 주식회사 에틸렌 중합 및 공중합용 촉매
KR100743912B1 (ko) * 2001-07-10 2007-07-30 삼성토탈 주식회사 에틸렌 중합 및 공중합용 촉매
KR100530795B1 (ko) 2001-12-26 2005-11-23 삼성토탈 주식회사 에틸렌 중합 및 공중합 방법
CN1169845C (zh) * 2002-02-07 2004-10-06 中国石油化工股份有限公司 用于烯烃聚合的固体催化剂组分和含该催化剂组分的催化剂及其应用
TWI253451B (en) * 2002-08-29 2006-04-21 Toho Catalyst Co Ltd Solid catalyst component, catalyst for polymerization of olefins, and polymerizing method of olefins
KR100496777B1 (ko) * 2003-01-23 2005-06-22 삼성토탈 주식회사 에틸렌 중합 및 공중합 방법
KR100715266B1 (ko) * 2006-01-12 2007-05-04 삼성토탈 주식회사 에틸렌 중합 및 공중합 방법
KR100715265B1 (ko) * 2006-01-12 2007-05-04 삼성토탈 주식회사 에틸렌 중합 및 공중합 방법
CN104558292B (zh) * 2013-10-28 2017-05-31 中国石油化工股份有限公司 一种用于烯烃聚合催化剂制备方法
CN108440692B (zh) * 2018-04-20 2019-08-27 天津科技大学 催化乙烯聚合Ziegler-Natta催化剂内给电子体、催化剂组分及制备方法
CN116041577B (zh) 2021-10-28 2024-12-06 中国石油化工股份有限公司 烯烃聚合催化剂组分、催化剂体系及应用和烯烃聚合方法

Family Cites Families (150)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3332927A (en) 1966-02-14 1967-07-25 Cabot Corp Process for polymerization
US3632620A (en) 1968-06-26 1972-01-04 Olin Mathieson Preparation of isocyanates from carbodiimides
CA920299A (en) 1968-08-01 1973-01-30 Mitsui Petrochemical Industries Process for the polymerization and/or copolymerization of olefins with use of ziegler-type catalytsts supported on carrier
US3642772A (en) 1968-09-04 1972-02-15 Boehringer Mannheim Gmbh Process for preparing s-adenosyl homocysteine
NL163522B (nl) 1970-07-20 1980-04-15 Montedison Spa Werkwijze om een katalysator te bereiden voor de polymerisatie van alkenen-1.
NL7114641A (pt) 1970-10-29 1972-05-03
US4226963A (en) 1971-06-25 1980-10-07 Montedison S.P.A. Process for the stereoregular polymerization of alpha-olephins
NL160286C (pt) 1971-06-25
US4107414A (en) 1971-06-25 1978-08-15 Montecatini Edison S.P.A. Process for the stereoregular polymerization of alpha olefins
US4156063A (en) 1971-06-25 1979-05-22 Montecanti Edison, S.p.A. Process for the stereoregular polymerization of alpha olefins
US4187196A (en) 1971-06-25 1980-02-05 Montedison S.P.A. Process for the stereoregular polymerization of alpha-olefins
US4107413A (en) 1971-06-25 1978-08-15 Montedison S.P.A. Process for the stereoregular polymerization of alpha olefins
BE785673A (fr) 1971-06-30 1973-01-02 Naphtachimie Sa Catalyseurs de polymerisation des olefines prepares a partir decomposesorganomagnesiens
US4013823A (en) 1972-06-09 1977-03-22 The B. F. Goodrich Company Process for preparing elastomeric copolymers of ethylene and higher alpha-olefins
US3953414A (en) 1972-09-13 1976-04-27 Montecatini Edison S.P.A., Catalysts for the polymerization of olefins to spherically shaped polymers
US4071674A (en) 1972-09-14 1978-01-31 Mitsui Petrochemical Industries Ltd. Process for polymerization or copolymerization of olefin and catalyst compositions used therefor
US4107415A (en) 1972-09-26 1978-08-15 Montecatini Edison S.P.A. Process for the stereospecific polymerization of alpha-olefins
US4071672A (en) 1972-11-10 1978-01-31 Mitsui Petrochemical Industries Ltd. Process for polymerizing or copolymerizing olefins
US3899477A (en) 1973-02-16 1975-08-12 Monsanto Co Polymerization of ethylene
GB1492618A (en) 1974-02-01 1977-11-23 Mitsui Petrochemical Ind Process for preparing highly stereoregular polyolefins and catalyst used therefor
US4157435A (en) 1974-08-10 1979-06-05 Mitsui Petrochemical Industries, Ltd. Process for preparing highly stereoregular polyolefins and catalyst used therefor
US4076924A (en) 1974-09-03 1978-02-28 Mitsui Petrochemical Industries Ltd. Process for polymerization or copolymerizing olefins containing at least 3 carbon atoms
US4614727A (en) 1975-01-23 1986-09-30 Montecatini Edison S.P.A. Polymerization catalyst
JPS565404B2 (pt) 1975-02-14 1981-02-04
JPS5328269Y2 (pt) 1975-03-20 1978-07-17
IT1042667B (it) 1975-09-18 1980-01-30 Montedison Spa Catalizzatori per la polimerizzazione di olefine a polimeri in forma seroidale
US4069169A (en) 1975-11-24 1978-01-17 Mitsui Petrochemical Industries Ltd. Process for preparation of catalyst component supported on high performance carrier
DE2605992B2 (de) 1976-02-14 1980-02-28 Flamuco Gmbh Vereinigte Farben- Und Lackfabriken, 8000 Muenchen Schnelltrocknende, lösemittelhaltige Anstrichstoffe mit erhöhtem Flammpunkt
JPS5517360Y2 (pt) 1976-02-19 1980-04-22
IT1062072B (it) 1976-06-03 1983-06-25 Montedison Spa Catalizzatori per la polimerizzazione di etilene
US4158642A (en) 1977-04-25 1979-06-19 Exxon Research & Engineering Co. Trialkyl aluminum cocatalyst
JPS53131826A (en) 1977-04-22 1978-11-17 Canon Inc Photographing system for photograph data of camera
US4148756A (en) 1977-04-25 1979-04-10 Exxon Research & Engineering Co. Novel trialkyl aluminum cocatalyst
GB1603724A (en) 1977-05-25 1981-11-25 Montedison Spa Components and catalysts for the polymerisation of alpha-olefins
IT1114822B (it) 1977-07-04 1986-01-27 Montedison Spa Componenti di catalizzatori per la polimerizzazione delle alfa-olefine
IT1113129B (it) 1978-04-12 1986-01-20 Montedison Spa Catalizzatori e componenti di catalizzatori per la polimerizzazione delle olefine
JPS5919566B2 (ja) * 1978-07-28 1984-05-07 東亜燃料工業株式会社 α−オレフイン重合用触媒成分の製造方法
IT1098272B (it) 1978-08-22 1985-09-07 Montedison Spa Componenti,di catalizzatori e catalizzatori per la polimerizzazione delle alfa-olefine
FR2436794A1 (fr) 1978-09-22 1980-04-18 Naphtachimie Sa Procede de polymerisation de l'ethylene et produits en resultant
JPS6037804B2 (ja) 1979-04-11 1985-08-28 三井化学株式会社 オレフイン重合触媒用担体の製法
JPS56811A (en) 1979-06-18 1981-01-07 Mitsui Petrochem Ind Ltd Preparation of olefin polymer or copolymer
US4482687A (en) 1979-10-26 1984-11-13 Union Carbide Corporation Preparation of low-density ethylene copolymers in fluid bed reactor
US4277372A (en) 1980-01-09 1981-07-07 Hercules Incorporated Solid catalyst component for olefin polymerization
JPS6023764B2 (ja) 1980-02-27 1985-06-10 チッソ株式会社 α−オレフイン重合体を製造する方法
US4384983A (en) 1981-05-26 1983-05-24 Standard Oil Company (Indiana) Catalyst and process for production of polyolefins of improved morphology
JPS5842639A (ja) 1981-09-07 1983-03-12 Toa Nenryo Kogyo Kk ポリオレフイン組成物
JPS5883006A (ja) 1981-11-13 1983-05-18 Mitsui Petrochem Ind Ltd オレフインの重合方法
JPS5883006U (ja) 1981-12-02 1983-06-04 株式会社日立製作所 温水暖房システム
FR2529207A1 (fr) 1982-06-24 1983-12-30 Bp Chimie Sa Procede pour la preparation de supports de catalyseurs pour la polymerisation des alpha-olefines et supports obtenus
FR2532649B1 (fr) 1982-09-07 1986-08-29 Bp Chimie Sa Copolymerisation d'ethylene et d'hexene-1 en lit fluidise
IT1195953B (it) 1982-09-10 1988-11-03 Montedison Spa Componenti e catalizzatori per la polimerizzazione di olefine
US4518706A (en) 1982-09-30 1985-05-21 E. I. Du Pont De Nemours And Company Hydrocarbon soluble catalyst supports and resultant polymerization catalysts
US4434282A (en) 1982-10-04 1984-02-28 The Dow Chemical Company Process for polymerizing olefins
JPS59117508A (ja) * 1982-12-24 1984-07-06 Mitsui Petrochem Ind Ltd エチレンの重合法
JPS59145206U (ja) 1983-03-14 1984-09-28 日新電機株式会社 閉鎖配電盤
US4477639A (en) 1983-05-27 1984-10-16 Shell Oil Company Olefin polymerization catalyst component and composition and method of preparation
JPS601241A (ja) 1983-06-17 1985-01-07 Kyowa Chem Ind Co Ltd 難燃性樹脂組成物
JPS60501762A (ja) 1983-07-01 1985-10-17 ユニオン　カ−バイド　コ−ポレ−シヨン 気相プロセスに適応されたオレフイン重合触媒
JPS60110738A (ja) 1983-11-22 1985-06-17 Asahi Glass Co Ltd 難燃性ポリオレフイン組成物
FR2560200B1 (fr) 1984-02-23 1986-06-27 Bp Chimie Sa Procede de preparation de catalyseurs supportes a base de composes de vanadium pour la polymerisation et la copolymerisation de l'ethylene
US4988656A (en) 1984-03-23 1991-01-29 Amoco Corporation Olefin polymerization catalyst
US5013702A (en) 1984-03-23 1991-05-07 Amoco Corporation Olefin polymerization catalyst
US4866022A (en) 1984-03-23 1989-09-12 Amoco Corporation Olefin polymerization catalyst
JPS60228504A (ja) 1984-04-26 1985-11-13 Sumitomo Chem Co Ltd オレフイン重合体の製造法
JPS61268704A (ja) 1985-05-23 1986-11-28 Mitsubishi Petrochem Co Ltd オレフイン重合用触媒
GB2176443B (en) 1985-06-10 1990-11-14 Canon Kk Liquid jet recording head and recording system incorporating the same
JPH07658B2 (ja) 1985-10-04 1995-01-11 宇部興産株式会社 α−オレフイン重合用触媒の調製法
JPH06104693B2 (ja) 1986-01-06 1994-12-21 東邦チタニウム株式会社 オレフイン類重合用触媒
DE3777339D1 (de) 1986-05-06 1992-04-16 Toho Titanium Co Ltd Katalysator zur polymerisation von olefinen.
JPS62267305A (ja) 1986-05-15 1987-11-20 Sumitomo Chem Co Ltd オレフイン重合体の製造法
JPS63308003A (ja) 1986-10-06 1988-12-15 Toho Titanium Co Ltd オレフイン類重合用触媒
JPH0832737B2 (ja) 1986-10-08 1996-03-29 東邦チタニウム株式会社 オレフイン類重合用固体触媒成分
DE3645090C2 (pt) 1986-10-23 1991-05-23 Behringwerke Ag, 3550 Marburg, De
US4777639A (en) 1986-12-15 1988-10-11 Prc Corporation Laser optical element mounting arrangement and method
IT1203330B (it) 1987-02-06 1989-02-15 Enichem Base Spa Componente di catalizzatore e catalizzatore per la polimerizzazione dell'etilene o la co-polimerizzazione dell-etilene con alfa-olefine
JPS63191811U (pt) 1987-05-26 1988-12-09
JPS63199703U (pt) 1987-06-15 1988-12-22
JP2502624B2 (ja) 1987-09-22 1996-05-29 東燃株式会社 オレフイン重合用触媒成分
JPH0717709B2 (ja) 1987-11-13 1995-03-01 日本石油株式会社 超高分子量ポリエチレンの製造方法
FR2623812B1 (fr) 1987-11-30 1992-02-21 Bp Chimie Sa Catalyseur de polymerisation d'olefines de type ziegler natta et procede de preparation a partir de dialcoxyde de magnesium
DE3888145T2 (de) 1987-12-26 1994-06-01 Toho Titanium Co Ltd Katalysator-Feststoff für Olefinpolymerisation und Olefinpolymerisationskatalysator.
US4912074A (en) 1988-01-15 1990-03-27 Mobil Oil Corporation Catalyst composition for preparing high density or medium density olefin polymers
EP0350170B2 (en) 1988-06-17 2001-09-12 Mitsui Chemicals, Inc. Process for polymerising olefins and polymerisation catalyst therefor
KR920002488B1 (ko) * 1988-06-17 1992-03-26 미쓰이 세끼유 가가꾸 고오교오 가부시끼가이샤 올레핀의 중합방법 및 중합용 촉매
US5134104A (en) 1988-06-28 1992-07-28 Sumitomo Chemical Company, Limited Liquid catalyst component, catalyst system containing said component and process for producing ethylene-α-olefin copolymer using said catalyst system
US5064798A (en) 1988-08-19 1991-11-12 Exxon Chemical Patents Inc. Catalyst for olefin polymerization
IT1227259B (it) 1988-09-30 1991-03-28 Himont Inc Catalizzatori per la polimerizzazione di olefine.
ATE122060T1 (de) 1989-03-02 1995-05-15 Mitsui Petrochemical Ind Verfahren zur polymerisation von olefinen und katalysator für olefinpolymerisation.
CA2013657C (en) 1989-04-04 1996-12-03 Shinichi Akitaya Flame retardant polypropylene resin composition
JP2893743B2 (ja) 1989-08-10 1999-05-24 三菱化学株式会社 α―オレフイン重合体の製造
FR2651001B1 (fr) 1989-08-17 1993-03-12 Bp Chemicals Sa Procede de preparation d'un catalyseur de type ziegler-natta a base de vanadium et de titane
US4946816A (en) 1989-08-21 1990-08-07 Amoco Corporation Morphology-controlled olefin polymerization catalyst
FR2656314B1 (fr) 1989-12-22 1992-04-17 Bp Chemicals Snc Catalyseur a base de zirconium supporte sur du chlorure de magnesium, procede de preparation et utilisation du catalyseur dans la polymerisation des olefines.
IT1241062B (it) 1990-01-10 1993-12-29 Himont Inc Componenti e catalizzatori per la polimerizzazione di olefine
US5021382A (en) 1990-02-28 1991-06-04 Exxon Chemical Patents Inc. Diene activated ziegler transition metal catalyst components for ethylene polymerization
JP3049569B2 (ja) 1990-03-23 2000-06-05 東ソー株式会社 ポリオレフィンの製造方法
US5726262A (en) 1990-04-13 1998-03-10 Mitsui Petrochemical Industries, Ltd. Solid titanium catalyst component for olefin polymerization, olefin polymerization catalyst, prepolymerized polyolefin-containing catalyst and method of olefin polymerization
DE69111354T2 (de) 1990-04-18 1995-12-21 Mitsui Petrochemical Industries, Ltd., Tokio/Tokyo Heissschmelzklebstoff.
JP2958923B2 (ja) 1990-04-27 1999-10-06 東邦チタニウム株式会社 オレフィン類重合用固体触媒成分及び触媒
US5081090A (en) 1990-07-23 1992-01-14 Amoco Corporation Dry olefin polymerization catalyst
US5124297A (en) 1990-12-07 1992-06-23 Amoco Corporation Olefin polymerization and copolymerization catalyst
US5218052A (en) 1991-02-04 1993-06-08 Amoco Corporation Olefin polymerization and copolymerization process
US5308816A (en) 1991-05-31 1994-05-03 Mitsui Petrochemical Industries, Ltd. Olefin polymerization solid catalyst, olefin polymerization catalyst and olefin polymerization
US5182245A (en) 1991-06-26 1993-01-26 Amoco Corporation Olefin polymerization and copolymerization catalyst
US5387567A (en) 1991-06-27 1995-02-07 Nippon Oil Co., Ltd. Catalyst components for polymerization of olefins
US5175332A (en) 1991-12-16 1992-12-29 Dow Corning Corporation Cycloalkoxysilanes
IT1262934B (it) 1992-01-31 1996-07-22 Montecatini Tecnologie Srl Componenti e catalizzatori per la polimerizzazione di olefine
US5968862A (en) 1992-06-10 1999-10-19 Chevron Chemical Company Transition metal-magnesium catalyst precursors for the polymerization of olefins
JP3280477B2 (ja) 1992-08-31 2002-05-13 三井化学株式会社 オレフィン重合用固体状チタン触媒成分の調製方法
US5587436A (en) 1992-11-12 1996-12-24 Quantum Chemical Corporation Process for controlling the polymerization of propylene and ethylene and copolymer products
TW300235B (pt) 1992-12-04 1997-03-11 Mitsui Petroleum Chemicals Ind
JPH06234777A (ja) 1992-12-14 1994-08-23 Dow Corning Corp ジシクロアルキル置換シランの製造方法
FI95387C (fi) 1992-12-29 1996-01-25 Borealis As Menetelmä -olefiinien polymeroimiseksi sekä esipolymeroitu katalyyttikompositio ja menetelmä tämän valmistamiseksi
EP0606125B1 (en) 1993-01-08 1997-05-21 Shell Internationale Researchmaatschappij B.V. Use of titanium and zirconium compounds as homogeneous catalyst and novel titanium and zirconium compounds
US5346872A (en) 1993-01-29 1994-09-13 Quantum Chemical Corporation Cocatalyst for vanadium/titanium containing polymerization catalyst
US5459116A (en) * 1993-05-07 1995-10-17 Samsung General Chemicals Co., Ltd. Highly active catalyst for the polymerization of olefins and method for the preparation of the same
JPH06340711A (ja) 1993-05-31 1994-12-13 Idemitsu Kosan Co Ltd オレフィン重合用触媒及び該触媒を用いたポリオレフィンの製造方法
US5419116A (en) 1993-07-02 1995-05-30 The United States Of America As Represented By The Secretary Of The Navy Miniscale ballistic motor testing method for rocket propellants
TW354792B (en) 1993-08-13 1999-03-21 Mitsui Petrochemical Ind Olefin polymerization catalyst and process for preparing polypropylene and propylene block copolymer
DE4332786A1 (de) 1993-09-27 1995-03-30 Hoechst Ag Verfahren zur Herstellung von ultrahochmolekularem Polyethylen mit hoher Schüttdichte
JPH07292029A (ja) * 1994-04-28 1995-11-07 Toho Titanium Co Ltd オレフィン類重合用触媒および重合方法
JP3472935B2 (ja) 1994-02-18 2003-12-02 三井化学株式会社 エチレン系重合体およびその製造方法、エチレン重合用固体状チタン触媒成分ならびにエチレン重合用触媒
US5869418A (en) 1994-05-31 1999-02-09 Borealis Holding A/S Stereospecific catalyst system for polymerization of olefins
RU2064836C1 (ru) 1994-06-20 1996-08-10 Институт катализа им. Г.К.Борескова СО РАН Способ получения нанесенного катализатора для полимеризации этилена и сополимеризации этилена с альфа-олефинами
TW369547B (en) 1994-09-21 1999-09-11 Mitsui Chemicals Inc Olefin polymerization catalyst and process for olefin polymerization
EP0717053B1 (en) 1994-11-25 2001-03-14 Japan Polyolefins Co., Ltd. Catalyst for olefin polymerization and process for producing polyolefin using the same
US5502128A (en) 1994-12-12 1996-03-26 University Of Massachusetts Group 4 metal amidinate catalysts and addition polymerization process using same
BR9607042A (pt) 1995-02-13 1997-12-30 Toho Titanium Co Ltd Componente de catalisador sólido para a polimerização de olefinas e catalisadro para a polimerização de olefinas
US6218331B1 (en) 1995-03-29 2001-04-17 Equistar Chemicals, L.P. Polymer-supported catalyst for olefin polymerization
RU2153932C2 (ru) * 1995-05-18 2000-08-10 Митсуи Кемикалс, Инк. Способ получения твердого титанового каталитического компонента, катализатор полимеризации олефина, содержащий его, и способ полимеризации олефина
US5817591A (en) 1995-06-07 1998-10-06 Fina Technology, Inc. Polyolefin catalyst from metal alkoxides or dialkyls, production and use
ATE173481T1 (de) 1995-10-02 1998-12-15 Pcd Polymere Ag Trägerkatalysator für die olefinpolymerisation
CN1108313C (zh) * 1995-10-11 2003-05-14 三井化学株式会社 烯烃聚合用的固体钛催化剂制备方法以及聚烯烃制备方法
JPH09165414A (ja) * 1995-10-11 1997-06-24 Mitsui Petrochem Ind Ltd 固体状チタン触媒成分とそのオレフィン重合触媒への利用
JP2759780B2 (ja) 1995-12-19 1998-05-28 三星綜合化学株式会社 エチレンの重合及びエチレンとα−オレフィンの共重合のための担持型触媒の製造方法
JPH09328513A (ja) * 1996-04-09 1997-12-22 Mitsui Petrochem Ind Ltd 固体状チタン触媒成分の調製方法、オレフィンの重合用触媒およびオレフィン重合方法
KR100223105B1 (ko) 1996-10-09 1999-10-15 유현식 올레핀 중합용 촉매와 이를 이용한 올레핀 중합방법
US5849655A (en) 1996-12-20 1998-12-15 Fina Technology, Inc. Polyolefin catalyst for polymerization of propylene and a method of making and using thereof
KR100334167B1 (ko) 1997-05-08 2002-11-22 삼성종합화학주식회사 알파-올레핀중합방법
GB2325004B (en) 1997-05-09 1999-09-01 Samsung General Chemicals Co A catalyst for polymerization and copolymerization of olefins
TW539690B (en) * 1997-08-11 2003-07-01 Mitsui Chemicals Inc Process for preparing solid titanium catalyst component, olefin polymerization catalyst, and olefin polymerization process
KR100240519B1 (ko) 1997-09-11 2000-01-15 유현식 새로운 올레핀 중합용 킬레이트 촉매 및 이를 이용한 올레핀중합 방법
KR100334164B1 (ko) 1998-04-17 2002-09-25 삼성종합화학주식회사 에틸렌 중합 및 에틸렌/α-올레핀 공중합용 TI/V 담지촉매의제조방법
JP3570264B2 (ja) 1998-12-28 2004-09-29 セルヴィシオス コンデュメクス ソシエダッド アノニマ デ・エ セ・ヴェ 自動車ケーブルの絶縁性保護のための耐火性、低発煙性、無ハロゲン性ポリオレフィン配合物
KR100705475B1 (ko) 1998-12-30 2007-12-20 삼성토탈 주식회사 올레핀 중합 및 공중합용 촉매
JP3689671B2 (ja) 1999-10-23 2005-08-31 サムソン ジェネラル ケミカルズ カンパニー リミテッド 改善されたオレフィン重合及び共重合用触媒
KR100361224B1 (ko) 1999-12-01 2002-11-29 삼성종합화학주식회사 에틸렌 중합 및 공중합용 촉매의 제조방법
KR100351386B1 (ko) 2000-04-24 2002-09-05 삼성종합화학주식회사 초고분자량 폴리에틸렌 제조용 촉매 및 이를 이용한초고분자량 폴리에틸렌 제조방법
KR100353960B1 (ko) 2000-05-31 2002-09-27 삼성종합화학주식회사 에틸렌 중합체 및 공중합체의 제조방법
KR100421553B1 (ko) 2000-12-27 2004-03-09 삼성아토피나주식회사 알파 올레핀 중합 방법

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ATE274529T1 (de) 2004-09-15
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DE69919753T2 (de) 2005-09-01
JP3533202B2 (ja) 2004-05-31
KR20000074913A (ko) 2000-12-15
CN1160376C (zh) 2004-08-04
US6855663B1 (en) 2005-02-15
DE69919753D1 (de) 2004-09-30
CA2374419A1 (en) 2000-12-07
EP1194455B1 (en) 2004-08-25
CN1373777A (zh) 2002-10-09
EP1194455A1 (en) 2002-04-10
BR9917328B1 (pt) 2009-08-11

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