BR9910779A - Método aperfeiçoado para fornecimento de catalisador, um alimentador de catalisador e o uso deles em um processo de polimerização - Google Patents
Método aperfeiçoado para fornecimento de catalisador, um alimentador de catalisador e o uso deles em um processo de polimerizaçãoInfo
- Publication number
- BR9910779A BR9910779A BR9910779-1A BR9910779A BR9910779A BR 9910779 A BR9910779 A BR 9910779A BR 9910779 A BR9910779 A BR 9910779A BR 9910779 A BR9910779 A BR 9910779A
- Authority
- BR
- Brazil
- Prior art keywords
- catalyst
- polymerization process
- feeder
- improved method
- polymerization
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 8
- 238000006116 polymerization reaction Methods 0.000 title abstract 5
- 238000000034 method Methods 0.000 title abstract 3
- 150000001336 alkenes Chemical class 0.000 abstract 1
- 239000002216 antistatic agent Substances 0.000 abstract 1
- 238000002716 delivery method Methods 0.000 abstract 1
- 239000003085 diluting agent Substances 0.000 abstract 1
- 239000003446 ligand Substances 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/26—Nozzle-type reactors, i.e. the distribution of the initial reactants within the reactor is effected by their introduction or injection through nozzles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/0005—Catalytic processes under superatmospheric pressure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/0015—Feeding of the particles in the reactor; Evacuation of the particles out of the reactor
- B01J8/003—Feeding of the particles in the reactor; Evacuation of the particles out of the reactor in a downward flow
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/0015—Feeding of the particles in the reactor; Evacuation of the particles out of the reactor
- B01J8/004—Feeding of the particles in the reactor; Evacuation of the particles out of the reactor by means of a nozzle
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
- B01J8/24—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles according to "fluidised-bed" technique
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00162—Controlling or regulating processes controlling the pressure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00164—Controlling or regulating processes controlling the flow
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
- B01J2219/00186—Controlling or regulating processes controlling the composition of the reactive mixture
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/901—Monomer polymerized in vapor state in presence of transition metal containing catalyst
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
- Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)
Abstract
Patente de Invenção: <B>"MéTODO APERFEIçOADO PARA FORNECIMENTO DE CATALISADOR, UM ALIMENTADOR DE CATALISADOR E O USO DELES EM UM PROCESSO DE POLIMERIZAçãO"<D>. A presente invenção refere-se a um método de fornecimento de catalisador aperfeiçoado para introduzir um sistema de catalisador do tipo de metaloceno de ligando volumoso suportado para um reator, para a polimerização de uma ou mais olefinas. Em particular, a invenção proporciona um método de introdução de um sistema de catalisador do tipo de metaloceno suportado em um reator de polimerização por e na presença de uma solução em veículo de um agente antiestático e de um diluente líquido. Também, a invenção é direcionada no sentido de um alimentador de catalisador para uso em um processo de polimerização.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/087,024 US6245868B1 (en) | 1998-05-29 | 1998-05-29 | Catalyst delivery method, a catalyst feeder and their use in a polymerization process |
| PCT/US1999/011747 WO1999061486A1 (en) | 1998-05-29 | 1999-05-27 | Catalyst delivery method and catalyst feeder |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BR9910779A true BR9910779A (pt) | 2001-02-13 |
| BR9910779B1 BR9910779B1 (pt) | 2010-06-01 |
Family
ID=22202582
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI9910779-1A BR9910779B1 (pt) | 1998-05-29 | 1999-05-27 | método para transferir um sistema de catalisador, processo para a polimerização de olefinas e monÈmeros em um reator, bem como composição de catalisador de polimerização e alimentador de catalisador. |
Country Status (10)
| Country | Link |
|---|---|
| US (3) | US6245868B1 (pt) |
| EP (1) | EP1082351B1 (pt) |
| JP (1) | JP2002516357A (pt) |
| AR (1) | AR018411A1 (pt) |
| AU (1) | AU743070B2 (pt) |
| BR (1) | BR9910779B1 (pt) |
| CA (1) | CA2328926C (pt) |
| DE (1) | DE69909473T2 (pt) |
| ES (1) | ES2204134T3 (pt) |
| WO (1) | WO1999061486A1 (pt) |
Families Citing this family (112)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8497330B2 (en) * | 1997-12-08 | 2013-07-30 | Univation Technologies, Llc | Methods for polymerization using spray dried and slurried catalyst |
| US6894131B2 (en) * | 1998-08-21 | 2005-05-17 | Univation Technologies, Llc | Polymerization process using a metallocene catalyst system |
| ATE236934T1 (de) | 1999-02-22 | 2003-04-15 | Borealis Tech Oy | Olefinpolymerisationsverfahren |
| US6825295B2 (en) * | 1999-12-10 | 2004-11-30 | Dow Global Technologies Inc. | Alkaryl-substituted group 4 metal complexes, catalysts and olefin polymerization process |
| ATE547437T1 (de) * | 1999-12-10 | 2012-03-15 | Dow Global Technologies Llc | Substituierte gruppe-4-metallkomplexe, katalysatoren und olefinpolymerisationsverfahren |
| DE19958604A1 (de) * | 1999-12-15 | 2001-06-21 | Targor Gmbh | Verfahren und Dosiervorrichtung zum regelbaren Einbringen von Stestoffen in Druckräume |
| US6720396B2 (en) * | 2000-11-30 | 2004-04-13 | Univation Technologies, Llc | Polymerization process |
| EP1308464A1 (en) * | 2001-10-19 | 2003-05-07 | BP Chemicals S.N.C. | Process for the gas-phase (co-)polymerisation of olefins in a fluidised bed reactor |
| DE10217182B4 (de) * | 2002-04-18 | 2009-05-07 | Lurgi Zimmer Gmbh | Vorrichtung zum Wechseln von Düsen |
| EP1498453B1 (en) * | 2002-04-25 | 2007-01-03 | Asahi Kasei Chemicals Corporation | Rubber composition and process for production thereof |
| US20040052690A1 (en) * | 2002-09-12 | 2004-03-18 | Eaton Gerald B. | Polymerization reactant injection system |
| DE60304196T2 (de) * | 2002-10-09 | 2006-12-14 | Exxonmobil Chemical Patents Inc., Baytown | Verfahren zur injektion von katalysator in einen polymerizationsreaktor |
| WO2004033506A1 (en) | 2002-10-09 | 2004-04-22 | Exxonmobil Chemical Patents Inc. | Methods of delivering catalyst systems for propylene polymerization |
| AU2003278856A1 (en) * | 2002-10-09 | 2004-05-04 | Exxonmobil Chemical Patents Inc. | Methods of feed purification for olefin polymerization |
| US6949612B2 (en) * | 2002-12-31 | 2005-09-27 | Univation Technologies, Llc | Processes for transitioning between metallocene and Ziegler-Natta polymerization catalysts |
| DE10317533A1 (de) * | 2003-04-16 | 2004-11-04 | Basell Polyolefine Gmbh | Verfahren zur diskontinuierlichen Katalysatordosierung in einen Gasphasenwirbelschichtreaktor |
| US20050148742A1 (en) * | 2004-01-02 | 2005-07-07 | Hagerty Robert O. | Method for controlling sheeting in gas phase reactors |
| US20070073012A1 (en) * | 2005-09-28 | 2007-03-29 | Pannell Richard B | Method for seed bed treatment before a polymerization reaction |
| US7119153B2 (en) * | 2004-01-21 | 2006-10-10 | Jensen Michael D | Dual metallocene catalyst for producing film resins with good machine direction (MD) elmendorf tear strength |
| US20050182210A1 (en) | 2004-02-17 | 2005-08-18 | Natarajan Muruganandam | De-foaming spray dried catalyst slurries |
| US7754830B2 (en) | 2004-05-20 | 2010-07-13 | Univation Technologies, Llc | Polymerization reaction monitoring with determination of induced condensing agent concentration for preventing discontinuity events |
| US7531606B2 (en) | 2004-05-26 | 2009-05-12 | Chevron Phillips Chemical Company Lp | Method for operating a gas phase polymerization reactor |
| US7473750B2 (en) * | 2004-12-07 | 2009-01-06 | Fina Technology, Inc. | Random copolymers and formulations useful for thermoforming and blow molding applications |
| US7220806B2 (en) * | 2005-04-29 | 2007-05-22 | Fina Technology, Inc. | Process for increasing ethylene incorporation into random copolymers |
| US20060247394A1 (en) * | 2005-04-29 | 2006-11-02 | Fina Technology, Inc. | Process for increasing ethylene incorporation into random copolymers |
| US7645834B2 (en) * | 2005-04-29 | 2010-01-12 | Fina Technologies, Inc. | Catalyst system for production of polyolefins |
| US7081285B1 (en) | 2005-04-29 | 2006-07-25 | Fina Technology, Inc. | Polyethylene useful for blown films and blow molding |
| EP1888653B1 (en) * | 2005-06-07 | 2016-01-13 | Saudi Basic Industries Corporation | Process for the polymerization of olefins |
| EP1731535A1 (en) * | 2005-06-07 | 2006-12-13 | Saudi Basic Industries Corporation Inc. | Process for polymerization of olefins |
| US7282546B2 (en) * | 2005-06-22 | 2007-10-16 | Fina Technology, Inc. | Cocatalysts for reduction of production problems in metallocene-catalyzed polymerizations |
| BRPI0506110A (pt) * | 2005-11-10 | 2007-08-14 | Braskem Sa | composição anti-estática útil na polimerização ou copolimerização de olefinas em suspensão, processo de polimerização ou copolimerização de olefinas em suspensão, e, polìmero ou copolìmero de olefina |
| US20070299222A1 (en) | 2006-04-04 | 2007-12-27 | Fina Technology, Inc. | Transition metal catalysts and formation thereof |
| US7683002B2 (en) | 2006-04-04 | 2010-03-23 | Fina Technology, Inc. | Transition metal catalyst and formation thereof |
| US20070235896A1 (en) * | 2006-04-06 | 2007-10-11 | Fina Technology, Inc. | High shrink high modulus biaxially oriented films |
| GB0610668D0 (en) * | 2006-05-30 | 2006-07-12 | Nova Chem Int Sa | Supported antistatic polymerization catalysts |
| US20080051538A1 (en) * | 2006-07-11 | 2008-02-28 | Fina Technology, Inc. | Bimodal pipe resin and products made therefrom |
| US7449529B2 (en) * | 2006-07-11 | 2008-11-11 | Fina Technology, Inc. | Bimodal blow molding resin and products made therefrom |
| US7893181B2 (en) * | 2006-07-11 | 2011-02-22 | Fina Technology, Inc. | Bimodal film resin and products made therefrom |
| US7514510B2 (en) | 2006-07-25 | 2009-04-07 | Fina Technology, Inc. | Fluorenyl catalyst compositions and olefin polymerization process |
| US7470759B2 (en) * | 2006-07-31 | 2008-12-30 | Fina Technology, Inc. | Isotactic-atactic polypropylene and methods of making same |
| ES2405556T3 (es) | 2006-09-07 | 2013-05-31 | Univation Technologies, Llc | Métodos para determinación en línea del grado de pegajosidad de una resina utilizando un modelo para depresión de la temperatura de iniciación de la fusión |
| US20080061468A1 (en) * | 2006-09-07 | 2008-03-13 | Frank Li | Fiber processing of high ethylene level propylene-ethylene random copolymers by use of nucleators |
| US7538167B2 (en) * | 2006-10-23 | 2009-05-26 | Fina Technology, Inc. | Syndiotactic polypropylene and methods of preparing same |
| US20080114130A1 (en) * | 2006-11-10 | 2008-05-15 | John Ashbaugh | Resin composition for production of high tenacity slit film, monofilaments and fibers |
| CA2664910A1 (en) | 2006-12-15 | 2008-07-03 | Fina Technology, Inc. | Polypropylene blown film |
| US7851578B2 (en) * | 2006-12-29 | 2010-12-14 | Fina Technology, Inc. | Succinate-containing polymerization catalyst system using n-butylmethyldimethoxysilane for preparation of polypropylene film grade resins |
| BRPI0605781A (pt) * | 2006-12-29 | 2008-08-19 | Braskem Sa | composição anti-estática para polimerização ou copolimerização de olefinas em fase gás, processo de polimerização ou copolimerização de olefinas em fase gás, e, polìmero ou copolìmero de olefina assim obtido |
| CN101235108B (zh) * | 2007-01-31 | 2012-06-27 | 住友化学株式会社 | 用于制备烯烃聚合物的方法 |
| US8859084B2 (en) * | 2008-01-29 | 2014-10-14 | Fina Technology, Inc. | Modifiers for oriented polypropylene |
| US8003741B2 (en) | 2008-02-07 | 2011-08-23 | Fina Technology, Inc. | Ziegler-Natta catalyst |
| US20090202770A1 (en) * | 2008-02-08 | 2009-08-13 | Fengkui Li | Polypropylene/polyisobutylene blends and films prepared from same |
| TWI433855B (zh) * | 2008-06-04 | 2014-04-11 | Univation Tech Llc | 漿液觸媒流分流器及其使用方法 |
| US7740070B2 (en) * | 2008-06-16 | 2010-06-22 | Halliburton Energy Services, Inc. | Wellbore servicing compositions comprising a density segregation inhibiting composite and methods of making and using same |
| US8268913B2 (en) * | 2008-06-30 | 2012-09-18 | Fina Technology, Inc. | Polymeric blends and methods of using same |
| US8545971B2 (en) * | 2008-06-30 | 2013-10-01 | Fina Technology, Inc. | Polymeric compositions comprising polylactic acid and methods of making and using same |
| US8759446B2 (en) * | 2008-06-30 | 2014-06-24 | Fina Technology, Inc. | Compatibilized polypropylene and polylactic acid blends and methods of making and using same |
| US9334342B2 (en) | 2008-10-01 | 2016-05-10 | Fina Technology, Inc. | Polypropylene for reduced plate out in polymer article production processes |
| EP2172262A1 (en) * | 2008-10-03 | 2010-04-07 | Ineos Europe Limited | Process |
| US8841391B2 (en) | 2008-10-03 | 2014-09-23 | Ineos Sales (Uk) Limited | Process for the introduction of a polymerisation catalyst into a gas-phase fluidised bed |
| US20100087602A1 (en) * | 2008-10-08 | 2010-04-08 | Fina Technology, Inc. | Long chain branched polypropylene for cast film applications |
| WO2010071798A1 (en) | 2008-12-18 | 2010-06-24 | Univation Technologies, Llc | Method for seed bed treatment for a polymerization reaction |
| US8653198B2 (en) | 2009-03-26 | 2014-02-18 | Fina Technology, Inc. | Method for the preparation of a heterophasic copolymer and uses thereof |
| US9090000B2 (en) | 2009-03-26 | 2015-07-28 | Fina Technology, Inc. | Injection stretch blow molded articles and random copolymers for use therein |
| US20100247887A1 (en) | 2009-03-26 | 2010-09-30 | Fina Technology, Inc. | Polyolefin films for in-mold labels |
| MY158186A (en) | 2009-07-28 | 2016-09-15 | Univation Tech Llc | Polymerization process using a supported constrained geometry catalyst |
| US9174384B2 (en) * | 2009-09-01 | 2015-11-03 | Fina Technology, Inc. | Multilayer polypropylene films and methods of making and using same |
| EP2510019A2 (en) * | 2009-12-07 | 2012-10-17 | Univation Technologies, LLC | Methods for reducing static charge of a catalyst and methods for using the catalyst to produce polyolefins |
| US8592535B2 (en) | 2010-01-11 | 2013-11-26 | Fina Technology, Inc. | Ziegler-natta catalyst systems and polymers formed therefrom |
| US10351640B2 (en) | 2010-04-22 | 2019-07-16 | Fina Technology, Inc. | Formation of Ziegler-Natta catalyst using non-blended components |
| US8278403B2 (en) | 2010-07-08 | 2012-10-02 | Fina Technology, Inc. | Multi-component catalyst systems and polymerization processes for forming broad composition distribution polymers |
| KR100999555B1 (ko) * | 2010-07-09 | 2010-12-08 | 대림산업 주식회사 | 삼상 유동층 반응기를 이용한 알파-올레핀의 삼상중합 방법 |
| US20120046429A1 (en) | 2010-08-23 | 2012-02-23 | Fina Technology, Inc. | Sequential Formation of Ziegler-Natta Catalyst Using Non-blended Components |
| WO2012041810A1 (en) * | 2010-09-28 | 2012-04-05 | Basell Polyolefine Gmbh | Method for feeding an antistatic compound to a polymerization reactor |
| BR112013006169B1 (pt) * | 2010-09-28 | 2020-02-11 | Basell Polyolefine Gmbh | Método para a alimentação de um composto antiestático a um reator de polimerização, pasta catalítica, seu uso e processo para a polimerização de olefinas |
| EP2465876A1 (en) | 2010-12-15 | 2012-06-20 | INEOS Manufacturing Belgium NV | Activating supports |
| US9012359B2 (en) | 2011-01-20 | 2015-04-21 | Ineos Sales (Uk) Limited | Activating supports |
| US10711077B2 (en) | 2011-02-07 | 2020-07-14 | Fina Technology, Inc. | Ziegler-natta catalyst composition with controlled morphology |
| US8586192B2 (en) | 2011-02-15 | 2013-11-19 | Fina Technology, Inc. | Compatibilized polymeric compositions comprising polyolefin-polylactic acid copolymers and methods of making the same |
| US9382347B2 (en) | 2011-02-16 | 2016-07-05 | Fina Technology Inc | Ziegler-Natta catalysts doped with non-group IV metal chlorides |
| US8628718B2 (en) | 2011-02-18 | 2014-01-14 | Fina Technology, Inc. | Modified polylactic acid, polymeric blends and methods of making the same |
| CA2749835C (en) * | 2011-08-23 | 2018-08-21 | Nova Chemicals Corporation | Feeding highly active phosphinimine catalysts to a gas phase reactor |
| JP5667949B2 (ja) * | 2011-09-08 | 2015-02-12 | 日本ポリエチレン株式会社 | ポリマーの粒子性状が改善されたオレフィンの重合方法 |
| CA2856988C (en) | 2011-11-30 | 2019-05-07 | Univation Technologies, Llc | Methods and systems for catalyst delivery |
| ES2682252T3 (es) | 2011-12-14 | 2018-09-19 | Ineos Europe Ag | Nuevos polímeros |
| US8580893B2 (en) | 2011-12-22 | 2013-11-12 | Fina Technology, Inc. | Methods for improving multimodal polyethylene and films produced therefrom |
| WO2014011357A1 (en) * | 2012-07-13 | 2014-01-16 | Univation Technologies, Llc | Increased polymer melt flow ratio via feed of a supported catalyst saturated with a selected liquid agent |
| CN105143285B (zh) * | 2013-02-07 | 2019-03-08 | 尤尼威蒂恩技术有限责任公司 | 聚烯烃的制备 |
| EP2803679A1 (en) | 2013-05-17 | 2014-11-19 | Basell Poliolefine Italia S.r.l. | Catalyst components for the polymerization of olefins |
| EP3087106B1 (en) | 2013-12-23 | 2019-02-20 | Ineos Europe AG | Scavenger injection |
| EP3087108B2 (en) | 2013-12-23 | 2022-04-20 | Ineos Europe AG | Process |
| US9206293B2 (en) | 2014-01-31 | 2015-12-08 | Fina Technology, Inc. | Polyethyene and articles produced therefrom |
| CN106459248B (zh) * | 2014-04-02 | 2020-03-03 | 尤尼威蒂恩技术有限责任公司 | 催化剂组合物、制备方法及在聚合工艺中的用途 |
| CN106458883A (zh) | 2014-06-11 | 2017-02-22 | 弗纳技术股份有限公司 | 耐氯聚乙烯化合物和由其制造的制品 |
| US9624321B2 (en) | 2014-06-13 | 2017-04-18 | Fina Technology, Inc. | Formation of a Ziegler-Natta catalyst |
| US9650448B2 (en) | 2014-06-13 | 2017-05-16 | Fina Technology, Inc. | Formation of a Ziegler-Natta catalyst |
| EP3034519B1 (en) * | 2014-12-17 | 2018-07-18 | Basell Poliolefine Italia S.r.l. | Improved gas phase process for the polymerization of olefins |
| US10494455B2 (en) | 2014-12-22 | 2019-12-03 | Sabic Global Technologies B.V. | Process for transitioning between incompatible catalysts |
| SG11201707037TA (en) | 2015-03-10 | 2017-09-28 | Univation Tech Llc | Spray dried catalyst compositions, methods for preparation and use in olefin polymerization processes |
| WO2016151098A1 (en) * | 2015-03-24 | 2016-09-29 | Sabic Global Technologies B.V. | Process for transitioning between incompatible catalysts |
| JP6658089B2 (ja) * | 2016-02-26 | 2020-03-04 | 日本ポリプロ株式会社 | ポリオレフィンの製造方法 |
| US10683408B2 (en) | 2016-10-28 | 2020-06-16 | Fina Technology, Inc. | Use of agents to reduce crystallinity in polypropylene for BOPP applications |
| EP3535301A1 (en) | 2016-11-03 | 2019-09-11 | ExxonMobil Chemical Patents Inc. | Multi-component catalyst composition supply system and process for producing polymers |
| CA3079148A1 (en) * | 2017-10-27 | 2019-05-02 | Univation Technologies, Llc | Polyethylene copolymer resins and films |
| US11993699B2 (en) | 2018-09-14 | 2024-05-28 | Fina Technology, Inc. | Polyethylene and controlled rheology polypropylene polymer blends and methods of use |
| KR102287064B1 (ko) | 2018-12-11 | 2021-08-05 | 한화솔루션 주식회사 | 올레핀 중합용 촉매의 제조방법 |
| US11866522B2 (en) | 2018-12-28 | 2024-01-09 | Braskem S.A. | Process for introducing catalyst in a polymerization process |
| JP7572961B2 (ja) | 2019-02-20 | 2024-10-24 | フイナ・テクノロジー・インコーポレーテツド | 低い反りを有するポリマー組成物 |
| EP3865517A4 (en) * | 2019-09-27 | 2022-05-18 | LG Chem, Ltd. | SUPPORTED HYBRID CATALYST AND METHOD OF MAKING POLYOLEFIN THEREWITH |
| KR102568406B1 (ko) * | 2019-09-27 | 2023-08-18 | 주식회사 엘지화학 | 혼성 담지 촉매 및 이용한 폴리올레핀의 제조 방법 |
| WO2021060908A1 (ko) * | 2019-09-27 | 2021-04-01 | 주식회사 엘지화학 | 혼성 담지 촉매 및 이용한 폴리올레핀의 제조 방법 |
| MX2023011768A (es) | 2021-04-26 | 2023-10-10 | Fina Technology | Laminas de polimero delgadas catalizadas en un solo sitio. |
| EP4626939A1 (en) | 2022-11-29 | 2025-10-08 | FINA Technology Inc. | Polypropylenes for additive manufacturing |
Family Cites Families (149)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3248179A (en) | 1962-02-26 | 1966-04-26 | Phillips Petroleum Co | Method and apparatus for the production of solid polymers of olefins |
| US3779712A (en) | 1971-11-26 | 1973-12-18 | Union Carbide Corp | Particulate solids injector apparatus |
| DE2742585A1 (de) | 1976-09-28 | 1978-03-30 | Asahi Chemical Ind | Neue polymerisationskatalysatoren und ihre verwendung (i) |
| US4137387A (en) * | 1976-09-30 | 1979-01-30 | The Badger Company, Inc. | Equipment for handling spent-aqueous Ziegler type catalyst in the polymerization of olefins |
| US4271060A (en) | 1979-09-17 | 1981-06-02 | Phillips Petroleum Company | Solution polymerization process |
| US4325837A (en) | 1980-08-12 | 1982-04-20 | Phillips Petroleum Company | Catalyst, method of producing the catalyst, and polymerization process employing the catalyst |
| US4543399A (en) | 1982-03-24 | 1985-09-24 | Union Carbide Corporation | Fluidized bed reaction systems |
| US4588790A (en) | 1982-03-24 | 1986-05-13 | Union Carbide Corporation | Method for fluidized bed polymerization |
| US4935474A (en) | 1983-06-06 | 1990-06-19 | Exxon Research & Engineering Company | Process and catalyst for producing polyethylene having a broad molecular weight distribution |
| US4530914A (en) | 1983-06-06 | 1985-07-23 | Exxon Research & Engineering Co. | Process and catalyst for producing polyethylene having a broad molecular weight distribution |
| US4937299A (en) | 1983-06-06 | 1990-06-26 | Exxon Research & Engineering Company | Process and catalyst for producing reactor blend polyolefins |
| US5324800A (en) | 1983-06-06 | 1994-06-28 | Exxon Chemical Patents Inc. | Process and catalyst for polyolefin density and molecular weight control |
| US4610574A (en) * | 1984-05-30 | 1986-09-09 | Amoco Corporation | Catalyst feeding system |
| US4613484A (en) | 1984-11-30 | 1986-09-23 | Phillips Petroleum Company | Loop reactor settling leg system for separation of solid polymers and liquid diluent |
| US4665208A (en) | 1985-07-11 | 1987-05-12 | Exxon Chemical Patents Inc. | Process for the preparation of alumoxanes |
| US4701432A (en) | 1985-11-15 | 1987-10-20 | Exxon Chemical Patents Inc. | Supported polymerization catalyst |
| US5124418A (en) | 1985-11-15 | 1992-06-23 | Exxon Chemical Patents Inc. | Supported polymerization catalyst |
| US5077255A (en) | 1986-09-09 | 1991-12-31 | Exxon Chemical Patents Inc. | New supported polymerization catalyst |
| DE3752260T2 (de) | 1986-09-24 | 1999-09-02 | Mitsui Chemicals | Verfahren zur Olefinpolymerisation |
| JPH0780933B2 (ja) | 1986-11-20 | 1995-08-30 | 三井石油化学工業株式会社 | オレフインの重合方法 |
| IL85097A (en) | 1987-01-30 | 1992-02-16 | Exxon Chemical Patents Inc | Catalysts based on derivatives of a bis(cyclopentadienyl)group ivb metal compound,their preparation and their use in polymerization processes |
| US5055438A (en) | 1989-09-13 | 1991-10-08 | Exxon Chemical Patents, Inc. | Olefin polymerization catalysts |
| US5384299A (en) | 1987-01-30 | 1995-01-24 | Exxon Chemical Patents Inc. | Ionic metallocene catalyst compositions |
| US5621126A (en) | 1987-01-30 | 1997-04-15 | Exxon Chemical Patents Inc. | Monocyclopentadienyl metal compounds for ethylene-α-olefin-copolymer production catalysts |
| US5096867A (en) | 1990-06-04 | 1992-03-17 | Exxon Chemical Patents Inc. | Monocyclopentadienyl transition metal olefin polymerization catalysts |
| PL276385A1 (en) | 1987-01-30 | 1989-07-24 | Exxon Chemical Patents Inc | Method for polymerization of olefines,diolefins and acetylene unsaturated compounds |
| US5198401A (en) | 1987-01-30 | 1993-03-30 | Exxon Chemical Patents Inc. | Ionic metallocene catalyst compositions |
| US5153157A (en) | 1987-01-30 | 1992-10-06 | Exxon Chemical Patents Inc. | Catalyst system of enhanced productivity |
| US5241025A (en) | 1987-01-30 | 1993-08-31 | Exxon Chemical Patents Inc. | Catalyst system of enhanced productivity |
| US5264405A (en) | 1989-09-13 | 1993-11-23 | Exxon Chemical Patents Inc. | Monocyclopentadienyl titanium metal compounds for ethylene-α-olefin-copolymer production catalysts |
| US5408017A (en) | 1987-01-30 | 1995-04-18 | Exxon Chemical Patents Inc. | High temperature polymerization process using ionic catalysts to produce polyolefins |
| JPH0742301B2 (ja) | 1987-02-14 | 1995-05-10 | 三井石油化学工業株式会社 | 微粒子状アルミノオキサン、その製法およびその用途 |
| US5026795A (en) | 1987-02-24 | 1991-06-25 | Phillips Petroleum Co | Process for preventing fouling in a gas phase polymerization reactor |
| JP2538588B2 (ja) | 1987-04-03 | 1996-09-25 | 三井石油化学工業株式会社 | オレフイン重合用固体触媒の製法 |
| US5206199A (en) | 1987-04-20 | 1993-04-27 | Mitsui Petrochemical Industries, Ltd. | Catalyst for polymerizing an olefin and process for polymerizing an olefin |
| US5017714A (en) | 1988-03-21 | 1991-05-21 | Exxon Chemical Patents Inc. | Silicon-bridged transition metal compounds |
| US5120867A (en) | 1988-03-21 | 1992-06-09 | Welborn Jr Howard C | Silicon-bridged transition metal compounds |
| US4871705A (en) | 1988-06-16 | 1989-10-03 | Exxon Chemical Patents Inc. | Process for production of a high molecular weight ethylene a-olefin elastomer with a metallocene alumoxane catalyst |
| US5229478A (en) | 1988-06-16 | 1993-07-20 | Exxon Chemical Patents Inc. | Process for production of high molecular weight EPDM elastomers using a metallocene-alumoxane catalyst system |
| FR2634212B1 (fr) | 1988-07-15 | 1991-04-19 | Bp Chimie Sa | Appareillage et procede de polymerisation d'olefines en phase gazeuse dans un reacteur a lit fluidise |
| US5091352A (en) | 1988-09-14 | 1992-02-25 | Mitsui Petrochemical Industries, Ltd. | Olefin polymerization catalyst component, olefin polymerization catalyst and process for the polymerization of olefins |
| DE3833444A1 (de) | 1988-10-01 | 1990-04-05 | Basf Ag | Vermeidung von farbigen verunreinigungen bei der herstellung von ultrahochmolekularen ethylenpolymerisaten mittels eines titan enthaltenden katalysatorsystems |
| DE3833445A1 (de) | 1988-10-01 | 1990-04-05 | Basf Ag | Vermeidung von farbigen verunreinigungen bei der herstellung von ultrahochmolekularen ethylenpolymerisaten mittels eines titan enthaltenden katalysatorsystems |
| US5097053A (en) | 1988-10-13 | 1992-03-17 | Basf Corporation | Fast-cure polyurethane sealant composition containing silyl-substituted guanidine accelerators |
| US4908463A (en) | 1988-12-05 | 1990-03-13 | Ethyl Corporation | Aluminoxane process |
| US5103031A (en) | 1989-02-21 | 1992-04-07 | Ethyl Corporation | Falling film aluminoxane process |
| US4968827A (en) | 1989-06-06 | 1990-11-06 | Ethyl Corporation | Alkylaluminoxane process |
| US4924018A (en) | 1989-06-26 | 1990-05-08 | Ethyl Corporation | Alkylaluminoxane process |
| US5066741A (en) | 1990-03-22 | 1991-11-19 | The Dow Chemical Company | Process for preparation of syndiotactic vinyl aromatic polymers |
| DK0426637T4 (da) | 1989-10-30 | 2002-01-14 | Fina Technology | Fremgangsmåde til fremstilling af metallocenkatalysatorer til polymerisation af olefiner |
| US5387568A (en) | 1989-10-30 | 1995-02-07 | Fina Technology, Inc. | Preparation of metallocene catalysts for polymerization of olefins |
| FR2660926B1 (fr) | 1990-04-11 | 1992-07-31 | Bp Chemicals Snc | Prepolymere d'alpha-olefine contenant un metal de transition et procede de polymerisation d'alpha-olefine en phase gazeuse mettant en óoeuvre le prepolymere. |
| EP0672689A1 (en) | 1990-06-22 | 1995-09-20 | Exxon Chemical Patents Inc. | Aluminum-free monocyclopentadienyl metallocene catalysts for olefin polymerization |
| JP2857916B2 (ja) * | 1990-07-20 | 1999-02-17 | 日本石油化学株式会社 | 気相重合流動床の触媒供給方法 |
| KR940009020B1 (ko) | 1990-07-24 | 1994-09-29 | 미쓰이 도오아쓰 가가쿠 가부시키가이샤 | α-올레핀의 중합촉매 및 그것을 이용한 폴리 α-올레핀의 제조방법 |
| DE59107973D1 (de) | 1990-11-12 | 1996-08-08 | Hoechst Ag | Verfahren zur Herstellung eines hochmolekularen Olefinpolymers |
| ES2071888T3 (es) | 1990-11-12 | 1995-07-01 | Hoechst Ag | Bisindenilmetalocenos sustituidos en posicion 2, procedimiento para su preparacion y su utilizacion como catalizadores en la polimerizacion de olefinas. |
| FR2670399B1 (fr) * | 1990-12-14 | 1994-08-05 | Bp Chemicals Snc | Procede et dispositif d'introduction d'une suspension dans un reacteur. |
| US5189192A (en) | 1991-01-16 | 1993-02-23 | The Dow Chemical Company | Process for preparing addition polymerization catalysts via metal center oxidation |
| US5206197A (en) | 1991-03-04 | 1993-04-27 | The Dow Chemical Company | Catalyst composition for preparation of syndiotactic vinyl aromatic polymers |
| US5399636A (en) | 1993-06-11 | 1995-03-21 | Phillips Petroleum Company | Metallocenes and processes therefor and therewith |
| US5210352A (en) | 1991-05-09 | 1993-05-11 | Phillips Petroleum Company | Fluorene compounds |
| ES2155492T3 (es) | 1991-05-27 | 2001-05-16 | Basell Polyolefine Gmbh | Procedimiento para la obtencion de poliolefinas con una amplia distribucion de pesos moleculares. |
| DE4119343A1 (de) | 1991-06-12 | 1992-12-17 | Basf Ag | Isolierbares, getraegertes katalysatorsystem zur polymerisation von c(pfeil abwaerts)2(pfeil abwaerts)- bis c(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)0(pfeil abwaerts)-alk-1-enen |
| US5721185A (en) | 1991-06-24 | 1998-02-24 | The Dow Chemical Company | Homogeneous olefin polymerization catalyst by abstraction with lewis acids |
| US5594078A (en) | 1991-07-23 | 1997-01-14 | Phillips Petroleum Company | Process for producing broad molecular weight polyolefin |
| US5157137A (en) | 1991-07-26 | 1992-10-20 | Ethyl Corporation | Method of making gel free alkylaluminoxane solutions |
| US5235081A (en) | 1992-03-18 | 1993-08-10 | Ethyl Corporation | Method of removing gel forming materials from methylaluminoxanes |
| US5308815A (en) | 1991-07-26 | 1994-05-03 | Ethyl Corporation | Heterogeneous methylaluminoxane catalyst system |
| US5391789A (en) | 1991-08-08 | 1995-02-21 | Hoechst Aktiengesellschaft | Bridged, chiral metallocenes, processes for their preparation and their use as catalysts |
| TW300901B (pt) | 1991-08-26 | 1997-03-21 | Hoechst Ag | |
| CA2077744C (en) | 1991-09-30 | 2003-04-15 | Edwar Shoukri Shamshoum | Homogeneous-heterogeneous catalyst system for polyolefins |
| US5589555A (en) | 1991-10-03 | 1996-12-31 | Novacor Chemicals (International) S.A. | Control of a solution process for polymerization of ethylene |
| JP3394997B2 (ja) | 1991-10-15 | 2003-04-07 | バーゼル・ポリオレフィン・ゲゼルシャフト・ミト・ベシュレンクテル・ハフツング | 特異的に置換されたインデニル配位子を持つメタロセンを用いてオレフィンポリマーを製造する方法 |
| US5281679A (en) | 1991-11-07 | 1994-01-25 | Exxon Chemical Patents Inc. | Catalyst and method of broadening polymer molecular weight distribution and increasing polymer tensile impact strength and products made thereof |
| US5359015A (en) | 1991-11-07 | 1994-10-25 | Exxon Chemical Patents Inc. | Metallocene catalysts and their production and use |
| JP3273944B2 (ja) | 1991-11-25 | 2002-04-15 | エクソンモービル・ケミカル・パテンツ・インク | ポリアニオン性遷移金属触媒組成物 |
| EP0549900B1 (de) | 1991-11-30 | 1996-08-21 | Hoechst Aktiengesellschaft | Metallocene mit benzokondensierten Indenylderivaten als Liganden, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren |
| JP3275078B2 (ja) | 1992-01-06 | 2002-04-15 | ザ ダウ ケミカル カンパニー | オレフィンの重合法 |
| US5391660A (en) | 1992-01-14 | 1995-02-21 | Nippon Oil Company, Limited | Process for preparing polyolefines |
| IT1262933B (it) | 1992-01-31 | 1996-07-22 | Montecatini Tecnologie Srl | Processo per la polimerizzazione in fase gas di alfa-olefine |
| US5329032A (en) | 1992-03-18 | 1994-07-12 | Akzo Chemicals Inc. | Polymethylaluminoxane of enhanced solution stability |
| US5352749A (en) | 1992-03-19 | 1994-10-04 | Exxon Chemical Patents, Inc. | Process for polymerizing monomers in fluidized beds |
| US5436304A (en) | 1992-03-19 | 1995-07-25 | Exxon Chemical Patents Inc. | Process for polymerizing monomers in fluidized beds |
| US5350723A (en) | 1992-05-15 | 1994-09-27 | The Dow Chemical Company | Process for preparation of monocyclopentadienyl metal complex compounds and method of use |
| US5434115A (en) | 1992-05-22 | 1995-07-18 | Tosoh Corporation | Process for producing olefin polymer |
| DE69224184T2 (de) | 1992-06-13 | 1999-06-02 | Targor GmbH, 55116 Mainz | Verfahren zur Herstellung von verbrückten, chiralen Metallocenkatalysatoren des Types Bisindenyl |
| US5504049A (en) | 1992-07-01 | 1996-04-02 | Exxon Chemical Patents Inc. | Transition metal olefin polymerization catalysts |
| US5248801A (en) | 1992-08-27 | 1993-09-28 | Ethyl Corporation | Preparation of methylaluminoxanes |
| PT586167E (pt) | 1992-09-04 | 2000-12-29 | Bp Chem Int Ltd | Composicoes de catalisadores e processo para a preparacao de poliolefinas |
| JP3301123B2 (ja) | 1992-09-09 | 2002-07-15 | 東ソー株式会社 | 芳香族ビニル化合物重合用触媒 |
| DE69322225T2 (de) | 1992-09-22 | 1999-05-12 | Idemitsu Kosan Co. Ltd., Tokio/Tokyo | Polymerisationskatalysatore und Verfahren zur Herstellung von Polymeren |
| WO1994007928A1 (en) | 1992-10-02 | 1994-04-14 | The Dow Chemical Company | Supported homogeneous catalyst complexes for olefin polymerization |
| US5317036A (en) | 1992-10-16 | 1994-05-31 | Union Carbide Chemicals & Plastics Technology Corporation | Gas phase polymerization reactions utilizing soluble unsupported catalysts |
| US5391793A (en) | 1992-11-02 | 1995-02-21 | Akzo Nobel N.V. | Aryloxyaluminoxanes |
| US5939346A (en) | 1992-11-02 | 1999-08-17 | Akzo Nobel N.V. | Catalyst system comprising an aryloxyaluminoxane containing an electron withdrawing group |
| US5332706A (en) | 1992-12-28 | 1994-07-26 | Mobil Oil Corporation | Process and a catalyst for preventing reactor fouling |
| US5391529A (en) | 1993-02-01 | 1995-02-21 | Albemarle Corporation | Siloxy-aluminoxane compositions, and catalysts which include such compositions with a metallocene |
| TW298593B (pt) | 1993-02-12 | 1997-02-21 | Hoechst Ag | |
| DE69330674T2 (de) | 1993-04-07 | 2002-07-04 | Atofina Research, Seneffe | Verfahren zur Herstellung von Polyolefinkatalysatoren |
| KR100190268B1 (ko) | 1993-04-26 | 1999-06-01 | 에인혼 해롤드 | 유동상에서 단량체를 중합시키는 방법 |
| US5462999A (en) * | 1993-04-26 | 1995-10-31 | Exxon Chemical Patents Inc. | Process for polymerizing monomers in fluidized beds |
| ZA943399B (en) | 1993-05-20 | 1995-11-17 | Bp Chem Int Ltd | Polymerisation process |
| US5804678A (en) | 1993-07-13 | 1998-09-08 | Mitsui Petrochemical Industries, Ltd. | Process for gas phase polymerization of olefin |
| US5563219A (en) | 1993-07-16 | 1996-10-08 | Mitsui Toatsu Chemicals, Inc. | Process for Preparing block copolymer of monoolefin |
| ES2141833T3 (es) | 1993-08-06 | 2000-04-01 | Exxon Chemical Patents Inc | Catalizadores de polimerizacion, su produccion y uso. |
| JPH07173214A (ja) | 1993-10-27 | 1995-07-11 | Nippon Oil Co Ltd | オレフィン類重合用触媒成分 |
| JPH09505340A (ja) | 1993-11-19 | 1997-05-27 | エクソン・ケミカル・パテンツ・インク | 重合用触媒系、その製造方法及び使用 |
| EP0654476B1 (de) | 1993-11-24 | 2001-01-24 | TARGOR GmbH | Metallocene, Verfahren zu ihrer Herstellung und ihrer Verwendung als Katalysatoren |
| US5491207A (en) | 1993-12-14 | 1996-02-13 | Exxon Chemical Patents Inc. | Process of producing high molecular weight ethylene-α-olefin elastomers with an indenyl metallocene catalyst system |
| FI945959A7 (fi) | 1993-12-21 | 1995-06-22 | Targor Gmbh | Metalloseenejä ja niiden käyttö katalyytteinä |
| FI96867C (fi) | 1993-12-27 | 1996-09-10 | Borealis Polymers Oy | Leijupetireaktori |
| US5473020A (en) | 1994-06-30 | 1995-12-05 | Phillips Petroleum Company | Polymer bound ligands, polymer bound metallocenes, catalyst systems, preparation, and use |
| IT1270070B (it) | 1994-07-08 | 1997-04-28 | Spherilene Srl | Componenti e catalizzatori per la polimerizzazione di olefine |
| US5453471B1 (en) | 1994-08-02 | 1999-02-09 | Carbide Chemicals & Plastics T | Gas phase polymerization process |
| US5643847A (en) | 1994-08-03 | 1997-07-01 | Exxon Chemical Patents Inc. | Supported ionic catalyst composition |
| US5763543A (en) | 1994-09-14 | 1998-06-09 | Exxon Chemical Patents Inc. | Olefin polymerization process with little or no scavenger present |
| JP3830513B2 (ja) | 1994-10-13 | 2006-10-04 | エクソンモービル・ケミカル・パテンツ・インク | 重合触媒系、それらの製造及び使用 |
| WO1996011961A1 (en) | 1994-10-13 | 1996-04-25 | Exxon Chemical Patents Inc. | Polymerization catalyst systems, their production and use |
| US5539124A (en) | 1994-12-19 | 1996-07-23 | Occidental Chemical Corporation | Polymerization catalysts based on transition metal complexes with ligands containing pyrrolyl ring |
| DE4447066A1 (de) | 1994-12-29 | 1996-07-04 | Hoechst Ag | Heterocyclische Carbene enthaltende Metallkomplexverbindungen |
| ATE238360T1 (de) | 1995-01-24 | 2003-05-15 | Du Pont | Polyolefine |
| US5616661A (en) | 1995-03-31 | 1997-04-01 | Union Carbide Chemicals & Plastics Technology Corporation | Process for controlling particle growth during production of sticky polymers |
| BR9602268A (pt) | 1995-05-16 | 1998-04-07 | Union Carbide Chem Plastic | Processo para a produção de polietileno e polietileno |
| US5661095A (en) | 1995-06-06 | 1997-08-26 | Quantum Chemical Corporation | Olefin polymerization catalyst component supported on a copolymer of an olefin and an unsaturated silane |
| US5519099A (en) | 1995-06-07 | 1996-05-21 | Industrial Technology Research Institute | Organometallic catalysts containing hydrotris(pyrazolyl) borate and cyclopentadienyl groups, and processes of employing the same |
| US5677375A (en) | 1995-07-21 | 1997-10-14 | Union Carbide Chemicals & Plastics Technology Corporation | Process for producing an in situ polyethylene blend |
| US5731253A (en) | 1995-07-27 | 1998-03-24 | Albemarle Corporation | Hydrocarbylsilloxy - aluminoxane compositions |
| US5648308A (en) | 1995-08-10 | 1997-07-15 | Albemarle Corporation | Process for upgrading metallocene catalysts |
| DE69602329T2 (de) | 1995-09-14 | 1999-09-23 | Showa Denko K.K., Tokio/Tokyo | Katalysator für ethylenische Polymerisation |
| US5969061A (en) | 1995-10-16 | 1999-10-19 | Eastman Chemical Company | Suppression of fines in a fluid bed polyethylene process |
| PL327407A1 (en) | 1995-10-27 | 1998-12-07 | Dow Chemical Co | Metal complexes capable of being readily deposited on a support |
| US5693838A (en) | 1995-11-13 | 1997-12-02 | Albemarle Corporation | Aluminoxane process and product |
| FR2741549B1 (fr) | 1995-11-29 | 1998-01-02 | Bp Chemicals Snc | Procede d'introduction d'un catalyseur dans un reacteur de polymerisation d'olefine en phase gazeuse |
| FI104825B (fi) | 1996-01-26 | 2000-04-14 | Borealis As | Olefiinien polymerointikatalysaattorisysteemi, sen valmistus ja käyttö |
| DE69701909T2 (de) | 1996-02-23 | 2000-08-17 | Tosoh Corp., Shinnanyo | Olefinpolymerisationskatalysator auf Basis von organometallischen Komplexen und Verfahren zur Herstellung von Polyolefinen mit diesem Katalysator |
| US5665818A (en) | 1996-03-05 | 1997-09-09 | Union Carbide Chemicals & Plastics Technology Corporation | High activity staged reactor process |
| US5627242A (en) | 1996-03-28 | 1997-05-06 | Union Carbide Chemicals & Plastics Technology Corporation | Process for controlling gas phase fluidized bed polymerization reactor |
| DE19615953A1 (de) * | 1996-04-22 | 1997-10-23 | Basf Ag | Verfahren zur Herstellung von Polymerisaten von Alk-1-enen in Gegenwart eines geträgerten Metallocenkatalysatorsystems und eines Antistatikums |
| DE19621838A1 (de) | 1996-05-31 | 1997-12-04 | Basf Ag | Verfahren zur Herstellung von Polymerisaten von C¶2¶- bis C¶1¶¶2¶-Alkenen unter Zusatz eines Reaktionsverzögerers |
| US5693727A (en) | 1996-06-06 | 1997-12-02 | Union Carbide Chemicals & Plastics Technology Corporation | Method for feeding a liquid catalyst to a fluidized bed polymerization reactor |
| CZ170897A3 (en) | 1996-06-06 | 1997-12-17 | Union Carbide Chem Plastic | Control of static charge in the course of polymerization process during which metallocene catalyst is used |
| US5712354A (en) | 1996-07-10 | 1998-01-27 | Mobil Oil Corporation | Bridged metallocene compounds |
| US5731451A (en) | 1996-07-12 | 1998-03-24 | Akzo Nobel Nv | Modified polyalkylauminoxane composition formed using reagent containing aluminum trialkyl siloxide |
| US5854166A (en) | 1996-08-19 | 1998-12-29 | Northwestern University | Synthesis and use of (perfluoroaryl) fluoro-aluminate anion |
| JP3727426B2 (ja) | 1996-09-18 | 2005-12-14 | 三井化学株式会社 | オレフィンの気相重合方法 |
| US5744656A (en) | 1996-10-25 | 1998-04-28 | Boulder Scientific Company | Conversion of hexafluorobenzene to bromopentafluorobenzene |
| AU4913597A (en) | 1996-11-01 | 1998-05-29 | Union Carbide Chemicals & Plastics Technology Corporation | Reduction of fouling in olefin polymerization systems |
| US6075101A (en) | 1997-02-19 | 2000-06-13 | Union Carbide Chemicals & Plastics Technology Corporation | Control of solution catalyst droplet size with a perpendicular spray nozzle |
-
1998
- 1998-05-29 US US09/087,024 patent/US6245868B1/en not_active Expired - Fee Related
-
1999
- 1999-05-27 BR BRPI9910779-1A patent/BR9910779B1/pt not_active IP Right Cessation
- 1999-05-27 AU AU42122/99A patent/AU743070B2/en not_active Ceased
- 1999-05-27 JP JP2000550889A patent/JP2002516357A/ja active Pending
- 1999-05-27 DE DE69909473T patent/DE69909473T2/de not_active Expired - Lifetime
- 1999-05-27 CA CA002328926A patent/CA2328926C/en not_active Expired - Fee Related
- 1999-05-27 EP EP99925935A patent/EP1082351B1/en not_active Revoked
- 1999-05-27 ES ES99925935T patent/ES2204134T3/es not_active Expired - Lifetime
- 1999-05-27 WO PCT/US1999/011747 patent/WO1999061486A1/en not_active Ceased
- 1999-05-28 AR ARP990102533A patent/AR018411A1/es unknown
-
2001
- 2001-03-14 US US09/808,615 patent/US20010020072A1/en not_active Abandoned
- 2001-03-14 US US09/808,576 patent/US6936226B2/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CA2328926A1 (en) | 1999-12-02 |
| DE69909473D1 (de) | 2003-08-14 |
| AR018411A1 (es) | 2001-11-14 |
| AU4212299A (en) | 1999-12-13 |
| WO1999061486A1 (en) | 1999-12-02 |
| BR9910779B1 (pt) | 2010-06-01 |
| JP2002516357A (ja) | 2002-06-04 |
| US6245868B1 (en) | 2001-06-12 |
| EP1082351A1 (en) | 2001-03-14 |
| US20010020072A1 (en) | 2001-09-06 |
| DE69909473T2 (de) | 2003-12-24 |
| US6936226B2 (en) | 2005-08-30 |
| EP1082351B1 (en) | 2003-07-09 |
| CA2328926C (en) | 2009-12-22 |
| ES2204134T3 (es) | 2004-04-16 |
| US20010012496A1 (en) | 2001-08-09 |
| AU743070B2 (en) | 2002-01-17 |
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