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BR9814448A - Interpolymers and thermoset foams, methods for producing them and their use - Google Patents

Interpolymers and thermoset foams, methods for producing them and their use

Info

Publication number
BR9814448A
BR9814448A BR9814448-0A BR9814448A BR9814448A BR 9814448 A BR9814448 A BR 9814448A BR 9814448 A BR9814448 A BR 9814448A BR 9814448 A BR9814448 A BR 9814448A
Authority
BR
Brazil
Prior art keywords
methods
weight percent
interpolymers
foams
question
Prior art date
Application number
BR9814448-0A
Other languages
Portuguese (pt)
Inventor
Kevin W Mckay
Francisc J Timmers
Edwin R Feig
Thoi H Ho
Seema V Karande
Original Assignee
Chemical Company
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US08/921,642 external-priority patent/US5977271A/en
Priority claimed from US08/921,641 external-priority patent/US5869591A/en
Application filed by Chemical Company filed Critical Chemical Company
Publication of BR9814448A publication Critical patent/BR9814448A/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10—Homopolymers or copolymers of propene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06—Hydrocarbons
    • C08F212/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06—Hydrocarbons
    • C08F212/12—Monomers containing a branched unsaturated aliphatic radical or a ring substituted by an alkyl radical
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
    • C08L53/025—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes modified
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65908—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an ionising compound other than alumoxane, e.g. (C6F5)4B-X+
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/22—Mixtures comprising a continuous polymer matrix in which are dispersed crosslinked particles of another polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
    • C08L23/0838—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with monomers including an aromatic carbocyclic ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2314/00—Polymer mixtures characterised by way of preparation
    • C08L2314/06—Metallocene or single site catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Artificial Filaments (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)

Abstract

"INTERPOLìMEROS E ESPUMAS TERMOFIXOS, MéTODOS PARA PRODUZìLOS E SEU USOS". O assunto da invenção provê um elastómero termofixo compreendendo um interpolímero reticulado pseudorandómico ou substancialmente randómico de: (a) de 15 a 70 por cento em peso de pelo menos uma <244>-olefina, (b) de 30 a 70 por cento em peso de pelo menos um composto aromático de vinilideno, e (c) de O a 15 por cento em peso de pelo menos um dieno. A invenção em questão adicionalmente provê um vulcanizado termoplástico compreendendo elastómeros termofixos da invenção como providos em uma matriz de poliolefina termoplástica. A invenção em questão adicionalmente provê processos para preparar os inventivos elastómeros termofixos e vulcanizados termoplásticos, bem como partes fabricadas a partir deles. Os materiais inventivos têm um equilíbrio superior de propriedades, se comparados com materiais baseados em EPM e EPDM. A invenção em questão também pertence a espumas e métodos para sua preparação."INTERPOLYMERS AND THERMOFIXED FOAMS, METHODS FOR PRODUCTION AND ITS USES". The subject of the invention provides a thermoset elastomer comprising a pseudo-random or substantially random crosslinked interpolymer of: (a) from 15 to 70 weight percent of at least one <244> -olefin, (b) from 30 to 70 weight percent of at least one vinylidene aromatic compound, and (c) from 0 to 15 weight percent of at least one diene. The invention in question further provides a thermoplastic vulcanized comprising thermoset elastomers of the invention as provided in a thermoplastic polyolefin matrix. The invention in question further provides processes for preparing the inventive thermosetting and thermoplastic vulcanized elastomers, as well as parts made from them. Inventive materials have a superior balance of properties when compared to materials based on EPM and EPDM. The invention in question also belongs to foams and methods for its preparation.

BR9814448-0A 1997-08-27 1998-08-26 Interpolymers and thermoset foams, methods for producing them and their use BR9814448A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US08/921,642 US5977271A (en) 1994-09-02 1997-08-27 Process for preparing thermoset interpolymers and foams
US08/921,641 US5869591A (en) 1994-09-02 1997-08-27 Thermoset interpolymers and foams
PCT/US1998/017673 WO1999010395A1 (en) 1997-08-27 1998-08-26 Thermoset interpolymers and foams

Publications (1)

Publication Number Publication Date
BR9814448A true BR9814448A (en) 2001-11-06

Family

ID=27378528

Family Applications (1)

Application Number Title Priority Date Filing Date
BR9814448-0A BR9814448A (en) 1997-08-27 1998-08-26 Interpolymers and thermoset foams, methods for producing them and their use

Country Status (9)

Country Link
EP (1) EP1007577A1 (en)
JP (1) JP2001514275A (en)
KR (1) KR20010023264A (en)
AU (1) AU8920998A (en)
BR (1) BR9814448A (en)
CA (1) CA2300062A1 (en)
HU (1) HUP0004824A3 (en)
NO (1) NO20000963L (en)
WO (1) WO1999010395A1 (en)

Families Citing this family (16)

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Publication number Priority date Publication date Assignee Title
AR018359A1 (en) * 1998-05-18 2001-11-14 Dow Global Technologies Inc HEAT RESISTANT ARTICLE, CONFIGURED, IRRADIATED AND RETICULATED, FREE FROM A SILANAN RETICULATION AGENT
US6709742B2 (en) 1998-05-18 2004-03-23 Dow Global Technologies Inc. Crosslinked elastic fibers
DE69928438T2 (en) * 1998-06-03 2006-08-03 Trexel, Inc., Woburn ELASTOMER MICROCELLULAR THERMOPLASTIC STRUCTURES
WO2000053669A1 (en) * 1999-03-11 2000-09-14 The Dow Chemical Company Olefin polymers and alpha-olefin/vinyl or alfa-olefin/vinylidene interpolymer blend foams
US6613811B1 (en) 1999-06-03 2003-09-02 Trexel, Inc. Microcellular thermoplastic elastomeric structures
US6365658B1 (en) 1999-08-12 2002-04-02 The Dow Chemical Company Polymer compositions
US6239242B1 (en) * 1999-08-21 2001-05-29 Nova Chemicals Corporation Vinylaromatic and olefin pseudoblock polymers
CN101090926B (en) * 2004-12-03 2011-06-29 陶氏环球技术公司 Wood fiber plastic composites
KR101224323B1 (en) 2004-12-17 2013-01-21 다우 글로벌 테크놀로지스 엘엘씨 Rheology modified polyethylene compositions
US8722831B2 (en) 2006-05-29 2014-05-13 Denki Kagaku Kogyo Kabushiki Kaisha Process for production of cross copolymers, cross copolymers obtained by the process, and use thereof
EP2270091B1 (en) 2008-04-15 2014-07-30 Denki Kagaku Kogyo Kabushiki Kaisha Thermoplastic resin composition
JP5719517B2 (en) * 2010-02-25 2015-05-20 東ソー・ファインケム株式会社 α-olefin / styrene copolymers and process for producing the same
KR101212637B1 (en) * 2011-06-09 2012-12-14 에스케이종합화학 주식회사 NEW CYCLOPENTA[b]FLUORENYL TRANSITION METAL COMPLEXES, CATALYSTS COMPOSITION CONTAINING THE SAME, AND METHODS FOR PREPARING ETHYLENE HOMOPOLYMERS OR COPOLYMERS OF ETHYLENE AND α-OLEFINS USING THE SAME
RU2523799C1 (en) 2011-12-20 2014-07-27 Чайна Петролеум Энд Кемикал Корпорейшн Additive and method of terminating polymerisation and/or reducing viscosity of polymer solution
KR102353554B1 (en) * 2015-03-04 2022-01-19 제이에스알 가부시끼가이샤 Copolymer, polymer composition, and crosslinked polymer
JPWO2019216109A1 (en) * 2018-05-08 2021-05-13 株式会社ブリヂストン Vulcanized rubber composition, tire tread and tire

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
IT1004558B (en) * 1972-08-31 1976-07-20 Ppg Industries Inc SILANATE COPULATING AGENT FOR RUBBER
JPS6011329A (en) * 1983-07-01 1985-01-21 Mitsubishi Petrochem Co Ltd Continuous manufacture of crosslinked and foamed body
NZ235032A (en) * 1989-08-31 1993-04-28 Dow Chemical Co Constrained geometry complexes of titanium, zirconium or hafnium comprising a substituted cyclopentadiene ligand; use as olefin polymerisation catalyst component
JP3219277B2 (en) * 1993-12-28 2001-10-15 出光興産株式会社 Method for producing olefin-based polymer and ethylene-based polymerization
ATE185822T1 (en) * 1994-09-02 1999-11-15 Dow Chemical Co HEAT SETTING ELASTOMERS

Also Published As

Publication number Publication date
JP2001514275A (en) 2001-09-11
NO20000963D0 (en) 2000-02-25
EP1007577A1 (en) 2000-06-14
KR20010023264A (en) 2001-03-26
HUP0004824A2 (en) 2001-04-28
WO1999010395A1 (en) 1999-03-04
NO20000963L (en) 2000-04-26
HUP0004824A3 (en) 2004-04-28
AU8920998A (en) 1999-03-16
CA2300062A1 (en) 1999-03-04

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