BR9813629A - Processo para desencadeamento de polimerização de olefina na fase gasosa - Google Patents
Processo para desencadeamento de polimerização de olefina na fase gasosaInfo
- Publication number
- BR9813629A BR9813629A BR9813629-1A BR9813629A BR9813629A BR 9813629 A BR9813629 A BR 9813629A BR 9813629 A BR9813629 A BR 9813629A BR 9813629 A BR9813629 A BR 9813629A
- Authority
- BR
- Brazil
- Prior art keywords
- olefin
- gas phase
- triggering
- olefin polymerization
- hydrogen
- Prior art date
Links
- 150000001336 alkenes Chemical class 0.000 title abstract 5
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 title abstract 5
- 238000006116 polymerization reaction Methods 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 2
- 239000007789 gas Substances 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 239000011261 inert gas Substances 0.000 abstract 1
- 230000000977 initiatory effect Effects 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 229910052723 transition metal Inorganic materials 0.000 abstract 1
- 150000003624 transition metals Chemical class 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/18—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with fluidised particles
- B01J8/1809—Controlling processes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/0015—Feeding of the particles in the reactor; Evacuation of the particles out of the reactor
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00168—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles
- B01J2208/00256—Controlling the temperature by indirect heat exchange with heat exchange elements outside the bed of solid particles in a heat exchanger for the heat exchange medium separate from the reactor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00017—Controlling the temperature
- B01J2208/00106—Controlling the temperature by indirect heat exchange
- B01J2208/00265—Part of all of the reactants being heated or cooled outside the reactor while recycling
- B01J2208/00274—Part of all of the reactants being heated or cooled outside the reactor while recycling involving reactant vapours
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00539—Pressure
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2208/00—Processes carried out in the presence of solid particles; Reactors therefor
- B01J2208/00008—Controlling the process
- B01J2208/00716—Means for reactor start-up
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/901—Monomer polymerized in vapor state in presence of transition metal containing catalyst
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S526/905—Polymerization in presence of transition metal containing catalyst in presence of hydrogen
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Abstract
<B>PROCESSO PARA DESENCADEAMENTO DE POLIMERIZAçãO DE OLEFINA NA FASE GASOSA<D> O assunto da presente invenção é portanto processo para iniciar uma reação de polimerização de olefina de fase gasosa realizada utilizando um catalisador tipo Ziegler-Natta baseado em um metal de transição em um reator de base fluidizada, através do qual passa uma mistura de gases de reação compreendendo a olefina, um gás inerte, hidrogênio e, opcionalmente, pelo menos um comonómero e que opera sob condições de temperatura e pressão que tornam possível iniciar a reação de polimerização, caracterizado pelo fato de que a pressão parcial da olefina e a taxa de introdução do catalisador no reator são aumentadas enquanto mantendo as razões das pressões parciais entre a olefina e o hidrogênio e o comonómero ou comonómeros opcionais substancialmente constantes.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9716209A FR2772383B1 (fr) | 1997-12-16 | 1997-12-16 | Procede de demarrage d'une polymerisation d'olefine en phase gazeuse |
| PCT/GB1998/003735 WO1999031142A1 (en) | 1997-12-16 | 1998-12-14 | Start-up polymerization process |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BR9813629A true BR9813629A (pt) | 2001-10-16 |
Family
ID=9514883
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR9813629-1A BR9813629A (pt) | 1997-12-16 | 1998-12-14 | Processo para desencadeamento de polimerização de olefina na fase gasosa |
Country Status (21)
| Country | Link |
|---|---|
| US (1) | US6265502B1 (pt) |
| EP (1) | EP1040129B1 (pt) |
| JP (1) | JP2002508407A (pt) |
| KR (1) | KR100522271B1 (pt) |
| CN (1) | CN1121418C (pt) |
| AR (1) | AR023294A1 (pt) |
| AT (1) | ATE234328T1 (pt) |
| AU (1) | AU735908B2 (pt) |
| BR (1) | BR9813629A (pt) |
| CA (1) | CA2314923A1 (pt) |
| DE (1) | DE69812163T2 (pt) |
| EG (1) | EG21507A (pt) |
| ES (1) | ES2194372T3 (pt) |
| FR (1) | FR2772383B1 (pt) |
| NO (1) | NO20003079L (pt) |
| PL (1) | PL341238A1 (pt) |
| PT (1) | PT1040129E (pt) |
| TR (1) | TR200001850T2 (pt) |
| TW (1) | TW577899B (pt) |
| WO (1) | WO1999031142A1 (pt) |
| ZA (1) | ZA9811459B (pt) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2772384B1 (fr) * | 1997-12-16 | 2000-02-04 | Bp Chemicals Snc | Procede de demarrage d'une polymerisation d'olefine en phase gazeuse |
| CN1271089C (zh) | 2000-12-18 | 2006-08-23 | 尤尼威蒂恩技术有限责任公司 | 多成分催化剂聚合体系的启动程序 |
| JP2006522189A (ja) * | 2003-04-03 | 2006-09-28 | バーゼル・ポリオレフィン・ゲーエムベーハー | 気相流動床反応器内における有機遷移金属化合物存在下での高分子量ポリオレフィンの製造 |
| US7157531B2 (en) * | 2004-06-21 | 2007-01-02 | Univation Technologies, Llc | Methods for producing polymers with control over composition distribution |
| KR100698518B1 (ko) * | 2005-01-17 | 2007-03-21 | 주식회사 에어화인 | 기화식 가습장치 |
| EP2172492A1 (en) * | 2008-10-03 | 2010-04-07 | Ineos Europe Limited | Process for start-up of a polymerisation reaction in a fluidised bed |
| US9926390B2 (en) | 2012-09-28 | 2018-03-27 | Ineos Europe Ag | Method for production of polymer |
| US9550847B2 (en) | 2012-09-28 | 2017-01-24 | Ineos Europe Ag | Method for production of polymer |
| WO2014060231A1 (en) | 2012-10-16 | 2014-04-24 | Ineos Europe Ag | Process for the production of a polymer in a gas phase fluidised bed reactor |
| RU2696875C2 (ru) * | 2014-11-25 | 2019-08-07 | ЮНИВЕЙШН ТЕКНОЛОДЖИЗ, ЭлЭлСи | Способы изменения скорости производства полиолефинов с применением композиции индуцированных конденсирующих агентов |
| CN115672208A (zh) * | 2022-11-17 | 2023-02-03 | 浙江中控技术股份有限公司 | 气相流化床法pe装置聚合反应总压与乙烯分压控制方法 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4564660A (en) * | 1983-06-30 | 1986-01-14 | Union Carbide Corporation | Use of alkylaluminum compounds and hydroxyl-containing compounds to initiate polymerization of ethylene with chromium oxide catalysts |
| FR2572083B1 (fr) * | 1984-10-24 | 1987-06-12 | Bp Chimie Sa | Procede de demarrage de polymerisation ou de copolymerisation en phase gazeuse d'alpha-olefines en presence de systeme catalytique ziegler-natta |
| US5672666A (en) * | 1995-06-05 | 1997-09-30 | Exxon Chemical Patents Inc. | Process for transitioning between incompatible polymerization catalysts |
| FR2772384B1 (fr) * | 1997-12-16 | 2000-02-04 | Bp Chemicals Snc | Procede de demarrage d'une polymerisation d'olefine en phase gazeuse |
-
1997
- 1997-12-16 FR FR9716209A patent/FR2772383B1/fr not_active Expired - Fee Related
-
1998
- 1998-12-14 WO PCT/GB1998/003735 patent/WO1999031142A1/en not_active Ceased
- 1998-12-14 TR TR2000/01850T patent/TR200001850T2/xx unknown
- 1998-12-14 DE DE69812163T patent/DE69812163T2/de not_active Expired - Fee Related
- 1998-12-14 PT PT98959065T patent/PT1040129E/pt unknown
- 1998-12-14 CN CN98813645A patent/CN1121418C/zh not_active Expired - Fee Related
- 1998-12-14 AU AU14993/99A patent/AU735908B2/en not_active Ceased
- 1998-12-14 BR BR9813629-1A patent/BR9813629A/pt not_active Application Discontinuation
- 1998-12-14 PL PL98341238A patent/PL341238A1/xx not_active Application Discontinuation
- 1998-12-14 ZA ZA9811459A patent/ZA9811459B/xx unknown
- 1998-12-14 CA CA002314923A patent/CA2314923A1/en not_active Abandoned
- 1998-12-14 KR KR10-2000-7006603A patent/KR100522271B1/ko not_active Expired - Fee Related
- 1998-12-14 ES ES98959065T patent/ES2194372T3/es not_active Expired - Lifetime
- 1998-12-14 JP JP2000539063A patent/JP2002508407A/ja not_active Withdrawn
- 1998-12-14 EP EP98959065A patent/EP1040129B1/en not_active Expired - Lifetime
- 1998-12-14 AT AT98959065T patent/ATE234328T1/de not_active IP Right Cessation
- 1998-12-15 AR ARP980106378A patent/AR023294A1/es unknown
- 1998-12-15 EG EG154898A patent/EG21507A/xx active
- 1998-12-16 TW TW087120974A patent/TW577899B/zh not_active IP Right Cessation
-
2000
- 2000-06-15 US US09/593,926 patent/US6265502B1/en not_active Expired - Lifetime
- 2000-06-15 NO NO20003079A patent/NO20003079L/no not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| ZA9811459B (en) | 2000-06-14 |
| US6265502B1 (en) | 2001-07-24 |
| TR200001850T2 (tr) | 2000-11-21 |
| EP1040129A1 (en) | 2000-10-04 |
| NO20003079D0 (no) | 2000-06-15 |
| AU1499399A (en) | 1999-07-05 |
| CA2314923A1 (en) | 1999-06-24 |
| AR023294A1 (es) | 2002-09-04 |
| JP2002508407A (ja) | 2002-03-19 |
| NO20003079L (no) | 2000-08-16 |
| WO1999031142A1 (en) | 1999-06-24 |
| KR20010033210A (ko) | 2001-04-25 |
| PT1040129E (pt) | 2003-07-31 |
| EP1040129B1 (en) | 2003-03-12 |
| ES2194372T3 (es) | 2003-11-16 |
| AU735908B2 (en) | 2001-07-19 |
| DE69812163D1 (de) | 2003-04-17 |
| FR2772383A1 (fr) | 1999-06-18 |
| EG21507A (en) | 2001-11-28 |
| ATE234328T1 (de) | 2003-03-15 |
| FR2772383B1 (fr) | 2000-02-04 |
| CN1284967A (zh) | 2001-02-21 |
| CN1121418C (zh) | 2003-09-17 |
| KR100522271B1 (ko) | 2005-10-18 |
| TW577899B (en) | 2004-03-01 |
| DE69812163T2 (de) | 2003-10-23 |
| PL341238A1 (en) | 2001-03-26 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FA10 | Dismissal: dismissal - article 33 of industrial property law | ||
| B11Y | Definitive dismissal - extension of time limit for request of examination expired [chapter 11.1.1 patent gazette] |