BR9813550A - "processo para tratamento de licor contendo lama vermelha de processo bayer e para preparação de copolìmeros em emulsão de alto peso molecular por meio de polimerização via radicais livres de monÈmeros, e, emulsão de um copolìmero de alto peso molecular formado por polimerização via radicais livres de monÈmeros." - Google Patents
"processo para tratamento de licor contendo lama vermelha de processo bayer e para preparação de copolìmeros em emulsão de alto peso molecular por meio de polimerização via radicais livres de monÈmeros, e, emulsão de um copolìmero de alto peso molecular formado por polimerização via radicais livres de monÈmeros."Info
- Publication number
- BR9813550A BR9813550A BR9813550-3A BR9813550A BR9813550A BR 9813550 A BR9813550 A BR 9813550A BR 9813550 A BR9813550 A BR 9813550A BR 9813550 A BR9813550 A BR 9813550A
- Authority
- BR
- Brazil
- Prior art keywords
- molecular weight
- monomers
- high molecular
- emulsion
- free radicals
- Prior art date
Links
- 239000000839 emulsion Substances 0.000 title abstract 5
- 238000004131 Bayer process Methods 0.000 title abstract 3
- 229920001577 copolymer Polymers 0.000 title abstract 3
- 238000000034 method Methods 0.000 title abstract 3
- 238000006116 polymerization reaction Methods 0.000 title abstract 3
- 239000010802 sludge Substances 0.000 title abstract 2
- 239000000178 monomer Substances 0.000 title 3
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 abstract 6
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract 4
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 4
- XJBRSZAYOKVFRH-UHFFFAOYSA-N (5-methyl-2-propan-2-ylcyclohexyl) prop-2-enoate Chemical compound CC(C)C1CCC(C)CC1OC(=O)C=C XJBRSZAYOKVFRH-UHFFFAOYSA-N 0.000 abstract 1
- 229920002319 Poly(methyl acrylate) Polymers 0.000 abstract 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 229910001570 bauxite Inorganic materials 0.000 abstract 1
- 238000005352 clarification Methods 0.000 abstract 1
- 238000001914 filtration Methods 0.000 abstract 1
- 229920006158 high molecular weight polymer Polymers 0.000 abstract 1
- 238000005065 mining Methods 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 238000011084 recovery Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/54—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
- C02F1/56—Macromolecular compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D21/00—Separation of suspended solid particles from liquids by sedimentation
- B01D21/01—Separation of suspended solid particles from liquids by sedimentation using flocculating agents
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F7/00—Compounds of aluminium
- C01F7/02—Aluminium oxide; Aluminium hydroxide; Aluminates
- C01F7/04—Preparation of alkali metal aluminates; Aluminium oxide or hydroxide therefrom
- C01F7/06—Preparation of alkali metal aluminates; Aluminium oxide or hydroxide therefrom by treating aluminous minerals or waste-like raw materials with alkali hydroxide, e.g. leaching of bauxite according to the Bayer process
- C01F7/0646—Separation of the insoluble residue, e.g. of red mud
- C01F7/0653—Separation of the insoluble residue, e.g. of red mud characterised by the flocculant added to the slurry
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- Geochemistry & Mineralogy (AREA)
- Geology (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Separation Of Suspended Particles By Flocculating Agents (AREA)
Abstract
"PROCESSOS PARA TRATAMENTO DE LICOR CONTENDO LAMA VERMELHA DE PROCESSO BAYER E PARA PREPARAçãO DE COPOLìMEROS EM EMULSãO DE ALTO PESO MOLECULAR POR MEIO DE POLIMERIZAçãO VIA RADICAIS LIVRES DE MONÈMEROS, E, EMULSãO DE UM COPOLìMERO DE ALTO PESO MOLECULAR FORMADO POR POLIMERIZAçãO VIA RADICAIS LIVRES DE MONÈMEROS" A presente invenção refere-se às melhorias no processo de mineração Bayer, usado para a recuperação de alumina de minério de bauxita. Polímeros em emulsão aquosa contínua são vantajosamente empregados para melhorar a clarificação, filtração e controle de incrustação da lama vermelha contendo licores gerados durante o processo Bayer. Polímeros de alto peso molecular preferidos são poli(acrilato de metila/ácido acrílico), poli(acrilato de metila), poli(acetato de vinila/ácido acrílico/acrilato de mentila) e uma combinação de poli(acrilato de metila/ácido acrílico) de alto peso molecular com um poli(acrilato de metila/ácido acrílico) de baixo peso molecular.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/991,103 US6036869A (en) | 1997-12-12 | 1997-12-12 | Water continuous methyl acrylate emulsion polymers for improved flocculation of red mud in the Bayer process |
| US09/074,706 US6048463A (en) | 1997-12-12 | 1998-05-08 | Water continuous methyl acrylate emulsion polymer combinations and methyl acrylate emulsion homopolymers for improved flocculation of red mud in the bayer process |
| US09/203,314 US6086771A (en) | 1997-12-12 | 1998-11-30 | Water continuous emulsion polymers for improving scale control in the bayer process |
| PCT/US1998/026207 WO1999030794A1 (en) | 1997-12-12 | 1998-12-10 | Water continuous emulsion polymers for improving the efficiency of filtration, clarification and scale control in the bayer process |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BR9813550A true BR9813550A (pt) | 2000-10-10 |
| BR9813550B1 BR9813550B1 (pt) | 2009-05-05 |
Family
ID=27372530
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI9813550-3A BR9813550B1 (pt) | 1997-12-12 | 1998-12-10 | processo para preparação de copolìmeros de alto peso molecular em emulsão, processo para floculação de sólidos suspensos no licor contendo lama vermelha do processo bayer, emulsão de um copolìmero de alto peso molecular, e, processo para inibir a formação de incrustação em equipamento de processo bayer. |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US6086771A (pt) |
| EP (1) | EP1051227B1 (pt) |
| AU (1) | AU746403B2 (pt) |
| BR (1) | BR9813550B1 (pt) |
| CA (1) | CA2314946A1 (pt) |
| WO (1) | WO1999030794A1 (pt) |
Families Citing this family (26)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6372882B1 (en) * | 2000-04-03 | 2002-04-16 | Nalco Chemical Company | Method for producing substantially dry water-insoluble polymers for improved flocculation in the bayer process |
| US7138472B2 (en) * | 2001-01-29 | 2006-11-21 | Nalco Company | High molecular weight polymers containing pendant salicylic acid groups for clarifying bayer process liquors |
| US6527959B1 (en) | 2001-01-29 | 2003-03-04 | Ondeo Nalco Company | Method of clarifying bayer process liquors using salicylic acid containing polymers |
| DE10113294A1 (de) * | 2001-03-16 | 2002-09-19 | Stockhausen Chem Fab Gmbh | Bildung von Aluminiumoxidhydrat-haltigen Kristallen aus kaustischen Mutterlaugen |
| US7390415B2 (en) * | 2002-07-22 | 2008-06-24 | Cytec Technology Corp. | Method and compositions for preventing or reducing aluminosilicate scale in alkaline industrial processes |
| US6814873B2 (en) * | 2002-07-22 | 2004-11-09 | Cytec Technology Corp. | Method of preventing or reducing aluminosilicate scale in a bayer process |
| US20060124553A1 (en) * | 2002-07-22 | 2006-06-15 | Taylor Matthew L | Method of preventing or reducing aluminosilicate scale in high level nuclear wastes |
| FR2846319B1 (fr) * | 2002-10-25 | 2004-12-10 | Pechiney Aluminium | Procede d'attaque de la bauxite ameliorant la filtrabilite des boues en sortie d'attaque |
| DE102004017034A1 (de) * | 2004-04-02 | 2005-10-20 | Stockhausen Chem Fab Gmbh | Verwendung von Copolymerisaten zur Verringerung von Ausfällungen und Belägen durch anorganische und organische Verunreinigungen im Bayer Prozess zur Gewinnung von Aluminiumhydroxid |
| CN101115776B (zh) * | 2005-02-09 | 2012-01-11 | Cytec技术有限公司 | 防止或减轻工业方法中铝硅酸盐污垢的方法 |
| US20080107578A1 (en) * | 2006-11-07 | 2008-05-08 | Jing Wang | The recovery of alumina trihydrate during the bayer process using a water continuous polymer |
| US8628737B2 (en) * | 2006-11-09 | 2014-01-14 | Nalco Company | Transfer of slurry in a bayer process |
| CN101164887B (zh) * | 2007-09-25 | 2010-06-16 | 中国铝业股份有限公司 | 氢氧化铝结疤的回收利用方法 |
| CN101412616B (zh) * | 2007-10-16 | 2011-06-08 | 贵州平坝宏大铝化工有限公司 | 一种制块石灰烧结法处理拜尔法赤泥的方法 |
| US9284625B2 (en) * | 2007-11-20 | 2016-03-15 | Nalco Company | Use of polyols as scale control reagents in the mining processes |
| US9487408B2 (en) | 2009-09-25 | 2016-11-08 | Nalco Company | Reducing aluminosilicate scale in the bayer process |
| US8545776B2 (en) * | 2009-09-25 | 2013-10-01 | Nalco Company | Reducing aluminosilicate scale in the Bayer process |
| US8889096B2 (en) * | 2009-09-25 | 2014-11-18 | Nalco Company | Reducing aluminosilicate scale in the bayer process |
| US9416020B2 (en) | 2009-09-25 | 2016-08-16 | Nalco Company | Surfactant based small molecules for reducing aluminosilicate scale in the bayer process |
| US9416490B2 (en) | 2010-03-10 | 2016-08-16 | Nalco Company | Cross-linked glycerol based polymers as digestion aids for improving wood pulping processes |
| US8728275B2 (en) | 2012-07-27 | 2014-05-20 | Ecolab Usa Inc. | Glycerol-based polymers for reducing deposition of organic contaminants in papermaking processes |
| CA2824338C (en) * | 2011-01-17 | 2015-04-07 | Clearflow Enviro Systems Group Inc. | Composition and system for flocculating or settling solids from liquids and methods for using same |
| EP2886178A1 (en) * | 2013-12-20 | 2015-06-24 | Rio Tinto Alcan International Limited | Process and installation for producing alumina trihydrate by alkaline digestion of bauxite ore |
| AU2014376173B2 (en) * | 2014-01-09 | 2019-01-17 | Nalco Company | Surfactant based small molecules for reducing aluminosilicate scale in the Bayer process |
| CN109437217A (zh) * | 2018-10-30 | 2019-03-08 | 东北大学设计研究院(有限公司) | 一种赤泥处理及氧化铝生产的方法 |
| CN110217811A (zh) * | 2019-06-27 | 2019-09-10 | 沈阳铝镁设计研究院有限公司 | 一种串联法氧化铝生产工艺 |
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| US3023162A (en) * | 1956-04-10 | 1962-02-27 | Rohm & Haas | Dewatering aqueous suspensions with quaternized dialkylaminoalkyl acrylates or methacrylates |
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| US3390959A (en) * | 1965-04-30 | 1968-07-02 | Nalco Chemical Co | Process of making alumina |
| US3445187A (en) * | 1966-05-25 | 1969-05-20 | Nalco Chemical Co | Process for separation of red mud from dissolved alumina |
| US3541009A (en) * | 1968-12-18 | 1970-11-17 | Nalco Chemical Co | Polymer-polysaccharide-caustic alkali compositions and process of separating solids from aqueous suspensions therewith |
| US3681012A (en) * | 1969-06-17 | 1972-08-01 | Nalco Chemical Co | Process for making alumina |
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| US4767540A (en) * | 1987-02-11 | 1988-08-30 | American Cyanamid Company | Polymers containing hydroxamic acid groups for reduction of suspended solids in bayer process streams |
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| US5091159A (en) * | 1991-06-10 | 1992-02-25 | Nalco Chemical Company | Use of dextran as a filtration aid for thickener overflow filtration in Kelly filters in the Bayer process |
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| US5286391A (en) * | 1993-02-04 | 1994-02-15 | Nalco Chemical Company | Red mud flocculation |
| US5346628A (en) * | 1993-10-29 | 1994-09-13 | Nalco Chemical Company | Polymers for flocculating red mud from bayer process liquors |
| US5415782A (en) * | 1993-11-22 | 1995-05-16 | Nalco Chemical Company | Method for the alteration of siliceous materials from bayer process liquors |
| US5534235A (en) * | 1995-09-05 | 1996-07-09 | Nalco Chemical Company | Polymers containing phosphonic acid groups for the treatment of red mud in the Bayer process |
| JPH07278233A (ja) * | 1994-04-13 | 1995-10-24 | Sekisui Chem Co Ltd | アクリル系エマルジョン型粘着剤の製造方法、アクリル系エマルジョン型粘着剤、粘着テープまたはシートおよび表面保護材 |
| US5601726A (en) * | 1994-06-06 | 1997-02-11 | Cytec Technology Corp. | Hydroxameted polymers in the bayer process to reduce solids |
| BR9508580A (pt) * | 1994-08-12 | 1997-12-23 | Cytec Tech Corp | Processo para estabilizar e para empilhar uma suspensão aquosa e composição possuindo características de fluxo estabilizadas |
| EP0733648A1 (en) * | 1995-03-23 | 1996-09-25 | Kao Corporation | Process for producing polymer particles |
| AU707514B2 (en) * | 1995-04-05 | 1999-07-15 | Nalco Chemical Company | Biopolymer use as a sand filter aid |
| US5951955A (en) * | 1995-11-07 | 1999-09-14 | Cytec Technology Corp. | Concentration of solids in the Bayer process |
| US5733459A (en) * | 1996-04-29 | 1998-03-31 | Cytec Technology Corp. | Use of hydroxamated polymers to alter bayer process scale |
| US5733460A (en) * | 1996-04-29 | 1998-03-31 | Cytec Technology Corp. | Use of hydroxamated polymers to alter Bayer Process scale |
-
1998
- 1998-11-30 US US09/203,314 patent/US6086771A/en not_active Expired - Lifetime
- 1998-12-10 EP EP98963024A patent/EP1051227B1/en not_active Expired - Lifetime
- 1998-12-10 WO PCT/US1998/026207 patent/WO1999030794A1/en not_active Ceased
- 1998-12-10 CA CA002314946A patent/CA2314946A1/en not_active Abandoned
- 1998-12-10 AU AU18136/99A patent/AU746403B2/en not_active Ceased
- 1998-12-10 BR BRPI9813550-3A patent/BR9813550B1/pt not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| CA2314946A1 (en) | 1999-06-24 |
| EP1051227B1 (en) | 2006-03-08 |
| AU1813699A (en) | 1999-07-05 |
| AU746403B2 (en) | 2002-05-02 |
| EP1051227A1 (en) | 2000-11-15 |
| US6086771A (en) | 2000-07-11 |
| EP1051227A4 (en) | 2001-11-28 |
| WO1999030794A1 (en) | 1999-06-24 |
| BR9813550B1 (pt) | 2009-05-05 |
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| B07A | Application suspended after technical examination (opinion) [chapter 7.1 patent gazette] | ||
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| B06A | Patent application procedure suspended [chapter 6.1 patent gazette] | ||
| B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
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Free format text: PRAZO DE VALIDADE: 10 (DEZ) ANOS CONTADOS A PARTIR DE 30/06/2009, OBSERVADAS AS CONDICOES LEGAIS. |
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| B21F | Lapse acc. art. 78, item iv - on non-payment of the annual fees in time |
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| B24J | Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12) |
Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2284 DE 14-10-2014 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013. |