BR9813034A - Crystalline double metal cyanide catalysts for the preparation of polyether polyols - Google Patents
Crystalline double metal cyanide catalysts for the preparation of polyether polyolsInfo
- Publication number
- BR9813034A BR9813034A BR9813034-0A BR9813034A BR9813034A BR 9813034 A BR9813034 A BR 9813034A BR 9813034 A BR9813034 A BR 9813034A BR 9813034 A BR9813034 A BR 9813034A
- Authority
- BR
- Brazil
- Prior art keywords
- preparation
- metal cyanide
- double metal
- polyether polyols
- cyanide catalysts
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 5
- 239000002184 metal Substances 0.000 title abstract 4
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 title abstract 3
- 229920005862 polyol Polymers 0.000 title abstract 3
- 239000004721 Polyphenylene oxide Substances 0.000 title abstract 2
- 229920000570 polyether Polymers 0.000 title abstract 2
- 150000003077 polyols Chemical class 0.000 title abstract 2
- 125000002947 alkylene group Chemical group 0.000 abstract 1
- 239000011230 binding agent Substances 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- 150000002825 nitriles Chemical class 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 239000007858 starting material Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
- C08G65/02—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring
- C08G65/26—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds
- C08G65/2642—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from cyclic ethers by opening of the heterocyclic ring from cyclic ethers and other compounds characterised by the catalyst used
- C08G65/2645—Metals or compounds thereof, e.g. salts
- C08G65/2663—Metal cyanide catalysts, i.e. DMC's
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/24—Nitrogen compounds
- B01J27/26—Cyanides
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- Toxicology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- General Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Catalysts (AREA)
- Polyethers (AREA)
- Polyesters Or Polycarbonates (AREA)
Abstract
Patente de Invenção: <B>"CATALISADORES DE CIANETO DE METAL DUPLO CRISTALINOS PARA A PREPARAçãO DE POLIéTER-POLIóIS"<D>. A invenção refere-se a catalisadores (DMC) de cianeto de metal duplo substancialmente cristalinos, altamente ativos para a preparação de poliéter-polióis mediante poliadição de óxidos de alquileno com compostos de partida que apresentam átomos de hidrogênio ativos, sendo que o catalisador a) contém compostos de cianeto de metal duplo, b) contém ligantes de complexo orgânico diferentes de c) e c) polímeros funcionalizados. Os catalisadores de acordo com a invenção possuem atividade fortemente aumentada para a preparação do polieterpoliol.Invention Patent: <B> "CRYSTALLINE DOUBLE METAL CYANIDE CATALYSTS FOR THE PREPARATION OF POLYETER-POLYOLS" <D>. The invention relates to substantially crystalline double metal cyanide catalysts (DMC), highly active for the preparation of polyether polyols by polyaddition of alkylene oxides with starting compounds which have active hydrogen atoms, the catalyst being a) contains double metal cyanide compounds, b) contains organic complex binders other than c) and c) functionalized polymers. The catalysts according to the invention have strongly increased activity for the preparation of polyetherpolyol.
Applications Claiming Priority (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19745120A DE19745120A1 (en) | 1997-10-13 | 1997-10-13 | Double metal cyanide catalyst useful for production of polyetherpolyols |
| DE19757574A DE19757574A1 (en) | 1997-12-23 | 1997-12-23 | Double metal cyanide catalyst |
| DE19810269A DE19810269A1 (en) | 1998-03-10 | 1998-03-10 | Improved double metal cyanide catalysts for the production of polyether polyols |
| DE19834573A DE19834573A1 (en) | 1998-07-31 | 1998-07-31 | Double metal cyanide catalysts for the preparation of polyether polyols |
| DE19842382A DE19842382A1 (en) | 1998-09-16 | 1998-09-16 | Double metal cyanide catalyst |
| PCT/EP1998/006312 WO1999019063A1 (en) | 1997-10-13 | 1998-10-05 | Crystalline double metal cyanide catalysts for producing polyether polyols |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BR9813034A true BR9813034A (en) | 2000-08-15 |
Family
ID=27512606
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR9813034-0A BR9813034A (en) | 1997-10-13 | 1998-10-05 | Crystalline double metal cyanide catalysts for the preparation of polyether polyols |
Country Status (12)
| Country | Link |
|---|---|
| US (1) | US6323375B1 (en) |
| EP (1) | EP1034035B1 (en) |
| JP (1) | JP2001519468A (en) |
| KR (1) | KR100544929B1 (en) |
| CN (1) | CN1273217C (en) |
| AU (1) | AU9542598A (en) |
| BR (1) | BR9813034A (en) |
| CA (1) | CA2306378C (en) |
| DE (1) | DE59808655D1 (en) |
| ES (1) | ES2201537T3 (en) |
| ID (1) | ID24172A (en) |
| WO (1) | WO1999019063A1 (en) |
Families Citing this family (37)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19834573A1 (en) * | 1998-07-31 | 2000-02-03 | Bayer Ag | Double metal cyanide catalysts for the preparation of polyether polyols |
| DE19842383A1 (en) * | 1998-09-16 | 2000-03-23 | Bayer Ag | Metal cyanide catalyst, useful for the production of polyether polyols, comprises double metal cyanide compound, carboxylic acid ester of a multi-valent alcohol and an organic complex ligand. |
| DE19905611A1 (en) * | 1999-02-11 | 2000-08-17 | Bayer Ag | Double metal cyanide catalysts for the production of polyether polyols |
| DE19913260C2 (en) * | 1999-03-24 | 2001-07-05 | Bayer Ag | Double metal cyanide catalysts for the production of polyether polyols |
| DE19918727A1 (en) | 1999-04-24 | 2000-10-26 | Bayer Ag | Polyether polyol useful for production of polyurethanes and/or polyureas has poly(oxyethylene/oxypropylene) endblock prepared in presence of double metal cyanide catalyst |
| DE19920552A1 (en) * | 1999-05-05 | 2000-11-16 | Bayer Ag | Double metal cyanide catalyst used for polyether polyol preparation comprises double metal cyanide compounds, organic complex ligand(s) and alpha,beta-unsaturated carboxylic acid esters |
| US6613714B2 (en) * | 1999-06-02 | 2003-09-02 | Basf Aktiengesellschaft | Multimetal cyanide compounds, their preparation and their use |
| US6800583B2 (en) | 1999-06-02 | 2004-10-05 | Basf Aktiengesellschaft | Suspension of multimetal cyanide compounds, their preparation and their use |
| DE19928156A1 (en) | 1999-06-19 | 2000-12-28 | Bayer Ag | Polyetherpolyols for preparation of soft polyurethane foams avoid increase in monofunctional polyethers and decrease in functionality with increased chain length and difficulty in alkoxylation of conventional starting compounds |
| JP2003504465A (en) * | 1999-07-09 | 2003-02-04 | ザ ダウ ケミカル カンパニー | Method for producing metal cyanide catalyst using polycarboxylic acid |
| DE19937114C2 (en) | 1999-08-06 | 2003-06-18 | Bayer Ag | Process for the preparation of polyether polyols |
| DE19953546A1 (en) * | 1999-11-08 | 2001-05-10 | Bayer Ag | Double metal cyanide catalysts for the production of polyether polyols |
| DE19958355A1 (en) * | 1999-12-03 | 2001-06-07 | Bayer Ag | Process for the production of DMC catalysts |
| ES2223846T3 (en) * | 2000-04-20 | 2005-03-01 | Bayer Materialscience Ag | PROCEDURE FOR THE PREPARATION OF DMC CATALYSTS. |
| US6642171B2 (en) | 2000-04-28 | 2003-11-04 | Synuthane International, Inc. | Double metal cyanide catalysts containing polyglycol ether complexing agents |
| DE50113038D1 (en) | 2000-11-28 | 2007-10-31 | Henkel Kgaa | CYCLODEXTRINE -GLUCANOTRANSFERASE (CG TASE) FROM BACILLUS AGARADHERENS (DSM 9948) AND WASHING AND CLEANING AGENT WITH THIS NEW CYCLODEXTRIN GLUCANOTRANSFERASE |
| DE10108484A1 (en) | 2001-02-22 | 2002-09-05 | Bayer Ag | Improved process for the production of polyether polyols |
| DE10108485A1 (en) | 2001-02-22 | 2002-09-05 | Bayer Ag | Improved process for the preparation of polyether polyols |
| KR100418058B1 (en) * | 2001-04-18 | 2004-02-14 | 에스케이씨 주식회사 | Catalyst of double metal cyanide complex for polyol manufacturing |
| DE10122020A1 (en) * | 2001-05-07 | 2002-11-14 | Bayer Ag | Double metal cyanide catalysts for the production of polyether polyols |
| DE10122019A1 (en) * | 2001-05-07 | 2002-11-14 | Bayer Ag | Double metal cyanide catalysts for the production of polyether polyols |
| ES2199666B1 (en) | 2002-02-25 | 2005-06-01 | Repsol Quimica, S.A. | POLYOLETER PRODUCTION PROCEDURE. |
| MXPA04009145A (en) * | 2002-03-21 | 2004-11-26 | Dow Global Technologies Inc | Method for preparing metal cyanide catalyst complexes using partially miscible complexing agents. |
| US6797665B2 (en) | 2002-05-10 | 2004-09-28 | Bayer Antwerpen | Double-metal cyanide catalysts for preparing polyether polyols |
| US6835801B2 (en) * | 2002-07-19 | 2004-12-28 | Bayer Antwerp, N.V. | Activated starter mixtures and the processes related thereto |
| US7094811B2 (en) * | 2002-10-03 | 2006-08-22 | Bayer Corporation | Energy absorbing flexible foams produced in part with a double metal cyanide catalyzed polyol |
| MXPA05004922A (en) * | 2002-11-07 | 2005-08-18 | Dow Global Technologies Inc | Method for preparing metal cyanide catalysts using polymerizable complexing agents. |
| ATE353348T1 (en) * | 2003-03-07 | 2007-02-15 | Dow Global Technologies Inc | CONTINUOUS PROCESS AND SYSTEM FOR PRODUCING POLYETHER POLYOLS |
| CN1308078C (en) * | 2004-11-29 | 2007-04-04 | 黎明化工研究院 | Catalyst of manganese cobalt hexacyanide complex, its preparation and usage |
| US7482480B2 (en) * | 2005-10-10 | 2009-01-27 | Council Of Scientific & Industrial Research | Process for the preparation of hydrocarbon fuel |
| WO2010072769A1 (en) | 2008-12-23 | 2010-07-01 | Basf Se | Method for producing polyether block copolymers |
| DE102010040517A1 (en) | 2010-09-09 | 2012-03-15 | Bayer Materialscience Aktiengesellschaft | Process for the preparation of polyether polyols |
| EP2548908A1 (en) * | 2011-07-18 | 2013-01-23 | Bayer MaterialScience AG | Method for manufacturing polyether polyols |
| EP2794711B1 (en) | 2011-12-20 | 2020-06-10 | Covestro Deutschland AG | Hydroxy aminopolymers and method for there manufacture |
| EP3609861A1 (en) * | 2017-04-10 | 2020-02-19 | Basf Se | Low volatile organic anti-oxidation stabilisers for polymeric systems, their production and use |
| KR102584168B1 (en) * | 2017-05-10 | 2023-10-05 | 다우 글로벌 테크놀로지스 엘엘씨 | Polyether polymerization method |
| BR112022014672A2 (en) * | 2020-01-31 | 2022-09-20 | Dow Global Technologies Llc | PROCESS FOR SEPARATING A FINE CATALYST COMPONENT AND CATALYST PRODUCT |
Family Cites Families (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1063525A (en) | 1963-02-14 | 1967-03-30 | Gen Tire & Rubber Co | Organic cyclic oxide polymers, their preparation and tires prepared therefrom |
| US3829505A (en) | 1970-02-24 | 1974-08-13 | Gen Tire & Rubber Co | Polyethers and method for making the same |
| US3941849A (en) | 1972-07-07 | 1976-03-02 | The General Tire & Rubber Company | Polyethers and method for making the same |
| US5158922A (en) | 1992-02-04 | 1992-10-27 | Arco Chemical Technology, L.P. | Process for preparing metal cyanide complex catalyst |
| US5712216A (en) | 1995-05-15 | 1998-01-27 | Arco Chemical Technology, L.P. | Highly active double metal cyanide complex catalysts |
| CA2138063C (en) * | 1993-12-23 | 2007-02-20 | Bi Le-Khac | Polyurethane foam-supported double metal cyanide catalysts for polyol synthesis |
| US5482908A (en) * | 1994-09-08 | 1996-01-09 | Arco Chemical Technology, L.P. | Highly active double metal cyanide catalysts |
| US5627122A (en) * | 1995-07-24 | 1997-05-06 | Arco Chemical Technology, L.P. | Highly active double metal cyanide complex catalysts |
| US5545601A (en) * | 1995-08-22 | 1996-08-13 | Arco Chemical Technology, L.P. | Polyether-containing double metal cyanide catalysts |
| US5639705A (en) | 1996-01-19 | 1997-06-17 | Arco Chemical Technology, L.P. | Double metal cyanide catalysts and methods for making them |
| US5627120A (en) | 1996-04-19 | 1997-05-06 | Arco Chemical Technology, L.P. | Highly active double metal cyanide catalysts |
| US5714428A (en) | 1996-10-16 | 1998-02-03 | Arco Chemical Technology, L.P. | Double metal cyanide catalysts containing functionalized polymers |
| US6013596A (en) * | 1998-05-18 | 2000-01-11 | Arco Chemical Technology, L.P. | Double metal cyanide catalysts containing cyclic, bidentate complexing agents |
-
1998
- 1998-10-05 US US09/509,979 patent/US6323375B1/en not_active Expired - Lifetime
- 1998-10-05 BR BR9813034-0A patent/BR9813034A/en not_active IP Right Cessation
- 1998-10-05 ES ES98949006T patent/ES2201537T3/en not_active Expired - Lifetime
- 1998-10-05 JP JP2000515686A patent/JP2001519468A/en active Pending
- 1998-10-05 CN CNB988101351A patent/CN1273217C/en not_active Expired - Fee Related
- 1998-10-05 WO PCT/EP1998/006312 patent/WO1999019063A1/en not_active Ceased
- 1998-10-05 AU AU95425/98A patent/AU9542598A/en not_active Abandoned
- 1998-10-05 DE DE59808655T patent/DE59808655D1/en not_active Expired - Lifetime
- 1998-10-05 KR KR1020007003925A patent/KR100544929B1/en not_active Expired - Fee Related
- 1998-10-05 CA CA002306378A patent/CA2306378C/en not_active Expired - Fee Related
- 1998-10-05 EP EP98949006A patent/EP1034035B1/en not_active Expired - Lifetime
- 1998-10-05 ID IDW20000653D patent/ID24172A/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| WO1999019063A1 (en) | 1999-04-22 |
| EP1034035A1 (en) | 2000-09-13 |
| KR100544929B1 (en) | 2006-01-24 |
| ID24172A (en) | 2000-07-13 |
| CA2306378A1 (en) | 1999-04-22 |
| JP2001519468A (en) | 2001-10-23 |
| EP1034035B1 (en) | 2003-06-04 |
| CA2306378C (en) | 2007-07-17 |
| DE59808655D1 (en) | 2003-07-10 |
| ES2201537T3 (en) | 2004-03-16 |
| KR20010015747A (en) | 2001-02-26 |
| CN1273217C (en) | 2006-09-06 |
| CN1275929A (en) | 2000-12-06 |
| US6323375B1 (en) | 2001-11-27 |
| AU9542598A (en) | 1999-05-03 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B08F | Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette] |
Free format text: REFERENTE A 10A ANUIDADE |
|
| B08K | Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette] |
Free format text: REFERENTE AO DESPACHO 8.6 DA RPI 1986 DE 27/03/2009. |