BR9812539A - Processo para a preparação de resinas de polieterésteres de diciclopentadieno - Google Patents
Processo para a preparação de resinas de polieterésteres de diciclopentadienoInfo
- Publication number
- BR9812539A BR9812539A BR9812539-7A BR9812539A BR9812539A BR 9812539 A BR9812539 A BR 9812539A BR 9812539 A BR9812539 A BR 9812539A BR 9812539 A BR9812539 A BR 9812539A
- Authority
- BR
- Brazil
- Prior art keywords
- dcpd
- resins
- polyetherester
- polyether
- thermosets
- Prior art date
Links
- 239000004721 Polyphenylene oxide Substances 0.000 title abstract 4
- 238000000034 method Methods 0.000 title abstract 4
- 229920000570 polyether Polymers 0.000 title abstract 4
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 title abstract 2
- 150000002148 esters Chemical class 0.000 title 1
- HECLRDQVFMWTQS-UHFFFAOYSA-N Dicyclopentadiene Chemical compound C1C2C3CC=CC3C1C=C2 HECLRDQVFMWTQS-UHFFFAOYSA-N 0.000 abstract 7
- 229920005989 resin Polymers 0.000 abstract 7
- 239000011347 resin Substances 0.000 abstract 7
- 229920001225 polyester resin Polymers 0.000 abstract 5
- 239000004645 polyester resin Substances 0.000 abstract 5
- 229920001187 thermosetting polymer Polymers 0.000 abstract 4
- 238000003780 insertion Methods 0.000 abstract 3
- 230000037431 insertion Effects 0.000 abstract 3
- 150000002009 diols Chemical class 0.000 abstract 2
- 239000000203 mixture Substances 0.000 abstract 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 abstract 1
- 230000015556 catabolic process Effects 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 230000009257 reactivity Effects 0.000 abstract 1
- 230000002195 synergetic effect Effects 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/66—Polyesters containing oxygen in the form of ether groups
- C08G63/668—Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/676—Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
- C08G63/52—Polycarboxylic acids or polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation
- C08G63/54—Polycarboxylic acids or polyhydroxy compounds in which at least one of the two components contains aliphatic unsaturation the acids or hydroxy compounds containing carbocyclic rings
- C08G63/553—Acids or hydroxy compounds containing cycloaliphatic rings, e.g. Diels-Alder adducts
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/06—Unsaturated polyesters
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyesters Or Polycarbonates (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Patente de Invenção <B>"PROCESSO PARA PREPARAçãO DE RESINAS DE POLIETERéSTER DE DICICLOPENTADIENO"<D> Revela-se uma maneira de baixo custo para modular a reatividade e o índice de acidez de resinas termorrígidas de polieteréster. São descritos processos "início" e "fim" para a preparação de resinas de polieteréster modificadas com diciclopentadieno (DCPD). O processo "início" compreende, primeiro, um poliéter, DCPD, um diol, um catalisador de inserção e um derivado de ácido carboxílico, para produzir uma mistura que contém o poliéter e um aduto de DCPD-diéster de diol. Aumentando-se a temperatura provoca-se a inserção do DCPD-diéster de diol ao poliéter, para dar uma resina de polieteréster de DCPD. O processo "fim" reage uma resina de polieteréster preparada por inserção com DCPD para dar uma resina de polieteréster de DCPD. Comparadas com resinas de poliéster de DCPD, aquelas da invenção dão termorrígidos mais flexíveis. Comparadas com resinas de polieteréster não modificadas, as resinas de polieteréster de DCPD oferecem, aos formuladores, mais controle sobre a cura, o que elimina a distorção do molde e o encolhimento ou a quebra de partes termorrígidas. Termorrígidos a partir de misturas das resinas em questão e resinas de poliéster de DCPD mostram aperfeiçoamentos de propriedades sinergéticas, comparados com termorrígidos a partir de cada resina isoladamente.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/937,778 US5780558A (en) | 1997-09-25 | 1997-09-25 | Process for making dicyclopentadiene polyetherester resins |
| PCT/EP1998/005423 WO1999015574A1 (en) | 1997-09-25 | 1998-08-26 | Process for making dicyclopentadiene polyetherester resins |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BR9812539A true BR9812539A (pt) | 2000-07-25 |
Family
ID=25470391
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR9812539-7A BR9812539A (pt) | 1997-09-25 | 1998-08-26 | Processo para a preparação de resinas de polieterésteres de diciclopentadieno |
Country Status (10)
| Country | Link |
|---|---|
| US (1) | US5780558A (pt) |
| EP (1) | EP1023355B1 (pt) |
| JP (1) | JP2001517718A (pt) |
| CN (1) | CN1271369A (pt) |
| AU (1) | AU737897B2 (pt) |
| BR (1) | BR9812539A (pt) |
| CA (1) | CA2301212A1 (pt) |
| DE (1) | DE69808961T2 (pt) |
| ES (1) | ES2181277T3 (pt) |
| WO (1) | WO1999015574A1 (pt) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19600149A1 (de) * | 1996-01-04 | 1997-07-10 | Beck & Co Ag Dr | Tränk-, Verguß- und Überzugsmassen |
| DE69803400T2 (de) * | 1997-10-10 | 2002-08-29 | Cook Composites And Polymers Co., North Kansas City | Wasserbeständige ungesättigte polyesterharzmischungen |
| US5952436A (en) * | 1998-01-13 | 1999-09-14 | Arco Chemical Technology, L.P. | Process for making water-resistant polyetherester resins and thermosets |
| US6348270B1 (en) | 1999-09-01 | 2002-02-19 | Reichhold Inc. | High performance polyetherester containing laminating resin compositions |
| US6977282B1 (en) | 2004-08-11 | 2005-12-20 | Lyondell Chemical Technology, L.P. | Preparation of dicyclopentadiene-containing unsaturated polyesters |
| CN102206310A (zh) * | 2011-04-22 | 2011-10-05 | 常州华科树脂有限公司 | 风机叶片类用真空导入不饱和聚酯树脂及其制备方法 |
| CN102504122B (zh) * | 2011-09-28 | 2013-12-04 | 嘉宝莉化工集团股份有限公司 | 高流平涂料用双环戊二烯型不饱和聚酯树脂的制备方法 |
| CA3008681C (en) * | 2015-12-21 | 2023-12-05 | Myriant Corporation | Dicyclopentadiene modified ester oligomers useful in coating applications |
| EP4174111B1 (en) * | 2021-10-29 | 2025-01-15 | SHPP Global Technologies B.V. | Copolymers derived from dicyclopentadiene |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1570550A1 (de) * | 1965-03-19 | 1970-04-02 | Bayer Ag | Verfahren zum Herstellen von Spachtelmassen und Formkoerpern |
| US3860052A (en) * | 1972-01-11 | 1975-01-14 | Du Pont | Cordless vehicle tire |
| US4148765A (en) * | 1977-01-10 | 1979-04-10 | The Dow Chemical Company | Polyester resins containing dicyclopentadiene |
| US4140724A (en) * | 1977-08-11 | 1979-02-20 | Rohm And Haas Company | Selective preparation of polyol monoethers of dicyclopentadiene |
| US4753982A (en) * | 1982-08-29 | 1988-06-28 | The Dow Chemical Company | Vinyl ester and norbornyl terminated unsaturated polyester (polyesteramide) blends |
| US5319006A (en) * | 1992-11-23 | 1994-06-07 | Arco Chemical Technology, L.P. | Preparation of polyesters from polyethers by an ester-insertion process |
| US5436313A (en) * | 1994-03-30 | 1995-07-25 | Arco Chemical Technology, L.P. | Process for making a polyetherester |
| US5436314A (en) * | 1994-04-18 | 1995-07-25 | Arco Chemical Technology, L.P. | Process for making a polyetherester by insertion of a carboxylic acid into a polyether |
| US5612444A (en) * | 1995-03-28 | 1997-03-18 | Arco Chemical Technology, L.P. | Process for making polyetheresters with high aromatic ester content |
| US5684086A (en) * | 1995-07-28 | 1997-11-04 | Arco Chemical Technology, Inc. | Cured thermosets and glass-reinforced composites from unsaturated polyetherester resins |
| US5696225A (en) * | 1996-02-28 | 1997-12-09 | Arco Chemical Technology, L.P. | Process for making high-performance polyetherester resins and thermosets |
| US5677396A (en) * | 1996-03-20 | 1997-10-14 | Arco Chemical Technology, L.P. | Polyetherester resins from diol diesters |
-
1997
- 1997-09-25 US US08/937,778 patent/US5780558A/en not_active Expired - Fee Related
-
1998
- 1998-08-26 CN CN98809423A patent/CN1271369A/zh active Pending
- 1998-08-26 CA CA002301212A patent/CA2301212A1/en not_active Abandoned
- 1998-08-26 DE DE69808961T patent/DE69808961T2/de not_active Expired - Fee Related
- 1998-08-26 ES ES98947459T patent/ES2181277T3/es not_active Expired - Lifetime
- 1998-08-26 JP JP2000512876A patent/JP2001517718A/ja active Pending
- 1998-08-26 AU AU94371/98A patent/AU737897B2/en not_active Ceased
- 1998-08-26 BR BR9812539-7A patent/BR9812539A/pt not_active IP Right Cessation
- 1998-08-26 WO PCT/EP1998/005423 patent/WO1999015574A1/en not_active Ceased
- 1998-08-26 EP EP98947459A patent/EP1023355B1/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| ES2181277T3 (es) | 2003-02-16 |
| US5780558A (en) | 1998-07-14 |
| EP1023355A1 (en) | 2000-08-02 |
| WO1999015574A1 (en) | 1999-04-01 |
| JP2001517718A (ja) | 2001-10-09 |
| AU737897B2 (en) | 2001-09-06 |
| EP1023355B1 (en) | 2002-10-23 |
| CN1271369A (zh) | 2000-10-25 |
| DE69808961T2 (de) | 2003-06-18 |
| CA2301212A1 (en) | 1999-04-01 |
| DE69808961D1 (de) | 2002-11-28 |
| AU9437198A (en) | 1999-04-12 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B08F | Application fees: application dismissed [chapter 8.6 patent gazette] |
Free format text: REFERENTE A 6A E 7A ANUIDADES. |
|
| B08K | Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette] |
Free format text: REFERENTE AO DESPACHO 8.6 PUBLICADO NA RPI 1838 DE 28/03/2006. |