BR9810709A - Processos para fabricar 2,6-dimetilnaftaleno, para se usar não 2,6-dimetilnaftaleno para se obter 2,6-dimetilnaftaleno, e para usar um catalisador ácido em uma etapa de hidroisomerização seguido por um catalisador de reforma não ácido em uma etapa de desidrogenação - Google Patents
Processos para fabricar 2,6-dimetilnaftaleno, para se usar não 2,6-dimetilnaftaleno para se obter 2,6-dimetilnaftaleno, e para usar um catalisador ácido em uma etapa de hidroisomerização seguido por um catalisador de reforma não ácido em uma etapa de desidrogenaçãoInfo
- Publication number
- BR9810709A BR9810709A BR9810709-7A BR9810709A BR9810709A BR 9810709 A BR9810709 A BR 9810709A BR 9810709 A BR9810709 A BR 9810709A BR 9810709 A BR9810709 A BR 9810709A
- Authority
- BR
- Brazil
- Prior art keywords
- dimethylnaphthalene
- catalyst
- acid
- dehydrogenation
- processes
- Prior art date
Links
- YGYNBBAUIYTWBF-UHFFFAOYSA-N 2,6-dimethylnaphthalene Chemical compound C1=C(C)C=CC2=CC(C)=CC=C21 YGYNBBAUIYTWBF-UHFFFAOYSA-N 0.000 title abstract 12
- 239000003054 catalyst Substances 0.000 title abstract 7
- 238000006356 dehydrogenation reaction Methods 0.000 title abstract 5
- 238000000034 method Methods 0.000 title abstract 4
- 238000002407 reforming Methods 0.000 title abstract 4
- 239000003377 acid catalyst Substances 0.000 title abstract 3
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 239000002253 acid Substances 0.000 title 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract 2
- 229910052782 aluminium Inorganic materials 0.000 abstract 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract 1
- 238000005984 hydrogenation reaction Methods 0.000 abstract 1
- 229910052751 metal Inorganic materials 0.000 abstract 1
- 239000002184 metal Substances 0.000 abstract 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C15/00—Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic parts
- C07C15/20—Polycyclic condensed hydrocarbons
- C07C15/24—Polycyclic condensed hydrocarbons containing two rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/02—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation
- C07C5/13—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by hydrogenation with simultaneous isomerisation
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
- C07C5/367—Formation of an aromatic six-membered ring from an existing six-membered ring, e.g. dehydrogenation of ethylcyclohexane to ethylbenzene
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
- C07C2521/04—Alumina
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
- C07C2521/08—Silica
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/12—Silica and alumina
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/08—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of gallium, indium or thallium
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/14—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of germanium, tin or lead
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2523/24—Chromium, molybdenum or tungsten
- C07C2523/26—Chromium
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2523/32—Manganese, technetium or rhenium
- C07C2523/36—Rhenium
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
- C07C2523/42—Platinum
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
- C07C2523/44—Palladium
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
- C07C2523/56—Platinum group metals
- C07C2523/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tatalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2523/656—Manganese, technetium or rhenium
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/74—Iron group metals
- C07C2523/745—Iron
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
- C07C2529/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11 containing iron group metals, noble metals or copper
- C07C2529/44—Noble metals
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
- C07C2529/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65 containing iron group metals, noble metals or copper
- C07C2529/74—Noble metals
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/82—Phosphates
- C07C2529/84—Aluminophosphates containing other elements, e.g. metals, boron
- C07C2529/85—Silicoaluminophosphates (SAPO compounds)
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2602/00—Systems containing two condensed rings
- C07C2602/02—Systems containing two condensed rings the rings having only two atoms in common
- C07C2602/04—One of the condensed rings being a six-membered aromatic ring
- C07C2602/10—One of the condensed rings being a six-membered aromatic ring the other ring being six-membered, e.g. tetraline
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2602/00—Systems containing two condensed rings
- C07C2602/02—Systems containing two condensed rings the rings having only two atoms in common
- C07C2602/14—All rings being cycloaliphatic
- C07C2602/26—All rings being cycloaliphatic the ring system containing ten carbon atoms
- C07C2602/28—Hydrogenated naphthalenes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
"PROCESSOS PARA FABRICAR 2,6-DIMETILNAFTALENO, PARA SE USAR NãO-2,6-DIMETILNAFTALENO PARA SE OBTER 2,6-DIMETILNAFTALENO, E PARA USAR UM CATALISADOR áCIDO EM UMA ETAPA DE HIDROISOMERIZAçãO SEGUIDO POR UM CATALISADOR DE REFORMA NãO áCIDO EM UMA ETAPA DE DESIDROGENAçãO". A invenção apresenta um processo de fabricação de 2,6-dimetilnaftaleno a partir de qualquer DMN com uma metila em cada anel em um processo de hidroisomerização/desidrogenação de duas etapas. O catalisador usado na etapa de hidroisomerização é um catalisador ácido tal como um catalisador de alumínio de sílica com um metal de hidrogenação/desidrogenação. O catalisador usado na etapa de desidrogenação é um catalisador tipo de reformação.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/892,508 US6015930A (en) | 1997-07-14 | 1997-07-14 | Method of making 2,6-dimethylnaphthalene from other dimethylnaphthalene isomers and from dimethyltetralins/dimethyldecalins with a methyl group on each ring |
| PCT/US1998/009928 WO1999003805A1 (en) | 1997-07-14 | 1998-05-14 | Method of making 2,6-dimethylnaphthalene from other dimethylnaphthalene isomers and from dimethyltetralins/dimethyldecalins with a methyl group on each ring |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BR9810709A true BR9810709A (pt) | 2000-08-08 |
Family
ID=25400042
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR9810709-7A BR9810709A (pt) | 1997-07-14 | 1998-05-14 | Processos para fabricar 2,6-dimetilnaftaleno, para se usar não 2,6-dimetilnaftaleno para se obter 2,6-dimetilnaftaleno, e para usar um catalisador ácido em uma etapa de hidroisomerização seguido por um catalisador de reforma não ácido em uma etapa de desidrogenação |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US6015930A (pt) |
| EP (1) | EP0996608B1 (pt) |
| JP (1) | JP2001510175A (pt) |
| KR (1) | KR20010021765A (pt) |
| CN (1) | CN1119305C (pt) |
| AU (1) | AU7387998A (pt) |
| BR (1) | BR9810709A (pt) |
| CA (1) | CA2295538A1 (pt) |
| DE (1) | DE69806387T2 (pt) |
| ID (1) | ID23664A (pt) |
| MY (1) | MY133173A (pt) |
| TW (1) | TW577872B (pt) |
| WO (1) | WO1999003805A1 (pt) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100621823B1 (ko) * | 2004-07-21 | 2006-09-14 | 재단법인서울대학교산학협력재단 | 2,6-디알킬테트랄린의 제조 방법 |
| GB0504079D0 (en) * | 2005-02-28 | 2005-04-06 | Davy Process Techn Ltd | Process |
| US7884163B2 (en) * | 2008-03-20 | 2011-02-08 | Chevron Phillips Chemical Company Lp | Silica-coated alumina activator-supports for metallocene catalyst compositions |
| US11208514B2 (en) | 2008-03-20 | 2021-12-28 | Chevron Phillips Chemical Company Lp | Silica-coated alumina activator-supports for metallocene catalyst compositions |
| PL2440328T3 (pl) | 2009-06-12 | 2017-06-30 | Albemarle Europe Sprl. | Katalizatory z sitem molekularnym sapo, ich otrzymywanie i zastosowania |
| CN104447180A (zh) * | 2013-09-24 | 2015-03-25 | 中国石油化工股份有限公司 | 利用费托反应产物中的戊烯生产2,6-二甲基萘的方法 |
| CN104447179A (zh) * | 2013-09-24 | 2015-03-25 | 中国石油化工股份有限公司 | 利用戊醇生产2,6-二甲基萘的方法 |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3243469A (en) * | 1962-08-10 | 1966-03-29 | Schneider Abraham | Production of 2, 6-dimethyl-naphthalene |
| US3890403A (en) * | 1973-11-14 | 1975-06-17 | Teijin Ltd | Process for separating and recovering 2,6-dimethylnaththalenes |
| US5004853A (en) * | 1988-03-29 | 1991-04-02 | Uop | Continuous process for the production of 2,6-dimethylnaphthalene |
| US5189234A (en) * | 1991-10-31 | 1993-02-23 | Amoco Corporation | Selective dehydrogenation processes and catalysts |
-
1997
- 1997-07-14 US US08/892,508 patent/US6015930A/en not_active Expired - Fee Related
-
1998
- 1998-05-14 CN CN98807159A patent/CN1119305C/zh not_active Expired - Fee Related
- 1998-05-14 WO PCT/US1998/009928 patent/WO1999003805A1/en not_active Ceased
- 1998-05-14 ID IDW20000057A patent/ID23664A/id unknown
- 1998-05-14 CA CA002295538A patent/CA2295538A1/en not_active Abandoned
- 1998-05-14 BR BR9810709-7A patent/BR9810709A/pt not_active IP Right Cessation
- 1998-05-14 KR KR1020007000328A patent/KR20010021765A/ko not_active Withdrawn
- 1998-05-14 DE DE69806387T patent/DE69806387T2/de not_active Expired - Fee Related
- 1998-05-14 JP JP2000503039A patent/JP2001510175A/ja active Pending
- 1998-05-14 AU AU73879/98A patent/AU7387998A/en not_active Abandoned
- 1998-05-14 EP EP98921216A patent/EP0996608B1/en not_active Expired - Lifetime
- 1998-06-15 TW TW087109494A patent/TW577872B/zh active
- 1998-07-13 MY MYPI98003191A patent/MY133173A/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CN1263518A (zh) | 2000-08-16 |
| CA2295538A1 (en) | 1999-01-28 |
| KR20010021765A (ko) | 2001-03-15 |
| ID23664A (id) | 2000-05-11 |
| JP2001510175A (ja) | 2001-07-31 |
| MY133173A (en) | 2007-10-31 |
| DE69806387D1 (de) | 2002-08-08 |
| TW577872B (en) | 2004-03-01 |
| US6015930A (en) | 2000-01-18 |
| CN1119305C (zh) | 2003-08-27 |
| WO1999003805A1 (en) | 1999-01-28 |
| AU7387998A (en) | 1999-02-10 |
| DE69806387T2 (de) | 2003-03-20 |
| EP0996608A1 (en) | 2000-05-03 |
| EP0996608B1 (en) | 2002-07-03 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B08F | Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette] |
Free format text: REFERENTE A 7A,8A E 9A ANUIDADES. |
|
| B08K | Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette] |
Free format text: REFERENTE AO DESPACHO 8.6 PUBLICADO NA RPI 1909 DE 07/08/2007. |