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BR9810754A - Catalyzing homogeneous oxidation using metal complexes - Google Patents

Catalyzing homogeneous oxidation using metal complexes

Info

Publication number
BR9810754A
BR9810754A BR9810754-2A BR9810754A BR9810754A BR 9810754 A BR9810754 A BR 9810754A BR 9810754 A BR9810754 A BR 9810754A BR 9810754 A BR9810754 A BR 9810754A
Authority
BR
Brazil
Prior art keywords
metal
lewi
target compound
catalyst
acid
Prior art date
Application number
BR9810754-2A
Other languages
Portuguese (pt)
Inventor
Terrence J Collins
Scott W Gordon-Wylie
Christiane G Woomer
Colin P Horwitz
Erich S Uffelman
Original Assignee
Univ Carnegie Mellon
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Univ Carnegie Mellon filed Critical Univ Carnegie Mellon
Publication of BR9810754A publication Critical patent/BR9810754A/en

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1805—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing nitrogen
    • B01J31/181—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine
    • B01J31/1815—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine
    • B01J31/182—Cyclic ligands, including e.g. non-condensed polycyclic ligands, comprising at least one complexing nitrogen atom as ring member, e.g. pyridine with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine comprising aliphatic or saturated rings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B53/00—Asymmetric syntheses
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/02—Compositional aspects of complexes used, e.g. polynuclearity
    • B01J2531/0238—Complexes comprising multidentate ligands, i.e. more than 2 ionic or coordinative bonds from the central metal to the ligand, the latter having at least two donor atoms, e.g. N, O, S, P
    • B01J2531/0258—Flexible ligands, e.g. mainly sp3-carbon framework as exemplified by the "tedicyp" ligand, i.e. cis-cis-cis-1,2,3,4-tetrakis(diphenylphosphinomethyl)cyclopentane
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/30—Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
    • B01J2531/38—Lanthanides other than lanthanum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/30—Complexes comprising metals of Group III (IIIA or IIIB) as the central metal
    • B01J2531/39—Actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/70—Complexes comprising metals of Group VII (VIIB) as the central metal
    • B01J2531/72—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/842—Iron

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

Patente de Invenção: <B>"CATALISAçãO DE OXIDAçãO HOMOGêNEA USANDO COMPLEXOS DE METAL"<D>. O presente método provê um método de transferência de oxigênio para pelo menos um sítio oxidável em um composto alvo. O método inclui as etapas seletivamente de oxidar um sítio oxidável em um composto alvo pela reação na solução: o composto alvo, uma fonte átomos alvo, uma fonte de ácido de Lewi's, tal como um próton, metal, alcalino terroso, terras raras e de transição ou de metal do grupo principal e um catalizador. O catalizador apresenta sua estrutura geral (I) em que Z é preverivelmente N, mas pode incluir o, e MO é uma espécies oxo-metal de transição, o ácido de Lewi's se liga a um sítio secundário bidentado no Ch1 substituído por um complexo catalítico de ácido de Lewi's.Invention Patent: <B> "HOMOGENEOUS OXIDATION CATALYST USING METAL COMPLEXES" <D>. The present method provides a method of transferring oxygen to at least one oxidizable site in a target compound. The method includes the steps of selectively oxidizing an oxidizable site in a target compound by reacting in the solution: the target compound, a target atoms source, a Lewi's acid source, such as a proton, metal, alkaline earth, rare earth and transition or metal of the main group and a catalyst. The catalyst has its general structure (I) in which Z is predictably N, but can include o, and MO is a transition oxo-metal species, Lewi's acid binds to a secondary bidentate site in Ch1 replaced by a catalytic complex of Lewi's acid.

BR9810754-2A 1997-06-20 1998-06-18 Catalyzing homogeneous oxidation using metal complexes BR9810754A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US87975297A 1997-06-20 1997-06-20
PCT/US1998/012749 WO1998058735A1 (en) 1997-06-20 1998-06-18 Homogeneous oxidation catalysis using metal complexes

Publications (1)

Publication Number Publication Date
BR9810754A true BR9810754A (en) 2000-08-15

Family

ID=25374825

Family Applications (1)

Application Number Title Priority Date Filing Date
BR9810754-2A BR9810754A (en) 1997-06-20 1998-06-18 Catalyzing homogeneous oxidation using metal complexes

Country Status (13)

Country Link
EP (1) EP0991468A1 (en)
JP (1) JP2002505688A (en)
KR (1) KR20010013986A (en)
CN (1) CN1267238A (en)
AP (1) AP9901723A0 (en)
AU (1) AU8152998A (en)
BR (1) BR9810754A (en)
CA (1) CA2295006A1 (en)
IL (1) IL133484A0 (en)
NO (1) NO996282L (en)
OA (1) OA11237A (en)
PL (1) PL337523A1 (en)
WO (1) WO1998058735A1 (en)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6797196B2 (en) 2001-01-10 2004-09-28 Kao Corporation Bleaching formulation
JP4104966B2 (en) 2002-03-06 2008-06-18 花王株式会社 Bleaching catalyst
KR100561058B1 (en) * 2004-09-23 2006-03-17 삼성토탈 주식회사 Catalyst for olefin polymerization containing phenoxy ligands and olefin (co) polymerization method using the same
JP5002761B2 (en) * 2007-03-09 2012-08-15 国立大学法人大阪大学 Oxoporphyrin-based electrode catalyst material
CN104785296B (en) * 2015-04-17 2017-03-08 中国石油大学(华东) A liquid cobalt sulfonated phthalocyanine catalyst for liquefied petroleum gas sweetening
CN106082419B (en) * 2016-05-10 2019-05-31 北京服装学院 Method and application of the degradation of macrocyclic amide metal complex containing organic pollutant wastewater
CN106111199B (en) * 2016-06-21 2018-10-12 中南民族大学 The nanocrystalline preparation and application of more sulfur-bearing aza porphyrin arrays
CN112675908A (en) * 2020-12-23 2021-04-20 清华大学 Aerobic oxidation method of alcohols
CN119977974A (en) * 2024-12-23 2025-05-13 河北工业大学 A benzimidazole-modified nickel phthalocyanine catalyst and its preparation method and application

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4758682A (en) * 1983-03-17 1988-07-19 California Institute Of Technology Homogeneous coordination compounds as oxidation catalysts
US5665890A (en) * 1995-03-14 1997-09-09 President And Fellows Of Harvard College Stereoselective ring opening reactions
US5847120A (en) * 1996-07-22 1998-12-08 Carnegie Mellon University Long-lived homogenous oxidation catalysts

Also Published As

Publication number Publication date
WO1998058735A1 (en) 1998-12-30
JP2002505688A (en) 2002-02-19
CA2295006A1 (en) 1998-12-30
IL133484A0 (en) 2001-04-30
NO996282D0 (en) 1999-12-17
AP9901723A0 (en) 1999-12-31
KR20010013986A (en) 2001-02-26
NO996282L (en) 2000-02-21
AU8152998A (en) 1999-01-04
CN1267238A (en) 2000-09-20
PL337523A1 (en) 2000-08-28
EP0991468A1 (en) 2000-04-12
OA11237A (en) 2003-05-27

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Legal Events

Date Code Title Description
FA10 Dismissal: dismissal - article 33 of industrial property law
B11Y Definitive dismissal - extension of time limit for request of examination expired [chapter 11.1.1 patent gazette]