BR9810564A - Composição de resina à base de um resol fenol-formaldeìdo modificado por uréia, processos para preparar a mesma, para melhorar a capacidade de ser diluìdo de um resol fenólico e para fabricar um produto à base de lã mineral e composição de encolamento - Google Patents
Composição de resina à base de um resol fenol-formaldeìdo modificado por uréia, processos para preparar a mesma, para melhorar a capacidade de ser diluìdo de um resol fenólico e para fabricar um produto à base de lã mineral e composição de encolamentoInfo
- Publication number
- BR9810564A BR9810564A BR9810564-7A BR9810564A BR9810564A BR 9810564 A BR9810564 A BR 9810564A BR 9810564 A BR9810564 A BR 9810564A BR 9810564 A BR9810564 A BR 9810564A
- Authority
- BR
- Brazil
- Prior art keywords
- resol
- composition
- formaldehyde
- urea
- phenol
- Prior art date
Links
- 229920003987 resole Polymers 0.000 title abstract 8
- 239000000203 mixture Substances 0.000 title abstract 7
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 title abstract 5
- 238000004519 manufacturing process Methods 0.000 title abstract 3
- 239000011490 mineral wool Substances 0.000 title abstract 3
- 238000004513 sizing Methods 0.000 title abstract 3
- SLGWESQGEUXWJQ-UHFFFAOYSA-N formaldehyde;phenol Chemical class O=C.OC1=CC=CC=C1 SLGWESQGEUXWJQ-UHFFFAOYSA-N 0.000 title abstract 2
- 238000000034 method Methods 0.000 title abstract 2
- 239000011342 resin composition Substances 0.000 title abstract 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract 9
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 abstract 2
- 239000004202 carbamide Substances 0.000 abstract 2
- 238000006386 neutralization reaction Methods 0.000 abstract 2
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 abstract 1
- 239000004327 boric acid Substances 0.000 abstract 1
- 230000005494 condensation Effects 0.000 abstract 1
- 238000009833 condensation Methods 0.000 abstract 1
- 238000010790 dilution Methods 0.000 abstract 1
- 239000012895 dilution Substances 0.000 abstract 1
- 230000004048 modification Effects 0.000 abstract 1
- 238000012986 modification Methods 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/24—Coatings containing organic materials
- C03C25/26—Macromolecular compounds or prepolymers
- C03C25/32—Macromolecular compounds or prepolymers obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
- C03C25/34—Condensation polymers of aldehydes, e.g. with phenols, ureas, melamines, amides or amines
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/24—Coatings containing organic materials
- C03C25/26—Macromolecular compounds or prepolymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G14/00—Condensation polymers of aldehydes or ketones with two or more other monomers covered by at least two of the groups C08G8/00 - C08G12/00
- C08G14/02—Condensation polymers of aldehydes or ketones with two or more other monomers covered by at least two of the groups C08G8/00 - C08G12/00 of aldehydes
- C08G14/04—Condensation polymers of aldehydes or ketones with two or more other monomers covered by at least two of the groups C08G8/00 - C08G12/00 of aldehydes with phenols
- C08G14/06—Condensation polymers of aldehydes or ketones with two or more other monomers covered by at least two of the groups C08G8/00 - C08G12/00 of aldehydes with phenols and monomers containing hydrogen attached to nitrogen
- C08G14/08—Ureas; Thioureas
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4209—Inorganic fibres
- D04H1/4218—Glass fibres
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- General Life Sciences & Earth Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Textile Engineering (AREA)
- Phenolic Resins Or Amino Resins (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Surface Treatment Of Glass Fibres Or Filaments (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
"COMPOSIçãO DE RESINA à BASE DE UM RESOL FENOL-FORMALDEìDO MODIFICADO POR URéIA, PROCESSOS PARA PREPARAR A MESMA, PARA MELHORAR A CAPACIDADE DE SER DILUìDO DE UM RESOL FENóLICO E PARA FABRICAR UM PRODUTO à BASE DE Lã MINERAL E COMPOSIçãO DE ENCOLAMENTO". A invenção refere-se a uma composição de resina à base de um resol fenol-formaldeído modificado por uréia que tem uma proporção molar de formaldeído / fenol de 2 a 5, que apresenta uma taxa de formaldeído livre inferior ou igual a 3% (em peso em relação ao peso total da composição), uma taxa de fenol livre inferior ou igual a 0,5% e uma capacidade de ser diluída medida a 20°C pelo menos igual a 1000%, assim como a um processo de preparação desta composição. Esta composição é caracterizada pelo fato de que ela contém um resol supercondensado obtido por condensação em meio básico de fenol e de formaldeído e eventualmente de uréia até que o produto tenha uma capacidade de ser diluída em àgua a pH 9 inferior ou igual a 2000% ou o produto de neutralização de um tal resol. A modificação de um resol fenólico supercondensado por neutralização com ácido bórico de acordo com a invenção permite aumentar a capacidade de ser diluído do resol. Aplicação a composições de encolamento para produtos à base de lã mineral com uma redução de poluição atmosférica à utilização do encolamento.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9708936A FR2766201A1 (fr) | 1997-07-15 | 1997-07-15 | Resine phenolique pour composition d'encollage, procede de preparation et composition d'encollage la contenant |
| PCT/FR1998/001484 WO1999003906A1 (fr) | 1997-07-15 | 1998-07-09 | Resine phenolique pour composition d'encollage, procede de preparation et composition d'encollage la contenant |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BR9810564A true BR9810564A (pt) | 2000-08-15 |
Family
ID=9509214
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR9810564-7A BR9810564A (pt) | 1997-07-15 | 1998-07-09 | Composição de resina à base de um resol fenol-formaldeìdo modificado por uréia, processos para preparar a mesma, para melhorar a capacidade de ser diluìdo de um resol fenólico e para fabricar um produto à base de lã mineral e composição de encolamento |
Country Status (24)
| Country | Link |
|---|---|
| US (1) | US6342271B1 (pt) |
| EP (2) | EP1795547A1 (pt) |
| JP (2) | JP4298159B2 (pt) |
| KR (1) | KR100566073B1 (pt) |
| CN (1) | CN1182171C (pt) |
| AR (1) | AR016345A1 (pt) |
| AT (1) | ATE358145T1 (pt) |
| AU (1) | AU750098B2 (pt) |
| BR (1) | BR9810564A (pt) |
| CA (1) | CA2296730C (pt) |
| CZ (1) | CZ302174B6 (pt) |
| DE (1) | DE69837435T2 (pt) |
| DK (1) | DK0996653T3 (pt) |
| ES (1) | ES2285781T3 (pt) |
| FR (1) | FR2766201A1 (pt) |
| HU (1) | HUP0002769A3 (pt) |
| NO (1) | NO332943B1 (pt) |
| PL (2) | PL206776B1 (pt) |
| PT (1) | PT996653E (pt) |
| RU (1) | RU2225416C2 (pt) |
| SI (1) | SI0996653T1 (pt) |
| TR (1) | TR200000095T2 (pt) |
| WO (1) | WO1999003906A1 (pt) |
| ZA (1) | ZA986024B (pt) |
Families Citing this family (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2810031B1 (fr) * | 2000-06-13 | 2003-03-07 | Saint Gobain Isover | Produit d'isolation, notamment thermique, et sa fabrication |
| AU2006202926A1 (en) * | 2000-06-13 | 2006-08-03 | Isover, Saint-Gobain | Insulating product in particular thermal containing a binder based on phenol-formaldehyde resin and method for making same |
| JP2006199594A (ja) * | 2005-01-18 | 2006-08-03 | Sumitomo Chemical Co Ltd | レゾルシンとメチルエチルケトンの反応生成物 |
| CN100443521C (zh) * | 2005-04-08 | 2008-12-17 | 任庆祥 | 一种纸质高压装饰防火板用浸渍水性酚醛树脂及生产工艺 |
| RU2318005C1 (ru) * | 2006-09-05 | 2008-02-27 | Государственное образовательное учреждение высшего профессионального образования "Алтайский государственный технический университет им. И.И. Ползунова" (АлтГТУ) | Политриэфир фенола и борной кислоты и способ его получения |
| FR2907122B1 (fr) * | 2006-10-11 | 2008-12-05 | Saint Gobain Isover Sa | Resine phenolique, procede de preparation, composition d'encollage pour fibres minerales et produits resultants |
| FR2907123B1 (fr) * | 2006-10-11 | 2008-12-05 | Saint Gobain Isover Sa | Resine phenolique, procede de preparation, composition d'encollage pour fibres minerales et produits resultants |
| FR2910481B1 (fr) * | 2006-12-22 | 2009-02-06 | Saint Gobain Isover Sa | Compsition d'encollage pour fibres minerales comprenant une resine phenolique, et produits resultants |
| RU2387678C2 (ru) * | 2007-06-29 | 2010-04-27 | Общество с ограниченной ответственностью "Борполимер" | СПОСОБ ОТВЕРЖДЕНИЯ ПОЛИМЕТИЛЕН-п-ТРИФЕНИЛОВОГО ЭФИРА БОРНОЙ КИСЛОТЫ |
| JP5716942B2 (ja) * | 2007-11-06 | 2015-05-13 | Dic株式会社 | レゾール型フェノール樹脂の製造方法、レゾール型フェノール樹脂、及び摩擦材 |
| FR2929953B1 (fr) | 2008-04-11 | 2011-02-11 | Saint Gobain Isover | Composition d'encollage pour fibres minerales et produits resultants |
| JP2010037347A (ja) * | 2008-07-31 | 2010-02-18 | Dic Corp | レゾール型フェノール樹脂及びその製造方法 |
| JP5376238B2 (ja) * | 2009-09-18 | 2013-12-25 | Dic株式会社 | フェノール樹脂の製造方法 |
| JP5387299B2 (ja) * | 2009-09-30 | 2014-01-15 | Dic株式会社 | フェノール樹脂の製造方法 |
| JP5472711B2 (ja) * | 2009-10-30 | 2014-04-16 | Dic株式会社 | フェノール樹脂の製造方法 |
| FR2964105B1 (fr) * | 2010-08-27 | 2012-09-28 | Saint Gobain Isover | Resine phenolique, procede de preparation, composition d'encollage pour fibres minerales et produit resultant. |
| CA2820559C (en) | 2010-12-06 | 2019-11-12 | Rockwool International A/S | Method of reducing the formaldehyde emission of a mineral fibre product, and mineral fibre product with reduced formaldehyde emission |
| CN102936325B (zh) * | 2012-11-13 | 2014-04-16 | 中国林业科学研究院林产化学工业研究所 | 高固含可发性尿素改性甲阶酚醛树脂及其制备方法 |
| JP5831497B2 (ja) * | 2013-05-14 | 2015-12-09 | Dic株式会社 | レゾール型フェノール樹脂の製造方法 |
| SI3309133T1 (sl) | 2013-10-16 | 2019-09-30 | Rockwool International A/S | Umetno narejena steklena vlakna |
| EP2884259A1 (en) | 2013-12-11 | 2015-06-17 | Rockwool International A/S | Method for detecting curing of the binder in a mineral fibre product |
| FR3015472A1 (fr) | 2013-12-23 | 2015-06-26 | Rockwool Int | Methode pour reduire les emissions de formaldehyde et de composes organiques volatils (cov) dans un produit a base de fibres minerales |
| SI2947117T2 (sl) | 2014-05-19 | 2023-01-31 | Rockwool International A/S | Analitično vezivo za izdelke iz mineralne volne |
| CN103965422B (zh) * | 2014-05-28 | 2016-04-06 | 贵阳学院 | 热固性酚醛树脂的制备方法 |
| SI3315470T1 (sl) * | 2016-10-27 | 2020-07-31 | Ursa Insulation, S.A. | Postopek za izdelavo izdelkov iz mineralne volne z vezivom na osnovi fenol-formaldehidnega rezola |
| DE102019126429A1 (de) * | 2019-07-26 | 2021-01-28 | Schaeffler Technologies AG & Co. KG | Verfahren zur Herstellung von Nasslaufreibpapier und Nasslaufreibpapier |
| CN115697935B (zh) | 2020-04-03 | 2025-03-18 | 洛科威有限公司 | 声学产品 |
| CN120535216A (zh) | 2020-04-03 | 2025-08-26 | 洛科威有限公司 | 绝缘制品 |
| JP2024502418A (ja) | 2020-12-30 | 2024-01-19 | ロックウール アクティーゼルスカブ | 高温低放出鉱物ウール製品 |
| EP4638375A1 (en) | 2022-12-23 | 2025-10-29 | Rockwool A/S | Mineral wool binder based on phenol formaldehyde resin and protein |
| WO2025046040A1 (en) | 2023-09-01 | 2025-03-06 | Rockwool A/S | Mineral wool binder based on phenol formaldehyde resin and carbohydrate |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2051990A5 (pt) * | 1969-07-03 | 1971-04-09 | Saint Gobain | |
| FR2555591B1 (fr) * | 1983-11-29 | 1986-09-26 | Saint Gobain Isover | Resine pour une composition d'encollage, son procede de fabrication et la composition d'encollage obtenue |
| US5270434A (en) * | 1990-10-12 | 1993-12-14 | Isover Saint-Gobain | Phenolic resin, procedure for preparation of the resin, and sizing composition for mineral fibers containing this resin |
| RU1815265C (ru) * | 1990-12-28 | 1993-05-15 | Производственное Объединение Синтетических Отделочных И Изоляционных Строительных Материалов "Мосстройпластмасс" | Способ получени пропиточного водного фенолоформальдегидного олигомера |
| AU658289B2 (en) * | 1992-11-25 | 1995-04-06 | Georgia-Pacific Resins, Inc. | Emulsifiable phenolic resole resin |
-
1997
- 1997-07-15 FR FR9708936A patent/FR2766201A1/fr active Pending
-
1998
- 1998-07-08 ZA ZA986024A patent/ZA986024B/xx unknown
- 1998-07-09 EP EP06126876A patent/EP1795547A1/fr not_active Withdrawn
- 1998-07-09 RU RU2000103440/04A patent/RU2225416C2/ru not_active IP Right Cessation
- 1998-07-09 WO PCT/FR1998/001484 patent/WO1999003906A1/fr not_active Ceased
- 1998-07-09 JP JP2000503127A patent/JP4298159B2/ja not_active Expired - Fee Related
- 1998-07-09 EP EP98937593A patent/EP0996653B1/fr not_active Revoked
- 1998-07-09 BR BR9810564-7A patent/BR9810564A/pt not_active IP Right Cessation
- 1998-07-09 ES ES98937593T patent/ES2285781T3/es not_active Expired - Lifetime
- 1998-07-09 SI SI9830886T patent/SI0996653T1/sl unknown
- 1998-07-09 HU HU0002769A patent/HUP0002769A3/hu not_active IP Right Cessation
- 1998-07-09 PL PL385756A patent/PL206776B1/pl not_active IP Right Cessation
- 1998-07-09 CZ CZ20000146A patent/CZ302174B6/cs not_active IP Right Cessation
- 1998-07-09 DE DE69837435T patent/DE69837435T2/de not_active Expired - Lifetime
- 1998-07-09 TR TR2000/00095T patent/TR200000095T2/xx unknown
- 1998-07-09 PT PT98937593T patent/PT996653E/pt unknown
- 1998-07-09 PL PL339216A patent/PL203691B1/pl unknown
- 1998-07-09 US US09/462,459 patent/US6342271B1/en not_active Expired - Lifetime
- 1998-07-09 AT AT98937593T patent/ATE358145T1/de active
- 1998-07-09 AU AU86335/98A patent/AU750098B2/en not_active Ceased
- 1998-07-09 DK DK98937593T patent/DK0996653T3/da active
- 1998-07-09 CN CNB988091364A patent/CN1182171C/zh not_active Expired - Fee Related
- 1998-07-09 CA CA2296730A patent/CA2296730C/fr not_active Expired - Fee Related
- 1998-07-09 KR KR1020007000349A patent/KR100566073B1/ko not_active Expired - Fee Related
- 1998-07-15 AR ARP980103444A patent/AR016345A1/es active IP Right Grant
-
2000
- 2000-01-07 NO NO20000084A patent/NO332943B1/no not_active IP Right Cessation
-
2009
- 2009-02-19 JP JP2009037245A patent/JP2009149904A/ja active Pending
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B06A | Patent application procedure suspended [chapter 6.1 patent gazette] | ||
| B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
| B16A | Patent or certificate of addition of invention granted [chapter 16.1 patent gazette] |
Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 09/07/1998, OBSERVADAS AS CONDICOES LEGAIS. |
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| B21F | Lapse acc. art. 78, item iv - on non-payment of the annual fees in time |
Free format text: REFERENTE A 18A ANUIDADE. |
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| B24J | Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12) |
Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2385 DE 20-09-2016 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013. |
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| B15K | Others concerning applications: alteration of classification |
Ipc: C03C 25/34 (2006.01), C03C 25/26 (2018.0 |