BR9809008A - Processo para a preparação de lactamas cìclicas - Google Patents
Processo para a preparação de lactamas cìclicasInfo
- Publication number
- BR9809008A BR9809008A BR9809008-9A BR9809008A BR9809008A BR 9809008 A BR9809008 A BR 9809008A BR 9809008 A BR9809008 A BR 9809008A BR 9809008 A BR9809008 A BR 9809008A
- Authority
- BR
- Brazil
- Prior art keywords
- preparation
- cyclic
- cycloalkyl
- alkyl
- formula
- Prior art date
Links
- 238000000034 method Methods 0.000 title abstract 5
- -1 cyclic lactams Chemical class 0.000 title abstract 2
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- 125000003118 aryl group Chemical group 0.000 abstract 2
- 125000000753 cycloalkyl group Chemical group 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 150000002825 nitriles Chemical class 0.000 abstract 1
- 125000001424 substituent group Chemical group 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D201/00—Preparation, separation, purification or stabilisation of unsubstituted lactams
- C07D201/02—Preparation of lactams
- C07D201/08—Preparation of lactams from carboxylic acids or derivatives thereof, e.g. hydroxy carboxylic acids, lactones or nitriles
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Other In-Based Heterocyclic Compounds (AREA)
- Polyamides (AREA)
- Hydrogenated Pyridines (AREA)
- Catalysts (AREA)
- Pyrrole Compounds (AREA)
Abstract
"PROCESSO PARA A PREPARAçãO DE LACTAMAS CìCLICAS". A invenção se refere a um processo para a produção de lactamas cíclicas de fórmula (I): na qual R^ 1^ representa um átomo de hidrogênio, um alquila, um ciclo-alquila ou um arila; A representa um radical alquileno C~ 3~-C~ 12~, que pode ser substituído por 1, 2, 3, 4, 5 ou 6 substituintes, selecionados, independentemente um dos outros, dentre grupos alquila, ciclo-alquila ou arila. Neste processo, uma nitrila de ácido <sym>-amino-carbónico de fórmula (II): HR^ 1^N - A - CN (II) na qual R^ 1^ e A têm os significados dados acima, é reagida na presença de um pelo menos um catalisador. O processo é caracterizado pelo fato de que a nitrila II é convertida numa mistura de oligómeros e então tratada com vapor d'água superaquecido.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19718706A DE19718706A1 (de) | 1997-05-02 | 1997-05-02 | Verfahren zur Herstellung cyclischer Lactame |
| PCT/EP1998/002571 WO1998050355A1 (de) | 1997-05-02 | 1998-04-30 | Verfahren zur herstellung cyclischer lactame |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BR9809008A true BR9809008A (pt) | 2000-08-08 |
Family
ID=7828520
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR9809008-9A BR9809008A (pt) | 1997-05-02 | 1998-04-30 | Processo para a preparação de lactamas cìclicas |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US6222033B1 (pt) |
| EP (1) | EP0980355B1 (pt) |
| JP (1) | JP2001526652A (pt) |
| KR (1) | KR20010012172A (pt) |
| CN (1) | CN1113865C (pt) |
| AR (1) | AR012617A1 (pt) |
| AU (1) | AU7910398A (pt) |
| BR (1) | BR9809008A (pt) |
| CA (1) | CA2288336A1 (pt) |
| DE (2) | DE19718706A1 (pt) |
| ES (1) | ES2196568T3 (pt) |
| ID (1) | ID24234A (pt) |
| MY (1) | MY125884A (pt) |
| TW (1) | TW430659B (pt) |
| WO (1) | WO1998050355A1 (pt) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1245563A1 (en) * | 2001-03-27 | 2002-10-02 | Dsm N.V. | Process for the preparation of epsilon-caprolactam |
| US6437089B1 (en) * | 2001-06-01 | 2002-08-20 | E. I. Du Pont De Nemours And Company | Process for the production of nylon 6 |
| TW202442633A (zh) * | 2023-02-27 | 2024-11-01 | 日商三菱瓦斯化學股份有限公司 | 環狀內醯胺之製造方法、及環狀內醯胺之製造裝置 |
| WO2025182802A1 (ja) * | 2024-02-26 | 2025-09-04 | 三菱瓦斯化学株式会社 | 環状ラクタムの製造方法 |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2245129A (en) | 1935-01-02 | 1941-06-10 | Du Pont | Process for preparing linear polyamides |
| US2301964A (en) | 1941-09-12 | 1942-11-17 | Du Pont | Method of preparing lactams |
| DE952442C (de) | 1955-02-17 | 1956-11-15 | Huels Chemische Werke Ag | Verfahren zur Herstellung von ªŠ-Caprolactam |
| US3485821A (en) | 1967-05-29 | 1969-12-23 | Techni Chem Co The | Process for preparing caprolactam and its alkyl substituted derivatives |
| JPS4821958B1 (pt) | 1969-01-28 | 1973-07-02 | ||
| US3988319A (en) | 1974-09-16 | 1976-10-26 | Allied Chemical Corporation | Process for producing caprolactam from 6-aminocaproic acid |
| US4568736A (en) | 1984-09-17 | 1986-02-04 | The Standard Oil Company | Preparation of polyamide from omega-aminonitrile with oxygen containing phosphorus catalyst |
| DE3524394A1 (de) | 1985-07-09 | 1987-01-15 | Basf Ag | Verfahren zur gewinnung von caprolactam durch spaltung von oligomeren des caprolactams |
| US4628085A (en) | 1985-09-03 | 1986-12-09 | Allied Corporation | Use of silica catalyst for selective production of lactams |
| US4625023A (en) | 1985-09-03 | 1986-11-25 | Allied Corporation | Selective conversion of aliphatic and aromatic aminonitriles and/or dinitriles into lactams |
| DE3643010A1 (de) | 1986-12-17 | 1988-06-30 | Basf Ag | Verfahren zur herstellung von caprolactam |
| DE3843793A1 (de) | 1988-12-24 | 1990-07-05 | Basf Ag | Verfahren zur herstellung von caprolactam |
| DE4033259A1 (de) | 1990-10-19 | 1992-04-23 | Basf Ag | Verfahren zur herstellung von 2-pyrrolidinonen |
| DE4211609A1 (de) | 1991-08-30 | 1993-03-04 | Bayer Ag | Gewinnung von caprolactam durch thermische spaltung von polyamid 6 |
| DE4339648A1 (de) * | 1993-11-20 | 1995-05-24 | Basf Ag | Verfahren zur Herstellung von Caprolactam |
| FR2714379B1 (fr) * | 1993-12-23 | 1996-02-02 | Rhone Poulenc Chimie | Procédé de préparation de lactame. |
| DE4441962A1 (de) * | 1994-11-25 | 1996-05-30 | Basf Ag | Verfahren zur Herstellung von Caprolactam |
| DE4442727A1 (de) * | 1994-12-01 | 1996-06-05 | Basf Ag | Verfahren zur Herstellung von Caprolactam |
| DE4443125A1 (de) * | 1994-12-03 | 1996-06-05 | Basf Ag | Verfahren zur Herstellung von Caprolactam |
| FR2729949A1 (fr) * | 1995-01-27 | 1996-08-02 | Rhone Poulenc Chimie | Procede de preparation de lactame |
| DE19517823A1 (de) | 1995-05-18 | 1996-11-21 | Basf Ag | Verfahren zur Herstellung von Caprolactam |
| DE19628805A1 (de) * | 1996-07-17 | 1998-01-22 | Basf Ag | Verfahren zur Herstellung von Caprolactam aus 6-Aminocapronitril |
-
1997
- 1997-05-02 DE DE19718706A patent/DE19718706A1/de not_active Withdrawn
-
1998
- 1998-04-29 AR ARP980101984A patent/AR012617A1/es unknown
- 1998-04-30 KR KR19997010121A patent/KR20010012172A/ko not_active Abandoned
- 1998-04-30 JP JP54770998A patent/JP2001526652A/ja not_active Withdrawn
- 1998-04-30 AU AU79103/98A patent/AU7910398A/en not_active Abandoned
- 1998-04-30 DE DE59807971T patent/DE59807971D1/de not_active Expired - Lifetime
- 1998-04-30 CA CA002288336A patent/CA2288336A1/en not_active Abandoned
- 1998-04-30 ID IDW991315A patent/ID24234A/id unknown
- 1998-04-30 ES ES98929277T patent/ES2196568T3/es not_active Expired - Lifetime
- 1998-04-30 MY MYPI98001951A patent/MY125884A/en unknown
- 1998-04-30 BR BR9809008-9A patent/BR9809008A/pt not_active IP Right Cessation
- 1998-04-30 US US09/403,655 patent/US6222033B1/en not_active Expired - Fee Related
- 1998-04-30 WO PCT/EP1998/002571 patent/WO1998050355A1/de not_active Ceased
- 1998-04-30 EP EP98929277A patent/EP0980355B1/de not_active Expired - Lifetime
- 1998-04-30 CN CN98804767A patent/CN1113865C/zh not_active Expired - Fee Related
- 1998-05-02 TW TW087106802A patent/TW430659B/zh not_active IP Right Cessation
Also Published As
| Publication number | Publication date |
|---|---|
| EP0980355B1 (de) | 2003-04-16 |
| AR012617A1 (es) | 2000-11-08 |
| AU7910398A (en) | 1998-11-27 |
| WO1998050355A1 (de) | 1998-11-12 |
| CA2288336A1 (en) | 1998-11-12 |
| DE19718706A1 (de) | 1998-11-05 |
| ES2196568T3 (es) | 2003-12-16 |
| JP2001526652A (ja) | 2001-12-18 |
| KR20010012172A (ko) | 2001-02-15 |
| US6222033B1 (en) | 2001-04-24 |
| EP0980355A1 (de) | 2000-02-23 |
| CN1254332A (zh) | 2000-05-24 |
| MY125884A (en) | 2006-08-30 |
| CN1113865C (zh) | 2003-07-09 |
| DE59807971D1 (de) | 2003-05-22 |
| ID24234A (id) | 2000-07-13 |
| TW430659B (en) | 2001-04-21 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B08F | Application dismissed because of non-payment of annual fees [chapter 8.6 patent gazette] |
Free format text: REFERENTE A 9A ANUIDADE |
|
| B08K | Patent lapsed as no evidence of payment of the annual fee has been furnished to inpi [chapter 8.11 patent gazette] |
Free format text: REFERENTE AO DESPACHO 8.6 PUBLICADO NA RPI 1912 DE 28/08/2007. |