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BR9807104A - Polìmero,processo para a preparação de polìmeros,nitróxidos,alcóxi amina,método para produzir o nitróxido,solução aquosa e método para produzir uma alcóxi amina - Google Patents

Polìmero,processo para a preparação de polìmeros,nitróxidos,alcóxi amina,método para produzir o nitróxido,solução aquosa e método para produzir uma alcóxi amina

Info

Publication number
BR9807104A
BR9807104A BR9807104-1A BR9807104A BR9807104A BR 9807104 A BR9807104 A BR 9807104A BR 9807104 A BR9807104 A BR 9807104A BR 9807104 A BR9807104 A BR 9807104A
Authority
BR
Brazil
Prior art keywords
producing
nitroxide
polymers
alkoxy amine
preparation
Prior art date
Application number
BR9807104-1A
Other languages
English (en)
Inventor
Albert G Anderson
Alexei Gridnev
Graeme Moad
Ezio Rizzardo
San Hoa Thang
Original Assignee
Du Pont
Commw Scient Ind Res Org
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Du Pont, Commw Scient Ind Res Org filed Critical Du Pont
Publication of BR9807104A publication Critical patent/BR9807104A/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
    • C07D233/04—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member
    • C07D233/28—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D233/30—Oxygen or sulfur atoms
    • C07D233/32—One oxygen atom
    • C07D233/38—One oxygen atom with acyl radicals or hetero atoms directly attached to ring nitrogen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D235/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, condensed with other rings
    • C07D235/02—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, condensed with other rings condensed with carbocyclic rings or ring systems
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00—Living radical polymerisation
    • C08F2438/02—Stable Free Radical Polymerisation [SFRP]; Nitroxide Mediated Polymerisation [NMP] for, e.g. using 2,2,6,6-tetramethylpiperidine-1-oxyl [TEMPO]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerization Catalysts (AREA)
  • Polymerisation Methods In General (AREA)
  • Graft Or Block Polymers (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

<B>POLìMERO, PROCESSO PARA A PREPARAçãO DE POLìMEROS, NITRóXIDOS, ALCóXI AMINA, MéTODO PARA PRODUZIR O NITRóXIDO, SOLUçãO AQUOSA E MéTODO PARA PRODUZIR UMA ALCóXI AMINA"<D> A presente invenção se refere à preparação de polímeros de baixa polidispersidade e/ou peso molecular e estrutura controlados e emprega a polimerização de radicais livres iniciada por um iniciador de alcóxi amina ou nitróxido mais, opcionalmente, um iniciador de radical livre; o polímero produzido pela mesma; iniciadores de nitróxido e alcóxi amina selecionados; e um processo para a produção dos iniciadores; sendo que os produtos poliméricos são úteis em revestimentos de proteção.
BR9807104-1A 1997-01-10 1998-01-07 Polìmero,processo para a preparação de polìmeros,nitróxidos,alcóxi amina,método para produzir o nitróxido,solução aquosa e método para produzir uma alcóxi amina BR9807104A (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US3472797P 1997-01-10 1997-01-10
PCT/US1998/000601 WO1998030601A2 (en) 1997-01-10 1998-01-07 Method of controlling polymer molecular weight and structure

Publications (1)

Publication Number Publication Date
BR9807104A true BR9807104A (pt) 2000-04-25

Family

ID=21878221

Family Applications (1)

Application Number Title Priority Date Filing Date
BR9807104-1A BR9807104A (pt) 1997-01-10 1998-01-07 Polìmero,processo para a preparação de polìmeros,nitróxidos,alcóxi amina,método para produzir o nitróxido,solução aquosa e método para produzir uma alcóxi amina

Country Status (10)

Country Link
US (3) US6271340B1 (pt)
EP (1) EP0951485B1 (pt)
JP (1) JP2001508485A (pt)
KR (1) KR100504055B1 (pt)
CN (2) CN1824655A (pt)
AU (1) AU750626B2 (pt)
BR (1) BR9807104A (pt)
CA (1) CA2277164C (pt)
DE (2) DE69829588T2 (pt)
WO (1) WO1998030601A2 (pt)

Families Citing this family (53)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
SG82601A1 (en) 1998-03-09 2001-08-21 Ciba Sc Holding Ag 1-alkoxy-polyalkyl-piperidine derivatives and their use as polymerization regulators
EP1100772B1 (en) * 1998-07-31 2004-04-14 Ciba SC Holding AG Open chain alkoxyamine compounds and their use as polymerization regulators
JP4593786B2 (ja) * 1998-09-29 2010-12-08 チバ ホールディング インコーポレーテッド Ｎ→ｏ末端基を含むポリマーの製造方法
FR2784111B1 (fr) * 1998-10-06 2003-08-01 Atochem Elf Sa Polymerisatin radicalaire en presence de plusieurs radicaux libres stables
TWI225483B (en) * 1998-10-16 2004-12-21 Ciba Sc Holding Ag Heterocyclic alkoxyamines as regulators in controlled radical polymerization process
AU3733800A (en) * 1999-03-09 2000-09-28 Symyx Technologies, Inc. Controlled free radical emulsion and water-based polymerizations and seeded methodologies
US6472486B2 (en) 1999-03-09 2002-10-29 Symyx Technologies, Inc. Controlled stable free radical emulsion polymerization processes
CA2375806A1 (en) * 1999-07-02 2001-01-11 Ciba Specialty Chemicals Holding Inc. Mono and multifunctional alkoxyamines for the preparation of functionalized macromers
ATE323113T1 (de) 1999-07-02 2006-04-15 Symyx Technologies Inc Polymerverzweigungen zur immobilisierung von molekülen auf oberflächen oder substraten, wobei die polymere wasserlösliche oder wasserdispergierbare segmente und sonden aufweisen
US6716948B1 (en) 1999-07-31 2004-04-06 Symyx Technologies, Inc. Controlled-architecture polymers and use thereof as separation media
AU6279900A (en) * 1999-08-12 2001-03-13 Ciba Specialty Chemicals Holding Inc. Polymer blends with improved impact resistance
AU7025600A (en) * 1999-09-08 2001-04-10 School Of Pharmacy, University Of London, The Uniform molecular weight polymers
AU7843300A (en) * 1999-09-30 2001-04-30 Noveon Ip Holdings Corp. Polymerization compositions and methods
TW541303B (en) 2000-03-22 2003-07-11 Ciba Sc Holding Ag 2,2,6,6 diethyl-dimethyl-1-alkoxy-piperidine compounds and their corresponding 1-oxides
DE10036801A1 (de) 2000-07-28 2002-02-07 Tesa Ag Acrylathaftklebemassen mit enger Molekulargewichtsverteilung
TWI225492B (en) 2000-09-25 2004-12-21 Ciba Sc Holding Ag Composition and process for enhancing controlled free radical polymerization
WO2002056021A2 (en) 2001-01-10 2002-07-18 Symyx Technologies Inc Polymer brushes for immobilizing molecules to a surface
US6547840B2 (en) 2001-04-02 2003-04-15 Ciba Specialty Chemicals Corporation Candle wax stabilized with imidazolidines
US6849679B2 (en) 2001-05-21 2005-02-01 Ciba Specialty Chemicals Corporation Pigment compositions with modified block copolymer dispersants
US20030073835A1 (en) 2001-07-31 2003-04-17 Dario Lazzari Imidazolidinone derivatives
EP1283240A1 (en) * 2001-07-31 2003-02-12 Ciba SC Holding AG Imidazolidinone derivatives
DE10149083A1 (de) 2001-10-05 2003-04-17 Tesa Ag Acrylathaftklebemassen mit enger Molekulargewichtsverteilung
DE10149084A1 (de) 2001-10-05 2003-06-18 Tesa Ag UV-vernetzbare Acrylathaftschmelzhaftkleber mit enger Molekulargewichtsverteilung
US6762263B2 (en) * 2002-02-01 2004-07-13 Atofina Chemicals, Inc. High-solids coatings resins via controlled radical polymerization
US6841636B2 (en) 2002-08-19 2005-01-11 National Starch And Chemical Investment Holding Corporation Dispersions containing living radicals
US7375175B2 (en) * 2002-08-19 2008-05-20 National Starch And Chemical Investment Holding Corporation Dispersions containing living radicals
FR2852963A1 (fr) * 2003-03-26 2004-10-01 Atofina Nouveau procede de synthese/fabrication de films acryliques
FR2852961B1 (fr) * 2003-03-26 2006-07-07 Atofina Nouveau procede de synthese/fabrication de films acryliques
DE10322830A1 (de) 2003-05-19 2004-12-09 Tesa Ag Verfahren zur kontinuierlichen Herstellung von Polymeren aus vinylischen Verbindungen durch Substanz-beziehungsweise Lösungsmittelpolymerisation
JP4046678B2 (ja) * 2003-10-15 2008-02-13 横浜ゴム株式会社 タイヤトレッド用ゴム組成物及びそれを用いた空気入りタイヤ
US7741510B2 (en) * 2005-01-13 2010-06-22 E. I. Du Pont De Nemours And Company Rheology control agents
US7652121B2 (en) * 2005-01-13 2010-01-26 E.I. Du Pont De Nemours And Company Rheology control agents for coating compositions
US20060155021A1 (en) * 2005-01-13 2006-07-13 Lenges Christian P Coating compositions containing rheology control agents
US7632882B2 (en) * 2005-01-13 2009-12-15 E.I. Du Pont De Nemours And Company Rheology control agents for coating compositions
JP4046734B2 (ja) 2005-01-18 2008-02-13 横浜ゴム株式会社 ポリマーの変性方法
US20060173142A1 (en) * 2005-02-01 2006-08-03 Hildeberto Nava Functionalized thermosetting resin systems
US7009011B1 (en) * 2005-05-31 2006-03-07 Xerox Corporation Copolymers of maleic anhydride by stable free redical polymerization
US20070028806A1 (en) * 2005-08-03 2007-02-08 Piro Bonnie D Coating compositions having improved appearance containing coated titanium dioxide pigments
JP5068765B2 (ja) * 2005-12-14 2012-11-07 ノバルティス アーゲー シリコーンヒドロゲルの製造方法
US20080021147A1 (en) * 2006-06-14 2008-01-24 Jun Lin Process for forming a dispersion of silica nano-particles
JP2009539603A (ja) * 2006-06-14 2009-11-19 イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー 向上した耐引掻き性及び耐摩耗性を有する塗装基材
US9051473B2 (en) * 2006-06-14 2015-06-09 Axalta Coating Systems Ip Co., Llc Clear coating compositions comprising dispersed silica nono-particles and processes for using
WO2008031733A2 (en) * 2006-09-12 2008-03-20 Ciba Holding Inc. Imidazolidinone nitroxides as electrode materials for energy storage devices
KR101574815B1 (ko) 2007-12-18 2015-12-04 바스프 에스이 바이오디젤 저온 흐름 개선제
EP2588520B1 (en) 2010-06-29 2014-06-25 Basf Se Process for improving the flow properties of polymer melts and use of comb or comb block copolymer
TWI413648B (zh) * 2010-12-31 2013-11-01 Chi Mei Corp 共軛二烯－乙烯基芳香烴共聚物及其製備方法
WO2013060708A1 (en) 2011-10-25 2013-05-02 Basf Se Use of comb or block copolymers as soil antiredeposition agents and soil release agents in laundry processes
EP2978786A1 (en) 2013-03-27 2016-02-03 Basf Se Block copolymers as soil release agents in laundry processes
FR3030525B1 (fr) * 2014-12-18 2018-05-11 Arkema France Polymerisation radicalaire d'alcoxyamines a basse temperature
CN104788594B (zh) * 2015-04-16 2018-07-24 厦门大学 一种端氨基聚合物的制备方法
EP3875566B1 (de) 2020-03-06 2023-01-11 Henkel AG & Co. KGaA Nitroxidverbindungen in wasch- oder reinigungsmitteln
US11886045B2 (en) 2020-11-04 2024-01-30 Alcon Inc. Method for making photochromic contact lenses
US12539650B2 (en) 2022-04-26 2026-02-03 Alcon Inc. Method for making embedded hydrogel contact lenses

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1528233A (fr) * 1966-06-15 1968-06-07 Sankyo Co Nouveaux composés 4-oxoimidazolidine-1-oxydes tétrasubstitués en position-2, 2, 5, 5 et procédé pour leur préparation
CH579117A5 (pt) * 1973-06-22 1976-08-31 Ciba Geigy Ag
DE2621947A1 (de) * 1975-05-23 1976-12-09 Ciba Geigy Ag Neue hydroxide von 3-alkyl-4-oxo- imidazolidinen
KR930000892B1 (ko) 1983-07-11 1993-02-11 커몬웰스 사이언티픽 앤드 인더스트리얼 리셔치 오가니제이숀 신규의 개시제를 사용하여 중합체 또는 공중합체를 제조하는방법

Also Published As

Publication number Publication date
CN1824655A (zh) 2006-08-30
AU6022998A (en) 1998-08-03
DE69812885T2 (de) 2004-01-29
CA2277164C (en) 2005-11-08
US20020061989A1 (en) 2002-05-23
KR20000070015A (ko) 2000-11-25
JP2001508485A (ja) 2001-06-26
KR100504055B1 (ko) 2005-07-27
US6271340B1 (en) 2001-08-07
DE69829588D1 (de) 2005-05-04
EP0951485A2 (en) 1999-10-27
US20030149208A1 (en) 2003-08-07
WO1998030601A2 (en) 1998-07-16
EP0951485B1 (en) 2003-04-02
AU750626B2 (en) 2002-07-25
DE69812885D1 (de) 2003-05-08
CN1280314C (zh) 2006-10-18
DE69829588T2 (de) 2006-01-19
CA2277164A1 (en) 1998-07-16
WO1998030601A3 (en) 1998-12-03
CN1249759A (zh) 2000-04-05

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