BR9803790A - Utilização de óxido nítrico para reduzir obstrução no reator durante copolimerização de enxerto de polipropileno - Google Patents
Utilização de óxido nítrico para reduzir obstrução no reator durante copolimerização de enxerto de polipropilenoInfo
- Publication number
- BR9803790A BR9803790A BR9803790-0A BR9803790A BR9803790A BR 9803790 A BR9803790 A BR 9803790A BR 9803790 A BR9803790 A BR 9803790A BR 9803790 A BR9803790 A BR 9803790A
- Authority
- BR
- Brazil
- Prior art keywords
- graft
- nitric oxide
- polymer material
- propylene polymer
- reactor during
- Prior art date
Links
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 title abstract 8
- 229920001155 polypropylene Polymers 0.000 title abstract 6
- 239000004743 Polypropylene Substances 0.000 title abstract 2
- 238000007334 copolymerization reaction Methods 0.000 title abstract 2
- -1 polypropylene Polymers 0.000 title abstract 2
- 239000002861 polymer material Substances 0.000 abstract 4
- 239000000178 monomer Substances 0.000 abstract 3
- 150000003254 radicals Chemical class 0.000 abstract 2
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- 229920000578 graft copolymer Polymers 0.000 abstract 1
- 239000003999 initiator Substances 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 239000007870 radical polymerization initiator Substances 0.000 abstract 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract 1
- 229920002554 vinyl polymer Polymers 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F255/00—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00
- C08F255/02—Macromolecular compounds obtained by polymerising monomers on to polymers of hydrocarbons as defined in group C08F10/00 on to polymers of olefins having two or three carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/08—Styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Abstract
Patente de Invenção: <B>"UTILIZAçãO DE óXIDO NìTRICO PARA REDUZIR OBSTRUçãO NO REATOR DURANTE COPOLIMERIZAçãO DE ENXERTO DE POLIPROPILENO"<D>. é produzido um copolímero de enxerto compreendendo uma estrutura de um material de polímero de propileno tendo um enxerto de monómero de vinila polimerizado nele, mediante (1) tratamento de um material polimérico de propileno com um iniciador de polimerização de radical livre, (2) tratamento do material polimérico de propileno com pelo menos um monómero de enxerto capaz de ser polimerizado por radicais livres, e (3) remoção de qualquer monómero de enxerto não-reagido do material polimérico de propileno copolimerizado de enxerto, decompondo qualquer iniciador não-reagido, e desativando quaisquer radicais livres residuais no material, em que as etapas (1) e (2) são realizadas na presença de uma introdução contínua de óxido nítrico. O óxido nítrico reduz a formação de depósitos de polímero nas paredes do reator, e circuitos de circulação do gás, ao mesmo tempo que não possui nenhum efeito na reação de copolimerização de enxerto.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/939,237 US5863994A (en) | 1997-09-29 | 1997-09-29 | Using nitric oxide to reduce reactor fouling during polypropylene graft copolymerization |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BR9803790A true BR9803790A (pt) | 1999-12-14 |
Family
ID=25472794
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR9803790-0A BR9803790A (pt) | 1997-09-29 | 1998-09-28 | Utilização de óxido nítrico para reduzir obstrução no reator durante copolimerização de enxerto de polipropileno |
Country Status (17)
| Country | Link |
|---|---|
| US (1) | US5863994A (pt) |
| EP (1) | EP0905155B1 (pt) |
| JP (1) | JPH11158234A (pt) |
| KR (1) | KR100538894B1 (pt) |
| CN (1) | CN1107086C (pt) |
| AR (1) | AR017165A1 (pt) |
| AT (1) | ATE233283T1 (pt) |
| AU (1) | AU735625B2 (pt) |
| BR (1) | BR9803790A (pt) |
| CA (1) | CA2248405C (pt) |
| DE (1) | DE69811586T2 (pt) |
| DK (1) | DK0905155T3 (pt) |
| ES (1) | ES2193457T3 (pt) |
| MY (1) | MY133544A (pt) |
| RU (1) | RU2216550C2 (pt) |
| TW (1) | TW479065B (pt) |
| ZA (1) | ZA988584B (pt) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SI9720025A (sl) * | 1996-03-29 | 1999-08-31 | Emishphere Technologies, Inc. | Spojine in sestavki za prenos aktivne snovi |
| US6359019B1 (en) * | 1997-11-12 | 2002-03-19 | Ballard Power Systems Inc. | Graft polymeric membranes and ion-exchange membranes formed therefrom |
| US6723758B2 (en) | 1997-11-12 | 2004-04-20 | Ballard Power Systems Inc. | Graft polymeric membranes and ion-exchange membranes formed therefrom |
| US6506847B1 (en) | 2001-08-08 | 2003-01-14 | Basell Poliolefine Italia S.P.A. | Controlling the molecular weight of graft copolymers using polymerizable chain transfer agents |
| US20040016693A1 (en) * | 2001-08-27 | 2004-01-29 | Ballard Power Systems Inc. | Process for preparing graft copolymer membranes |
| US7937145B2 (en) * | 2002-03-22 | 2011-05-03 | Advanced Neuromodulation Systems, Inc. | Dynamic nerve stimulation employing frequency modulation |
| US7236822B2 (en) * | 2002-03-22 | 2007-06-26 | Leptos Biomedical, Inc. | Wireless electric modulation of sympathetic nervous system |
| US7239912B2 (en) * | 2002-03-22 | 2007-07-03 | Leptos Biomedical, Inc. | Electric modulation of sympathetic nervous system |
| US7702386B2 (en) * | 2002-03-22 | 2010-04-20 | Leptos Biomedical, Inc. | Nerve stimulation for treatment of obesity, metabolic syndrome, and Type 2 diabetes |
| US7689276B2 (en) * | 2002-09-13 | 2010-03-30 | Leptos Biomedical, Inc. | Dynamic nerve stimulation for treatment of disorders |
| US7689277B2 (en) * | 2002-03-22 | 2010-03-30 | Leptos Biomedical, Inc. | Neural stimulation for treatment of metabolic syndrome and type 2 diabetes |
| US7551964B2 (en) * | 2002-03-22 | 2009-06-23 | Leptos Biomedical, Inc. | Splanchnic nerve stimulation for treatment of obesity |
| KR101113341B1 (ko) * | 2002-10-15 | 2012-09-27 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 올레핀 중합용 다중 촉매 시스템 및 이로부터 제조된중합체 |
| US7700707B2 (en) | 2002-10-15 | 2010-04-20 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions and articles made therefrom |
| US7550528B2 (en) | 2002-10-15 | 2009-06-23 | Exxonmobil Chemical Patents Inc. | Functionalized olefin polymers |
| US7541402B2 (en) | 2002-10-15 | 2009-06-02 | Exxonmobil Chemical Patents Inc. | Blend functionalized polyolefin adhesive |
| US7623924B2 (en) * | 2004-08-31 | 2009-11-24 | Leptos Biomedical, Inc. | Devices and methods for gynecologic hormone modulation in mammals |
| US20070269601A1 (en) * | 2006-05-18 | 2007-11-22 | Air Products And Chemicals, Inc. | Surface Fluorination of Plastics Materials |
| US8295926B2 (en) | 2006-06-02 | 2012-10-23 | Advanced Neuromodulation Systems, Inc. | Dynamic nerve stimulation in combination with other eating disorder treatment modalities |
| US20090118777A1 (en) * | 2007-08-09 | 2009-05-07 | Kobi Iki | Efferent and afferent splanchnic nerve stimulation |
| CN108349848A (zh) | 2015-11-12 | 2018-07-31 | 沙特基础全球技术有限公司 | 使用一氧化氮抑制丁二烯加工过程中米花状聚合的方法 |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3964979A (en) * | 1974-12-09 | 1976-06-22 | Cosden Technology, Inc. | NO polymerization inhibitor for vinyl aromatic compound distillation |
| JPS5221091A (en) * | 1975-08-11 | 1977-02-17 | Mitsubishi Monsanto Chem Co | Process for suspension polymerizing vinyl chloride or a vinyl monomer mixture consisting mainly of the vinyl chloride |
| US4070419A (en) * | 1975-12-01 | 1978-01-24 | Cosden Technology, Inc. | Polymerization of styrene |
| JPS5655433A (en) * | 1979-10-09 | 1981-05-16 | Mitsubishi Petrochem Co Ltd | Stretched film |
| US4341600A (en) * | 1981-04-06 | 1982-07-27 | Cosden Technology, Inc. | Polymerization inhibitor for vinyltoluene |
| US4754058A (en) * | 1987-06-02 | 1988-06-28 | Hoechst Celanese Corporation | Inhibition of polymerization fouling during distillation of monomers in the presence of sulfur oxides |
| US4803251A (en) * | 1987-11-04 | 1989-02-07 | Union Carbide Corporation | Method for reducing sheeting during polymerization of alpha-olefins |
| ZA909902B (en) * | 1989-12-21 | 1991-10-30 | Himont Inc | Graft copolymers of polyolefins and a method of producing same |
| CA2031406C (en) * | 1989-12-21 | 2002-05-28 | Paolo Galli | Graft copolymers of polyolefins and a method of producing same |
| US5140074A (en) * | 1990-01-26 | 1992-08-18 | Himont Incorporated | Method of producing olefin polymer graft copolymers |
| KR960002301B1 (ko) * | 1992-06-03 | 1996-02-16 | 주식회사엘지화학 | Hcfc내성이 우수한 열가소성수지 조성물의 제조방법 |
| US5399644A (en) * | 1992-07-28 | 1995-03-21 | General Electric Company | Sulfur dioxide for vapor phase elimination of styrene and acrylonitrile popcorn polymer in bulk san production |
| US5272231A (en) * | 1992-07-28 | 1993-12-21 | General Electric Company | Nitric oxide for vapor phase elimination of styrene and acrylonitrile popcorn polymer in bulk SAN production |
| US5589541A (en) * | 1994-03-28 | 1996-12-31 | Dainippon Ink And Chemicals Inc. | Process for producing modified propylene polymer and modified propylene polymer composition |
| JP3417695B2 (ja) * | 1994-12-14 | 2003-06-16 | 東北リコー株式会社 | 印刷装置 |
-
1997
- 1997-09-29 US US08/939,237 patent/US5863994A/en not_active Expired - Fee Related
-
1998
- 1998-09-18 ZA ZA988584A patent/ZA988584B/xx unknown
- 1998-09-21 TW TW087115683A patent/TW479065B/zh not_active IP Right Cessation
- 1998-09-21 MY MYPI98004327A patent/MY133544A/en unknown
- 1998-09-22 CA CA002248405A patent/CA2248405C/en not_active Expired - Fee Related
- 1998-09-26 AT AT98118277T patent/ATE233283T1/de not_active IP Right Cessation
- 1998-09-26 ES ES98118277T patent/ES2193457T3/es not_active Expired - Lifetime
- 1998-09-26 EP EP98118277A patent/EP0905155B1/en not_active Expired - Lifetime
- 1998-09-26 DE DE69811586T patent/DE69811586T2/de not_active Expired - Fee Related
- 1998-09-26 DK DK98118277T patent/DK0905155T3/da active
- 1998-09-28 AU AU87103/98A patent/AU735625B2/en not_active Ceased
- 1998-09-28 RU RU98117917/04A patent/RU2216550C2/ru not_active IP Right Cessation
- 1998-09-28 BR BR9803790-0A patent/BR9803790A/pt active Search and Examination
- 1998-09-29 JP JP10274729A patent/JPH11158234A/ja active Pending
- 1998-09-29 KR KR1019980040442A patent/KR100538894B1/ko not_active Expired - Fee Related
- 1998-09-29 AR ARP980104843A patent/AR017165A1/es active IP Right Grant
- 1998-09-29 CN CN98120895A patent/CN1107086C/zh not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CA2248405C (en) | 2003-03-11 |
| CN1212969A (zh) | 1999-04-07 |
| EP0905155A1 (en) | 1999-03-31 |
| US5863994A (en) | 1999-01-26 |
| DE69811586D1 (de) | 2003-04-03 |
| DK0905155T3 (da) | 2003-06-10 |
| KR100538894B1 (ko) | 2006-03-22 |
| ZA988584B (en) | 1999-03-31 |
| DE69811586T2 (de) | 2003-11-20 |
| AU8710398A (en) | 1999-04-15 |
| AR017165A1 (es) | 2001-08-22 |
| CA2248405A1 (en) | 1999-03-29 |
| JPH11158234A (ja) | 1999-06-15 |
| AU735625B2 (en) | 2001-07-12 |
| RU2216550C2 (ru) | 2003-11-20 |
| KR19990030222A (ko) | 1999-04-26 |
| EP0905155B1 (en) | 2003-02-26 |
| CN1107086C (zh) | 2003-04-30 |
| ES2193457T3 (es) | 2003-11-01 |
| ATE233283T1 (de) | 2003-03-15 |
| MY133544A (en) | 2007-11-30 |
| TW479065B (en) | 2002-03-11 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| B06A | Patent application procedure suspended [chapter 6.1 patent gazette] | ||
| B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
| B11D | Dismissal acc. art. 38, par 2 of ipl - failure to pay fee after grant in time |