BR9712754A - Leather treatment process, amphiphilic copolymer, use and process of obtaining it, leather, and aqueous composition. - Google Patents
Leather treatment process, amphiphilic copolymer, use and process of obtaining it, leather, and aqueous composition.Info
- Publication number
- BR9712754A BR9712754A BR9712754-0A BR9712754A BR9712754A BR 9712754 A BR9712754 A BR 9712754A BR 9712754 A BR9712754 A BR 9712754A BR 9712754 A BR9712754 A BR 9712754A
- Authority
- BR
- Brazil
- Prior art keywords
- leather
- amphiphilic copolymer
- obtaining
- aqueous composition
- group
- Prior art date
Links
- 239000010985 leather Substances 0.000 title abstract 5
- 238000000034 method Methods 0.000 title abstract 5
- 229920001577 copolymer Polymers 0.000 title abstract 4
- 125000000217 alkyl group Chemical group 0.000 abstract 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 125000004429 atom Chemical group 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 125000002843 carboxylic acid group Chemical group 0.000 abstract 1
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 150000003839 salts Chemical class 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 125000001424 substituent group Chemical group 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C14—SKINS; HIDES; PELTS; LEATHER
- C14C—CHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
- C14C9/00—Impregnating leather for preserving, waterproofing, making resistant to heat or similar purposes
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Treatment And Processing Of Natural Fur Or Leather (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
"PROCESSO DE TRATAMENTO DE COURO, COPOLìMERO ANFIFìLICIO, USO E PROCESSO DE OBTENçãO DO MESMO, COURO, E, COMPOSIçãO AQUOSA". A presente invenção fornecer um copolímero anfifílico que compreende as unidades de repetição (I) e (II) em que: R~ f~ representa um grupo alquila fluorado que tem pelo menos 3 átomos de carbonol Q e Q' cada um independentemente representa um grupo orgânico de ligação ou outra ligaçãp química; R^ 1^ e R^ 2^ cada um independentemente representa hidrogênio ou um grupo C~ 1~ a C~ 4~ alquila; e R~ h~ representa um grupo hidrocarboneto que tem pelo menos 8 átomos de carbono e opcionalmente contendo 1 a 3 substituintes; e uma unidade de repetição que compreende pelo menos um grupo ácido carboxílico ou sal do mesmo. A presente invenção também fornece um processo para a obtenção do copolímero anfifílico acima. O copolímero anfifílico pode ser usado em um tratamento de couro para conferir impermeabilidade ao couro."LEATHER TREATMENT PROCESS, AMPHIFYLIC COPOLIMER, USE AND PROCESS OF OBTAINING THE SAME, LEATHER, AND, WATER COMPOSITION". The present invention provides an amphiphilic copolymer comprising repeating units (I) and (II) wherein: R ~ f ~ represents a fluorinated alkyl group having at least 3 carbonol atoms Q and Q 'each independently represents a group organic bonding or other chemical bonding; R ^ 1 ^ and R ^ 2 ^ each independently represents hydrogen or a C ~ 1 ~ to C ~ 4 ~ alkyl group; and R ~ h ~ represents a hydrocarbon group having at least 8 carbon atoms and optionally containing 1 to 3 substituents; and a repeating unit comprising at least one carboxylic acid group or salt thereof. The present invention also provides a process for obtaining the above amphiphilic copolymer. The amphiphilic copolymer can be used in a leather treatment to confer impermeability to the leather.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP96117814A EP0841405B1 (en) | 1996-11-07 | 1996-11-07 | Use of amphilic copolymers containing a fluorinated monomer to impart waterproofness to leather |
| PCT/US1997/018386 WO1998020170A1 (en) | 1996-11-07 | 1997-10-15 | Use of amphiphilic copolymers containing a fluorinated monomer to impart waterproofness to leather |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| BR9712754A true BR9712754A (en) | 1999-10-19 |
Family
ID=8223375
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BR9712754-0A BR9712754A (en) | 1996-11-07 | 1997-10-15 | Leather treatment process, amphiphilic copolymer, use and process of obtaining it, leather, and aqueous composition. |
Country Status (11)
| Country | Link |
|---|---|
| EP (1) | EP0841405B1 (en) |
| JP (1) | JP3911549B2 (en) |
| KR (1) | KR100475495B1 (en) |
| CN (1) | CN1152142C (en) |
| AR (1) | AR009410A1 (en) |
| AU (1) | AU4899897A (en) |
| BR (1) | BR9712754A (en) |
| DE (1) | DE69605925T2 (en) |
| ES (1) | ES2143125T3 (en) |
| TW (1) | TW419524B (en) |
| WO (1) | WO1998020170A1 (en) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7049379B2 (en) | 1999-05-11 | 2006-05-23 | 3M Innovative Properties Company | Alkylated fluorochemical oligomers and use thereof in the treatment of fibrous substrates |
| US6525127B1 (en) | 1999-05-11 | 2003-02-25 | 3M Innovative Properties Company | Alkylated fluorochemical oligomers and use thereof in the treatment of fibrous substrates |
| BR0307265B1 (en) * | 2002-01-31 | 2012-11-27 | substantially solvent-free composition, concentrated emulsion, and process for treating and imparting water repellency to fibrous materials, leather, leather and textiles. | |
| KR20030073514A (en) * | 2002-03-12 | 2003-09-19 | 강석일 | eel skin with waterproof film and manufacturing method |
| EP1801133A1 (en) | 2005-12-19 | 2007-06-27 | Lanxess Deutschland GmbH | Curable fluorinated copolymers and coatings and processes thereof |
| EP1820809A1 (en) | 2006-02-17 | 2007-08-22 | Lanxess Deutschland GmbH | Coating of substrates with curable fluorinated copolymers |
| DE102006027400A1 (en) * | 2006-06-13 | 2007-12-20 | Wacker Chemie Ag | Process for treating proteinaceous fibrous matter with beta-ketocarbonyl-functional siloxane polymers |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2803615A (en) | 1956-01-23 | 1957-08-20 | Minnesota Mining & Mfg | Fluorocarbon acrylate and methacrylate esters and polymers |
| US3923715A (en) | 1973-07-26 | 1975-12-02 | Du Pont | Aqueous dispersions of perfluoroalkyl esters and vinyl polymers for treating textiles |
| US4525305A (en) | 1982-10-25 | 1985-06-25 | Minnesota Mining And Manufacturing Company | Leather with fluorochemical finish |
| US4539006A (en) | 1983-09-13 | 1985-09-03 | Minnesota Mining And Manufacturing Company | Leather treatment |
| EP0213580B1 (en) | 1985-08-30 | 1990-07-18 | Hoechst Aktiengesellschaft | Urethane containing perfluoroalkyl and epichlorhydrine groups, their aqueous dispersion and their use |
| FR2588555B1 (en) | 1985-10-16 | 1987-12-11 | Atochem | FLUORINATED ACRYLIC MONOMERS, DERIVATIVE POLYMERS THEREOF, AND THEIR APPLICATION TO WATER-REPELLENT AND WATER-REPELLENT TREATMENT OF VARIOUS SUBSTRATES |
| FR2590895B1 (en) | 1985-12-03 | 1988-01-15 | Atochem | FLUORINATED ACRYLIC MONOMERS, DERIVATIVE POLYMERS AND THEIR APPLICATION AS HYDROPHOBIC AND OLEOPHOBIC AGENTS |
| DE3622284A1 (en) | 1986-07-03 | 1988-01-07 | Hoechst Ag | URETHANES MADE FROM ALIPHATIC FLUORAL ALCOHOLS, ISOCYANATES AND AROMATIC COMPOUNDS, METHOD FOR THE PRODUCTION THEREOF AND THEIR USE |
| DE3722375A1 (en) | 1987-07-07 | 1989-01-19 | Hoechst Ag | URETHANES CONTAINING FLUOR AND POLYSILOXANE, METHOD FOR THE PRODUCTION THEREOF AND THEIR USE |
| DE3800629A1 (en) | 1988-01-12 | 1989-07-20 | Basf Ag | METHOD FOR HYDROPHOBIZING LEATHER, FURS AND LEATHER REPLACEMENT MATERIALS |
| DE3800845A1 (en) * | 1988-01-14 | 1989-07-27 | Bayer Ag | Graft copolymers, a process for their production and use |
| TNSN89128A1 (en) | 1988-12-02 | 1991-02-04 | Rohn And Haas Company Independance Mall West | LEATHER TREATMENT WITH SELECTED AMPHIPHITE COPOLYMERS |
| DE3931039A1 (en) | 1989-09-16 | 1991-03-28 | Basf Ag | USE OF COPOLYMERISATS BASED ON LONG-CHAIN UNSATURATED ESTERS AND ETHYLENICALLY UNSATURATED CARBONIC ACIDS FOR THE HYDROPHOBICATION OF LEATHER AND FUR SKINS |
| FR2653772B1 (en) * | 1989-11-02 | 1992-01-17 | Atochem | FLUORINATED ACRYLIC TELOMERS AND THEIR APPLICATION TO WATER-REPELLENT AND WATER-REPELLENT TREATMENT OF VARIOUS SUBSTRATES. |
| CA2071596A1 (en) | 1991-07-10 | 1993-01-11 | Frederick E. Behr | Perfluoroalkyl halides and derivatives |
| BR9206741A (en) | 1991-11-12 | 1995-10-31 | Minnesota Mining & Mfg | Fluorochemical composition Article and process for preparing the fluorochemical composition |
| DE4223111A1 (en) | 1992-07-14 | 1994-01-20 | Henkel Kgaa | New leather greasing agents and their use |
| DE4244951C2 (en) | 1992-12-01 | 1998-08-06 | Minnesota Mining & Mfg | New poly:siloxane cpd(s) and carboxylic acid derivs., prepn. and use |
| DE4240274B4 (en) * | 1992-12-01 | 2004-02-12 | Minnesota Mining And Manufacturing Co., Saint Paul | Polysiloxanes with fluoroaliphate and carboxyl-containing terminal groups, their preparation and their use in the treatment of fiber substrates |
| DE4416415A1 (en) | 1994-05-10 | 1995-11-16 | Hoechst Ag | Copolymers based on ethylenically unsaturated dicarboxylic acid anhydrides, long-chain olefins and fluoroolefins |
-
1996
- 1996-11-07 ES ES96117814T patent/ES2143125T3/en not_active Expired - Lifetime
- 1996-11-07 DE DE69605925T patent/DE69605925T2/en not_active Expired - Lifetime
- 1996-11-07 EP EP96117814A patent/EP0841405B1/en not_active Expired - Lifetime
-
1997
- 1997-10-15 AU AU48998/97A patent/AU4899897A/en not_active Abandoned
- 1997-10-15 JP JP52140298A patent/JP3911549B2/en not_active Expired - Fee Related
- 1997-10-15 KR KR10-1999-7004022A patent/KR100475495B1/en not_active Expired - Fee Related
- 1997-10-15 BR BR9712754-0A patent/BR9712754A/en not_active IP Right Cessation
- 1997-10-15 WO PCT/US1997/018386 patent/WO1998020170A1/en not_active Ceased
- 1997-10-15 CN CNB971995338A patent/CN1152142C/en not_active Expired - Fee Related
- 1997-11-05 TW TW086116460A patent/TW419524B/en not_active IP Right Cessation
- 1997-11-06 AR ARP970105170A patent/AR009410A1/en active IP Right Grant
Also Published As
| Publication number | Publication date |
|---|---|
| CN1152142C (en) | 2004-06-02 |
| DE69605925D1 (en) | 2000-02-03 |
| ES2143125T3 (en) | 2000-05-01 |
| AR009410A1 (en) | 2000-04-12 |
| AU4899897A (en) | 1998-05-29 |
| WO1998020170A1 (en) | 1998-05-14 |
| EP0841405A1 (en) | 1998-05-13 |
| TW419524B (en) | 2001-01-21 |
| JP3911549B2 (en) | 2007-05-09 |
| CN1236397A (en) | 1999-11-24 |
| DE69605925T2 (en) | 2000-07-20 |
| JP2001504874A (en) | 2001-04-10 |
| EP0841405B1 (en) | 1999-12-29 |
| KR100475495B1 (en) | 2005-03-10 |
| KR20000053098A (en) | 2000-08-25 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FB36 | Technical and formal requirements: requirement - article 36 of industrial property law | ||
| B06A | Notification to applicant to reply to the report for non-patentability or inadequacy of the application [chapter 6.1 patent gazette] | ||
| B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
| B16A | Patent or certificate of addition of invention granted | ||
| B21F | Lapse acc. art. 78, item iv - on non-payment of the annual fees in time |
Free format text: REFERENTE A 17A ANUIDADE. |
|
| B24J | Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12) |
Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2275 DE 12-08-2014 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013. |